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1.
云南星云湖沉积物正构烷烃记录的近代环境变化   总被引:2,自引:2,他引:0       下载免费PDF全文
为探讨气候变化与人类活动对湖泊环境影响在湖泊沉积中的记录,在云南星云湖水深8.2m处采集1支85cm长的柱状沉积岩芯,利用气相色谱-质谱联用仪(GC-MS)对沉积岩芯中的类脂物分子进行分析,揭示了近160年以来星云湖地区环境演变过程。分析结果表明沉积岩芯中的正构烷烃碳数分布C15~C35呈有规律变化:85~60cm深度表现为低碳数相对优势,60~32cm逐步变为以高碳数为优势,32~10cm高碳数较前阶段降低,10~0cm深度低碳数显现明显优势。同时,平均碳链长度(ACL)、高碳数同系物与低碳数同系物比值(H/L)以及C27/C31等结果还揭示出:近160年来湖泊沉积中有机物输入经历了内源低碳(1920s前)、外源高碳(1920s~1980s初)和内源低碳(1980s初~2004年)为优势的演变过程;在人类活动干扰较小状况下,H/L变化与气候的冷暖变化具有显著的对应关系,即H/L低值段明显对应于气候的相对寒冷期,H/L高值段明显对应于气候的温暖期。在1990年代以后,尽管气候持续变暖,但由于人类活动影响加剧,湖泊富营养化快速发展,H/L值却随之急剧降低,反映出沉积岩芯中的类脂物可敏感记录人类活动对湖泊环境变化的影响。  相似文献   

2.
分子地层学的原理、方法及应用实例   总被引:2,自引:1,他引:2  
当前分子地层学研究已涉及蛋白质、核酸、碳水化合物、类脂物和木质素等多种生物化学组分。在地层中,分子化石具有分布的广泛性、定量的准确性、应用的指纹性和信息的多样性等特点,其地层学应用的主要原理是依据分子化石的生物源信息和其离开生物体后发生的一系列转化途径来实现的,其表述方法可以是含量、相对丰度、碳数分布和单体同位素特征等。在各类年代学框架下,由这些分子化石参数所揭示的各类生物事件和环境事件可以成为区域性乃至全球性地层对比的主要依据。分子地层学与分子古生物学、生物地球化学、有机地球化学密切相关,它与传统三大地层学分支学科明显不同,目前还没有明确的分子地层单位,也没有进行广泛的分子地层划分与对比工作。对各类生物事件与环境事件有重要指示作用的分子地层学,与生态地层学、事件地层学等地层学分支学科类似,其主要任务是在传统生物地层学或其他年代学框架下,提高地层划分和对比的精度。以浙江长兴煤山二叠纪-三叠纪界线地层和第四纪泥炭为例,以高分辨率的生物事件与环境事件为切入点,分别探讨在生物地层学或其他年代学框架下的分子地层工作,由此提出了分子地层学的分类单位——分子化石带。  相似文献   

3.
泥炭分子化石单体碳氢同位素的古气候意义   总被引:9,自引:0,他引:9  
为了查明泥炭分子化石记录的古植被状况与古植物学分析结果的差异,并进一步探讨这些分子化石所记录的古气候信息,本文利用气相色谱仪(CC)、气相色谱—质谱联用仪(GC—MS)、气相色谱—燃烧-同位素比质谱仪(GC-C-IRMS)、气相色谱-热转换—同位素比质谱仪(CC—TC—IRMS)详细分析了一个40cm(约220年)长的泥炭岩芯中的分子化石及其单体碳、氢同位素组成。正构烷烃分子化石的主峰化合物(C23)及其碳、氢同位素组成与温度有很好的对应关系,工业革命以来化石燃料的燃烧效应也在单体碳同位素上反映出来。这些结果反映了泥炭分子化石具有很好的古气候和古环境意义。  相似文献   

4.
何大双  黄海平  侯读杰  张鹏辉 《地质学报》2020,94(12):3864-3878
为了进一步了解泥炭中脂类分子化合物的分布与植被演化和气候变化的响应关系,对采自加拿大阿尔伯塔省东北部阿萨巴斯卡地区的JPH4、Mildred和McMurray泥炭柱样品中的脂类分子进行测定。根据正构烷烃、正烷酮、甾类和萜类等分子化合物的地球化学分析,结合年代学资料,重建了研究区近千年来的古气候演化过程。现代暖期以来(1990年以来),区内大范围的锈色泥炭藓发育,指示温暖干旱的气候条件;现代暖期早期(1900年以来),陆源高等植物和狭叶泥炭藓共存于干- 湿交替的气候环境下;JPH4泥炭柱记录了小冰期期间寒冷干旱的气候环境,该时期莎草科等陆生维管植物发育;上述结论与前人记录的区域植被和气候变化具有较好的可比性。研究区发育的锈色泥炭藓种类特殊,多形成于干旱环境且具有C 31 正构烷烃优势分布,ACL、 P aq 、C 23 /(C 27 +C 31 )正构烷烃指标能够有效表征植被输入特征和气候变化。正烷酮主要来源于相应正构烷烃的微生物氧化作用,正烷酮指标CPI- ket、ACL- ket和(K 23 +K 25 )/(K 27 +K 29 +K 31 )有效地记录了泥炭沉积时期气候的演变过程。甾类、萜类化合物的丰度明显高于直链烷基类化合物,γ- 内酯/生育酚、C 29 甾酮/C 29 甾醇、甾醇/甾类化合物等指标能够初步应用于指示区域气候的干湿冷暖变化,微生物的改造作用可能会影响这些指标的分布。  相似文献   

5.
青藏高原东北部全新世泥炭正构烷烃的生物记录   总被引:2,自引:0,他引:2  
通过对正构烷烃分布特点的系统分析,恢复了青藏高原东北部全新世以来泥炭的生物记录。正构烷烃nC25和nC31相对含量在泥炭序列中呈现的规律性变化揭示出,在全新世期间因气候的变化幅度不同而引起了生物形态种或化学种的取代,即当气候变化幅度大时,沼泽地可能出现了水生植物和陆生植物群落之间的相互演替;当气候波动小时,则出现了分子(化学)种之间的相互取代。将这一研究结果与同一地区的孢粉资料对比、验证,分析了它们之间的差异性,提出了类脂分子化石可作为恢复植被的有效工具,与孢粉相结合,可获取更为全面的植被演化历史。这一研究为青藏高原地区全新世以来的有关生物学信息提供了新的证据。  相似文献   

6.
天目山泥炭类脂物记录的微生物特征和植被演替   总被引:3,自引:0,他引:3  
为进一步了解泥炭中微生物特征和植被的变化,对采自浙江天目山的样品进行了类脂生物标志物与有机碳同位素(δ13Corg)的测定。有机碳δ13Corg值整体偏负,显示C3植物占优势的特点。正构烷烃的分布特征表明,大多数样品来源于陆生高等植物和低等菌藻类生物,其中高碳数正构烷烃主要以C29为主峰,显示植被类型以木本植物为主,但草本植物的相对比例也发生了多次变化,且这种变化与有机质的相对贡献量密切相关。在深度100~68cm,不同来源的有机质,特别是低等菌藻类的相对贡献量都相对较少;在深度68~30cm,低等菌藻类生物的贡献逐渐变大;而表层泥炭的有机质主要来源于高等植被,菌藻类的输入较少。泥炭有机碳同位素与类脂生物标志物的综合特征表明,该区植被经历了几次明显变化,并据此可将研究区中全新世以来环境演化分为早(4100~3200aB.P.)、中(3200~700aB.P.)、晚(700aB.P.以来)三个环境演化阶段,其结论与前人的环境演化与全球气候变化研究具有较好的可比性。  相似文献   

7.
大气环境变化的泥炭地质档案   总被引:2,自引:0,他引:2       下载免费PDF全文
雨养泥炭沼泽是一种重要的泥炭沼泽类型,具有全球广泛分布的特点,其养分补给主要源于大气降水(包括雨、雪和空气尘埃).它是一个记录大气环境变化的积极的信息储备系统,记录有大气输入的海盐气溶胶、沙尘颗粒、酸沉降、重金属和有机污染物等信息.采用地质定年技术将泥炭深度剖面转化到年代坐标上,并结合泥炭生物地球化学指标检测分析,提取...  相似文献   

8.
根据青藏高原东北部甘肃南部郎木寺泥炭总有机碳含量的时间序列,重建了该区7.3~4.0kaB.P.(中全新世)期间气候演变的历史,其中较为显著的变冷事件分别集中在6.8cal.kaB.P.,5.0cal.kaB.P.和4.3cal.kaB.P.。同时分析了3个不同深度的泥炭脂类分子化合物。结果表明,正构烷烃和直链烷基-2-酮都由长链组分所构成,具有明显的奇碳优势和很高的碳优势指数值(CPI>5)表明,这些长链组分来自草本高等植物。样品中还检出脂肪酸甲酯系列,也以长链组分为主,可能是沉积早期生物地球化学作用的产物。异构烯烃的存在及菲系列化合物低的甲基菲指数(MPI)和镜质体反射率(Rc)值,说明样品受成岩作用的影响很小而且几乎没有遭受现代的污染,即泥炭保存完好,各个指标可以真实反映泥炭的组成、性质及其形成时的环境条件。根据总有机碳含量的时间序列和不同阶段样品中的脂类分子化石的组合特征,探讨了各阶段气候和植被的演化特征。  相似文献   

9.
为进一步理解中国南方岩溶区现代土壤生物有机地球化学演化规律,对采自湖北清江流域典型岩溶洞穴上覆土壤开展了系统的分析。分别采用稳定同位素质谱仪(MAT-251)与气相色谱质谱仪(GC-MS)测试了样品中的有机碳同位素与生物标志物指标。其中有机碳同位素值(δ13Corg)在-28.3‰~-27.4‰之间变化,并随深度的增大呈逐渐正偏的趋势,指示了当地的植被类型自土壤层形成以来主要为C3植物。而可抽提有机质的总量、正构烷烃高碳数奇偶优势(CPIh值)、高碳数与低碳数含量比值(Rh/l值)、平均链长(ACL值)以及脂肪酸C16:1/C16:0等指标随土壤剖面深度的增大呈现逐渐降低的趋势,与土壤有机碳同位素的变化趋势基本一致,说明岩溶地区表层土壤中有机碳同位素和生物标志物均与土壤层内微生物活动的强弱密切相关。另一方面,也暗示了有机碳源是制约岩溶地区土壤微生物活动的重要因素之一。为进一步深入理解湖北清江和尚洞洞穴石笋记录提供了新的思路。  相似文献   

10.
新疆干旱区柴窝堡湖沉积记录的150年来气候环境特征   总被引:6,自引:5,他引:1  
通过乌鲁木齐附近柴窝堡湖钻孔岩芯的粒度、有机质含量、化学元素以及同位素等多项分析,开展了研究区近150年来的气候环境演化研究.通过沉积记录与器测气象资料比较,认为沉积物的有机质含量反映了流域降水的变化,而有机质碳同位素的变化则与温度相关.在运用有序样品最优聚类分析对沉积物地球化学元素序列进行阶段划分的基础上,综合粒度、有机质含量以及同位素等多环境代用指标的分析,恢复了不同阶段的气候环境信息.结果表明,1860~1910A.D.,各环境指标显示当时湖泊水位较高,湖水较深,显示偏冷、偏湿的气候环境特征.1910~1950A.D.,粒度、地球化学元素、有机质、磁化率等指标波动明显,虽然有机碳同位素值有所升高,但仍然总体偏负,显示该阶段湖泊环境总体上波动强烈,气候不稳定.其中约1920A.D.左右,粒度显示突然变化,有机碳同位索、烧失量、元素含量等也均发生了显著的波动,指示明显气候环境事件的存在.1950A.D.以来,钻孔岩芯的磁化率升高,重金属元素含量以及总磷含量呈现明显富集,而有机质及其碳同位素变化却与器测温度和降水变化一致,指示了近期气候和人类活动对湖泊环境的影响.  相似文献   

11.
A number of studies have revealed that the climate in the eastern margin of the Tibetan Plateau and Northeast China is sensitive to postglacial changes. Unfortunately, the link of the past climate evolution between the two regions is not well understood. In this study, two cores are analyzed to determine this link directly. The high-resolution n-alkanol distribution patterns from two typical peat sequences covering the past 16,000 cal years in the northeastern margin of the Tibetan Plateau and Northeast China, respectively, are closely examined by gas chromatograph–mass spectrometry analysis. In combination with other palaeoclimatic proxies, it is proposed that the n-alkanol average chain length and (C22 + C24)/(C26 + C28) ratio could reflect past climate changes in the two peat sequences. The n-alkanol proxies reveal several climatic intervals in the period from the last deglaciation through the Holocene. A comparison of n-alkanol records between the northeastern margin of the Tibetan Plateau and Northeast China indicates that the start and end of the warm Holocene Optimum differed at the two locations. The spatially asynchronous pattern of climatic change is possibly a result of different responses to change in solar radiation. The evolution of the Holocene paleoclimate is more consistent with changes in Northern Hemisphere solar radiation in Northeast China than on the Tibetan Plateau. The Holocene Optimum began and terminated earlier in Northeast China than in the northeastern margin of the Tibetan Plateau. Thus, the two n-alkanol proxies provide valuable insights into the regional Holocene climate and local environmental conditions.  相似文献   

12.
Most research on long chain methyl ketones has focused on their origins and distributions. Their application in paleoclimate studies is less common than that of other n-alkyl lipids. The goal of this research was to explore this potential by studying n-alkan-2-ones from the Hani peat sequence in northeastern China. They were identified using gas chromatography-mass spectrometry (GC-MS) and showed a distribution ranging from C19 to C31 with a strong odd/even predominance. This type of distribution is considered to derive from Sphagum and microbial oxidation of n-alkanes. Comparison with climate sensitive indicators and macrofossil analysis shows that microbial oxidation of n-alkanes derived from higher plants was enhanced during the warm early Holocene period. This led us to develop three n-alkan-2-one proxies - C27/ΣC23-31 (C27/HMW-KET), carbon preference index (CPIH-KET) and average chain length (ACL(27-31)-KET) - as possible indicators of paleoclimate in the peat-forming environment. These proxies, in combination with C27n-alkane δD values and peat cellulose δ18O records, might allow examination of paleo-ecosystem behavior during climatic evolution in northeastern China over the past 16,000 yr.  相似文献   

13.
安徽宣城更新世红土正构烷烃分布特征及其古植被意义   总被引:7,自引:1,他引:6  
利用气相色谱一质谱联用仪(GC-MS)在安徽宣城更新世红土中检测出了微量的分子化石,包括正构烷烃、一元正脂肪酸、一元正脂肪醇以及α-正构脂肪酮等.正构烷烃的分布型式表明其来源于低等菌藻类生物和陆生高等植物,其中高碳数正构烷烃主要以C29为主峰,显示流域中的植被类型以木本植物为主;(C27 C29)/(C31 C33)比值的变化反映出,在以木本植物占优势的背景下,流域中草本植物的相对比例也发生了多次变化.这一比值在本剖面上表现出多阶段的变化.而且这种变化与岩性、粒度变化密切相关,反映出这些参数可能还蕴涵着古气候信息.  相似文献   

14.
猪野泽记录的季风边缘区全新世中期 气候环境演化历史*   总被引:4,自引:16,他引:4  
通过季风边缘区石羊河古终端湖猪野泽QTL剖面年代学及沉积物粒度、碳酸盐、有机碳、碳氮比和有机质稳定同位素等多项气候代用指标的综合分析,建立了季风边缘区9~3cal.kaB.P. 的古气候演化序列。结果表明,9cal.kaB.P. 到7.8cal.kaB.P. 期间,流域的水分条件和温度逐渐上升,植被状况好转,此时气候逐渐转暖湿;而在7.8~7.5cal.kaB.P. 出现了显著的百年尺度的干旱事件,沉积物主要以砂质沉积为主,此时湖泊生产力显著下降;全新世期间最为暖湿的气候适宜期出现在7.5~5.0cal.kaB.P.;约5.0cal.kaB.P. 以来,该区域出现了较为明显的干旱化趋势。另外,对猪野泽地区的白碱湖的湖泊地貌学和年代学研究表明该区域在7.5~5.0cal.kaB.P. 出现了3次高湖面,并且湖岸堤时序变化指示了全新世后半期湖泊逐渐退缩的过程进而指示该区域出现了显著的干旱化趋势。  相似文献   

15.
测定了新疆罗布泊地区湖相沉积物CK-2钻孔样品的总有机碳含量(TOC)及其同位素组成、碳酸盐含量和C/N比值等环境代用指标,以及石膏矿物的质谱-铀系年龄。测试结果表明,20~9kaB.P.期间沉积物δ13Corg.在-23.4‰~-16.1‰之间波动且阶段性明显,与TOC呈现良好的相关关系,整体变化趋势同南极Dome C冰芯中记录的全球大气CO2浓度一致;C/N比值表明有机碳来源主要是陆生高等植物。因此大气CO2浓度变化是影响20~9kaB.P.期间罗布泊湖相沉积物δ13Corg.值变化的主导因素,周围山体上C3/C4植物相对生物量的变化则是另一重要因素。依据δ13Corg.的变化序列将此时间段湖区古环境的演化分成6个阶段:20.0~14.1kaB.P.期间受到末次盛冰期的影响,气温偏低,湖水丰沛;14.1~13.3kaB.P.是一个气候不稳定期,冷暖波动较频繁,但以暖为趋势;13.3~12.8kaB.P.期间经历了一段冷期,于12.8kaB.P.结束了末次冰期,随后气候开始转暖至11.8kaB.P.;其后气温再次变冷并维持到10kaB.P.;最后从10kaB.P.进入全新世暖期。δ13Corg.序列明显向偏负方向变化,表明该地区变暖的趋势相当明显。罗布泊地区日益干旱化是全球气候变化的结果,尤其是受到全球CO2浓度的不断升高所制约。  相似文献   

16.
Based on paleoclimatic reconstructions using various proxies, the Holocene Climate Optimum (10.5–6 ka) has been characterized as a warmer and wetter period in most of East Asia. The summer monsoons associated with the East Asian Monsoon evidently intensified and extended further inland from the Pacific Ocean, a source region of moisture. A notable exception to this general pattern exists in northeast China, where less wet conditions are recorded. We determined molecular compositions of individual plant wax hydrocarbons and their hydrogen isotope compositions (δD values) in a radiocarbon-dated peat core recovered from the Hani marsh in Jilin Province (China) and confirmed that the temperature-dependent effective precipitation in northeast China decreased during the Holocene Climate Optimum. A combination of Paq, an indicator of the relative contribution of aquatic to terrestrial plants, and the difference in δD between low (C23, C25 and C27) and high molecular weight (C31) n-alkanes in the Hani peat bog indicates a dramatic change in vegetation from the deglaciation to the Holocene. No significant differences were observed between the δD values of low and high molecular weight n-alkanes with relatively high δD values and low Paq during the early Holocene, indicating that all n-alkanes were produced by evapotranspiration-sensitive terrestrial plants during that time. However, lower δD values of mid-chain n-alkanes (C23, C25 and C27) relative to the long chain n-alkane (C31), together with higher Paq values during the deglaciation (14–11 ka), suggest an increase in the contribution of aquatic plants and a higher water level during the period. The study demonstrates that northeast China was under a markedly wetter climate condition during the late deglaciation. For the 16 kyr record in the Hani peat sequence, we infer that moisture delivery by the East Asian Monsoon was relatively invariable in northeast China, but increased evaporation during the warmer Holocene Climate Optimum reduced the effective precipitation, defined by the balance between precipitation and evaporation.  相似文献   

17.
结合含水量、TOC含量和TOC/TN比值变化曲线,18·5kaB·P·以来的四海龙湾玛珥湖沉积物全岩有机碳同位素组成(δ13CTOC)记录可划分为3个阶段:1)末次冰期晚期(18·5~14·7kaB·P·),δ13CTOC值偏正,变化范围为-29·50‰~-26·18‰,平均值约为-28·10‰;2)末次冰消期(14·7~11·7kaB·P·),δ13CTOC值显著偏负,变化范围为-33·92‰~-28·40‰,平均值约为-31·75‰,在δ13CTOC值变化曲线上表现为一个低谷,但在类似YoungerDryas的冷干事件期间(12·7~11·7kaB·P·),δ13CTOC值再次显著偏正,最高可达-28·4‰;3)全新世以来(11·7kaB·P.至今),δ13CTOC值变化幅度不大(-30·85‰~-27·37‰),基本上都在平均值-29·1‰左右。研究表明,大气CO2浓度变化是影响18·5kaB·P·以来四海龙湾玛珥湖δ13CTOC值变化的主导因素。  相似文献   

18.
Bulk geochemical characterization (total organic carbon, grain size distribution, carbon isotope composition) and molecular biomarkers (lignin phenols, straight chain aliphatic hydrocarbons, glycerol dialkyl glycerol tetraethers) were analyzed for a 21 m core from the Bohai Sea (North China), spanning ca 21 ka BP. These paleo-proxies presented remarkable differences between the late glacial period and the Holocene, reflecting continental and coastal environments, respectively. Two peat layers were deposited during the period of ca 9000-8460 yr BP. Thereafter the core site has been consistently covered by seawater until recent reclamation of land from the sea. The occurrence of a total organic carbon maximum from ca 6000-3800 yr BP was attributed to delivery of organic carbon enriched sediments via the Yellow River, consistent with increased vegetation density and higher development of soil under warm and humid mid-Holocene climate conditions. The distributions of lignin phenol compositions and C31/C29n-alkane ratio suggested the largest expansion of woody plants between ca 5300 and 4000 yr BP, corresponding to the extremely favorable climatic conditions. Since ca 3800 yr BP, an abrupt increase in the C31/C29n-alkane ratio suggested higher abundance of grasses, consistent with a drying climate trend after the mid-Holocene. Since our coastal sediments close to the Yellow River outflow contain catchment-integrated environmental signals of the river basin, molecular proxies demonstrate that the variability of vegetation distributions in the Holocene is a widespread phenomenon in those areas adjacent to Yellow River Basin.  相似文献   

19.
There has been much recent debate about Holocene climate variation in the monsoon region of China, especially the temporal pattern of variations in precipitation, the time-transgressive nature of the Holocene precipitation maximum, and the extent to which variations in regions influenced by the Indian Summer Monsoon (ISM) and the East Asian Summer Monsoon (EASM) have been synchronous. We summarize and compare carbonate oxygen-isotope records (δ18Ocarb) from ten lakes within the present-day ISM region. We discuss their paleoclimate significance considering the present-day moisture source, isotopic composition of precipitation and the hydrological setting. The δ18Ocarb records are controlled mainly by the isotopic composition of lake water, which in turn is a function of regional Precipitation/Evaporation (P/E) balance and the proportion of precipitation that is monsoon-derived. We normalized the δ18Ocarb data and used these records to generate an integrated moisture index. This index, along with oxygen-isotope records from speleothems and carbon-isotope records (δ13Corg) from peats within the monsoon region, suggests that Holocene climate was broadly synchronous across the monsoon region and, within the limits of accuracy of the existing age models, provides no strong evidence for previously-proposed anti-phasing of the ISM and the EASM. Stable-isotope records from lake sediments and peat bogs have excellent potential for providing high-quality paleoclimate data for monsoon Asia, and complement high-resolution speleothem sequences, which are only found in certain localities.  相似文献   

20.
High resolution records of long chain n-alkanol biomarkers were obtained from a peat-lacustrine core from the Dingnan profile in southern China. The n-alkanol distributions are characterized by the predominance of even-over-odd carbon number and maximize at C24 or C26. On the basis of the reported n-alkanol records in the literature and the n-alkane record in our samples, we concluded that the n-alkanol ratio of C26/C30 varying from 1.25 to 6.48, together with the n-alkanol ratio C22/C24 less than unity, is indicative of the presence of a dominant forest paleovegetation. A 2000-year cycling in the variation of the n-alkanol ratio C26/C30 is identifiable in our profile, and probably results from the change in the abundance of the grass relative to trees induced by a cyclic paleoclimate. The n-alkanol ratio C24/C26 appears to be more sensitive to change in precipitation than in temperature, and may be a potential indicator of precipitation/humidity, with increased values being associated with relatively dry conditions. The paleovegetation and the paleoclimate reconstructed on the basis of the n-alkanol records for the recent 18000 cal a BP in general accord with the pollen data and other lipid evidence recorded in the Dingnan region in southern China. In particular, both the n-alkanol records and the pollen data infer the different paleoclimate conditions for the two peat sequences, with a cool and wet climate dominating in the lower peat deposition formed during the latest Pleistocene and a change to a drier and cooler climate occurring in the upper peat sequence in mid-Holocene.  相似文献   

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