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西藏羌塘盆地中生代发育广泛的海相碳酸盐地层,前人对该区地层的对比研究多局限于古生物地层学,本文尝试通过锶同位素地层学方法对上侏罗-下白垩统索瓦组地层进行全球对比。根据锶同位素地层学的基本原理,本文在对样品进行显微组构分析、阴极发光分析、Ca、Si、Sr和Mn等元素含量分析及评估其对同期海水代表性和样品溶解过程合理性的基础上,测试了羌塘盆地半岛湖地区上侏罗-下白垩统锶同位素组成,并建立了相应的演化曲线,进行了全球对比研究。结果表明,样品的锶同位素组成与前人已公布的同期海水锶同位素组成数据较为接近,其演化曲线与国际上已公布的锶同位素演化曲线有着较好的可对比性,晚侏罗-早白垩世时期全球海平面的变化和侵蚀作用的强弱是控制锶同位素演化曲线的主要因素。此外,通过对索瓦组海相碳酸盐锶同位素的研究,我们认为索瓦组的顶部可能延伸到早白垩世欧特里夫期,近而说明了羌塘盆地在早白垩世欧特里夫期还存在大规模的海相地层。 相似文献
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上扬子石炭-二叠纪海相碳酸盐的锶同位素演化与全球海平面变化 总被引：29，自引：1，他引：29
地质历史中海水的锶同位素组成是时间的函数,全球海平面变化是其最主要的控制因素,上扬子地区石炭-二叠纪海相碳酸盐的锶同位素演化曲线与海平面变化曲线有着很好的一致性。锶同位素演化曲线说明:1)早石炭世是一个海水逐渐加深的全球海平面上升时期,锶同位素最小值所显示的最大海泛面的年龄为 34 2Ma,位于杜内阶和韦宪阶的界线上 ;2 )晚石炭世是一个全球海平面下降时期 ;3)整个二叠纪都是全球海平面上升时期,晚二叠世的海平面上升不仅幅度大,而且海水在短时间内迅速加深 ;4)晚二叠世具有古生代海相碳酸盐的锶同位素最小值,显示晚二叠世末的全球淹没事件,最大海泛面的年龄为 2 5 0Ma,正好在二叠 /三叠纪界线附近 ;5 )二叠 /三叠纪之交的全球生物绝灭事件可能与二叠世末的全球淹没事件有关。 相似文献
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地质历史中海水的锶同位素组成是时间的函数，全球海平面变化是其最主要的控制因素，上扬子地区石炭—二叠纪海相碳酸盐的锶同位素演化曲线与海平面变化曲线有着很好的一致性。锶同位素演化曲线说明:1）早石炭世是一个海水逐渐加深的全球海平面上升时期，锶同位素最小值所显示的最大海泛面的年龄为342 Ma，位于杜内阶和韦宪阶的界线上；2）晚石炭世是一个全球海平面下降时期；3）整个二叠纪都是全球海平面上升时期，晚二叠世的海平面上升不仅幅度大，而且海水在短时间内迅速加深；4）晚二叠世具有古生代海相碳酸盐的锶同位素最小值，显示晚二叠世末的全球淹没事件，最大海泛面的年龄为250 Ma，正好在二叠/ 三叠纪界线附近；5）二叠/ 三叠纪之交的全球生物绝灭事件可能与二叠世末的全球淹没事件有关。 相似文献
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本文简要介绍了锶同位素地层学的基本原理，根据贵州惠水地区石炭系剖面中的19个锶同位素测试数据建立了此锶面的锯同位素演化曲线并与R．E．Denison的北美同时代铅同位素曲线进行了对比。两条锶同位素演化曲线的极大相似性，证实了地质历史上古海洋中的铅同位素组成具有全球一致的演化规律，是进行全球年代地层对比的可靠工具。根据对比，笔者讨论了石炭纪的全球性海平面变化和惠水石炭系剖面的年代地层划分对比，认为下石炭统与上石炭统的界线大致位于摆佐组的近底部，证实了石炭一二叠系的界线位于马平组内部。 相似文献
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四川江油石炭纪锶同位素曲线—年代地层对比和海平面变化 总被引：4，自引：0，他引：4
据从采自四川江油马角坝石炭系剖面中的未蚀变海相岩石样品中获得的22个锶同位素测试数据，建立了剖面的石炭纪锶同位素演化曲线。马角坝剖面的锶同位素曲线与我们在贵州惠水、Denison等在北美建立的同时代锶同位素曲线总体上是一致的，表明了锶同位素曲线对海相地层进行年代地层划分对比的重要性，根据对比结果，讨论了马角坝石炭系剖面的年代地层划分和海平面变化。 相似文献
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中新生代海水锶同位素演化和古海洋事件 总被引：21，自引：1，他引：20
中新生代是地质历史中海水锶同位素组成变化最大的时期。晚白垩世以来海水N(87 Sr)/N(86Sr)值的持续上升与全球海平面的持续下降有关。喜马拉雅造山运动造成了40 Ma以来N(87 Sr)/N(86 Sr)值上升速度的显著加快;侏罗纪—早白垩世海水锶同位素的变化在很大程度上受泛大陆的解体控制,该地质事件使侏罗纪—早白垩世海水锶同位素总体上呈降低趋势;二叠/三叠纪界线的生物绝灭事件及界线后三叠纪初期的生态萧条控制了晚二叠世—早三叠世海水的锶同位素组成,早三叠世在全球海平面上升的背景下反而出现了锶同位素比值的急剧上升,单位时间的上升幅度居显生宙之首。与二叠/三叠纪界线生物绝灭有关的全球大陆植被的缺乏和风化速率加快是其主要控制因素;发生于中生代的海相红层事件记录了海水锶同位素比值的上升,显示风化作用的加剧可能诱发海相红层;但晚白垩世的大洋红层对应着全球海平面下降,其成因还与在全球变冷的背景下,温度较低且富氧的大洋表层水以及从两极向赤道方向运动的低温富氧海水与大洋深层水交换并造成大洋底层水富氧和沉积物的氧化有关。中生代的三次大洋缺氧事件均发生在锶同位素下降的时间间隔中,这与洋中脊洋壳生产和有关热液活动的增加有关,洋壳生产的增加导致了CO2 排气作用的增强和全球变暖,最 相似文献
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西成矿化集中区热水沉积岩物质来源的同位素示踪及其意义 总被引：11，自引：3，他引：11
利用硅同位素、锶同位素和碳氧同位素,对西成矿化集中区与矿体紧密伴生的热水沉积岩的物质来源进行了探讨。硅质岩的硅同位素δ3 0 SiNBS -2 8=- 0.6‰～ - 0.1‰,硅主要来源于下伏沉积岩;热水沉积岩的锶同位素比值87Sr/ 86Sr变化于 0.70 938～ 0.72 812之间,位于海洋锶和陆壳锶之间,为混合锶,其锶主要来源于下伏沉积地层柱;碳同位素组成略低于正常沉积碳酸盐岩,碳主要来源于下伏沉积地层柱在循环碳,同时又受其它来源碳的影响。同位素研究结果表明,热水沉积岩的组成物质主要来源于下伏沉积地层柱 (地壳内部 ),形成方式主要是外生沉积作用,即热水沉积岩是内生作用与外生作用共同作用的结果,是内外生矛盾的统一体。 相似文献
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Strontium speciation transferring in strontium residue and mixing strontium ore are investigated with extracting experiment, X-ray powder diffraction （XRD）, X-ray fluorescence spectrometer （XRF） and Atomic Absorption Spectroscopy （AAS）. The results show that there are strontium carbonate, strontium sulfate, strontium sulfide, and a little amount of strontium silicate and strontium ferrite in strontium residue. Impurities in strontium residue mainly contain carbonate and oxide of calcium, iron, magnesium and aluminum etc. The amount of strontium sulfide in strontium residue is larger than that in strontium ore. And a little strontium silicate and strontium ferrite are found in strontium ore. It is concluded that acid soluble method is used firstly in the process of producing strontium carbonate from mixing strontium ore. In addition, mechanical smash method and surface active treatment to strontium samples are beneficial to the ratio-leaching increase of strontium. The research achievement helps to save energy and decrease pollutants emission in strontium processing industry. 相似文献
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中国南方二叠纪古海洋锶同位素演化 总被引：17，自引：3，他引：17
本文以贵州罗甸沫阳二叠系剖面为研究对象，通过对海相碳酸盐岩的锶同位素组成变化的研究，探讨了中国南方二叠纪古海洋锶同位素组成特点、演化及其地质意义。 相似文献
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龙门山泥盆纪腕足化石锶同位素组成特征及其古环境意义 总被引：1，自引：0，他引：1
生物成因的海相碳酸盐岩中Sr同位素组成与演化是目前研究古海平面变化、造山运动以及古气候变化的主要工具,在海相地层定年及全球等时对比研究中发挥着重要作用。对四川龙门山泥盆纪剖面腕足化石Sr同位素组成进行了研究。保存鉴定结果显示：腕足化石壳体结构保存完整;阴极射线照射下壳体不发光或部分壳体呈微弱橙黄色;大多数壳体微量元素Mn〈250μg／g、Sr〉400μg／g。表明腕足化石保存完好,后期成岩作用影响微弱。锶同位素结果显示：龙门山泥盆纪sr同位素演化同全球泥盆纪Sr同位素演化基本一致,表明龙门山泥盆纪Sr同位素演化受全球性变化影响。早泥盆世较高Sr同位素比值（甘溪组0．708437）可能是受加里东造山运动的影响,大量古陆的出露,风化作用的加强所致。其后的缓慢下降可能受海平面上升古陆面积缩小的影响。中泥盆世Sr同位素组成低值平台显示着幔源Sr和陆源Sr（风化作用较弱）输入量之间的平衡。随后的Sr同位素组成的上升可能是受中泥盆世开始温度上升的影响,致使风化作用的加强所致。 相似文献
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应用热力学原理对平顶山煤矿八矿地层中的长石、石英、高岭土及碳酸锶在该区热力学条件下溶解的可能性进行了计算。结果表明,该区矿泉水中的可溶性硅主要来自随温度升高溶解度增大的石英,锶来源于灰岩中碳酸锶的溶解。 相似文献
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Susan A Carroll Sarah K Roberts Louise J Criscenti Peggy A O'Day 《Geochemical transactions》2008,9(1):2
Strontium sorption to amorphous silica and goethite was measured as a function of pH and dissolved strontium and carbonate
concentrations at 25°C. Strontium sorption gradually increases from 0 to 100% from pH 6 to 10 for both phases and requires
multiple outer-sphere surface complexes to fit the data. All data are modeled using the triple layer model and the site-occupancy
standard state; unless stated otherwise all strontium complexes are mononuclear. Strontium sorption to amorphous silica in
the presence and absence of dissolved carbonate can be fit with tetradentate Sr2+ and SrOH+ complexes on the β-plane and a monodentate Sr2+complex on the diffuse plane to account for strontium sorption at low ionic strength. Strontium sorption to goethite in the
absence of dissolved carbonate can be fit with monodentate and tetradentate SrOH+ complexes and a tetradentate binuclear Sr2+ species on the β-plane. The binuclear complex is needed to account for enhanced sorption at hgh strontium surface loadings. In the presence
of dissolved carbonate additional monodentate Sr2+ and SrOH+ carbonate surface complexes on the β-plane are needed to fit strontium sorption to goethite. Modeling strontium sorption as outer-sphere complexes is consistent
with quantitative analysis of extended X-ray absorption fine structure (EXAFS) on selected sorption samples that show a single
first shell of oxygen atoms around strontium indicating hydrated surface complexes at the amorphous silica and goethite surfaces. 相似文献
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We have collected and analyzed a larger set of stream waters for major ions and strontium isotopes in Taylor Valley, McMurdo Dry Valleys, Antarctica. These new data substantiate the concept that the dissolution of carbonate minerals is a significant source of strontium, even in polar desert environments where liquid water is primarily limited to stream channels. In Taylor Valley, most of the carbonate minerals present are the result of secondary processes, such as mineral precipitation and/or eolian deposition, and not through primary geologic sources, such as bedrock or till sources. In Von Guerard Stream (Lake Fryxell basin) and Andersen Creek (Lake Hoare basin), water samples were collected during the austral summer to determine short-term 87Sr/86Sr patterns. The observed variability in both time and space may be dependent on the relative amounts of primary and secondary carbonates present in the streambeds and hyporheic zone as well as contingent on the relative proportions of carbonate and aluminosilicate weathering. 相似文献
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Sr/Ca ratios in the clay (< 2 μ) weathering products of basalt rocks from the Lake Kinneret drainage basin were found to be very similar to the ratios in the rocks, indicating similar depletion intensities for the two elements. In the clays from the scoriae and some lapilli tuffs the ratios were found to be somewhat higher than in the corresponding rocks, indicating preferential retention of strontium in the clays. The ratio in drainage water from these areas was much lower than that obtained by mass balance calculations.The Sr/Ca ratio in Jordan river water draining primarily limestone areas is 2.3 · 10?3. Very high Sr/Ca ratios in Lake Kinneret water were attributed to the influence of saline sublacustrine springs. The carbonate fraction from recent lake sediments was shown to have the Sr/Ca ratios characteristic for calcite precipitated biogenically in marine environments. The relative enrichment in strontium of the lake water was explained by the intensive precipitation of carbonates with low strontium distribution coefficients. 相似文献
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V. I. Vinogradov G. A. Belenitskaya M. I. Bujakaite V. N. Kuleshov M. A. Minaeva B. G. Pokrovskii 《Lithology and Mineral Resources》2006,41(3):271-279
In previous communications based on the study of sulfur and strontium, we showed that Lower Cambrian rocks of the Irkutsk Amphitheater underwent a significant epigenetic transformation. All postsedimentary alterations of rocks are related to the influence of water solutions that provoke the direct (physical) dissolution of material and its chemical transformation. In particular, an appreciable portion of anhydrites disappeared from the section due to reduction. Probably, these processes took place several times in the past and they are continuing at present. A similar conclusion was deduced from the strontium isotopic composition of carbonate rocks. Their strontium isotopic composition is usually shifted relative to the primary composition, although the prevalence of sulfate and carbonate rocks in the section promotes the stability of strontium isotopic composition with respect to secondary alterations. The carbon isotope system is even more stable due to the abundance of carbonate rocks in the section. This circumstance is probably responsible for the incapacity of isotope data to serve as obvious evidence of the epigenetic transformation of carbonates. The major elements of the evolution of carbon isotope signature could be retained since the sedimentation stage. 相似文献
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研究了次灵敏线407．8nm原子吸收光谱法测定工业碳酸锶中碳酸锶含量的条件,建立了一种全新的分析方法,即在测定过工业碳酸锶的杂质含量后,用高纯物质配制与被测样品成分一致的工作溶液,与样品溶液比较测定。该方法要求两种溶液的基体;介质;酸度;释放剂尽量一致,并同时使用标准曲线法和直线比较法。该方法准确,简单,快速,同一样品八次测定结果的极差小于0.3％,相对标准标差为0．10％。测定结果与国标方法相吻合。 相似文献