共查询到20条相似文献，搜索用时 46 毫秒
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利用广西红辉沸石资源水热制备纳米微孔材料——沸石分子筛，其工艺流程为“红辉沸石”(预处理) 氢氧化钠 铝酸钠 水→水热反应→晶化合成→过滤、洗涤、烘干→沸石分子筛产品。基于大量实验研究，确定了水热制备A型、P型和X型沸石的最佳工艺技术参数，制备出了质量较高的沸石分子筛产品，并综合分析了红辉沸石粒度、石英杂晶、晶化时间以及反应混合物组成对沸石分子筛水热制备的影响，指明了今后研究工作的努力方向。 相似文献
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文章研究了采用酸、碱、盐改性红辉沸石和加热活化红辉沸石对改性红辉沸石去除水溶液中氨氮的影响效果。实验结果表明：（1）用红辉沸石去除溶液中氨氮的实验条件选择如下：1搅拌时间为30min;2沸石粒度为40～60目;3沸石用量为2g;4氯化氨溶液浓度为40mg/L;5氯化氨溶液用量为80ml。（2）采用高温活化对提高红辉沸石去除氨氮效率的作用不明显。（3）酸和碱改性对提高红辉沸石去除氨氮的效率有一定的作用,其中盐酸改性的红辉沸石去除氨氮效率为16.2%,硫酸改性的红辉沸石去除氨氮效率为13.1%,碱改性的红辉沸石去除氨氮效率为25.6%。（4）盐改性对红辉沸石去除水溶液中氨氮的影响效果巨大：经盐改性后,去除率由9.6%升高至72.6%。 相似文献
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以依兰矿区煤矸石为原料研究了4A型沸石的合成方法及其合成动力学模型.推导出含有速率常数的分段式动力学方程;实验分析了最佳反应条件下,不同反应时间内产品的结晶度,通过待定系数法确定出各方程速率常数,整合动力学方程,最终得到利用煤矸石制备4(A)沸石的动力学模型.采用模型方程对实验晶化曲线进行拟合,得到如下结论:4(A)沸石结晶反应发生在凝胶后期;在晶化后期,凝胶的溶解速率决定了晶体生长速率和在有限晶化时间内产品的结晶度. 相似文献
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广西资源车田红辉沸石特征的初步研究 总被引：19，自引：2，他引：19
红辉沸石属斜方晶系，a=1．36，b=1．81，c=1．78nm，V=4.394nm3。化学成分分析结果（％）：SiO258．76，Al2O314.13，CaO8．80，K2O0．11，Na2O0．18，Fe2O30．44，H2O 16．87，H2O1．25。计算的化学式为：（K0.017Na0.042Ca1.13）1.189［Al1.997，Si7.05，O18」·6．75H2O。Si／Al=3．53.N。=1．501，Nβ=1．495，Nγ=1．488。D=2.13g／cm3（实测）。钾离子（K ）交换量9．34～13·08mg／g，氨离子（NH4 ）交换量92.76～130．26mmol／100g。佛石晶体呈透明一半透明，为乳白色、瓷白色。单晶体呈板状、板柱状，集合体呈放射状、束状。单晶体长度可达30cm以上，但通常为5～15cm。红辉沸石呈脉状产出在断裂带中，矿体中沸石含量达95％以上，矿石的白度为91．7。它是一种质量较好、用途较广的极为罕见的沸石矿，也是国内外目前唯一具有工业意义的红辉沸石矿床。 相似文献
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水热条件下利用微波加热从粉煤灰合成沸石研究 总被引：14，自引：0，他引：14
着重选用NaOH水溶液为反应前驱物, 通过改变反应温度、NaOH浓度与合成时间等参数, 在水热条件下利用微波加热直接对粉煤灰进行晶化, 合成得到了浊沸石、菱沸石、NaP1沸石3种沸石.粉煤灰转化为沸石率约15%~40%.研究表明: (1) 反应体系在15min左右即有合成沸石产生, 30min左右合成沸石转化率达到最佳; (2) 为保证沸石晶核生成和晶体的生长, 反应体系的溶液/粉煤灰比不应低于2.5; (3) 在溶液/粉煤灰比为2.5时, 应控制加热时间在30min左右. 相似文献
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摘要本文介绍了用福建龙岩东宫下高岭土,经选矿、煅烧、晶化、过滤、干燥成功地合成新型洗涤助剂——4A沸石的工艺条件。高岭土经煅烧使其脱羟形成具有反应活性的无定型非晶质偏高岭石,偏高岭石在氢氧化钠溶液中反应一定的时间即形成4A沸石。我们合成的4A沸石的主要技术指标为:钙交换容量290—316(mgCaCO_3/g沸石),白度>85％,平均粒度4μm。我们合成的4A沸石应用于洗涤剂工业,取得了良好效果。在肥皂中。可以用3％的沸石代替4％的脂肪酸钠,在超浓缩洗衣粉中,可以用4A沸石代替其中5％的三聚磷酸钠。 相似文献
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Gilles Serge Odin 《Comptes Rendus Geoscience》2002,334(6):409-414
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414. 相似文献
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Inter-regional correlation of transgressions and regressions in the Cretaceous period 总被引：1，自引：0，他引：1
T. Matsumoto 《Cretaceous Research》1980,1(4):359-373
Well investigated platforms have been selected in each continent, and the history of Cretaceous transgressions and regressions there is concisely reviewed from the available evidence. The factual records have been summarized into a diagram and the timing of the events correlated between distant as well as adjoining areas.On a global scale, major transgressions were stepwise enlarged in space and time from the Neocomian, via Aptian-Albian, to the Late Cretaceous, and the post-Cretaceous regression was very remarkable. Minor cycles of transgression-regression were not always synchronous between different areas. Some of them were, however, nearly synchronous between the areas facing the same ocean.Tectono-eustasy may have been the main cause of the phenomena of transgression-regression, but certain kinds of other tectonic movements which affected even the so-called stable platforms were also responsible for the phenomena. The combined effects of various causes may have been unusual in the Cretaceous, since it was a period of global tectonic activity. The slowing down of this activity followed by readjustments may have been the cause of the global regression at the end of the Cretaceous. 相似文献
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The Afyon stratovolcano exhibits lamprophyric rocks, emplaced as hydrovolcanic products, aphanitic lava flows and dyke intrusions, during the final stages of volcanic activity. Most of the Afyon volcanics belong to the silica-saturated alkaline suite, as potassic trachyandesites and trachytes, while the products of the latest activity are lamproitic lamprophyres (jumillite, orendite, verite, fitztroyite) and alkaline lamprophyres (campto-sannaite, sannaite, hyalo-monchiquite, analcime–monchiquite). Afyon lamprophyres exhibit LILE and Zr enrichments, related to mantle metasomatism. 相似文献
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正20140751 Guo Xincheng(Geological Party,BGMRED of Xinjiang,Changji 831100,China);Zheng Yuzhuang Determination and Geological Significance of the Mesoarchean Craton in Western Kunlun Mountains,Xinjiang,China(Geological Review,ISSN0371-5736,CN11-1952/P,59(3),2013,p.401-412,8 相似文献
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正20141058 Chen Ling(Key Laboratory of Mathematical Geology of Sichuan Province,Chengdu University of Technology,Chengdu610059,China);Guo Ke Study of Geochemical Ore-Forming Anomaly Identification Based on the Theory of Blind Source Separation(Geosci- 相似文献
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正20141334 Chen Kun(Institute of Geophysics,China Earthquake Administration,Beijing100081,China);Yu Yanxiang Shakemap of Peak Ground Acceleration with Bias Correction for the Lushan,Sichuan Earthquake on April20,2013(Seismology and Geology,ISSN0253-4967,CN11-2192/P,35(3),2013,p.627-633,2 illus.,1 table,9 refs.)Key words:great earthquakes,Sichuan Province 相似文献
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正20141624 Cai Xiongfei(Key Laboratory of Geobiology and Environmental Geology,Ministry of Education,China University of Geosciences,Wuhan 430074,China);Yang Jie A Restudy of the Upper Sinian Zhengmuguan and Tuerkeng Formations in the Helan Mountains(Journal of Stratigraphy,ISSN0253-4959CN32-1187/P,37(3),2013,p.377-386,5 illus.,2 tables,10 refs.) 相似文献
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正20142263Lü Shaojun(Geological Survey of Jiangxi Province,Nanchang 330030,China)Early-Middle Permian Biostratigraphical Characteristics in Qiangduo Area,Tibet(Resources SurveyEnvironment,ISSN1671-4814,CN32-1640/N,34(4),2013,p.221-227,2illus.,2tables,22refs.)Key words:biostratigraphy,Lower Permian,Middle Permian,Tibet 相似文献
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正20142560Hu Hongxia(Regional Geological and Mineral Resources Survey of Jilin Province,Changchun 130022,China);Dai Lixia Application of GIS Map Projection Transformation in Geological Work(Jilin Geology,ISSN1001-2427,CN22-1099/P,32(4),2013,p.160-163,4illus.,2refs.) 相似文献
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正20140692 Duo Tianhui(No.402 Geological Team,Exploration of Geology and Mineral Resources of Sichuan Authority,Chengdu611730,China);Wang Yongli Computer Simulation of Neptunium Existing Forms in the Groundwater(Computing Techniques for Geophysical and Geochemical Exploration,ISSN1001-1749,CN51-1242/P,35(3), 相似文献