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湘西—黔东下寒武统铅锌矿床流体包裹体和硫、铅、碳同位素地球化学特征 总被引：5，自引：0，他引：5
湘西—黔东下寒武统铅锌矿床位于湘西—鄂西成矿带西南部湘黔边境地区,是一类产于寒武系清虚洞组藻灰岩中的铅锌矿床。对李梅、狮子山、嗅脑、卜口场4个矿床开展了流体包裹体及硫、铅、碳同位素地球化学分析,分析结果表明:铅锌矿石流体包裹体具有低温、中-高盐度特点;硫化物δ34S值较高;围岩及方解石的δ13C、δ18O组成均为正常海相碳酸盐的碳、氧同位素组成;矿石与围岩的铅同位素组成变化范围不大,所有铅同位素数据在207Pb/204Pb-206Pb/204Pb图中呈线性分布。综合分析认为,湘西—黔东下寒武统铅锌矿床成矿流体可能为区域迁移流体与地层封存水构成的混合流体,成矿物质大部分来源于碳酸盐岩围岩地层,可能有部分Pb、Zn等金属元素随区域迁移流体带入,矿床的形成可能为两种来源流体混合后Pb、Zn等金属元素因物理化学条件的改变而沉淀成矿,矿床成因类型应为密西西比型铅锌矿床。 相似文献
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黔西北成矿区为川滇黔接壤矿集区的重要组成部分之一,但该地区以往未见有大型以上铅锌矿的报道。近些年来,贵州科技工作者在五指山地区取得重大的找矿突破,发现多个大中型铅锌矿床,提交铅锌金属资源量超过250万吨。为了使地质工作者更好地认识该矿田铅锌矿成矿作用,并为研究区及邻区找矿预测提供理论依据,本文系统总结五指山地区铅锌矿近些年的研究进展,并与川滇黔与湘西-黔东地区铅锌矿床从地质、地球化学以及成矿时代进行对比,尝试探讨五指山地区铅锌矿成矿带归属。地质和地球化学的综合研究表明,五指山地区的铅锌矿床的成矿物质主要来源于变质基底,水岩反应作用致使围岩贡献了少量的成矿物质,成矿流体具有多源性,主要为低温、中高盐度的卤水,可能混入少量的地层水,矿床成因类型属于MVT型铅锌矿床。年代学数据揭示,五指山地区铅锌矿成矿时代为(458.2±2.9) Ma,可能与武夷—云开陆内造山事件有关,暗示湘西—黔东地区同时代的铅锌成矿作用可能延伸到该地区。通过系统的地质和地球化学对比发现,五指山矿田内铅锌矿床与川滇黔接壤地区典型的铅锌矿床存在差异明显,而与湘西—黔东铅锌成矿带内典型矿床相似,故暂将其划分到该成矿带。 相似文献
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铅锌矿是湘西-黔东地区的优势矿种,资源丰富,开发历史悠久,找矿潜力巨大。综合分析前人有关湘西-黔东生物礁的资料,介绍了藻灰岩的沉积特征,并结合大量实际地质资料,对藻灰岩控矿进行了论述。结果表明: 成矿物质主要来源于藻类及碳酸盐泥对Pb2+、Zn2+离子的吸取,矿床成因属于沉积成岩矿床类型,兼有成岩期后矿床性质; 藻礁灰岩与不同岩性的接合部位及其附近等微地球化学障区,往往就是铅锌富矿体产出部位; 藻礁灰岩与礁间通道的薄层泥质白云质灰岩呈指状交叉接触处,也常有铅锌富矿体产出; 铅锌富矿体基本上产于清虚洞组灰岩段中,且明显受该段藻礁灰岩控制。为满足国内外对铅锌矿日益增长的消费需要,深入研究区内铅锌矿的地层岩相岩石控矿因素及其富集规律,指导该地区藻灰岩中铅锌矿找矿工作,具有重要的现实意义。 相似文献
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贵州铅锌矿的地球化学特征 总被引：17，自引：8，他引：17
贵州铅锌矿的分布受断控盆地的控制,主要铅锌矿带沿断控盆地边缘分布,盆地的充填序列—层序对铅锌矿的分布和矿床的地球化学特征有明显的制约作用。由此可在贵州划出索克上部含矿层等多个铅锌矿的含矿层序。同一含矿层序的铅锌矿即使相距很远,其地球化学特征也颇为相似:不同含矿层序的铅锌矿即使近在咫尺,其地球化学特征也迥然不同,表明不同含矿层序有不同矿质来源。根据对矿石铅和岩石中微量铅(岩铅)铅同位素组成特征,以及地层中Pb、Zn等元素背景含量的研究,各含矿层序的矿质主要来源于层序下部的细碎屑岩,个别亦可能来自上下层序紧邻层位的细碎屑岩。铅同位素研究还表明黔东铅锌成矿带形成在加里东晚期,黔西北铅锌成矿区形成在印支期之后。 对铅同位素和稳定同位素地球化学特征的研究表明,贵州铅锌矿多属盆源热液矿床,硫主要来源于含矿层序中的硫酸盐,在成矿过程中存在两种热液:盆源热液和下渗热液,成矿和它们的掺混有一定关系。硫同位素研究还揭示了成矿过程中的pH值变化和成矿体系对硫酸盐的开放程度。 相似文献
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黔西南龙潭组微量元素地球化学特征与金矿成矿物质来源研究 总被引：1，自引：0，他引：1
通过野外调查采样和测试分析等,对黔西南龙潭组岩性、岩相及岩矿石元素地球化学特征进行了研究,认为:龙潭组为海陆交互相沉积环境,成岩物质主要来源于西北部陆源泥质碎屑、炭质、钙质、硅质等,其次来源于西北部峨眉山玄武岩喷发物质的沉积或再沉积,少数来源于东南部深水海槽中的硅质、钙质等;龙潭组成岩物质以正常陆源碎屑沉积为主,但混入了部分火山碎屑岩沉积,纵向上为氧化-弱氧化-弱还原沉积环境;Au、As、Sb等中低温热液成矿元素共同指示了金、锑等热液蚀变-成矿作用,以及峨眉山玄武岩喷发可能对金矿成矿的贡献;Au、As、Sb、Tl、Co、W等成矿元素的聚类关系,可推论龙潭组富含的火山凝灰物质是金矿的重要成矿物质来源,龙潭组及其下覆的峨眉山玄武岩组是金矿的矿源层之一。 相似文献
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《矿物学报》2018,(6)
铅锌属于紧缺资源之一,"湘西—黔东铅锌成矿带"是我国重要铅锌成矿带之一,贵州境内部分称为"黔东成矿带",该区铅锌矿床(点)分布广泛,具有成群成带分布等特征。由于相关地质地球化学研究相对薄弱,黔东地区铅锌地质勘探进展缓慢,并未像湘西地区一样取得重大突破。本文通过总结"黔东成矿带"内铅锌成矿作用地质与地球化学特征,探讨该区存在的诸多科学研究薄弱环节,结合MVT铅锌矿床研究现状,提出该区铅锌成矿作用与MVT矿床基本一致,是国内研究MVT铅锌矿床理想基地,采用原位分析等先进测试技术,加强矿床地质地球化学特征对比、成矿物质来源、成矿流体和同位素定年等研究,以揭示各矿区与区域成矿流体系统的性质及其演化,建立合理成矿模式及与研究区构造和古油藏演化的关系,并探讨其形成的动力学背景,不仅突出黔东MVT铅锌成矿作用特色,从而促进MVT铅锌矿成矿作用和分散元素超常富集理论发展,更重要的是可为拓宽黔东地区铅锌找矿思路提供理论依据。 相似文献
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黔东麻江地区位于上扬子台地东南缘,下寒武统(相当于2008年国际地层年表中的寒武纪第二统)清虚洞组发育浅海碳酸盐岩沉积。露头观察、微相分析和地球化学数据综合得出,麻江地区清虚洞组可划分为浅海陆棚、潮下带、浅滩、潮间带4种沉积环境。由下向上,构成了5个向上变浅的旋回(C1-C5)。C1-C3旋回为浅海陆棚-潮下带-潮间带序列,以细晶白云岩为主,局部见鲕粒或灰泥的交代残余;C4-C5旋回为台缘浅滩-潮间带序列,浅滩特征明显。麻江地区沉积环境的纵向演化和邻区沉积环境的对比表明,湘西黔东地区清虚洞组经历了碳酸盐岩缓坡向镶边台地的过渡转化。 相似文献
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湘西黔东地区铅锌矿床与古油藏关系初探 总被引：3，自引：0，他引：3
本文以湖南花垣铅锌矿床和贵州牛角塘铅锌矿床为例,探讨了湘西黔东地区铅锌矿与古油藏的关系。二者在空间分布上关系密切,存在"共生"和"上油下矿"两种关系,下寒武统清虚洞组既是铅锌矿重要的赋矿层位也是古油藏储集层之一;铅锌矿源层可能为新元古代基底岩系或下寒武统石牌组碎屑岩,古油藏烃源岩主要为下寒武统牛蹄塘组。古油藏中的油田卤水萃取了石牌组碎屑岩中的铅锌等成矿物质,形成成矿流体并运移,在古油藏形成后,由于加里东末期的构造运动的影响,古油藏和成矿流体的平衡被打破导致铅锌矿质沉淀,在这个过程中古油藏中的油田卤水可能为铅锌矿的沉淀提供了部分硫源。铅锌矿成矿时代与加里东期形成或破坏的古油藏时间上较为一致。 相似文献
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Zircon textures, chemistry and microstructures have been characterized in situ within Carboniferous sandstones from the Midland Valley of Scotland using back‐scattered electron and cathodoluminescence images, electron backscatter diffraction techniques and chemical analyses. The study of polished thin sections reveals a variety of zircon types including unmodified detrital zircon, zircon outgrowths and different forms of modified zircon that formed in low‐temperature conditions within the sedimentary rocks. These rocks have only experienced temperatures of <100 °C during burial; however, altered zircon is abundant and characterized by a low mean atomic number, with relatively high contents of non‐formula elements and a nano‐crystalline or microcrystalline structure. It forms by replacement of detrital zircon that subsequently became metamict. Two types of replacement mechanisms are effective in sedimentary environments and involve either dissolution–reprecipitation or solid‐state reaction, but both require fluid access to the radiation‐damaged areas. The former process appears to become the dominant replacement mechanism as temperature increases and produces highly porous, inclusion‐rich zircon. Metamict zircon is extremely reactive in near‐surface conditions and the production of low‐temperature zircon is sensitive to both parent zircon characteristics and environmental conditions. As such, the alteration of zircon has the potential to yield unique information on the diagenetic history of sedimentary rocks. Low‐temperature zircon would be unlikely to survive sedimentary transport or the rock crushing procedures that characterize many investigations of detrital zircon populations and consequently may generate severe biases in studies of this type. 相似文献
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In calcic plagioclase (Ca, Na) [(Al, Si) AlSi2O8] Al-Si ordering produces superstructures with periodic and non periodic antiphase boundaries (APB's). Crystals growing at high temperature close to the melting point and cooling fairly rapidly order by nucleation of ordered domains which grow, resulting in an irregular pattern of curved APB's (b plagioclase). A modulated structure with periodic APB's forms by continuous ordering at large undercooling below the critical ordering temperature (e plagioclase). During annealing APB's are eliminated by pairwise recombination of adjacent APB's to reduce strain energy along the boundaries thereby transforming nonstable e plagioclase into stable b plagioclase without change in chemical composition. This process is often accompanied by a chemical phase separation with APB's providing favorable surfaces for diffusion. Transformations are documented by transmission electron microscopy (TEM) micrographs illustrating the variation in morphology of APB patterns in igneous and metamorphic plagioclase. They are in agreement with Korekawa et al.'s (1978) model of intermediate plagioclase which relies on periodic stacking of basic units rather than wavelike modulations. The paper includes observations of a new type of satellite in Stillwater bytownite (‘h’ satellites) which are due to fine lamellar exsolution. 相似文献
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S. F. Vinokurov V. Yu. Prokof’ev V. I. Malkovsky Yu. M. Dymkov A. V. Chugaev M. V. Nesterova 《Geology of Ore Deposits》2013,55(6):411-437
The structural, hydrochemical, mineralogical, and geochemical features of the Khokhlovskoe uranium deposit related to neotectonic processes are considered. The structural feature is expressed in neotectonic dislocations in the form of overall intense fragmentation of host rocks and widespread low-amplitude strike-slip faulting. The hydrochemical specificity is determined by the appearance of thermal carbonated formation water in ore-bearing aquifers. This water is similar in chemical and gas composition to hydrothermal solutions in fluid inclusions and mineral waters abundant in this district. The mineralogical and geochemical features comprise the occurrence of newly formed ferroan carbonates and late iron hydroxides in altered (bleached) pelitic rocks; the formation of silicic opal segregations in ore-bearing sand and sandstone; late sulfides, arsenides, and selenides of iron and other metals; and multiphase gel-pitchblende enriched in Zr especially typical of high-grade uranium ore. The age of high-grade ore determined by a precision uranium-ionium method coincides with the time when thermal carbonated water appeared in the host rocks. This time was estimated from a mathematical model of heat transfer and regional dynamics of underground water. This coincidence clearly indicates that the aforementioned processes are related to the late Quaternary neotectonic reactivation of the eastern Transural region. 相似文献
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Episyenite is a quartz-depleted vuggy rock resulting from hydrothermal alteration of granitic rocks. This is the first report of its existence in an island arc, which is identified in a deep drill core of the Toki Cretaceous granite distributed in central Japan. In order to understand the petrographical features of the episyenite, neutron porosity measurement, geochemical analysis, microscopic observation, and X-ray computed tomography scanning were carried out. The results show remarkably high porosity (35.4 %) due to interconnecting vugs and the removal of quartz, plagioclase, and biotite. The Rb–Sr isotopic results and the paragenetic sequence of secondary minerals in the vugs suggest that the hydrothermal alteration process can be divided into an episyenitization stage and a later hydrothermal stage. At the episyenitization stage (70.6 ± 3.1 Ma) ca. 6 million years after the emplacement of the unaltered granite (76.3 ± 1.5 Ma), dissolution of quartz, biotite, and plagioclase occurred and was followed by the precipitation of albite, vermicular chlorite, and platy calcite. The episyenitization is considered as a local alteration of the Toki granite in an isotopically closed system. At the later hydrothermal stage, illite and secondary quartz precipitated from circulating meteoric-derived water in the dissolution vugs. Superimposing alteration at the later hydrothermal stage is limited, which results in the preservation of the episyenite in an almost primitive condition. 相似文献
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辽宁本溪歪头山条带状铁矿的成因类型、形成时代及构造背景 总被引：12，自引：9，他引：3
辽宁鞍本地区位于华北克拉通东北缘,分布有诸多大型-特大型条带状铁矿床。本文对该区歪头山铁矿进行了岩石学、矿物学及年代学研究。歪头山铁建造以条带状铁矿石为主,兼含有少量的块状矿石,其顶底板围岩及矿体夹层主要为太古界鞍山群斜长角闪岩。元素地球化学分析表明,铁矿石富集重稀土[(La/Yb)PAAS=0.24~0.33],具La正异常(La/La*=1.43~1.61)、Eu正异常(Eu/Eu*=2.40~4.54)及Y正异常(Y/Y*=1.10~1.30),Y/Ho值平均30.59,Sr/Ba值平均17.62,Ti/V值平均19.45,反映成矿物质可能来源于由海底火山活动带来的高温热液与海水的混合溶液。铁矿石无明显Ce负异常(Ce/Ce*=0.92~1.06),暗示BIF沉积时海水处于缺氧环境。除Fe2O3T与SiO2外,铁矿石中其它氧化物含量均非常低,且贫Th、U、Zr等具有陆源性质的元素,表明大陆碎屑物质对BIF贡献极少。斜长角闪岩稀土元素配分型式近于平坦[(La/Yb)N=0.80~1.10],无明显Ce异常(Ce/Ce*=0.95~0.99)与Eu异常(Eu/Eu*=0.88~1.16);其大离子亲石元素富集,高场强元素无明显亏损。地球化学分析表明,斜长角闪岩原岩可能为产于弧后盆地的玄武质火山岩。锆石形态与微量元素分析显示,斜长角闪岩中的锆石均属岩浆成因。SIMS锆石U-Pb定年显示斜长角闪岩原岩形成于2533±11Ma,代表了歪头山BIF的成矿年龄;在玄武质岩浆喷发过程中,还捕获了一组年龄为2610±5Ma的锆石。电子探针分析显示磁铁矿成分纯净(FeOT=92.04%~93.05%),其标型组分特征暗示歪头山BIF属沉积变质型铁矿。综合分析认为,歪头山铁矿属Algoma型BIF,成矿与弧后盆地岩浆活动密切相关,指示了新太古代末华北克拉通普遍发育的一期BIF成矿事件。 相似文献
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A. Piestrzyński 《Mineralium Deposita》1990,25(2):146-151
The Kupferschiefer in Poland has an increased U content. The facies high in organic matter are significantly enriched in U. The maximum values of U are mostly in the lower part of the Kupferschiefer sequence. The mean (x) U content in the Kupferschiefer from the Lubin-Sieroszowice district is 61.5 ppm and from the rest of the Polish Zechstein basin is about 26 ppm. Thorium occurs only in small quantities (x) = 1.5 and 5 ppm respectively). The high variance of U and Th in the Kupferschiefer is due to multistage diagenetic processes. The main U carrier is thucholite. The investigated thucholite showed a Th-content below 0.36 ppm. Thucholite with uraninite exolutions showed small (up to 1.0 wt.%) admixtures of U and thucholite without microscopically visible exsolutions (up to 37.85 wt.% U). The phosphates showed significant amounts of U (up to 0.24 wt.). The U content in the Kupferschiefer is significantly lower than in black shales from other part of the world. Uranium in the Lubin district is not economic. 相似文献
18.
Nontronite, limonite (with opal) and vivianite are forming at present in the aereated, shallower parts (water depths <250 m) of Lake Malawi. They overlie diatomite or coarse grained clastic sediments. Our investigations indicate a precipitation of nontronite and limonite (and opal) at the sediment/oxic water interface from geothermal solutions rich in SiO2 percolating through the sedimentary fill of the basin. Under reducing conditions and a pH less than 7 (as occurring in the deeper parts of our sediment cores) iron and manganese are leached and discharged into the lake. In the anoxic parts of the lake (water depth greater than 250 m) Fe3+- and Mn3+-hydroxide are precipitated within the lake's water in the mixing zone of the aerobic with the anaerobic water bodies. High dispersion and a strong supply of detrital material, however, prevent a stronger enrichment of the hydroxides in the sediment. The formation of vivianite can be explained by a dissolution of Ca-phosphate (fish debris) within the sediment and a re-deposition as Fe-phosphate in the uppermost sediment layers under reducing but slightly alkaline conditions. The results of our investigations on Recent iron formation in Lake Malawi offer an explanation for the genesis of certain sedimentary iron ores in the geological past. They indicate that a formation of iron-rich sediments — including the silicate facies — is not restricted to the marine environment.
Zusammenfassung Nontronit, Limonit (und Opal) sowie Vivianit werden an zahlreichen Stellen des südlichen Malawi-Sees in Wassertiefen bis 250 m (aerober Bereich) abgeschieden und bilden dort die jüngste sedimentäre Einheit über Diatomit oder grobklastischem Sediment. Es muß angenommen werden, daß die Bildung der Eisenmineralien aus geothermalen Lösungen erfolgt, die reich an gelöster Kieselsäure und Fe2+ (untergeordnet Mn2+) sind, wobei Eisen und Mangan aus dem Sediment selber stammen, da heiße Quellen außerhalb des Malawi-Sees diese Elemente nicht enthalten. Die Auslösung von Eisen und Mangan erfolgt durch saure Lösungen im reduzierenden Milieu unter Bedingungen, wie sie im tieferen Teil der Sediment-Kerne angetroffen wurden (pH bis 3,6!). Beim Zusammentreffen dieser Lösungen mit dem sauerstoffhaltigen, schwach alkalischen Wasser des Malawi-Sees kommt es zur Ausfällung von Nontronit oder — bei wahrscheinlich höherem Redox-Potential — von Limonit und Opal. Beim Austritt der Fe2+, Mn2+- und SiO2-reichen Lösungen in den anaeroben Teil des Malawi-Sees (Wassertiefen größer als 250 m) unterbleibt zunächst eine Ausfällung. Erst in der Mischzone des anoxischen mit dem oxischen Wasserkörper können Fe3+- und Mn3+-Hydroxide ausgeschieden werden, die jedoch infolge hoher Dispergierung und starker Zufuhr von klastischem Material eine starke Verdünnung erfahren. Für die Vivianit-Bildung kann angenommen werden, daß ein in den Sedimenten häufig vorhandener Apatit-Anteil (Fischreste) durch die sauren Lösungen aufgelöst und in den obersten Sedimentschichten (reduzierendes Milieu, pH jedoch >7) zusammen mit Fe2+ der Lösung als Vivianit abgeschieden wird. Die vorliegenden Untersuchungen geben Hinweise auf die Bildung bestimmter fossiler sedimentärer Eisenerze und zeigen gleichzeitig, daß die Genese eisenreicher Sedimente — auch von silikatischem Fazies-Typ — nicht an den marinen Ablagerungsraum gebunden ist.相似文献
19.
The formation of a shoal was investigated in the Piscataqua River, New Hampshire, which is a well-mixed channel with low freshwater flow and tidal currents up to 2.3 m s?1. Observations of sediment characteristics, bathymetry, and bottom current were made, and theory was used to predict bedload transport. Sediment sampling showed the bottom material to be coarse sand and gravel, and sidescan sonar revealed large sand waves directed upriver at the shoal. Bottom current measurements were made along transects upriver and downriver of the shoal and downriver of an adjacent deepwater area that was also studied for comparison. Bedload flux inferred from current measurements using the Brown-Einstein theory indicated that transport is generally directed upriver. Sediment budget calculations showed the shoal area to be depositional before, immediately after, and subsequent to a dredging operation at rates of 0.36 m yr?1, 1.06 m yr?1, and 0.35 m yr?1, respectively. Predredge and subsequent rates were consistent with the historical record of removal by dredging at the shoal. 相似文献
20.
A. Del Popolo 《Astronomy Reports》2007,51(3):169-196
This paper provides a review of the types of dark matter that are thought to be fundamental components of the Universe, and
their role in the origin and evolution of structures, together with some new original results concerning improvements to the
spherical collapse model. In particular, we show how the spherical collapse model is modified when dynamical friction and
tidal torques are taken into account.
Published in Russian in Astronomicheskiĭ Zhurnal, 2007, Vol. 84, No. 3, pp. 195–226.
The text was submitted by the author in English. 相似文献