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1.
对滇东南马关火山爆砾岩筒以及玄武岩中的单斜辉石巨晶进行了主量元素、微量元素、原位Sr同位素以及含水性研究,结果显示,单斜辉石巨晶均为铝质普通辉石,Mg#与Al、Fe、Ti呈负相关,与Ca呈正相关;稀土元素总量不高,HREE及LREE亏损,而MREE相对富集,大离子亲石元素均出现明显亏损,高场强元素Nb、Zr出现亏损而Hf略富集,Nb、Ta与Zr、Hf分馏明显,Rb、Ba的变化范围较大。原位Sr同位素87Sr/86Sr值为0. 703 92～0. 705 06,巨晶单斜辉石来源于上地幔,形成于同一母岩浆,与寄主玄武岩同源,为源岩浆在高压下的结晶产物。运用显微红外-傅里叶变换红外光谱仪(Micro-FTIR)分析测试了单斜辉石巨晶的水含量,结果显示OH吸收峰位于3 700～2 800cm-1,含水量赋值范围为318×10-6～693×10-6,水含量稍富于女山及汉诺坝地区的单斜辉石巨晶,也高于马关地区幔源橄榄岩包体中的单斜辉石结构水含量,暗示该区上地幔岩石圈具高含水性,这同时证实了俯冲洋壳在研究区的活动。新近纪到达地幔过渡带的西太平洋洋壳俯冲发生转向东撤,此时新特提斯洋洋壳正在NE向俯冲,是马关地区深部地幔富水的主因,到达软流圈(或地幔过渡带)的新特提斯洋俯冲洋壳导致该区地幔熔融,岩浆随之而生。 相似文献
2.
华北晚中生代和新生代玄武岩中单斜辉石巨晶来源及其对寄主岩岩浆过程的制约:以莒南和鹤壁为例 总被引：3，自引：0，他引：3
本文对华北克拉通晚中生代和新生代碱性玄武质岩石中的单斜辉石巨晶进行了主、微量元素和Sr-Nd同位素的综合研究,发现晚中生代和新生代单斜辉石巨晶存在明显的主、微量元素和同位素组成上的差异。新生代单斜辉石巨晶有Al-普通辉石和次透辉石两类;而中生代单斜辉石巨晶只有Al-普通辉石。新生代单斜辉石SiO_2含量高、REE配分型式为上凸型、LILE和放射性元素含量高,并具有比寄主碱性玄武岩更亏损的Sr和Nd同位素组成;而中生代单斜辉石SiO_2含量低、REE配分型式为LREE富集型、LILE和部分HFSE以及放射性元素含量低,并具有比寄主碱性玄武岩稍富集的Sr和Nd同位素组成;巨晶的结构、矿物成分和地球化学特征,以及Mg-Fe在熔体与单斜辉石间的分配状况皆说明,新生代碱性玄武岩中单斜辉石巨晶是碱性玄武岩浆在高压下结晶的,因此二者是同源的;而中生代单斜辉石巨晶是被寄主岩浆偶然捕获的捕虏晶,是不同源的。华北新生代单斜辉石巨晶存在于碱性玄武岩和拉斑玄武岩中,它们具有比寄主碱性玄武岩更亏损的Sr和Nd同位素组成,说明即使是碱性玄武岩也不能完全代表软流圈来源的原始岩浆,其在上升过程中或多或少存在同位素组成富集的物质的混入。同时,拉斑玄武岩不是碱性玄武质岩浆直接结晶分异的产物,亦不是完全由部分熔融程度的不同造成的。拉斑玄武岩中存在岩石圈地幔物质的贡献或是岩浆房内碱性玄武质岩浆受地壳混染作用的结果。 相似文献
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南海北部边缘新生代玄武岩广泛分布，分布于海南岛北部的全新世早期石山组玄武岩，岩石组成为碱性橄榄玄武岩，其中可见较大颗粒的橄榄石斑晶，橄榄石斑晶具有较高的Fo值（82. 8～83. 5）和Ni含量（0. 14%～0. 20%）。橄榄玄武岩的微量元素及同位素组成与洋岛玄武岩（OIB）高度吻合，富集大离子亲石元素Rb、Ba和轻稀土元素，同时富集高场强元素Nb、Ta、Zr和Hf。矿物组成及主微量元素特征指示其源区为含石榴子石辉石岩源区，经历了较低程度的部分熔融（约5%）。此外，石山组橄榄玄武岩具有基本一致的Sr- Nd- Pb同位素组成，表明岩浆在上升过程中没有明显的地壳物质的混染，但是相比正常洋中脊玄武岩（MORB），石山组橄榄玄武岩具有较高的87 Sr/86 Sr比值，较低的ε Nd ( t )值，以及较高的207 Pb/204 Pb（15. 639～15. 643）和208 Pb/204 Pb（38. 977～38. 996）比值，说明其源区为亏损地幔（DM）和富集地幔端元（EMII）的混合。结合地球物理学证据，我们认为亏损地幔来源于软流圈，而EMII端元为含再循环古洋壳及俯冲沉积物的地幔柱，随着海南地幔柱上升，再循环物质熔融并与周围软流圈地幔橄榄岩反应形成含石榴子石辉石岩，随着地幔柱的不断上升，辉石岩首先发生部分熔融，形成的岩浆经历了橄榄石和微弱单斜辉石的分离结晶作用后形成了石山组橄榄玄武岩。华南新生代玄武岩同石山组橄榄玄武岩具有相似的地球化学特征，反映二者具有相同的物质端元组成，但两者岩浆演化上升的动力学机制不同，同时不同端元混合的比例及部分熔融程度也有差异。 相似文献
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报道了徐淮地区早白垩世埃达克质岩中首次发现的含橄榄石单斜辉石岩捕虏体的岩相学与矿物化学资料, 该类捕虏体显示堆积结构、块状构造, 主要由单斜辉石(~80%)、斜方辉石(~5%)、橄榄石(~5%)和普通角闪石(~10%)组成.橄榄石外侧发育有斜方辉石反应边, 角闪石沿辉石粒间分布, 呈嵌晶结构.矿物化学分析结果表明: 橄榄石的镁橄榄石分子值(Fo)=77.7~79.3, Ni=623×10-6~773×10-6; 斜方辉石的Mg#=75.6~80.2, Cr=161×10-6~684×10-6, Ni=79×10-6~708×10-6; 单斜辉石的Mg#=84.5~86.4, CaO=21.59%~23.13%, Al2O3=1.72%~2.44%.上述矿物与中、新生代玄武岩中橄榄石、斜方辉石和单斜辉石斑晶以及堆积成因辉石岩中的斜方辉石和单斜辉石成分类似.此外, 单斜辉石的稀土配分型式以相对富含中稀土元素的上凸型为特征, 稀土元素含量较低(∑REE=10.14×10-6~12.71×10-6), 无明显的铕异常(δEu=0.90~1.16), 类似于新生代玄武岩中单斜辉石斑晶.捕虏体中的普通角闪石的Mg#=74.0~80.4、SiO2=43.2%~44.5%、Na2O=2.04%~2.29%, 稀土元素分馏不明显, 显示亏损高场强元素(HFSEs, 如Nb、Ta、Zr、Hf), 富集Sr、Rb、Ba的特征, 与新生代玄武岩中角闪石捕虏晶成分不同.结合其嵌晶结构, 普通角闪石应是寄主岩浆贯入结晶的产物.综合上述特征, 可以看出含橄榄石单斜辉石捕虏体为镁铁质岩浆高压堆晶成因.结合华北克拉通东部早白垩世双峰式火山岩组合的出现, 推断含橄榄石单斜辉石岩捕虏体可能是早白垩世基性岩浆底侵的产物. 相似文献
5.
报道了徐淮地区早白垩世埃达克质岩中首次发现的含橄榄石单斜辉石岩捕虏体的岩相学与矿物化学资料,该类捕虏体显示堆积结构、块状构造,主要由单斜辉石(~80%)、斜方辉石(~5%)、橄榄石(~5%)和普通角闪石(~10%)组成.橄榄石外侧发育有斜方辉石反应边,角闪石沿辉石粒间分布,呈嵌晶结构.矿物化学分析结果表明:橄榄石的镁橄榄石分子值(Fo)=77.7~79.3,Ni=623×10-6~773×10-6;斜方辉石的Mg#=75.6~80.2,Cr=161×10-6~684×10-6,Ni=79×10-6~708×10-6;单斜辉石的Mg#=84.5~86.4,CaO=21.59%~23.13%,Al2O3=1.72%~2.44%.上述矿物与中、新生代玄武岩中橄榄石、斜方辉石和单斜辉石斑晶以及堆积成因辉石岩中的斜方辉石和单斜辉石成分类似.此外,单斜辉石的稀土配分型式以相对富含中稀土元素的上凸型为特征,稀土元素含量较低(∑REE=10.14×10-6~12.71×10-6),无明显的铕异常(δEu=0.90~1.16),类似于新生代玄武岩中单斜辉石斑晶.捕虏体中的普通角闪石的Mg#=74.0~80.4、SiO2=43.2%~44.5%、Na2O=2.04%~2.29%,稀土元素分馏不明显,显示亏损高场强元素(HFSEs,如Nb、Ta、Zr、Hf),富集Sr、Rb、Ba的特征,与新生代玄武岩中角闪石捕虏晶成分不同.结合其嵌晶结构,普通角闪石应是寄主岩浆贯入结晶的产物.综合上述特征,可以看出含橄榄石单斜辉石捕虏体为镁铁质岩浆高压堆晶成因.结合华北克拉通东部早白垩世双峰式火山岩组合的出现,推断含橄榄石单斜辉石岩捕虏体可能是早白垩世基性岩浆底侵的产物. 相似文献
6.
中国东部几个地区新生代玄武岩中单斜辉石—熔体平衡温压—兼论幔源包体的成因 总被引：5，自引：1，他引：4
以中国东部宽甸、汉诺坝和明溪含有幔源包体的新生代玄武岩中的单斜辉石斑（巨）晶为研究对象,采用最新的单斜辉石－熔体平衡温压计对单斜辉石斑（巨）晶－熔体进行了平衡温压计算。结果表明,碱性玄武岩中的单斜辉石斑晶结晶温度和压力高于共生的亚碱性玄武岩中的单斜辉石斑晶,单斜辉石巨晶的结晶温度和压力高于单斜辉石斑晶。这说明碱性玄武岩的形成深度大于亚碱性玄武岩,单斜辉石巨晶是更高压力下的结晶产物,单斜辉石斑晶在岩浆上升的不同深度均有晶出。回归分析表明,尽管携带幔源包体的玄武岩浆上升速度较快,但并不是绝热上升。单斜辉石斑（巨）晶的结晶温压条件与同一地点幔源包体平衡温压条件的对比表明,单斜辉石巨晶和碱性玄武岩中的部分单斜辉石斑（巨）晶的结晶温压大于幔源包体的平衡温压,表明了包体寄主岩浆的来源深度大于包体的深度。因此,幔源包体是寄主岩浆上升途中捕虏的上地幔碎块,而非寄主岩浆形成源区的残留体。 相似文献
7.
通过对辽东菜园子玄武岩中的橄榄石和单斜辉石捕虏晶进行K-Ar定年及岩石地球化学测试,研究华北克拉通东部新生代岩石圈地幔的性质及深部作用过程,结果表明,辽东菜园子玄武岩形成于古近纪,K-Ar年龄为36.33 Ma±0.97 Ma和39.34 Ma±1.27 Ma;属于碱性玄武岩系列;玄武岩中Sr,Ba相对富集,Zr,Hf相对亏损;ISr和εNd(t)值分别介于。0.704 73～0.705 16和 0.22～ 2.27之间。橄榄石捕虏晶发育环状裂隙和扭折带,具有明显的成分环带,自核至边Mg#值逐渐降低(核部Mg#值介于88.7～94.3之间,边部Mg#值介于76.6～77.8之间),核部与新生代玄武岩地幔橄榄岩包体中橄榄石的成分类似,边部与玄武岩中橄榄石斑晶成分相当。单斜辉石捕虏晶为透辉石,具有反环带结构,核部具有较高的FeO,MnO,Na2O,Al2O3质量分数,反映了壳源成因;过渡部分MgO,Cr2O3质量分数明显升高,反映了壳源物质与软流圈物质反应的结果;向边部MgO,Cr2O3质量分数逐渐降低;FeO,MnO,Na2O,Al2O3质量分数逐渐升高,暗示与寄主岩浆反应的效应。上述结果表明,华北克拉通东部新生代岩石圈地幔具有亏损性质,但岩浆形成过程中有陆壳物质加入。环带状橄榄石捕虏晶反映了新生代岩石圈地幔中橄榄岩与熔体之间相互作用的存在。 相似文献
8.
《矿物岩石地球化学通报》2018,(6)
本文通过研究峨眉山大火成岩省白马层状岩体和二滩高钛玄武岩中单斜辉石的主量和微量元素组成,反演与单斜辉石平衡的熔体成分,以查明层状岩体和高钛玄武岩之间的成因联系。结果显示,不同岩石中单斜辉石的稀土配分型式基本相似,在微量元素配分图解中均表现出Sr、Zr、Hf、Ti、Zn、Co和Ni负异常。二滩高钛玄武岩中单斜辉石斑晶环带核部的成分与高钛苦橄岩中单斜辉石斑晶的成分类似。模拟结果显示,白马岩体中与单斜辉石平衡的熔体成分与峨眉山高钛玄武岩成分类似,单斜辉石的Zr-Hf负异常与Zr和Hf在单斜辉石和熔体之间的分配系数较低有关。因此,高钛玄武岩和白马岩体分别代表深部岩浆房高钛苦橄质岩浆经分离结晶作用产生的高钛玄武质岩浆的喷出和侵入产物。 相似文献
9.
山东昌乐新生代碱性玄武岩中的巨晶单斜辉石成因研究 总被引：2，自引：0，他引：2
山东昌乐新生代碱性玄武岩中除斑晶单斜辉石和基质单斜辉石外,还发育大量巨晶单斜辉石和同源斜方辉石捕掳晶。巨晶单斜辉石与玄武岩间发育复杂和简单两种类型的反应边。复杂反应边往往发育在颗粒较大的巨晶单斜辉石外围。复杂反应边可分为4个带：内部带、过渡带、外部带和边缘带,其中,内部带、过渡带和外部带均由具不同结构特征的单斜辉石＋熔体＋金属氧化物构成,边缘带为不含熔体和金属氧化物的干净的单斜辉石;内部带的单斜辉石具梳状构造,过渡带的单斜辉石具细密筛孔构造,外部带为具似砂钟构造的筛孔状单斜辉石。反应边中单斜辉石、熔体及金属氧化物的成分显示,只有内部带受到单斜辉石巨晶的影响,其余带均受玄武岩浆的制约。简单反应边往往发育在颗粒较小的巨晶单斜辉石外围。简单反应边仅发育不含熔体和金属氧化物的干净的单斜辉石。巨晶单斜辉石的反应边是巨晶与玄武岩浆间温度差造成的。在与玄武岩浆反应的过程中,大颗粒的单斜辉石巨晶需要较长的时间与玄武岩浆达到温度平衡,从而有足够的时间发育包含4个带的复杂反应边;反之,由于缺乏足够的反应时间,小颗粒单斜辉石巨晶的外围只发育不含熔体和金属氧化物的简单反应边。同源斜方辉石捕掳晶的成分与地幔二辉橄榄岩包体中的斜方辉石类似,其边部发育类似于Bowen反应（1956）形成的单斜辉石环边。在单斜辉石AlIV-AlVI图解上,巨晶单斜辉石、二辉橄榄岩包体中的单斜辉石以及部分单斜辉石斑晶的核部,均位于较高压力的“麻粒岩和玄武岩中包体”区域,反应边中单斜辉石、基质单斜辉石以及绝大部分斑晶单斜辉石位于“火成岩”区域,说明部分斑晶单斜辉石核部来源于地幔二辉橄榄岩,属于捕掳晶。结合单斜辉石结晶压力的估算,笔者认为巨晶单斜辉石的成因模式为：来自软流圈的碱质基性熔体上侵到地幔岩石圈下部,结晶形成单斜辉石巨晶,后来该熔体携带巨晶单斜辉石与来自上地幔岩石圈、夹带大量二辉橄榄岩包体以及斜方辉石（和单斜辉石）捕掳晶的玄武岩浆混合,巨晶单斜辉石随混合后的碱性玄武岩浆上升、喷出地表。 相似文献
10.
我国华北北部新近纪喷发的汉诺坝玄武岩,岩层出露比较完整,普遍含有超镁铁岩包体和各种高压巨晶。大麻坪代黄沟剖面出露较好,主要岩性为玄武岩,从上到下可分为上三、二、一层和底层。岩相学观察显示这些玄武岩含有1%~5%的捕虏晶且斑晶数量很少。橄榄岩包体为尖晶石二辉橄榄岩,轻稀土略微亏损,轻重稀土无分馏,显示这是只经过少量部分熔融后的原始地幔包体。通过对代黄沟碱性玄武岩中橄榄石、辉石和斜长石等斑晶或捕虏晶的矿物学分析,得出它们的成分变化是玄武岩混合了分解的地幔橄榄岩快速上升造成的。玄武岩的主量元素与二辉橄榄岩相平衡的原生熔体相比,Mg#(52.0~62.7)以及CaO(7.3%~8.5%)、Ni((82~192)×10-6)和Cr((65~192)×10-6)含量都较低。玄武岩的稀土分配模式为轻稀土富集的右倾型,δEu=1.01~1.05,δCe=0.95~1.02,富集高场强元素Nb、Ta、Zr及大离子亲石元素Ba、Sr。玄武岩痕量元素Ba/Rb和Rb/Sr的比值显示源区可能遭受过流体的交代作用。同时,痕量元素显示这一系列玄武岩主要受到部分熔融的控制,大量的结晶分异并未发生,且源区残留石榴子石。分析认为玄武岩岩浆应该是原生岩浆,而不是演化岩浆,影响整个岩浆的形成的过程可能是部分熔融而不是分离结晶。基于目前已发表的实验岩石学结果和理论分析认为汉诺坝玄武岩与辉石岩类相平衡,源区主要矿物相为单斜辉石和石榴子石,可能存在少量的橄榄石。 相似文献
11.
W. F. McDonough H. -G. Stosch N. G. Ware 《Contributions to Mineralogy and Petrology》1992,110(2-3):321-328
The concentrations of titanium and rare earth elements (REE) in olivines, orthopyroxenes, clinopyroxenes and spinels from four anhydrous, spinel-bearing peridotite xenoliths have been determined. The distribution of titanium (used as an analogue for the high field strength elements: HFSE) relative to the REE between clinopyroxenes and orthopyroxenes varies as a function of the whole rock composition and modal mineralogy. The distribution coefficients for titanium and the REE in these peridotites do not reflect mineral-melt equilibria. It is believed that subsolidus distribution coefficients for HFSE relative to REE vary with temperature. Ratios of various incompatible elements (e.g., Ti/Eu, Zr/Sm, Hf/Sm and P/Nd) in peridotite minerals differ from those in most primary basalts. However, the abundance ratios of incompatible elements in the bulk peridotite are comparable to those found in modern basalts. Given this and the differing contribution of melt from each phase during melting, near constant ratios of such incompatible elements in primary and primitive basalts and komatiites reflect the buffering of the melt by its residue. These ratios are fixed in the magma during the initial stages of melting because of similar and low distribution coefficients between melt and bulk residue for these element pairs. Differences in the relative abundances of titanium and REE in clinopyroxenes and orthopyroxenes demonstrate that mantle normalized abundance patterns for clinopyroxene are not equivalent to those of the whole rock. Therefore, claims of a widespread HFSE-depleted reservoir in the upper mantle base solely on the relative abundances of incompatible elements in peridotitic clinopyroxenes are invalid. 相似文献
12.
辽河盆地沙三期火山-侵入岩地球化学与岩石成因 总被引：8，自引：0，他引：8
辽河盆地沙三期火山-侵入岩为一套偏碱性的双峰式岩系，其基性端元为碱性玄武岩，中偏碱性端元为粗面质熔岩和侵入岩。碱性玄武岩富集高场强元素(如Nb、Th、Zr、Hf、V等)和轻稀土、Sr、Ba等大离子亲石元素，而亏损Rb和K，具有与板内碱性玄武岩和洋岛玄武岩类似的特征。粗面质岩石显示与基性端元相似的地球化学特征，其不相容元素含量总体上高于碱性玄武岩，但具强烈的Sr和Eu亏损。矿物学、岩石学及地球化学证据表明，玄武质岩石是软流圈地幔低程度部分熔融的产物，并经历了橄榄石和辉石的分离结晶作用，其源区可能有金云母和石榴石残留。玄武质岩浆上升到较浅部位后进一步发生橄榄石、辉石、斜长石和磁铁矿等的分离结晶作用而形成粗面质岩浆，地壳物质混染作用不显著。 相似文献
13.
XIANG Zhongjin YAN Quanren YAN Zhen WANG Zongqi WANG Tao ZHANG Yingli QIN Xiaofeng 《《地质学报》英文版》2011,85(1):145-163
The Taohekou Formation is a volcanic-sedimentary terrane formed in the early Silurian in the northern Daba Mountains, China. The volcanic rocks, with dominant alkali basalts and minor mantle xenoliths, are enriched in clinopyroxene phenocrysts. Geochemical analysis shows that the composition of clinopyroxenes from different lithofacies has a close affinity. There is a liner correlation present in composition of clinopyroxenes (including phenocryst, microcrystal and xenocryst) from coarse porphyritic basalts, pillow or fine porphyritic basalts to amygdaloidal basalts. All the clinopyroxenes, except the clinopyroxenes in mantle xenoliths, show a similar pattern of trace elements and REE, which indicates that they are likely products of successive fractional crystallization from cognate magma. Clinopyroxenes in mantle xenoliths, however, are mantle xenocrysts. The crystallization pressure of clinopyroxenes gradually decreases from mantle xenolith, deep-seated xenocryst, coarse porphritic basalts, pillow or fine porphritic basalts, to amygdaloidal basalts, which are 1.92-4.41 GPa, 1.18-2.36 GPa, 1.13-2.05 GPa, 0.44-0.62 GPa and 0.14-0.28 GPa respectively. Calculation results suggest that the primary magma originated from a mantle region deeper than 68 km and stagnates in intervals of 37-68 km, 15-20 km and 5-9 km during its ascent. The alkali basalts are characterized by increasing concentrations of Si and alkaline with the magmatic evolution. Meanwhile, they are markedly enriched in LREE, and the patterns of trace elements and REE are similar to those of oceanic island basalts. 相似文献
14.
A clinopyroxene-rich dike of the Trinity ophiolite sheeted-dike complex shows three different magmatic pulses, probably injected in a short period of time (no well developed chilled margin) and important variations of the clinopyroxene and plagioclase percentages between its core (highly porphyritic) and margins (aphyric). This variation, interpreted as related to a flow differentiation phenomenon (mechanical phenocryst redistribution), has important geochemical consequences. It produces increases in the FeO, MgO, CaO, Cr and Ni contents from the margin to the core, together with increases in the clinopyroxene percentage, and decreases in the SiO2, Zr, Y, Nb and REE contents together with a decrease in the percentage of the fine-grained groundmass toward the core of the dike. This mineralogical redistribution, which also affects the incompatible trace element ratios because of the difference in plagioclase and clinopyroxene mineral/liquid partition coefficients, illustrate the importance of fractionation processes outside of a magma chamber. 相似文献
15.
Anton P. le Roex A. J. Erlank H. D. Needham 《Contributions to Mineralogy and Petrology》1981,77(1):24-37
Bulk rock major and trace element variations in selected basalts from the Famous area, in conjunction with a detailed study of the chemical compositions of phenocryst minerals and associated melt inclusions are used to place constraints on the genetic relationship among the various lava types. The distribution of NiO in olivine and Cr-spinel phenocrysts distinguishes the picritic basalts, plagioclase phyric basalts and plagioclase-pyroxene basalts from the olivine basalts. For a given Mg/Mg+Fe2+ atomic ratio of the mineral, the NiO content of these phenocrysts in the former three basalt types is low relative to that in the phenocrysts in the olivine basalts. The Zr/Nb ratio of the lavas similarly distinguishes the olivine basalts from the plagioclase phyric and plagioclase pyroxene basalts and, in addition, distinguishes the picritic basalts from the other basalt types. These differences indicate that the different magma groups could not have been processed through the same magma chamber, and preclude any direct inter-relationship via open or closed system fractional crystallization.The Fe-Mg partitioning between olivine and host rock suggests that the picritic basalts represent olivine (±Cr-spinel) enriched magmas, derived from a less MgO rich parental magma. The partitioning of Fe and Mg between olivine, Cr-spinel and coexisting liquid is used to predict a primary magma composition parental to the picritic basalts. This magma is characterized by relatively high MgO (12.3%) and CaO (12.6%) and low FeO* (7.96%) and TiO2 (0.63%).Least squares calculations indicate that the plagioclase phyric basalts are related to the plagioclase-pyroxene basalts by plagioclase and minor clinopyroxene and olivine accumulation. The compositional variations within the olivine basalts can be accounted for by fractionation of plagioclase, clinopyroxene and olivine in an open system, steady state, magma chamber in the average proportions 453223. It is suggested that the most primitive olivine basalts can be derived from a pristine mantle composition by approximately 17% equilibrium partial melting. Although distinguished by its higher Zr/Nb ratio and lower NiO content of phenocryst phases, the magma parental to the picritic basalts can be derived from a similar source composition by approximately 27% equilibrium partial melting. It is suggested that the parental magma to the plagioclase-pyroxene and plagioclase phyric basalts might have been derived from greater depth resulting in the fractionation of the Zr/Nb ratio by equilibration with residual garnet.C.O.B. Contribution No. 722 相似文献
16.
金沙江蛇绿岩带蛇纹岩中浅色岩类的成因 总被引：4，自引：0，他引：4
浅色岩类的岩石类型包括斜长岩和斜长花岗岩,它们均呈岩块状包裹于蛇纹岩中。浅色岩的正Ｅｕ异常明显,ＲＥＥ参数图解、Ｎｂ／Ｔａ和Ｚｒ／Ｈｆ值等均呈现分离结晶趋势,不相容元素Ｓｒ、Ｂａ、Ｎｂ、Ｔａ、Ｚｒ、Ｈｆ富集,相容元素Ｓｃ、Ｖ、Ｃｏ、Ｎｉ亏损,并与其寄主岩－蛇纹岩形成强烈的互补关系。这些特征表明,浅地是幔源超基性岩浆晚期结晶分异的产物。 相似文献
17.
E. Dunworth E.-R. Neumann J. Rosenbaum 《Contributions to Mineralogy and Petrology》2001,140(6):701-719
The Skien lavas, which form the earliest phase of basaltic magmatism within the Permo-Carboniferous Oslo Rift, contain multiple generations of clinopyroxene which exhibit strong petrological and geochemical disequilibrium. Three principal core compositions have been identified: (1) low-jadeite, high-Mg, Cr-diopside cores (CrMgDi) with strongly depleted trace-element signatures, which are believed to be xenocrystic in origin; (2) Mg-rich, Cr-poor diopside cores (MgDi) with moderately depleted trace-element signatures which probably represent early cognate growth; and (3) more dominant, low-Mg, phenocrystic diopside cores (PhenDi). Several samples contain CrMgDi or MgDi cores which have been subjected to resorption and partial re-equilibration with their host melts, indicative of extensive disequilibrium and magma mixing. These three core types are overgrown by trace-element-enriched Ti-augite, which also forms megacrysts and late-stage lava groundmass. Calculated Ti-augite/melt partition coefficients show clinopyroxene compatibility of the M-HREE, Zr, Hf and Y. The LILE, Sr, and Nb remain incompatible. )Sr300 and )Nd300 of Ti-augite overgrowths, phenocrystic diopside, and MgDi diopside cores show that intrasample isotopic disequilibrium existed when the host basalts were erupted. All epsilon values lie within the range of data previously published for the Skien lavas. Detailed examination of the chemical, isotopic and textural disequilibrium features seen in these lavas has enabled us to place constraints upon the magmatic evolution of this basalt suite, ranging from xenocryst incorporation to cognate multistage pyroxene growth, as well as identifying clear evidence of magma mixing and possible crustal contamination. 相似文献
18.
In this paper we report the results of the analysis of rare earth (REE), large-ion lithophile (LILE), and high field strength (HFSE) elements in minerals from the alkaline lamprophyre dikes of the Kola region and the Kaiserstuhl province by the local method of laser ablation inductively coupled plasma mass spectrometry. The contents of Y, Li, Rb, Ba, Th, U, Ta, Nb, Sr, Hf, Zr, Pb, Be, Sc, V, Cr, Ni, Co, Cu, Zn, Ga, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu were measured in olivine, melilite, clinopyroxene, amphibole, phlogopite, nepheline, apatite, perovskite, and the host fine-grained groundmass. The obtained data on trace element partitioning among the mineral phases of the alkaline ultrabasic rocks of the dike series indicate that the main mineral hosts for the HFSEs and REEs in alkaline picrites, olivine melanephelinites, and melilitites are perovskite and apatite comprising more than 90% of these elements. Among major rock-forming minerals, melilite, clinopyroxene, and highly magnesian amphibole make a significant contribution to the balance of REEs during the evolution of melanephelinite melts. The partition coefficients of Ni, Co, Cu, Zn, Sc, V, Cr, Ga, Y, Li, Rb, Ba, Th, U, Ta, Nb, Sr, Hf, Zr, Pb, Be, and all of the REEs were calculated for olivine, clinopyroxene, amphibole, phlogopite, nepheline, perovskite, and apatite on the basis of mineral/groundmass ratios. Variations in the composition of complex zoned clinopyroxene phenocrysts reflect the conditions of polybaric crystallization of melanephelinite melt, which began when the magmas arrived at the base of the lower crust and continued during the whole period of their ascent to the surface. The formation of green cores in clinopyroxene is an indicator of mixing between primary melanephelinite melts and phonolite magmas under upper mantle conditions. The estimation of the composition of primary melts for the rocks of the alkaline ultrabasic series of the Kola province indicated a single primary magma for the whole series. This magma produced pyroxene cumulates and complementary melilitolites, foidolites, and nepheline syenites. 相似文献