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浙江省萤石矿床区域成矿规律与找矿方向研究 总被引：2，自引：1，他引：1
萤石矿是浙江省的优势矿种之一,储量在中国名列前茅。根据矿床成因可分为火山-次火山热液充填型、岩浆期后热液充填型和岩浆热液交代型3种类型。火山-次火山热液充填型萤石矿床主要分布于浙东南火山岩分布区,成矿作用与中生代火山活动关系密切;岩浆期后热液充填型和岩浆热液交代型萤石矿床主要分布于浙西北燕山期花岗岩周围,成矿作用与燕山期岩浆侵入活动密切相关。文章根据浙江省萤石矿床的成因类型、成矿作用、构造环境、成矿时代等特征,可将其归纳为2个成矿系列:与中生代火山-次火山热液有关的萤石矿床成矿系列和与中生代岩浆侵入作用有关的萤石矿床成矿系列。其中,与中生代岩浆侵入作用有关的萤石矿床成矿系列又可分为与燕山期中酸性岩浆期后热液充填作用有关的萤石矿床成矿亚系列及与燕山期中酸性岩浆热液交代作用有关的萤石矿床成矿亚系列。在此基础上,提出了2大萤石矿床成矿系列的找矿方向分别为浙东南晚白垩世火山断陷盆地边缘断裂、火山口环形和放射状断裂及浙西北高氟岩体。 相似文献
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笔者总结了福建余朋—南口地区火把山萤石矿床的地质特征, 并通过萤石的微量元素及稀土元素地球化学特征, 探讨了矿床的成因及成矿物质、流体来源。萤石矿石的微量元素及稀土元素结果显示: 火把山萤石呈中等Eu负异常及弱Ce异常, 稀土元素配分模式具有轻稀土富集型及轻稀土弱亏损的平缓型等两种曲线型式。根据萤石矿石特征、微量元素、稀土元素等特征及Y/Ho-La/Ho图解, 可知萤石存在至少三期成矿地质作用。依据M?ller的Tb/La-Tb/Ca成因判别图解, 结合常口萤石矿床的萤石及围岩的稀土元素特征, 认为火把山萤石成矿流体一方面与常口大型萤石矿床受同一成矿流体场控制, 并在有利的部位富集成矿; 另一方面, 成矿热液流体流经下峰岩组发生了淋滤、萃取、交换作用, 形成了不同地球化学特征的另一成矿期次的萤石。综合分析认为, 火把山萤石矿床为受断裂控制的大气降水成因的中低温热液充填矿床。 相似文献
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四川牦牛坪稀土矿床萤石Sr、Nd同位素对地幔成矿流体的指示意义 总被引：14，自引：0，他引：14
萤石是四川牦牛坪稀土矿床主要的脉石矿物之一，其形成贯穿了整个稀土成矿过程，因此同位素的研究对探讨萤石和稀土成矿流体的来源具有重要的价值。矿区6件萤石样品的Sr、Nd同位素组成没有明显差异，结合围岩（碳酸岩－正长岩，花岗岩）同位素组成特征研究表明，不同颜色、来自不同矿石类型、具有不同REE类型的萤石为同源产物，稀土成矿流体来源于富集地幔，与区内碳酸岩－正长岩岩浆活动密切相关。 相似文献
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通过对中国萤石矿床的成矿作用研究,综合考虑萤石矿床的成因类型和工业类型,将中国萤石矿床划分为沉积改造型、热液充填型和伴生型3种矿床类型。在全面分析萤石矿典型矿床的成矿条件、控矿因素和成矿作用的基础上,总结成矿要素,以相同或相似的二级成矿必要要素组合确定沉积改造型、热液充填型萤石矿床的亚类型,沉积改造型进一步划分出2个矿床式,热液充填型划分出5个矿床式,伴生型按伴生主矿种划分出4个矿床式。文章分析了每一个矿床式的成矿地质背景,成矿条件、矿床特征、控矿因素和成矿作用,总结了每一个矿床式的二级成矿必要要素。 相似文献
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萤石是四川牦牛坪稀土矿最重要的脉石矿物之一。根据稀土含量、有关参数及配分模式，矿区萤石可分为LREE富集型、KLEE平坦型和LREE亏损型3种，不同类型萤石之间以及每种类型萤石的稀土地球化学特征具有连续变化规律。分析结果表明：矿区3种类型的萤石为同源不同阶段形成的产物；矿床成矿流体主要来源于本区正长岩－碳酸岩岩浆演化分异的相对富集LREE的流体；矿床成矿过程中较少再有相对富集LREE的流体参与；成矿环境由相对氧化向相对还原变化。 相似文献
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江西宁都葛藤嘴浅变质岩离子吸附型稀土矿成矿模式 总被引：1，自引：0，他引：1
江西宁都葛藤嘴离子吸附型稀土矿床是新近发现的新类型稀土矿床,成矿母岩为一套浅变质岩系。本文对矿区内的浅变质岩岩石类型、稀土元素含量及风化壳中稀土分布特征进行了研究,总结了成矿模式。矿区内岩石类型有变质砂岩、变质凝灰岩、千枚岩及片岩类。稀土元素含量普遍偏高,平均为384×10-6,变质凝灰岩类可达723×10-6,属于LREE型。风化壳钻孔样品中稀土含量增高,稀土配分继承了母岩特征。此类矿床最为特殊的是成矿母岩呈层产出,母岩的岩石类型、厚度及层位是重要的找矿要素。宁都地区浅变质岩类中良好的成矿母岩主要为变质砂岩和变质凝灰岩,两者不仅稀土含量较高,产出厚度较大,风化壳矿体也较为连续。 相似文献
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冕西稀土成矿带成矿条件探讨 总被引：7，自引：0，他引：7
该区之南河断裂及雅龙江断裂是成岩成矿流体的通道，控制了矿带的展布。哈哈、棉沙湾次级断裂带的有利部位直接控制了矿床的产出，更次级的断层、节理为矿脉、矿体提供了良好的赋存空间；霓石碱性花岗岩是稀土成矿的直接母岩，矿床与之紧密共生。含矿杂岩体的生成过程就是稀土成矿的过程，它的发育程度，决定矿床规模和价值，成矿带内已发现的稀土矿床均为充填断裂带的脉型矿床。深部构造＋北北东走向地壳深断裂带＋幔质碱性杂岩体“三位一体”是基本的成矿条件和模式。区内具有良好的找矿远景。 相似文献
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浙江“常山式”萤石矿床特征及成矿模式 总被引：1，自引：0，他引：1
"常山式"萤石矿床是近年在钦杭成矿带发现并被评价的一种新类型矿床,与产于碳酸盐岩中的充填交代及层控型萤石矿床不同,其矿体赋存位置及矿石特征有其独特性。以往勘查的矿体主要分布在岩前短轴背斜的南东翼、岩前岩体与寒武系碳酸盐岩外接触带。位于背斜转折端的苦麻岭矿床的发现,丰富了"常山式"萤石矿床的成矿理论。研究表明,寒武系碳酸盐岩岩性差异与成矿关系并不密切,矿体顶底板Ca F2含量特征说明成矿作用以充填为主。燕山晚期高氟岩体侵位是矿床最重要的控制因素,岩体外接触带的"虚脱冒落"构造及层间构造带为主要控矿构造。通过矿床地质特征及成矿规律研究,总结了矿床成因,建立了成矿模式,为浙西北乃至华南地区寻找同类型矿床提供了新思路。 相似文献
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REE and fluid inclusions in zoned fluorites from Eastern Transbaikalia: Distribution and geochemical significance 总被引：1，自引：0，他引：1
S. F. Vinokurov V. N. Golubev T. L. Krylova V. Yu. Prokof’ev 《Geochemistry International》2014,52(8):654-669
Special methodology was used to study the distribution of REE and some other elements in zoned fluorites from the different deposits of Eastern Transbaikalia. Fluorites from the uranium and polymetallic ore fields sharply differ in their REE distribution pattern and the composition of fluid inclusions, which reflects the geochemical specifics and indicates the possible sources of parental solutions. A gradual change in REE distribution patterns established in the successive growth zones of fluorites clearly coincides with the gradual decrease of temperature and mineralization of fluid inclusions. It is suggested that a change in the REE distribution pattern was provoked by the crystallochemical differentiation related to the formation of nano-sized mineral admixtures of REE phosphates and/or fluorcarbonates, which possess an ability to the selective accumulation of different REE groups. It was found that the zoned fluorites from the Streltsovka and Garsonui deposits show an opposite trends in the change of REE pattern with zonation. With a general decrease in total REE contents, fluorite from the Streltsovka deposit shows a change from positive parabolic to subchondritic pattern, while that from the Garsonui deposit, varies from the negative via subchondritic to the positive patterns. 相似文献
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YUAN Shunda ;PENG Jiantang ;HU Ruizhong ;BI Xianwu ;QI Liang ;LI Zhaoli ;LI Xiaomin ;SHUANG Yan 《中国地球化学学报》2008,27(4):342-350
In this paper the authors present the REE concentrations and Sr and Nd isotopic compositions of fluorites from the Bailashui tin deposit of the Furong ore field, southern Hunan Province. The results showed that the total amount of REE in fluorites is usually low, ranging from 0.705 to 8.785 μg/g with the chondrite-normalized REE distribution patterns similar to those of the Qitianling granites in the study area, characterized by LREE-enrichment patterns with pronounced negative Eu anomalies. The fluorites vary in Sr isotopic composition within the range of 0.7083-0.7091, the values are lower than those of the granites and higher than those of the host carbonate rocks in this area. The εNd（t） values of fluorites vary between -9.4 and ＋10.3, revealing that both the crust- and mantle-source materials were involved in the ore-forming hydrothermal fluids. Combined with previous studies on this ore deposit, the Bailashui tin deposit is temporally and spatially closely related with granitic magmatism in this area. The hydrothermal fluorites are the product of fluid/rock interactions between granitic magmatic hydrothermal fluid and marine carbonate rocks. The REE and F in the ore-forming fluid were derived from the granites, whereas Sr in the ore-forming fluid came mainly from the granitic magmatic hydrothermal fluid and marine carbonate rocks, although variations in Sr isotopic composition cannot be explained by a simple mixture of these two end-members. Evidence demonstrated that the ore-forming fluids are of crustal-mantle mixing origin, but that the fluids were probably incompletely homogenized and this may be caused by inhomogeneous mixing of the fluids of different sources. 相似文献
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F. J. Nie 《Mineralium Deposita》1994,29(6):488-498
Located in the Luonan county, Shaanxi Province, northwest China, Jinduicheng, Shijiawan and Huanglongpu molybdenum deposits constitute the most important molybdenum mineralized district in China. Among these three deposits, the Jinduicheng and Shijiawan molybdenum deposits are connected spatially and genetically with granitoid porphyry (124 ± 6 Ma, K-Ar biotite), and consist of disseminated-veinlet ores. Geochemical studies of rare earth elements (REE) furnish further evidence for understanding the rock- and ore-forming processes of these two porphyry molybdenum deposits and their related granitoid rocks. The REE distribution in molybdenum ore, granitoids and their Middle Proterozoic meta-volcanic wall rocks is discussed. The similarities between the REE signatures of the Shijiawan molybdenum-bearing monzogranite porphyry and the neighbouring Laoneushan monzogranite (130 ± 5 Ma, K-Ar biotite) show that they were produced at the same evolutional stage of granitoid magma derived mainly from crustal anatexis. The Shijiawan biotite monzogranite porphyry may be an apophysis of the Laoneushan granitoid batholith. Compared to the Shijiawan monzogranite porphyry, the Jinduicheng molybdenum-bearing granite porphyry is characterized by a high content of HREE, and depletion in LREE. The unique REE patterns indicates that the molybdenum-bearing granite porphyry was formed by thermogravitation diffusion of a granitoid magma. The slight depletion of REE abundance in the altered granitoid porphyry and meta-volcanic wall rocks shows that leaching of REE occurred during breakdown of the primary mineral assemblage, and crystallization of secondary minerals. The high REE content of molybdenum ore represented re-deposition of the mobilized molybdenum and REE. 相似文献
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西昆仑库科西力克一带多金属矿地质及地球化学特征的初步研究 总被引：1，自引：0，他引：1
新疆阿克陶县恰尔隆一带1：5万区调工作中曾在库科西力克一带发现数个具有一定工业价值的矿点,这些矿点位于西昆仑铜钼多金属元素富集带,其矿种齐全,涉及Au、Ag、Cu、Pb—Zn、M0、W和Fe等,分布较为集中,资源前景较好,找矿潜力巨大。本文从矿床地质及元素地球化学的角度对一些典型矿点进行了系统调查、采样、分析及研究,发现库尔尕斯金铜矿点主成矿元素中Ag、Cu和Pb具有一致的成矿阶段,而Au受后期构造作用可能滞后富集成矿。同时各矿点间REE含量及分布模式存在较大的差异。除库尔尕斯金铜矿点外,各矿点中矿石和围岩REE总量和分布模式差别也较为明显。认为库科西力克一带各矿点在成矿地质条件上具有一定的联系,成矿物质可能主要来源于深部,主要受区域性断裂（库科西力克断裂）及岩浆活动的影响,但各矿点之间具有各自的成矿特点,这与各矿点不同的矿床类型相关。 相似文献
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Geochemistry of Apatite from the Apatite-rich Iron Deposits in the Ningwu Region, East Central China 
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下载免费PDF全文 YU Jinjie ZHANG Qi MAO Jingwen YAN Shenghao 《《地质学报》英文版》2007,81(4):637-648
Four types of apatite have been identified in the Ningwu region.The first type of apatite is widely distributed in the middle dark colored zones(i.e.iron ores) of individual deposits.The assemblage includes magnetite,apatite and actinolite(or diopside).The second type occurs within magnetite-apatite veins in the iron ores.The third type is seen in magnetite-apatite veins and (or) nodules in host rocks(i.e.gabbro-diorite porphyry or gabbro-diorite or pyroxene diorite).The fourth type occurs within apatite-pyrite-quartz veins filling fractures in the Xiangshan Group.Rare earth elements (REE) geochemistry of apatite of the four occurrences in porphyry iron deposits is presented.The REE distribution patterns of apatite are generally similar to those of apatites in the Kiruna-type iron ores,nelsonites.They are enriched in light REE,with pronounced negative Eu anomalies.The similarity of REE distribution patterns in apatites from various deposits in different locations in the world indicates a common process of formation for various ore types,e.g. immiscibility.Early magmatic apatites contain 3031.48-12080×10~(-6) REE.Later hydrothermal apatite contains 1958×10~(-6) REE,indicating that the later hydrothermal ore-forming solution contains lower REE.Although gabbro-diorite porphyry and apatite show similar REE patterns,gabbro-diorite porphyries have no europium anomalies or feeble positive or feeble negative europium anomalies, caused both by reduction environment of mantle source region and by fractionation and crystallization(immiscibility) under a high oxygen fugacity condition.Negative Eu anomalies of apatites were formed possibly due to acquisition of Eu~(2+) by earlier diopsite during ore magma cooling. The apatites in the Aoshan and Taishan iron deposits yield a narrow variation range of ~(87)Sr/~(86)Sr values from 0.7071 to 0.7073,similar to those of the volcanic and subvolcanic rocks,indicating that apatites were formed by liquid immiscibility and differentiation of intermediate and basic magmas. 相似文献
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<正>Carbonatites are commonly related to the accumulation of economically valuable substances such as REE.Cu,and P.The debate over the origin of carbonatites and their relationship to associated silicate rocks has been ongoing for about 45 years.Worldwide,the rocks characteristically display more geochemical enrichments in Ba,Sr and REE than sedimentary carbonate rocks.However,carbonatite's geochemical features are disputed because of secondary mineral effects.Rock-forming carbonates from carbonatites at Qinling.Panxi region,and Bayan Obo in China show REE distribution patterns ranging from LREE enrichment to flat patterns.They are characterized by a Sr content more than 10 times higher than that of secondary carbonates.The coarse- and fine-grained dolomites from Bayan Obo H8 dolomite marbles also show similar high Sr abundance,indicating that they are of igneous origin.Some carbonates in Chinese carbonatites show REE(especially HREE) contents and distribution patterns similar to those of the whole rocks.These intrusive carbonatites display lower platinum group elements and stronger fractionation between Pt and Ir relative to high-Si extrusive carbonatite.This indicates that most intrusive carbonatites may be carbonate cumulates.Maoniuping and Daluxiang in Panxi region are large REE deposits.Hydrothermal fluorite ore veins occur outside of the carbonatite bodies and are emplaced in wallrock syenite.The fiuorite in Maoniuping has Sr and Nd isotopes similar to carbonatite.The Daluxiang fiuorite shows Sr and REE compositions different from those in Maoniuping.The difference is reflected by both the carbonatites and rock-forming carbonates,indicating that REE mineralization is related to carbonatites.The cumulate processes of carbonate minerals make fractionated fluids rich in volatiles and LREE as a result of low partition coefficients for REE between carbonate and carbonatite melt and an increase from LREE to HREE.The carbonatite-derived fluid has interacted with wallrock to form REE ore veins.The amount of carbonatite dykes occurring near the Bayan Obo orebodies may support the same mineralization model,i.e.that fluids evolved from the carbonatite dykes reacted with H8 dolomite marble,and thus the different REE and isotope compositions of coarse- and fine-grained dolomite may be related to reaction processes. 相似文献
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山东招掖金矿带内花岗岩与金矿化关系探讨 总被引：3，自引：1，他引：2
以花岗岩类及脉岩类的精确定年结果为基础,结合区内金矿床地质特征和近年来研究新进展,探讨了花岗岩类侵入与金矿化之间的空间、时间和成因关系。尽管区内花岗石类侵入体与金矿床间存在密切的窨及时间关系。但它们之间并不存在直接的成因联系,即这些金矿床并不是岩浆热液矿床。花岗石类侵入体和脉岩类的侵位通道和先存韧性剪切带是贯通深部流体的导矿构造,有利于深部成矿流体和上升和流体循环;花岗岩类与围岩的接触带及其内部断 相似文献