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1.
藏东玉龙斑岩铜矿带磷灰石微量元素地球化学特征研究   总被引：1，自引：0，他引：1  
藏东玉龙斑岩铜矿是我国最大的斑岩型铜矿带。该铜矿带分布有大量的花岗斑岩体,这些斑岩体具有相似的全岩地球化学特征,仅小部分成矿,多数并未发现有工业价值的金属矿床。副矿物磷灰石除具有和全岩高度一致的地球化学属性外,其微量元素含量及比值等对反映成矿过程中的流体演化和岩浆来源具有明显的指示意义。本文对玉龙铜矿带周缘的6个成矿和4个不成矿斑岩体磷灰石进行了主元素和微量元素地球化学特征研究,结果显示含矿斑岩磷灰石富Sr、Ba、Th、Pb和Zr,贫Y,同时显示出富稀土元素、轻重稀土分馏明显和具Ce正异常的地球化学特征。研究还显示,相对于不成矿斑岩,成矿斑岩磷灰石的Sr/Eu、Sr/Ce、Sr/Y和Th/U比值相对较低且变化范围相对较小,而Ce/Pb、Lu/Hf比值较高且变化范围较大,La/Yb比值及变化范围与不含矿斑岩接近。此外,成矿斑岩磷灰石高的Ce/Pb和Lu/Hf和低的Sr/Ce、Sr/Eu、Sr/Y和Th/U比值说明成矿斑岩形成于更高的氧逸度环境。  相似文献   

2.
邢凯  舒启海  赵鹤森  徐浩楠 《岩石学报》2018,34(5):1427-1440
滇西普朗斑岩铜矿床位于三江特提斯构造带义敦岛弧南端,是晚三叠世甘孜-理塘洋壳俯冲背景下的成矿作用产物。本文选取普朗矿床含矿石英闪长玢岩和石英二长斑岩中蚀变和未蚀变磷灰石进行研究,以探讨其对成岩、成矿作用的指示意义。结果显示,相比于未蚀变磷灰石,蚀变磷灰石的Na、S、Mn、Ca、Y及REE等元素含量均有不同程度的降低。总体而言,普朗矿床中磷灰石均具有高Sr、δEu,低Y的特征,指示了其母岩浆具似埃达克质特点。本次研究表明磷灰石的卤素、Sr和REE可以用来追踪成矿母岩浆成分、氧化状态和结晶演化过程。与三叠纪不成矿的休瓦促岩体相比,普朗矿床成矿岩体的磷灰石具高δEu、低Mn和δCe的特点,且δEu和δCe总体呈负相关趋势,表明普朗矿床成矿岩体氧逸度相对较高。此外,磷灰石中(La/Sm)_N、(La/Yb)_N和(Sm/Yb)_N比值降低可能是岩浆中独居石结晶或含Cl热液出溶的结果。与邻区的春都矿床、白垩纪休瓦促成矿岩体对比研究表明,普朗斑岩成矿岩浆具有高Cl/F特征,可能形成于典型的大洋俯冲环境。  相似文献   

3.
舒小超  孟凡巍  陶瑞  王坤 《地质学报》2023,97(12):4101-4116
产于华北克拉通北缘的晚三叠世矾山超钾质碱性岩杂岩体主要由单斜辉石岩和辉石正长岩等组成,以发育内生磷灰石-磁铁矿矿床而闻名。本文选取矾山杂岩体中的磷灰石为研究对象,通过测试磷灰石的主微量元素及原位Sr-Nd同位素组成以探讨母岩浆的氧逸度及含水性特征。研究表明,矾山磷灰石以轻稀土元素富集、重稀土元素亏损为特征,显示出缺乏显著Ce异常的“右倾”的稀土配分型式,且具有较低的Ga含量及较高的δEu值,暗示杂岩体具有较高的岩浆氧逸度,这也得到了磷灰石Mn氧逸度计的支持。所有磷灰石以高Sr、低Y为特征,具有较高的Sr/Y(>30)和La/Yb(>90)比值,且Sr/Y与La/Yb存在明显的正相关关系,表明矾山超钾质岩浆具有较高的含水量。矾山磷灰石的原位Sr-Nd同位素投点位于地幔序列,明显偏离地壳趋势。母岩浆的“氧化且富水”特征是矾山杂岩体得以发生磷灰石-磁铁矿矿化的重要因素,其主要与板片俯冲过程中蚀变洋壳对岩石圈地幔的交代作用有关。通过对比矾山杂岩体与全球范围内其他地质环境中磷灰石的成分数据,发现具有“高Sr、低F、少Cl”特征的磷灰石可作为识别超钾质碱性岩杂岩体(及其相关金属矿床)的...  相似文献   

4.
《福建地质》2021,40(2)
闽东西朝钼矿成矿岩体具高SiO_2、富Al_2O_3、高Sr,低Y、Yb、MgO,高Sr/Y比值和(La/Yb)_N比值的地球化学特征,为典型的埃达克质岩的特征。该岩体具有较低的Ni、Cr和V含量,稀土元素配分为典型的轻重稀土强烈分馏右陡倾,微量元素蛛网图上表现出Rb、Ba、Th、U等LILE富集,P、Ti等HFSE强烈亏损、Sr富集,(~(87)Sr/~(86)Sr)_i比值为0.709 778～0.710 097,εNd(t)值为-7.09～-5.77,这些特征均与华夏地块早白垩世加厚下地壳部分熔融成因的埃达克质岩特征相近。西朝钼矿的成岩成矿是早白垩世挤压向伸展拉张构造环境转换的背景下,在地幔物质上涌加热作用下,加厚的下地壳发生部分熔融且有幔源物质加入形成的。  相似文献   

5.
内蒙古北山地区咸水沟一带红柳园组火山岩岩性为细碧岩、玄武岩、流纹岩,具双峰式岩浆组合特征。基性岩稀土元素总量∑REE(包括Y元素)变化于123×10~(-6)~217×10~(-6)之间,轻稀土明显富集((La/Yb)_N=2.42~4.74)。在原始地幔标准化的蛛网图中,Nb、Ta、Ti元素明显亏损;具有高的Th/Nb比值(3.14~10.2)和低的Nb/La比值(0.3~0.71);Mgo和Cr、Ni总体呈正相关关系,反映了橄榄石±辉石的结晶分异作用。细碧岩ε_(Hf)(t)值变化于6.0~11.5,表明岩浆来源于亏损地幔,两阶段模式年龄(T_(DM2)=631~982 Ma)明显大于其结晶年龄,结合ε_(Hf)(t)值揭示出岩浆源区受到地壳物质混染的可能。流纹岩具有向强过铝质岩石过渡趋势(A/CNK=1.08~1.32),稀土元素总量∑REE(包括Y元素)较高(133×10~(-6)~383×10~(-6)),轻稀土明显富集((La/Yb)_N=4.5~8.0),Eu负异常强烈(δEu=0.1~0.5);Ga/Al比值(10 000*Ga/Al=1.8~4.2)较高,具A型花岗岩特征。其下部细碧岩LA-ICP-MS锆石U-Pb测年表明其形成年龄为359.9±1.4 Ma。咸水沟红柳园组基性岩的形成表明北山地区在石炭纪早期幔源岩浆活动非常强烈,这些幔源岩浆的底侵导致了浅部地壳发生脱水熔融形成具有A型花岗岩特征的酸性火山岩。地质与地球化学特征表明,咸水沟红柳园组火山岩形成于裂谷构造背景。  相似文献   

6.
西藏高原西北缘钾质火山岩地球化学特征及其地质涵义   总被引：1，自引：0，他引：1  
鲍佩声  肖序常  苏犁 《地质学报》2006,80(10):1578-1588
西藏高原西北缘钾质火山岩属橄榄玄粗岩(shoshonite)系列。其K-Ar同位素年龄变化于0.28~7.79Ma,属中新世末—更新世;其K2O/Na2O几乎均>1,Mg#值有较宽的范围(从0.51~0.64),且具有较低的Cr,Ni含量(均≤326×10-6)。它们代表着经历了不同程度分异演化的岩浆结晶产物。研究区钾质火山岩(shoshon-ites)以高度富集LREE和LILE(K,Rb,Sr,Ba,Th)以及高度亏损HREE和HFSE(Nb,Ta,Zr,Hf,Ti)等元素为特征。(La/Yb)n高达29.82~84.94。钾质火山岩对球粒陨石标准化的REE配分型式均为向右陡倾的LREE富集型。对原始地幔标准化的痕量元素蛛网图均具有明显的Nb,Ta,Ti负异常。钾质火山岩具有较高的87Sr/86Sr(0.707755~0.710426)和较低的143Nd/144Nd(0.51196~0.512439)比值。上述特征表明这些火山岩来源于富集的地幔源区。钾质火山岩较高的Ba/Nb比值(40.84~97.28)、较高的Th/Ta及Ce/Yb比值(131~366)、和较低的Nb/Y比值(0.9~3.3),结合Th/Yb-Ta/Yb及(Th×100)/Zr-(Nb×100)/Zr判别图,提示了它们也形成于活动大陆边缘,但与其伴生的钙碱性火山岩为早期与俯冲作用有关的火山岩,而钾质火山岩则为晚期岩石圈拆沉作用的产物。  相似文献   

7.
张荣伟  薛传东  薛力鹏  刘星 《岩石学报》2019,35(5):1407-1422
甭哥金矿床位于西南三江造山带北段的义敦弧南缘,属于与富碱侵入岩有关的金矿床。目前,对其成矿机理认识仍较为薄弱,制约了资源评价和找矿勘查进展。本文选取甭哥金矿床强矿化的正长斑岩和弱矿化的黑云辉石正长岩中的磷灰石作为研究对象,详细剖析磷灰石的地球化学特征,探讨其记录的成岩成矿信息。结果表明,磷灰石的稀土元素含量特征及配分模式显示富碱岩浆主要来自于壳幔混合的源区,黑云辉石正长岩中磷灰石的(La/Sm)N、(La/Yb)N、(Sm/Yb)N值和Sr含量呈正相关,说明长石结晶对岩浆结晶分异有重要的影响;正长斑岩中磷灰石具有高Sr/Y、Ce/Pb值,而Th/U、(Sm/Yb)N值较低,指示强烈的流体活动参与了岩浆结晶过程;磷灰石挥发分(F、Cl)含量及比值特征指示金矿成矿流体主要来自地幔源区,成矿与富碱、高氯的成矿流体有关。磷灰石Mn氧逸度计估算结果显示,甭哥富碱侵入岩具有高氧逸度特性,但两种不同岩性岩石的氧逸度具有差异性。其中,正长斑岩的logf_(O_2)值为-12～-10. 3,黑云辉石正长岩的logf_(O_2)值为-15. 5～-11. 1,磷灰石中SO_3含量及Ga含量也暗示正长斑岩的氧逸度高于黑云辉石正长岩的特征;结合磷灰石低Mn、Ga含量和高的Cl、SO_3含量,反映甭哥金矿床金的成矿是在高氧逸度条件下金氯络合物迁移、富集而沉淀的结果。因而,磷灰石的地球化学特征对金矿床成矿过程示踪和勘查评价具有重要的指示意义。  相似文献   

8.
赣中变质岩带变泥砂质岩石地球化学特征及其地质意义   总被引：5，自引：2，他引：3  
赣中变质岩带主要由变泥砂质岩石和少量斜长角闪岩组成.30个变泥砂质岩石样品分析表明,稀土元素分布模式显示明显富集轻稀土元素及Eu负异常[∑REE=129～296μg/g,δEu=0.51～0.86,(La/Yb)N=3.95～12.9],其不相容元素比值高(Th/Sc=0.57～3.59、La/Sc=1.46～12.4、La/Yb=5.84～19.0、La/Sm=4.69～6.87、Th/U=3.40～6.42),大离子亲石元素富集,Zr、Hf、Sc、Ti、Y、HREE和Sr含量较低,其原岩应为一套砂泥质岩石,沉积于远离陆地的克拉通大陆架浅海环境;δBa=0.10～0.93,Nd同位素亏损地幔模式年龄tDM=1597～2525Ma,εNd(0)=-9.9～-15.8,其源区物质主体由古元古代富铝富钾的花岗质岩石和(或)碎屑沉积岩构成,经历了较强的化学风化作用.  相似文献   

9.
东南沿海分布大面积的白垩纪晚期侵入岩。这些岩石可分为两期:其中115~100Ma以钙碱性系列岩石为主,岩石组合为辉长岩-闪长岩-花岗闪长岩-二长花岗岩-碱性长石花岗岩;而100~86Ma的岩石为碱性系列,岩石组合为石英二长斑岩-正长斑岩-碱性长石花岗岩。115~100Ma的辉长岩以角闪辉长岩为主,具有极高的CaO、MgO和Al_(2)O_(3)含量,具有极低的SiO_(2)(42.9%~53.8%)、全碱(K_(2)O+Na_(2)O:0.86%~5.28%)、Ba、Nb、Th、Rb和Zr含量,也具有极低的FeO^(T)/MgO、La/Yb和Zr/Hf比值,较高的Eu/Eu^(*)、Sr/Y比值和Sr含量,为基性-超基性堆晶岩。与辉长岩同期的闪长岩和细粒暗色包体具有较高的SiO_(2)(50.34%~63.68%),较低的CaO、P_(2)O_(5)、MgO、Al_(2)O_(3)含量,相对低的Eu/Eu^(*)和Sr/Y比值,变化较大的La/Yb和Zr/Hf比值,代表了从基性岩浆储库中抽取的富硅熔体。115~100Ma的花岗闪长岩和二长花岗岩类岩石为准铝质岩石,SiO_(2)含量变化较大(61.7%~75.3%),具有较低的FeO^(T)/MgO、Ga/Al比值和Nb、Zr及Nb+Zr+Ce+Y元素含量,显示出典型I型花岗岩的特征。这些花岗岩具有相对高的La/Yb、Eu/Eu^(*)和Zr/Hf比值和高的Sr、Ba和Zr含量。结合岩相学特征,这些花岗岩为堆晶花岗岩。而115~100Ma的碱性长石花岗岩具有极高的SiO_(2)含量(大于75%),低的Eu/Eu^(*)、La/Yb、Zr/Hf和Sr/Y比值,具有低的Ba、Sr和Zr含量和高的Rb、Nb、Y和Th含量和Rb/Sr比值,表明这些花岗岩是由富硅岩浆储库中抽离的高硅熔体侵入地壳形成。100~86Ma期间形成的二长斑岩和正长斑岩具有极高的全碱含量,可以达到8%~12%,其SiO_(2)主要集中在60%~70%,具有极高的Zr、Sr和Ba含量和Eu/Eu^(*)、La/Yb和Sr/Y比值,显示出堆晶花岗岩的特征。而100~86Ma期间形成的大部分碱性长石花岗岩具有极高的SiO_(2)含量(大于75%),并显示出A型花岗岩的特征,具有高的Rb/Sr比值和高的Rb、Y和Th和低的Ba、Sr含量和低的Zr/Hf、La/Yb、Eu/Eu^(*)和Sr/Y比值,表明它们是由富硅岩浆储库抽离的高硅熔体侵入浅部地壳形成。东南沿海高硅花岗岩的形成和穿地壳岩浆系统密切相关,高硅花岗岩是由浅部地壳内晶体-熔体分异产生的熔体侵入地壳所形成,而高硅花岗岩的地球化学特征与岩浆储库的水及挥发份含量密切相关。115~100Ma期间,从富水的岩浆储库抽离的熔体形成具有低高场强元素含量和低Rb/Sr比值的高硅花岗岩,这一过程与古太平洋板块俯冲有关;100~86Ma期间,从富挥发份的岩浆储库抽离的熔体形成碱性特征、富含高场强元素和具有高的Rb/Sr比值的高硅花岗岩,这一过程和古太平洋板块回撤软流圈上涌有关。  相似文献   

10.
基性岩墙,与层状、环状基性杂岩体和高Ti、低Ti玄武岩共同组成了峨眉山大火成岩省岩石组合.为进一步确定大火成岩省及相关生物灭绝事件的时间联系,及更深化研究大火成岩省的成因,对分布于贵州省南部的基性岩墙进行了主、微量元素、Sr-Nd同位素测定和锆石SHRIMP U-Pb年代学研究.黔南基性岩墙∑REE=135.66×10-6~280.59×10-6,LREE/HREE为6.42~7.54,（La/Yb）N为7.94~9.85,轻重稀土分异明显,δEu为1.0~1.3,具有Ba、Sr、K等LILE富集,Nb、Ta、Zr、Hf等HFSE亏损特征,显示与峨眉山高钛玄武岩相似的地球化学特征.Th/Ta（1.80~1.94）、Nb/U（30.8~39.88）、Th/La（0.08~0.10）、Nb/Th（7.89~8.40）比值与原始地幔相似,较低的初始（87Sr/86Sr）i比值（0.705 278~0.706 052）、εNd（t）（-0.5~+1.6）、以及Th/Ta比值（< 2.13）显示岩浆无明显的地壳混染,岩浆可能形成于受地幔柱作用的富集石榴石地幔源区10%~12%的部分熔融.SHRIMP锆石206Pb/238U加权平均年龄为261.2±2.6 Ma,反映峨眉山大火成岩的喷发时间可能集中在260 Ma左右,并可能与瓜德鲁普末期的生物灭绝有关.   相似文献   

11.
Over 700 apatite grains from a range of rock types have been analysed by laser-ablation microprobe ICPMS for 28 trace elements, to investigate the potential usefulness of apatite as an indicator mineral in mineral exploration. Apatites derived from different rock types have distinctive absolute and relative abundances of many trace elements (including rare-earth elements (REE), Sr, Y, Mn, Th), and chondrite-normalised trace-element patterns. The slope of chondrite-normalised REE patterns varies systematically from ultramafic through mafic/intermediate to highly fractionated granitoid rock types. (Ce/Yb)cn is very high in apatites from carbonatites and mantle-derived lherzolites (over 100 and over 200, respectively), while (Ce/Yb)cn values in apatites from granitic pegmatites are generally less than 1, reflecting both HREE enrichment and LREE depletion. Within a large suite of apatites from granitoid rocks, chemical composition is closely related to both the degree of fractionation and the oxidation state of the magma, two important parameters in determining the mineral potential of the magmatic system. Apatite can accept high levels of transition and chalcophile elements and As, making it feasible to recognise apatite associated with specific types of mineralisation. Multivariate statistical analysis has provided a user-friendly scheme to distinguish apatites from different rock types, based on contents of Sr, Y, Mn and total REE, the degree of LREE enrichment and the size of the Eu anomaly. The scheme can be used for the recognition of apatites from specific rock types or styles of mineralisation, so that the provenance of apatite grains in heavy mineral concentrates can be determined and used in geochemical exploration.  相似文献   

12.
Rock samples representing various igneous and metamorphic rocks of southern Obudu Plateau were analyzed for rare-earth element ( REE ) behavior by ICP-MS. Results of the analyses indicate a range of REE abundances and distinctive patterns from highly fraetionated patterns with negative Eu anomalies in granitic rocks to relatively low abundances and less REE fractionated flat patterns with little Eu anomaly in some paragneisses, schists, enderbites and dolerites to unfractionated patterns with positive Eu anomalies in some paragneisses and charnockites. Over all, there are low to high ∑ REE contents with negative to positive Eu anomalies. The ratios of different parameters, especially La/Yb and Ce/Yb, show behaviors consistent with crustal to mantle derivation. The heterogeneity of REE abundances and REE patterns reflects mantle to crustal petrogenetic variations of different rock suites on the Plateau. The LREE content is higher than the HREE content in the highly differentiated rocks, as evidenced by their La/Yb,Ce/Yb and La/Sm ratios, which are normally higher in residual products than in primary melts. The dominantly intermediate nature of the source rock of the orthogneisses is suggested by the generally low ∑ REE. The granites enriched in LREE and depleted in HREE and some of the charnockites with negative Eu anomalies were probably formed by partial melting and crystallization.  相似文献   

13.
《International Geology Review》2012,54(12):1541-1552
The Mt Vulture carbonatites are the only carbonatite occurrence in the southern Apennines. We present new trace element data for these rocks in order to evaluate the factors influencing rare earth element (REE) and other trace element fractionations and their REE grade. This study focuses on massive hyalo-alvikites from two lava flows and one dike, which have different relative abundances of silicate and carbonate (i.e. Si/Ca). These differences are also evident from CaO/(CaO + MgO + FeO(T) + MnO) and Sr/Ba ratios. The REE grade of the Mt Vulture carbonatites is very similar to that of the global average for calcio-carbonatites. R-mode factor analysis shows that most of the trace element variance reflects the relative roles of carbonate and silicate minerals in influencing trace element distributions. Silicates largely control heavy rare earth element (HREE), transition metal, Zr, and Th abundances, whereas carbonate minerals control light rare earth element (LREE), Ba, and Pb abundances. In addition, apatite influences LREE concentrations. Increasing silica contents are accompanied by decreases in (La/Yb)N and (La/Sm)N ratios and less marked LREE enrichment. In contrast, higher carbonate contents are associated with increases in (La/Yb)N and (La/Sm)N. The Si/Ca ratio has little influence on Eu anomalies and middle rare earth element (MREE) to HREE fractionations. Apatite has a negligible effect on inter-REE fractionations amongst the carbonatites.  相似文献   

14.
刘军  靳淑韵 《中国地质》2010,37(2):324-333
弓长岭二矿区既是大型条带状铁矿床,同时又是大型磁铁富矿床,自1949年建矿以来,一直是鞍钢的主体矿山和高品位富矿的主要供应地。笔者在总结矿床地质特征的基础上,对矿区的主要变质岩-斜长角闪岩类的主量元素、微量元素和稀土元素进行了分析。结果显示:主量元素的平均化学成分与基性火山岩中玄武岩成分相似,MgO和CaO含量比较高,而且Na2OK2O;微量元素:相容元素Sc、V、Cr、Co、Ni、Cu的含量比较高,属于右倾型;(Rb/Yb)N值为5.95～132.93,平均值为49.34,远远大于1,为强不相容元素富集型;大离子亲石元素Rb、Ba、K、Sr明显富集,但Th、U强亏损;高场强元素中Zr、Hf明显富集,而Nb、P为中等亏损,Ti为弱亏损,与亏损型洋中脊拉斑玄武岩很相近;稀土元素具有∑REE低(21.09×10-6～69.13×10-6,平均40.44×10-6)、LREE略有富集(LREE/HREE=1.70～2.58,平均2.27;(La/Yb)N:0.93～4.27,平均值1.60)的稍右倾型或平坦型特征。轻稀土分馏不明显((La/Sm)N:0.87～3.28,平均值1.42)。根据主量、微量和稀土元素的特征,并结合环境构造判别图解,笔者认为,研究区斜长角闪岩的原岩为大洋中脊拉斑玄武岩。  相似文献   

15.
This paper presents abundances of major and trace elements of apatites in granitic rocks associated with different types of ore deposits in Central Kazakhstan on the basis of electron probe microanalysis and laser ablation inductively coupled plasma mass spectrometry. Our results demonstrate that the concentrations and ratios of elements in apatites from different granitoid rocks show distinct features, and are sensitive to magma evolution, petrogenetic and metallogenetic processes. Apatites in the rocks associated with Mo‐W deposits have high content of F and MnO, low content of Cl, which may be indicative of sedimentary sources, while apatites from a Pb‐Zn deposit show relatively high content of Cl and low F content, which possibly suggest a high water content. In these apatites, Sr contents decrease, while Mn and Y contents increase with magma evolution. This relationship reflects that these elements in apatites are related with the degree of magmatic differentiation. Four types of REE patterns in apatites are identified. Type 1 character of highest (La/Yb)N in apatites of Aktogai porphyry Cu‐Mo deposit, Sayak‐I skarn Cu deposit and Akzhal skarn Pb‐Zn depposit is likely produced by the crystallization of heavy REE‐enriched minerals. Type 2 character of upward‐convex light REE in apatite of Aktogai porphyries likely results from La‐enriched mineral crystallization. Type 3 feature of Nd depletion in apatites of East Kounrad and Zhanet deposits both from Mo‐W deposits primarily inherits the character of host‐rock. Type 4 apatites of Aktogai deposit and Akshatau W‐Mo deposit with wide range of REE contents may suggest that apatites crystallize under a wide temperature range. Three types of apatite with distinct redox states are identified based on Eu anomaly. The Aktogai apatite with slight negative Eu anomaly displays the most oxidized state of the magma, and the apatites of other samples at Aktogai, East Kounrad and Akzhal with moderate negative Eu anomaly show moderate oxidizing condition of these rocks, while the remaining apatites with strong En anomaly indicate a moderate reductive state of these rocks.  相似文献   

16.
根据矿物组成白云鄂博矿区的碳酸岩岩可墙可分为白云石型、白云石－方解石共存型和方解石型三种类型。REE和微量元素地球化学表明，这三类碳酸岩岩墙为碳酸岩浆演化不同阶段的产物，白云石型和白云石－方解石共存型对应于早期岩浆阶段，其（La/Nd)n、(La/Yb)n比值随稀土总量的增加而增大，方解石型则对应于碳酸岩浆演化的晚期热液阶段，其稀土总量明显富集，但其（La/Nd)n、(La/Y)n和（La/Yb)n比值随稀土总量的增加却有减小的趋势，热液阶段也是白云鄂博稀土矿化的主要阶段。  相似文献   

17.
Carbonatites found in the Dara-i-Pioz alkaline massif, Tajikistan, form linearly-elongated, steeply-dipping and, sometimes, rounded in plan pipe-like bodies of mainly calcitic composition. As compared to reference carbonatites, they have lower contents of Fe, Mg, Ti, Sr, Ba, Mn, P, REE, Zr, Nb, Ta, and other elements but elevated contents of Rb, Cs, Al, Si, Na, K, and others. However, the Dara-i-Pioz carbonatites are characterized by such typomorphic features of carbonatites as the sharp predominance of LREE over HREE and high ΣCe: ΣY, La: Yb, and Sr: Ba ratios.  相似文献   

18.
Rare earth element (REE) contents, and Sr and Nd isotopic compositions were measured for three suites of mantle xenoliths from the Kuandian, Hannuoba and Huinan volcanoes in the north of the Sino-Korean Platform. From the correlations of Yb contents with Al/Si and Ca/Si ratios, the peridotites are considered to be the residues of partial melting of the primitive mantle. The chondrite-normalized REE compositions are diverse, varying from strongly LREE-depleted to LREE-enriched, with various types of REE patterns. Metasomatic alteration by small-volume silicate melts, of mantle peridotites previously variably depleted due to fractional melting in the spinel peridotite field, can account for the diversity of REE patterns. The Sr/ Ba versus La/Ba correlation indicates that the metasomatic agent was enriched in Ba over Sr and La, suggestive of its volatile-rich signature and an origin by fluid-triggered melting in an ancient subduction zone. The Sr and Nd isotopic compositions of these xenoliths, even from  相似文献   

19.
孙渺  陈伟  曲晓明  马旭东  丁吉顺 《地球科学》2018,43(9):3234-3251
江巴组火山岩是西藏雄梅地区近年来发现的火山岩,但其岩石成因尚不明确.通过开展系统的岩相学、地球化学、同位素定年示踪研究,结果表明英安质火山岩锆石U-Pb年龄为85.1±1.0 Ma,为晚白垩世.安山质和英安质火山岩显示出明显的埃达克质岩特征,主量元素显示出较高的SiO2和Al2O3含量及Mg#值;稀土元素整体呈轻稀土元素富集,重稀土元素强烈亏损,轻重稀土元素分异明显,（La/Yb）N值较高,无明显Eu异常;微量元素具有明显的高Sr,低Y、Yb和高Sr/Y值,相对富集Th、Zr和Hf,亏损Nb、Ta和Ti的特点;英安质火山岩锆石εHf（t）值均为正值,在+2.7~+7.1之间,指示有亏损地幔物质参与成岩作用;以上表明安山质和英安质火山岩可能形成于加厚新生下地壳拆沉的部分熔融并有亏损地幔物质的加入.流纹质火山岩具相对低的MgO、TiO2含量;LREEs富集、HREEs亏损,但轻重稀土元素分馏明显较安山质和英安质火山岩弱,微量元素富集Rb、Th和K,强烈亏损Eu,Sr,Ba,P和Ti,明显的负Eu异常,表明流纹质火山岩为地壳发生深熔而形成.综合对比江巴组火山岩的地球化学性质,表明班公湖-怒江缝合带中段昂龙岗日-班戈弧地区在晚白垩世期间存在一期板内加厚下地壳拆沉减薄事件.   相似文献   

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