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1.
贵州半坡锑矿床卤素元素地球化学研究   总被引:4,自引:1,他引:3  
潘家永  张乾 《地质与勘探》1998,34(6):33-36,43
半坡锑矿矿石及近矿围岩中Br与I含量很高,分别是地壳丰度值的数十倍至数百倍,这在热液矿床是十分罕见的,从远矿围岩→近矿围岩→矿石,Cl,Br,I含量有规律地增高,而F主要富集在近矿蚀变围岩中,F,Cl,Br,I在矿石与近矿蚀变岩中富集表明这些元素很可能能作为建筑该类隐优矿体的指示元素。  相似文献   

2.
贵州低温汞锑矿床卤素元素地球化学特征及其找矿意义   总被引:1,自引:0,他引:1  
潘家永  张乾 《贵州地质》1998,15(3):259-262
本文对贵州万山汞矿,独山半坡锑矿卤素元素地球化学特征进行了较系统的研究,研究表明,Br与I在矿区赋矿围岩,蚀变岩及矿石中都有不同程度的富集,从赋矿围岩→蚀变岩→矿石。其含量明显升高,而F,Cl主要富集于蚀变岩中,在隐伏矿体上部围岩中,F,Cl,Br,I都有异常显示,这种卤素元素异常对寻找隐伏矿体具有指示意义。  相似文献   

3.
卡林型金矿指示元素研究   总被引:5,自引:2,他引:5  
研究表明,卡林型金矿带中金矿及其共生的低温Hg、As、Sb矿床中普遍含有较高的Tl、F、Cl、I和B,这些元素与金有明显的相关性,它们含量变化从远矿赋矿岩→近矿围岩→矿化岩→矿石明显呈依次递增趋势。根据矿床岩矿石中Tl、F、Cl、I和B的含量变化和分布特点及其与Au的相关性,尝试把富集系数和铊含量作为指示元素的应用指标。富集系数〉5、5 ̄0.5和0.5 ̄0.1分别为矿床,矿田和矿带标志;铊含量〉1  相似文献   

4.
万山汞矿卤素元素地球化学特征及其地质意义   总被引:5,自引:1,他引:4  
本文对万山汞放卤素元素地球化学特征进行了较系统的研究。研究表明,Br与1在矿区赋矿城、蚀变岩及矿石中都不同程度富集,从赋矿围岩→蚀变岩→矿石,含量明显升高,而F与Cl主要富集于蚀变岩石中,在隐伏矿体上部围岩中,F、Cl、Br、1都有异常显示,这种卤素元素异常对寻找隐伏矿体具有指示意义。  相似文献   

5.
明矾石矿床中钒、镓萃取实验和综合利用的建议   总被引:5,自引:0,他引:5  
梁祥济  王福生 《矿床地质》1999,18(3):276-284
通过对浙江平阳矾山明矾石矿山矿石利用率低、环境污染十分严重的调查和深入研究该明矾石矿床野外地质、采矿工艺及分析岩石、矿石中有用元素含量的基础上,提出了矿床综合利用的建议。同时,对达到回收品位的钒(V)、镓(Ga)稀有金属进行了萃取实验。实验采用天然的明矾石矿石、矾化围岩和提炼明矾后的废料-矾浆、矾碴和炉灰作为试料,配制含一定浓度的HCl、HBr、HClO4、HF、C6H6O8和C6H5CH3等不同  相似文献   

6.
卤素和硼—金锑砷汞铊矿床指示元素   总被引:4,自引:1,他引:4  
张忠  张宝贵 《矿物学报》1995,15(2):192-198
本文通过205个样品,820个F、Cl、I、B分析数据讨论它们在Au、Sb、As、Hg、和Tl矿床中含量变化、富集程度及与矿的关系,特别是与Au、Tl成矿的密切关系,提出卤素和硼是低温矿床有重要意义的指示元素。它们在矿床岩矿石中含量,除个别样品外,一般富集系数均在0.n ̄n范围变化。  相似文献   

7.
对浙江遂昌地区所发现的金(银)矿床之矿物包裹体研究表明,其均一化温度多集中在140~260℃,成矿压力(0.2~0.6)×102MPa,气液比在5%~27%。成矿流体为液态,矿液中主要有Au,Ag,Cu,Pb,Zn,Bi,K,Na,Ca,Si.Mg,H2O,CO2.Cl,F,S,Mn,Li.Ti,Cr,Co,Ni等组分。成矿时的含矿流体呈弱酸性─中性(pH4.56~5.14),盐度较高(NaCl(20~32)wB%).根据这些特征,并综合其产出的大地构造环境及成矿地质条件,认为该区所产出的金(银)矿床在成因上属地洼型火山─次火山中(─低)温热液矿床。  相似文献   

8.
八庙-青山金红石矿床地球化学特征   总被引:6,自引:0,他引:6  
徐少康 《矿产与地质》1999,13(5):293-298
金红石矿床含矿岩石常量元素总体上与玄武岩接近,但以低硅,高钛,高CO2,高碱度为特征。矿床微量元素与地壳的差别显著,稀土元素较高,分布模式呈轻稀土富集型,Eu一般为正常型与碧玄岩最接近,Ti与Ba,Co,Pb,Sr,Th,V,Y及稀土元素呈正相关与Cr和Ni呈负相关,δ^34S多数与(超)铁镁质岩石接近,最大值小于且靠近现代海水。  相似文献   

9.
热水解离子色谱法测定地质物料中的卤族元素   总被引:1,自引:0,他引:1  
报道了一种快速,高效和无干扰测定地质物料中卤族元素的热水解离子色谱方法及热水解装置,该方法F^-,Cl^-,Br^-的检出限分别为1.4,1.7,15.5μg/l,方法的精密度(RSD%),F^-,Cl^-,Br^-,I^-分别为1.4,0.88,2.34,3.82。  相似文献   

10.
游云飞  陆士立 《铀矿地质》1994,10(6):367-371
本文介绍了汞热释谱技术及在找铀矿、金矿中的应用。其主要内容是;成矿期石英的HgS/HgCl2比值的R>1,而矿前期石英R<1;岩石的矛热释话通常为低温(<280℃)普通峰,而矿石、矿物的汞热释谱则为中温(280—600℃)、高温(600—800℃)特征峰;在矿床中汞化合物具有水平分带性:HgS在内带,HgCl2在外带;成功地应用于对硅化带合矿性评价。  相似文献   

11.
The Zimudang gold deposit is a large Carlin‐type gold deposit in the Southwest Guizhou Province, China, with an average Au content of 6.2 g/t. Gold is mainly hosted in the fault zone and surrounding strata of the F1 fault and Permian Longtan Formation, and the ore bodies are strictly controlled by both the faults and strata. Detailed mineralogy and geochemistry studies are conducted to help judge the nature of ore‐forming fluids. The results indicate that the Au is generally rich in the sulfides of both ores and wall rocks in the deposit, and the arsenian pyrite and arsenopyrite are the main gold‐bearing sulfides. Four subtypes of arsenian pyrite are found in the deposit, including the euhedral and subhedral pyrite, framboidal pyrite, pyrite aggregates and pyrite veins. The euhedral and subhedral pyrite, which can take up about 80% of total pyrite grains, is the dominant type. Au distributed unevenly in the euhedral and subhedral pyrite, and the content of the Au in the rim is relatively higher than in the core. Au in the pyrite veins and pyrite aggregates is lower than the euhedral and subhedral pyrite. No Au has been detected in the points of framboidal pyrites in this study. An obvious highly enriched As rim exists in the X‐ray images of euhedral pyrites, implying the ore‐forming fluids may be rich in As. The relationship between Au and As reveals that the Au may host as a solid solution (Au+) and nanoparticles of native gold (Au0) in the sulfides. The high Co/Ni ratio (>1) of sulfides and the enrichment of W in the ores all reflect that the gold‐bearing minerals and ore‐forming process were mainly related to the hydrothermal fluids, but the magmatic and volcanic activities cannot be neglected. The general existence of Au and As in the sulfides of both ores and wall rocks and the REE results suggest that the ore‐forming fluids may mainly be derived from the basin itself. The enrichment of Tl suggests that the ore‐forming fluids may be enriched in Cl. The Ce and Eu show slightly or apparently negative anomalies, which means the ore fluids were probably formed under reducing environment. The Y/Ho ratios of ore samples fluctuate around 28, implying the bicarbonate complexation and fluorine were both involved in the ore‐forming process. Combined with the previous studies and our results, we infer that the ore‐forming fluids enriched Au, As, HS? and halogen (F, Cl) were derived from the mixture of reducing basinal fluids and magmatic or volcanic hydrothermal fluids.  相似文献   

12.
Halogen elements play an important role in the metallogenesis of metallic ore deposits and are involved in the whole process of remobilization, transport and precipitation of metallic elements. However, with the exception of fluorine, which, as a component of fluorite and mica minerals, can be occasionally concentrated in ores, Cl, Br and I are hard to enrich in the ores. Investigations have found that the halogen elements tend to diffuse toward country rocks with the development of hydrothermal alteration in the process of their involvement in metallogenesis, especially during the post-ore stage when extensive halogen diffusion halos over orebodies would be formed. Such halogen element diffusion halos over the Chadong As–Ag–Au deposit extend as widely as 200 m. The largest diffusion extent is for I and the diffusion halos of Br are most noticeable 50–130 m away from the orebodies. In areas of ore exposure and the strongly altered zone, the Cl, Br and I contents are close to those of the strata with a V-shaped distribution pattern in the periphery of the mining district. Comparatively speaking, in going away from the altered zone, the major metallic elements Au and Ag in the deposit tend to decrease suddenly to their normal contents in the strata. This variation feature of halogen elements can be used as geochemical indicators for exploring concealed orebodies at depth. In the Chadong ore deposit, halogen element anomalies can be used to predict concealed orebodies at the depth range of 0–200 m.  相似文献   

13.
湘西南漠滨地区元古界地层地球化学研究   总被引:1,自引:0,他引:1  
孙承辕  张干 《物探与化探》1992,16(4):295-303
本文研究了湘西南漠滨地区元古界板溪群五强溪组地层中金的分布、微量元素地球化学及其与金的成矿关系,研究表明,本区五强溪组呈现明显的金亏损,而地层则具有富As、Sb,贫Hg、Sr,以及Co/Ni比值大于 1、Au/Ag及 Sr/Ba比值低的地球化学特点。金的分布在空间上有一定变化规律,从远离矿区的地层岩石到矿床内部的脉旁围岩,根据其丰度高低,相应地划分出背景区—亏损区—富集区—亏损区—富集区五个区段,后四者组成一个共轭体系。两次金亏损都是水热淋滤作用的结果,但二者在形成的时间、规模及地球化学特征上都存在显著差异。这种淋滤的阶段性,导致了漠滨金矿床的两期成矿作用。金以及其他成矿元素的亏损区或亏损带的出现有一定普通性,因而对找矿具有重要的指导意义。  相似文献   

14.
文章较为全面地总结了卡休他他铁(金、钴)矿床的地质特征,并通过元素地球化学分析,探讨了该矿床的成矿作用与形成规律。卡休他他中型铁矿床由南、北2个矿带组成,共圈定24个铁矿体,其中以北矿带的3号矿体规模最大,其长约1300m,厚12.9~57m,斜深近200m。铁矿体的产出严格受辉长岩与震旦系浅变质岩接触带附近的矽卡岩控制。钴矿体在南、北矿带铁矿体和矿体外围的矽卡岩带中均有产出,金矿体则全部产出于北矿带矽卡岩带中,金和钴矿体在空间产出上与绝大多数铁矿体并不一致,它们主要与金属硫化物具有密切的成生关系,因此它们的形成可能晚于磁铁矿。元素地球化学分析结果表明,矿区内南、北矿带总体上是同一期成矿作用的产物,它们的少数成矿元素含量和矿石磁性之间的差别,可能与南矿带曾遭受后期二长岩侵入活动的影响,造成了部分成矿元素(如Au、Cu等)的活化迁移有关。卡休他他铁、金和钴矿的形成可能是同一成矿事件中不同阶段的产物,磁铁矿体属于早期岩浆气液阶段接触交代的产物,而钴和金的富集则可能是稍后的中高温热液阶段的产物。因此,卡休他他铁矿床属于接触交代型或矽卡岩型。  相似文献   

15.
该文以山东招远大尹格庄金矿床中微量元素为研究对象,通过对矿床围岩、矿石等微量元素的研究,表明大尹格庄金矿围岩中微量元素以富含 Bi,Au,Pb,W,Ag,Sn 为特点,矿体和矿化体中元素组合为 Au,Ag,As,Sb,Hg,B, Cu,Zn,Bi,Mo,Mn,Co,Ni,W。在5个成矿阶段中,第二阶段与第三阶段微量元素的富集程度较明显,表现为 Au, Ag,As,Co,Bi,Cu,Pb,Zn 等的富集,成矿元素可分为2个分带序列,主成矿元素为 Au Ag Cu Pb Zn Bi 组合、头晕元素 As Sb Hg 组合和尾晕元素 Co Ni 组合。  相似文献   

16.
笔者简单介绍了乔夏哈拉铜(铁)金矿床的基本成矿及其微量元素地球化学特征,指出其主矿体具有“垂向分带”及“铜、金向下同步富集”的特点,认为其容矿火山岩与中基性侵入岩脉具有基本相似的微量元素地球化学行为,铜、金矿石同其容矿火山岩相比具有相对贫K、Rb、Th、Ba,相对富W、Ni、Co、As、Sb、Zn及明显偏低的Th/Ta、La/Yb值。研究稀土元素地球化学,发现铜、金矿石具有明显不同于其容矿火山岩的强Eu富集,后期形成的地质体一般具有相对更为偏低的∑REE值。综合分析表明,该铜(铁)金矿床为一与“层状夕卡岩”有关的火山热液型“层控”矿床。  相似文献   

17.
内蒙古乌努格吐山斑岩型铜钼矿床元素迁移定量探讨   总被引:2,自引:0,他引:2  
元素的富集贫化是矿床中固有的客观规律。在以往相关研究中, 研究者们多从定性的角度对此进行讨论, 定量研究不够系统。本文以内蒙古乌努格吐山斑岩型铜钼矿床为例, 利用Grant方程, 定量探讨了该矿床蚀变围岩中元素的带入、带出特征。结果表明, 不同元素的质量迁移在矿化蚀变范围内表现出一定的规律性, 相对于原岩而言, 各蚀变带中Cu、Mo、Au、Ag、W、Sn、As、F、Hg、S等表现为明显的带入特征, 而CaO、Na2O、TiO2、Zr、Ba、Sr、Rb和REE则表现为明显的带出特征。这些元素的带入带出导致矿床及蚀变围岩中元素的富集贫化。元素质量迁移定量计算思路和方法, 为地球化学勘查向定量化方向发展提供了可行的途径。  相似文献   

18.
New data on the mineral composition and the first data on the geochemical composition of ores of the Rogovik gold-silver deposit (Omsukchan ore district, northeastern Russia) have been obtained. Study of the regularities of the spatial distribution of ore mineralization shows that the deposit ores formed in two stages. Epithermal Au-Ag ores of typical poor mineral and elemental compositions were generated at the early volcanic stage. The major minerals are low-fineness native gold, electrum, acanthite, silver sulfosalts, kustelite, and pyrite. The typomorphic elemental composition of ores is as follows: Au, Ag, Sb, As, Se, and Hg. The content of S is low, mostly < 1%. Silver ores of more complex mineral and elemental compositions were produced under the impact of granitoid intrusion at the late volcanoplutonic stage. The major minerals are high-Hg kustelite and native silver, silver sulfosalts and selenides, fahlore, pyrite, chalcopyrite, galena, and sphalerite. The typomorphic elemental composition of ores is as follows: Ag, As, Sb, Se, Hg, Pb, Zn, Cu, and B. The content of S is much higher than 1%. The ores also have elevated contents of Mo, Ge, F, and LREE (La, Ce, and Nd). At the volcanoplutonic stage, polychronous Au-Ag ores formed at the sites of the coexistence of silver and epithermal gold-silver mineralization. Their specific feature is a multicomponent composition and a strong variability in chemical composition (both qualitative and quantitative). Along with the above minerals, the ores contain high-Hg gold, hessite, argyrodite, canfieldite, orthite, fluorapatite, and arsenopyrite. At the sites with strongly rejuvenated rocks, the ores are strongly enriched in Au, Ag, Hg, Cu, Pb, Zn, Ge, Se, La, Ce, Nd, S, and F and also contain Te and Bi. The hypothesis is put forward that the late silver ores belong to the Ag-complex-metal association widespread in the Omsukchan ore district. A close relationship between the ores of different types and their zonal spatial distribution have been established. In the central part of the Rogovik deposit, epithermal Au-Ag ores are widespread in the upper horizons, Ag ores are localized in the middle horizons, and rejuvenated polyassociation Au-Ag ores occur at the sites (mostly deep-seated) with ore-bearing structures of different ages.  相似文献   

19.
通过对额仁套勒盖银矿床卤素和Ag的研究,发现卤素在银矿床中具有明显的水平和垂直分带现象,地表和近地表矿石相对富Cl和I,深部矿石相对富F;矿体中相对富Cl和I,近矿围岩中相对富F。卤素与Ag有密切的关系。但是矿石类型不同,卤素与Ag的关系也不同,F与Ag多为负相关,Cl与Ag,I与Ag多为正相关。表明卤素在银的活化、溶解、长距离迁移和沉淀富集过程中可能起着非常重要的作用。  相似文献   

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