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1.
This study explores garnet coronas around hedenbergite, which were formed by the reaction plagioclase + hedenbergite→garnet + quartz, to derive information about diffusion paths that allowed for material redistribution during reaction progress. Whereas quartz forms disconnected single grains along the garnet/hedenbergite boundaries, garnet forms ～20‐μm‐wide continuous polycrystalline rims along former plagioclase/hedenbergite phase boundaries. Individual garnet crystals are separated by low‐angle grain boundaries, which commonly form a direct link between the reaction interfaces of the plagioclase|garnet|hedenbergite succession. Compositional variations in garnet involve: (i) an overall asymmetric compositional zoning in Ca, Fe2+, Fe3+ and Al across the garnet layer; and (ii) micron‐scale compositional variations in the near‐grain boundary regions and along plagioclase/garnet phase boundaries. These compositional variations formed during garnet rim growth. Thereby, transfer of the chemical components occurred by a combination of fast‐path diffusion along grain boundaries within the garnet rim, slow diffusion through the interior of the garnet grains, and by fast diffusion along the garnet/plagioclase and the garnet/hedenbergite phase boundaries. Numerical simulation indicates that diffusion of Ca, Al and Fe2+ occurred about three to four, four and six to seven orders of magnitude faster along the grain boundaries than through the interior of the garnet grains. Fast‐path diffusion along grain boundaries contributed substantially to the bulk material transfer across the growing garnet rim. Despite the contribution of fast‐path diffusion, bulk diffusion through the garnet rim was too slow to allow for chemical equilibration of the phases involved in garnet rim formation even on a micrometre scale. Based on published garnet volume diffusion data the growth interval of a 20‐μm‐wide garnet rim is estimated at ～103–104 years at the inferred reaction conditions of 760 ± 50 °C at 7.6 kbar. Using the same parameterization of the growth law, 100‐μm‐ and 1‐mm‐thick garnet rims would grow within 105–106 and 106–107 years respectively.  相似文献   

2.
The metabasites of Chadegan, including eclogite, garnet amphibolite and amphibolite, are forming a part of Sanandaj–Sirjan Zone. These rocks have formed during the subduction of the Neo–Tethys ocean crust under Iranian plate. This subduction resulted in a subduction metamorphism under high pressuremedium temperature of eclogite and amphibolites facies condition. Then the metamorphic rocks were exhumed during the continental collision between the Afro–Arabian continent and the Iranian microcontinent. In the metabasite rocks, with typical MORB composition, garnet preserved a compositional zoning occurred during metamorphism. The magnesium (XMg) gradually increases from core to rim of garnets, while the manganese (XMn) decreases towards the rim. Chondrite–normalized Rare Earth Element patterns for these garnets exhibit core–to–rim increases in Light Rare Earth Elements. The chondrite–normalized REE patterns of garnets, amphiboles and pyroxenes display positive trend from LREEs to Heavy Rare Earth Elements (especially in garnet), which suggests the role of these minerals as the major controller of HREE distribution. The geochemical features show that the studied eclogite and associated rocks have a MORB origin, and probably formed in a deep–seated subduction channel environment. The geothermometry estimation yields average pressure of ~22 kbar and temperature of 470–520°C for eclogite fomation. The thermobarometry results gave T = 650–700°C and P ≈ 10–11 kbar for amphibolite facies.  相似文献   

3.
Northward subduction of the leading edge of the Indian continental margin to depths greater than 100 km during the early Eocene resulted in high‐pressure (HP) quartz‐eclogite to ultrahigh‐pressure (UHP) coesite–eclogite metamorphism at Tso Morari, Ladakh Himalaya, India. Integrated pressure–temperature–time determinations within petrographically well‐constrained settings for zircon‐ and/or monazite‐bearing assemblages in mafic eclogite boudins and host aluminous gneisses at Tso Morari uniquely document segments of both the prograde burial and retrograde exhumation path for HP/UHP units in this portion of the western Himalaya. Poikiloblastic cores and inclusion‐poor rims of compositionally zoned garnet in mafic eclogite were utilized with entrapped inclusions and matrix minerals for thermobarometric calculations and isochemical phase diagram construction, the latter thermodynamic modelling performed with and without the consideration of cation fractionation into garnet during prograde metamorphism. Analysis of the garnet cores document (M1) conditions of 21.5 ± 1.5 kbar and 535 ± 15 °C during early garnet growth and re‐equilibration. Sensitive high resolution ion microprobe (SHRIMP) U–Pb analysis of zircon inclusions in garnet cores yields a maximum age determination of 58.0 ± 2.2 Ma for M1. Peak HP/UHP (M2) conditions are constrained at 25.5–27.5 kbar and 630–645 °C using the assemblage garnet rim–omphacite–rutile–phengite–lawsonite–talc–quartz (coesite), with mineral compositional data and regional considerations consistent with the upper P–T bracket. A SHRIMP U–Pb age determination of 50.8 ± 1.4 Ma for HP/UHP metamorphism is given by M2 zircons analysed in the eclogitic matrix and that are encased in the garnet rim. Two garnet‐bearing assemblages from the Puga gneiss (host to the mafic eclogites) were utilized to constrain the subsequent decompression path. A non‐fractionated isochemical phase diagram for the assemblage phengite–garnet–biotite–plagioclase–quartz–melt documents a restricted (M3) P–T stability field centred on 12.5 ± 0.5 kbar and 690 ± 25 °C. A second non‐fractionated isochemical phase diagram calculated for the lower pressure assemblage garnet–cordierite–sillimanite–biotite–plagioclase–quartz–melt (M4) documents a narrow P–T stability field ranging between 7–8.4 kbar and 705–755 °C, which is consistent with independent multiequilibria P–T determinations. Th–Pb SHRIMP dating of monazite cores surrounded by allanite rims is interpreted to constrain the timing of the M4 equilibration to 45.3 ± 1.1 Ma. Coherently linking metamorphic conditions with petrographically constrained ages at Tso Morari provides an integrated context within which previously published petrological or geochronological results can be evaluated. The new composite path is similar to those published for the Kaghan UHP locality in northern Pakistan, although the calculated 12‐mm a?1 rate of post‐pressure peak decompression at Tso Morari would appear less extreme.  相似文献   

4.
Lawsonite eclogite (metabasalt and metadolerite) and associated metasedimentary rocks in a serpentinite mélange from an area just south of the Motagua fault zone (SMFZ), Guatemala, represent excellent natural records of the forearc slab–mantle interface. Pseudosection modelling of pristine lawsonite eclogite reproduces the observed predominant mineral assemblages, and garnet compositional isopleths intersect within the phase fields, yielding a prograde P–T path that evolves from 20 kbar, 470 °C (M1) to 25 kbar, 520 °C (M2). The dominant penetrative foliation within the eclogite blocks is defined by minerals developed during the prograde evolution, and the associated deformation, therefore, took place during subduction. Thermometry using Raman spectra of carbonaceous material in metasedimentary rocks associated with the SMFZ eclogites gives estimates of peak‐T of ～520 °C. Barometry using Raman spectroscopy shows unfractured quartz inclusions in garnet rims retain overpressures of up to ～10 kbar, implying these inclusions were trapped at conditions just below the quartz/coesite transition, in agreement with the results of phase equilibrium analysis. Additional growth of Ca‐rich garnet indicates initial isothermal decompression to 20 kbar (M3) followed by hydration and substantial cooling to the lawsonite–blueschist facies (M4). Further decompression of the hydrated eclogite blocks to the pumpellyite–actinolite facies (3–5 kbar, 230–250 °C) is associated with dehydration and veining (M5). The presence of eclogite as m‐ to 10 m‐sized blocks in a serpentinite matrix, lack of widespread deformation developed during exhumation and derived prograde P–T path associated with substantial dehydration of metabasites within the antigorite stability field suggest that the SMFZ eclogites represent the uppermost part of the forearc slab crust sampled by an ascending serpentinite diapir in an active, moderate‐T subduction zone.  相似文献   

5.
Abstract The prograde metamorphism of eclogites is typically obscured by chemical equilibration at peak conditions and by partial requilibration during retrograde metamorphism. Eclogites from the Eastern Blue Ridge of North Carolina retain evidence of their prograde path in the form of inclusions preserved in garnet. These eclogites, from the vicinity of Bakersville, North Carolina, USA are primarily comprised of garnet–clinopyroxene–rutile–hornblende–plagioclase–quartz. Quartz, clinopyroxene, hornblende, rutile, epidote, titanite and biotite are found as inclusions in garnet cores. Included hornblende and clinopyroxene are chemically distinct from their matrix counterparts. Thermobarometry of inclusion sets from different garnets record different conditions. Inclusions of clinozoisite, titanite, rutile and quartz (clinozoisite + titanite = grossular + rutile + quartz + H2O) yield pressures (6–10 kbar, 400–600 °C and 8–12 kbar 450–680 °C) at or below the minimum peak conditions from matrix phases (10–13 kbar at 600–800 °C). Inclusions of hornblende, biotite and quartz give higher pressures (13–16 kbar and 630–660 °C). Early matrix pyroxene is partially or fully broken down to a diopside–plagioclase symplectite, and both garnet and pyroxene are rimmed with plagioclase and hornblende. Hypersthene is found as a minor phase in some diopside + plagioclase symplectites, which suggests retrogression through the granulite facies. Two‐pyroxene thermometry of this assemblage gives a temperature of c. 750 °C. Pairing the most Mg‐rich garnet composition with the assemblage plagioclase–diopside–hypersthene–quartz gives pressures of 14–16 kbar at this temperature. The hornblende–plagioclase–garnet rim–quartz assemblage yields 9–12 kbar and 500–550 °C. The combined P–T data show a clockwise loop from the amphibolite to eclogite to granulite facies, all of which are overprinted by a texturally late amphibolite facies assemblage. This loop provides an unusually complete P–T history of an eclogite, recording events during and following subduction and continental collision in the early Palaeozoic.  相似文献   

6.
Eclogite boudins occur within an orthogneiss sheet enclosed in a Barrovian metapelite‐dominated volcano‐sedimentary sequence within the Velké Vrbno unit, NE Bohemian Massif. A metamorphic and lithological break defines the base of the eclogite‐bearing orthogneiss nappe, with a structurally lower sequence without eclogite exposed in a tectonic window. The typical assemblage of the structurally upper metapelites is garnet–staurolite–kyanite–biotite–plagioclase–muscovite–quartz–ilmenite ± rutile ± silli‐manite and prograde‐zoned garnet includes chloritoid–chlorite–paragonite–margarite, staurolite–chlorite–paragonite–margarite and kyanite–chlorite–rutile. In pseudosection modelling in the system Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O (NCKFMASH) using THERMOCALC, the prograde path crosses the discontinuous reaction chloritoid + margarite = chlorite + garnet + staurolite + paragonite (with muscovite + quartz + H2O) at 9.5 kbar and 570 °C and the metamorphic peak is reached at 11 kbar and 640 °C. Decompression through about 7 kbar is indicated by sillimanite and biotite growing at the expense of garnet. In the tectonic window, the structurally lower metapelites (garnet–staurolite–biotite–muscovite–quartz ± plagioclase ± sillimanite ± kyanite) and amphibolites (garnet–amphibole–plagioclase ± epidote) indicate a metamorphic peak of 10 kbar at 620 °C and 11 kbar and 610–660 °C, respectively, that is consistent with the other metapelites. The eclogites are composed of garnet, omphacite relicts (jadeite = 33%) within plagioclase–clinopyroxene symplectites, epidote and late amphibole–plagioclase domains. Garnet commonly includes rutile–quartz–epidote ± clinopyroxene (jadeite = 43%) ± magnetite ± amphibole and its growth zoning is compatible in the pseudosection with burial under H2O‐undersaturated conditions to 18 kbar and 680 °C. Plagioclase + amphibole replaces garnet within foliated boudin margins and results in the assemblage epidote–amphibole–plagioclase indicating that decompression occurred under decreasing temperature into garnet‐free epidote–amphibolite facies conditions. The prograde path of eclogites and metapelites up to the metamorphic peak cannot be shared, being along different geothermal gradients, of about 11 and 17 °C km?1, respectively, to metamorphic pressure peaks that are 6–7 kbar apart. The eclogite–orthogneiss sheet docked with metapelites at about 11 kbar and 650 °C, and from this depth the exhumation of the pile is shared.  相似文献   

7.
A re‐evaluation of the P–T history of eclogite within the East Athabasca granulite terrane of the Snowbird tectonic zone, northern Saskatchewan, Canada was undertaken. Using calculated pseudosections in combination with new garnet–clinopyroxene and zircon and rutile trace element thermometry, peak metamorphic conditions are constrained to ～16 kbar and 750 °C, followed by near‐isothermal decompression to ～10 kbar. Associated with the eclogite are two types of occurrences of sapphirine‐bearing rocks preserving a rich variety of reaction textures that allow examination of the retrograde history below 10 kbar. The first occurs as a 1–2 m zone adjacent to the eclogite body with a peak assemblage of garnet–kyanite–quartz interpreted to have formed during the eclogite facies metamorphism. Rims of orthopyroxene and plagioclase developed around garnet, and sapphirine–plagioclase and spinel–plagioclase symplectites developed around kyanite. The second variety of sapphirine‐bearing rocks occurs in kyanite veins within the eclogite. The veins involve orthopyroxene, garnet and plagioclase layers spatially organized around a central kyanite layer that are interpreted to have formed following the eclogite facies metamorphism. The layering has itself been modified, with, in particular, kyanite being replaced by sapphirine–plagioclase, spinel–plagioclase and corundum–plagioclase symplectites, as well as the kyanite being replaced by sillimanite. Petrological modelling in the CFMAS system examining chemical potential gradients between kyanite and surrounding quartz indicates that these vein textures probably formed during further essentially isothermal decompression, ultimately reaching ～7 kbar and 750 °C. These results indicate that the final reaction in these rocks occurred at mid‐crustal levels at upper amphibolite facies conditions. Previous geochronological and thermochronological constraints bracket the time interval of decompression to <5–10 Myr, indicating that ～25 km of exhumation took place during this interval. This corresponds to minimum unroofing rates of ～2–5 mm year?1 following eclogite facies metamorphism, after which the rocks resided at mid‐crustal levels for 80–100 Myr.  相似文献   

8.
The high-pressure (HP) eclogite in the western Dabie Mountain encloses numerous hornblendes, mostly barroisite. Opinions on the peak metamorphic P-T condition, PT path and mineral paragenesis of it are still in dispute. Generally, HP eclogite involves garnet, omphacite, hornblendes and quartz, with or without glaucophane, zoisite and phengite. The garnet has compositional zoning with XMg increase, XCa and XMn decrease from core to rim, which indicates a progressive metamorphism. The phase equilibria of the HP eclogite modeled by the P-T pseudosection method developed recently showed the following: (1) the growth zonation of garnet records a progressive metamorphic PT path from pre-peak condition of 1.9–2.1 GPa at 508°C–514°C to a peak one of 2.3–2.5 GPa at 528°C–531°C for the HP eclogite; (2) the peak mineral assemblage is garnet+omphacite+glaucophane+quartz±phengite, likely paragenetic with lawsonite; (3) the extensive hornblendes derive mainly from glaucophane, partial omphacite and even a little garnet due to the decompression with some heating during the post-peak stage, mostly representing the conditions of about 1.4–1.6 GPa and 580°C–640°C, and their growth is favored by the dehydration of lawsonite into zoisite or epidote, but most of the garnet, omphacite or phengite in the HP eclogite still preserve their compositions at peak condition, and they are not obviously equilibrious with the hornblendes.  相似文献   

9.
Eclogite, felsic orthogneiss and garnet–staurolite metapelite occur in a 5 km long profile in the area of Mi?dzygórze in the Orlica–?nie?nik dome (Bohemian Massif). Petrographic observations and mineral equilibria modelling, in the context of detailed structural work, are used to document the close juxtaposition of high‐pressure and medium‐pressure rocks. The structural succession in all lithologies shows an early shallow‐dipping fabric, S1, that is folded by upright folds and overprinted by a heterogeneously developed subvertical foliation, S2. Late recumbent folds associated with a weak shallow‐dipping axial‐plane cleavage, S3, occur locally. The S1 fabric in the eclogite is defined by alternation of garnet‐rich (grs = 22–29 mol.%) and omphacite‐rich (jd = 33–36 mol.%) layers with oriented muscovite (Si = 3.26–3.31 p.f.u.) and accessory kyanite, zoisite, rutile and quartz, indicating conditions of ～19–22 kbar and ～700–750 °C. The assemblage in the retrograde S2 fabric is formed by amphibole, plagioclase, biotite and relict rutile surrounded by ilmenite and sphene that is compatible with decompression and cooling from ～9 kbar and ～730 °C to 5–6 kbar and 600–650 °C. The S3 fabric contains in addition domains with albite, chlorite, K‐feldspar and magnetite indicating cooling to greenschist facies conditions. The metapelites are composed of garnet, staurolite, muscovite, biotite, quartz, ilmenite and chlorite. Chemical zoning of garnet cores that contain straight ilmenite and staurolite inclusion trails oriented perpendicular to the external S2 fabric indicates prograde growth, from ～5 kbar and ～520 °C to ～7 kbar and ～610 °C, during the formation of the S1 fabric. Inclusion trails parallel with the S2 fabric at garnet and staurolite rims are interpreted to be a continuation of the prograde path to ～7.5 and ～630 °C in the S2 fabric. Matrix chlorite parallel to the S2 foliation indicates that the subvertical fabric was still active below 550 °C. The axial planar S2 fabrics developed during upright folding are associated with retrogression of the eclogite under amphibolite facies conditions, and with prograde evolution in the metapelites, associated with their juxtaposition. The shared part of the eclogite and metapelite P–T paths during the development of the subvertical fabric reflects their exhumation together.  相似文献   

10.
Numerous lenses of eclogite occur in a belt of augen orthogneisses in the Gubaoquan area in the southern Beishan orogen, an eastern extension of the Tianshan orogen. With detailed petrological data and phase relations, modelled in the system NCFMASHTO with thermocalc , a quantitative P–T path was estimated and defined a clockwise P–T path that showed a near isothermal decompression from eclogite facies (>15.5 kbar, 700–800 °C, omphacite + garnet) to high‐pressure granulite facies (12–14 kbar, 700–750 °C, clinopyroxene + sodic plagioclase symplectitic intergrowths around omphacite), low‐pressure granulite facies (8–9.5 kbar, ～700 °C, orthopyroxene + clinopyroxene + plagioclase symplectites and coronas surrounding garnet) and amphibolite facies (5–7 kbar, 600–700 °C, hornblende + plagioclase symplectites). The major and trace elements and Sm–Nd isotopic data suggest that most of the Beishan eclogite samples had a protolith of oceanic crust with geochemical characteristics of an enriched or normal mid‐ocean ridge basalt. The U–Pb dating of the Beishan eclogites indicates an Ordovician age of c. 467 Ma for the eclogite facies metamorphism. An 39Ar/40Ar age of c. 430 Ma for biotite from the augen gneiss corresponds to the time of retrograde metamorphism. The combined data from geological setting, bulk composition, clockwise P–T path and geochronology support a model in which the Beishan eclogites started as oceanic crust in the Palaeoasian Ocean, which was subducted to eclogite depths in the Ordovician and exhumed in the Silurian. The eclogite‐bearing gneiss belt marks the position of a high‐pressure Ordovician suture zone, and the calculated clockwise P–T path defines the progression from subduction to exhumation.  相似文献   

11.
A mid‐ocean ridge basalt (MORB)‐type eclogite from the Moldanubian domain in the Bohemian Massif retains evidence of its prograde path in the form of inclusions of hornblende, plagioclase, clinopyroxene, titanite, ilmenite and rutile preserved in zoned garnet. Prograde zoning involves a flat grossular core followed by a grossular spike and decrease at the rim, whereas Fe/(Fe + Mg) is also flat in the core and then decreases at the rim. In a pseudosection for H2O‐saturated conditions, garnet with such a zoning grows along an isothermal burial path at c. 750 °C from 10 kbar in the assemblage plagioclase‐hornblende‐diopsidic clinopyroxene‐quartz, then in hornblende‐diopsidic clinopyroxene‐quartz, and ends its growth at 17–18 kbar. From this point, there is no pseudosection‐based information on further increase in pressure or temperature. Then, with garnet‐clinopyroxene thermometry, the focus is on the dependence on, and the uncertainties stemming from the unknown Fe3+ content in clinopyroxene. Assuming no Fe3+ in the clinopyroxene gives a serious and unwarranted upward bias to calculated temperatures. A Fe3+‐contributed uncertainty of ±40 °C combined with a calibration and other uncertainties gives a peak temperature of 760 ± 90 °C at 18 kbar, consistent with no further heating following burial to eclogite facies conditions. Further pseudosection modelling suggests that decompression to c. 12 kbar occurred essentially isothermally from the metamorphic peak under H2O‐undersaturated conditions (c. 1.3 mol.% H2O) that allowed the preservation of the majority of garnet with symplectitic as well as relict clinopyroxene. The modelling also shows that a MORB‐type eclogite decompressed to c. 8 kbar ends as an amphibolite if it is H2O saturated, but if it is H2O‐undersaturated it contains assemblages with orthopyroxene. Increasing H2O undersaturation causes an earlier transition to SiO2 undersaturation on decompression, leading to the appearance of spinel‐bearing assemblages. Granulite facies‐looking overprints of eclogites may develop at amphibolite facies conditions.  相似文献   

12.
The Sivrihisar Massif, Turkey, is comprised of blueschist and eclogite facies metasedimentary and metabasaltic rocks. Abundant metre‐ to centimetre‐scale eclogite pods occur in blueschist facies metabasalt, marble and quartz‐rich rocks. Sivrihisar eclogite contains omphacite + garnet + phengite + rutile ± glaucophane ± quartz + lawsonite and/or epidote. Blueschists contain sodic amphibole + garnet + phengite + lawsonite and/or epidote ± omphacite ± quartz. Sivrihisar eclogite and blueschist have similar bulk composition, equivalent to NMORB, but record different P–T conditions: ～26 kbar, 500 °C (lawsonite eclogite); 18 kbar, 600 °C (epidote eclogite); 12 kbar, 380 °C (lawsonite blueschist); and 15–16 kbar, 480–500 °C (lawsonite‐epidote blueschist). Pressures for the Sivrihisar lawsonite eclogite are among the highest reported for this rock type, which is rarely exposed at the Earth's surface. The distribution and textures of lawsonite ± epidote define P–T conditions and paths. For example, in some lawsonite‐bearing rocks, epidote inclusions in garnet and partial replacement of matrix epidote by lawsonite suggest an anticlockwise P–T path. Other rocks contain no epidote as inclusions or as a matrix phase, and were metamorphosed entirely within the lawsonite stability field. Results of the P–T study and mapping of the distribution of blueschists and eclogites in the massif suggest that rocks recording different maximum P–T conditions were tectonically juxtaposed as kilometre‐scale slices and associated high‐P pods, although all shared the same exhumation path from ～9–11 kbar, 300–400 °C. Within the tectonic slices, alternating millimetre–centimetre‐scale layers of eclogite and blueschist formed together at the same P–T conditions but represent different extents of prograde reaction controlled by strain partitioning or local variations in fO2 or other chemical factors.  相似文献   

13.
Sm–Nd garnet‐whole rock geochronology, phase equilibria, and thermobarometry results from Garnet Ledge, south‐eastern Alaska, provide the first precisely constrained P–T–t path for garnet zone contact metamorphism. Garnet cores from two crystals and associated whole rocks yield a four point isochron age for initial garnet growth of 89.9 ± 3.6 Ma. Garnet rims and matrix minerals from the same samples yield a five point isochron age for final garnet growth of 89 ± 1 Ma. Six size fractions of zircon from the adjacent pluton yield a concordant U–Pb age of 91.6 ± 0.5 Ma. The garnet core and rim, and zircon ages are compatible with single‐stage garnet growth during and/or after pluton emplacement. All garnet core–whole rock and garnet rim‐matrix data from the two samples constrain garnet growth duration to ≤5.5 my. A garnet mid‐point and the associated matrix from one of the two garnet crystals yield an age of 90.0 ± 1.0 Ma. This mid‐point result is logically younger than the 90.7 ± 5.6 Ma core–whole rock age and older than the 88.4 ± 2.5 Ma rim‐matrix age for this sample. A MnNaCaKFMASH phase diagram (P–T pseudosection) and the garnet core composition are used to predict that cores of garnet crystals grew at 610 ± 20 °C and 5 ± 1 kbar. This exceeds the temperature of the garnet‐in reaction by c. 50 °C and is compatible with overstepping of the garnet growth reaction during contact metamorphism. Intersection of three reactions involving garnet‐biotite‐sillimanite‐plagioclase‐quartz calculated by THERMOCALC in average P–T mode, and exchange thermobarometry were used to estimate peak metamorphic conditions of 678 ± 58 °C at 6.1 ± 0.9 kbar and 685 ± 50 °C at 6.3 ± 1 kbar, respectively. Integration of pressure, temperature, and age estimates yields a pressure‐temperature‐time path compatible with near isobaric garnet growth over an interval of c. 70 °C and c. 2.3 my.  相似文献   

14.
Conditions of the prograde, peak‐pressure and part of the decompressional P–T path of two Precambrian eclogites in the eastern Sveconorwegian orogen have been determined using the pseudosection approach. Cores of garnet from a Fe–Ti‐rich eclogite record a first prograde and syn‐deformational stage along a Barrovian gradient from ~670 °C and 7 kbar to 710 °C and 8.5 kbar. Garnet rims grew during further burial to 16.5–19 kbar at ~850–900 °C, along a steep dP/dT gradient. The pseudosection model of a kyanite‐bearing eclogite sample of more magnesian bulk composition confirms the peak conditions. Matrix reequilibration associated with subsequent near‐isothermal decompression and partial exhumation produced plagioclase‐bearing symplectites replacing kyanite and clinopyroxene at an estimated 850–870 °C and 10–11 kbar. The validity of the pseudosections is discussed in detail. It is shown that in pseudosection modelling the fractionation of FeO in accessory sulphides may cause a significant shift of field boundaries (here displaced by up to 1.5 kbar and 70 °C) and must not be neglected. Fast burial, exhumation and subsequent cooling are supported by the steepness of both the prograde and the decompressional P–T paths as well as the preservation of garnet growth zoning and the symplectitic reaction textures. These features are compatible with deep tectonic burial of the eclogite‐bearing continental crust as part of the underthrusting plate (Eastern Segment, continent Baltica) in a collisional setting that led to an effectively doubled crustal thickness and subsequent exhumation of the eclogites through tectonic extrusion. Our results are in accordance with regional structural and petrological relationships, which demonstrate foreland‐vergent partial exhumation of the eclogite‐bearing nappe along a basal thrust zone and support a major collisional stage at c. 1 Ga. We argue that the similarities between Sveconorwegian and Himalayan eclogite occurrences emphasize the modern style of Grenvillian‐aged tectonics.  相似文献   

15.
Fine grained rodingite‐like rocks containing epidote, clinozoisite, garnet, chlorite, phengite and titanite occur within antigorite serpentinite boudins from the high‐pressure metamorphic Maksyutovo Complex in the Southern Urals. Pseudomorphs after lawsonite, resorption of garnet by chlorite and phengite and stoichiometry suggest the reaction lawsonite + garnet + K‐bearing fluid → clinozoisite + chlorite + phengite, and define a relic assemblage of lawsonite + garnet + chlorite + titanite ± epidote as well as a later post‐lawsonite assemblage of clinozoisite + phengite + chlorite + titanite. The reaction lawsonite + titanite → clinozoisite + rutile + pyrophyllite + H2O delimits the maximum stability of former lawsonite + titanite to pressures >13 kbar. P–T conditions of 18–21 kbar/520–540 °C result, if the average chlorite, Mg‐rich garnet rim and average epidote compositions are used as equilibrium compositions of the former lawsonite assemblage. These estimates indicate a similar depth of formation but lower temperatures to those recorded in nearby eclogites. The metamorphic conditions of the lawsonite assemblage are considerably higher than previously suggested and, together with published structural data, support a model in which a normal fault within the Maksyutovo complex acted as the major transport plane of eclogite exhumation. The maximum Si content of phengite and minimum Fe content in clinozoisite constrain the metamorphic conditions of the later pseudomorph assemblage to be >4.5 kbar and <440 °C. Rb–Sr isotopic dating of the pseudomorph assemblage results in a formation age of 339 ± 6 and 338 ± 5 Ma, respectively. These results support the recent exhumation models for this complex.  相似文献   

16.
New eclogite localities and new 40Ar/39Ar ages within the Western Gneiss Region of Norway define three discrete ultrahigh‐pressure (UHP) domains that are separated by distinctly lower pressure, eclogite facies rocks. The sizes of the UHP domains range from c. 2500 to 100 km2; if the UHP culminations are part of a continuous sheet at depth, the Western Gneiss Region UHP terrane has minimum dimensions of c. 165 × 50 × 5 km. 40Ar/39Ar mica and K‐feldspar ages show that this outcrop pattern is the result of gentle regional‐scale folding younger than 380 Ma, and possibly 335 Ma. The UHP and intervening high‐pressure (HP) domains are composed of eclogite‐bearing orthogneiss basement overlain by eclogite‐bearing allochthons. The allochthons are dominated by garnet amphibolite and pelitic schist with minor quartzite, carbonate, calc‐silicate, peridotite, and eclogite. Sm/Nd core and rim ages of 992 and 894 Ma from a 15‐cm garnet indicate local preservation of Precambrian metamorphism within the allochthons. Metapelites within the allochthons indicate near‐isothermal decompression following (U)HP metamorphism: they record upper amphibolite facies recrystallization at 12–17 kbar and c. 750 °C during exhumation from mantle depths, followed by a low‐pressure sillimanite + cordierite overprint at c. 5 kbar and c. 750 °C. New 40Ar/39Ar hornblende ages of 402 Ma document that this decompression from eclogite‐facies conditions at 410–405 Ma to mid‐crustal depths occurred in a few million years. The short timescale and consistently high temperatures imply adiabatic exhumation of a UHP body with minimum dimensions of 20–30 km. 40Ar/39Ar muscovite ages of 397–380 Ma show that this extreme heat advection was followed by rapid cooling (c. 30 °C Myr?1), perhaps because of continued tectonic unroofing.  相似文献   

17.
The late Palaeozoic western Tianshan high‐pressure /low‐temperature belt extends for about 200 km along the south‐central Tianshan suture zone and is composed mainly of blueschist, eclogite and epidote amphibolite/greenschist facies rocks. P–T conditions of mafic garnet omphacite and garnet–omphacite blueschist, which are interlayered with eclogite, were investigated in order to establish an exhumation path for these high‐pressure rocks. Maximum pressure conditions are represented by the assemblage garnet–omphacite–paragonite–phengite–glaucophane–quartz–rutile. Estimated maximum pressures range between 18 and 21 kbar at temperatures between 490 and 570 °C. Decompression caused the destabilization of omphacite, garnet and glaucophane to albite, Ca‐amphibole and chlorite. The post‐eclogite facies metamorphic conditions between 9 and 14 kbar at 480–570 °C suggest an almost isothermal decompression from eclogite to epidote–amphibolite facies conditions. Prograde growth zoning and mineral inclusions in garnet as well as post‐eclogite facies conditions are evidence for a clockwise P–T path. Analysis of phase diagrams constrains the P–T path to more or less isothermal cooling which is well corroborated by the results of geothermobarometry and mineral textures. This implies that the high‐pressure rocks from the western Tianshan Orogen formed in a tectonic regime similar to ‘Alpine‐type’ tectonics. This contradicts previous models which favour ‘Franciscan‐type’ tectonics for the southern Tianshan high‐pressure rocks.  相似文献   

18.
Low‐T eclogites in the North Qilian orogen, NW China share a common assemblage of garnet, omphacite, glaucophane, epidote, phengite, quartz and rutile with or without paragonite. Phase relations for the low‐T eclogites can be modelled well in the system NCKFMASHO with the updated solid‐solution models for amphibole and clinopyroxene. Garnet in the eclogite typically exhibits growth zonations in which pyrope increases while grossular somewhat decreases from core to rim, which is modelled as having formed mainly in the P–T conditions of lawsonite‐eclogite facies at the pre‐peak stage. Omphacite shows an increase in jadeite component as aegirine and also total FeO decrease in going from the inclusions in garnet to grains in the matrix, and from core to rim of zoned crystals, reflecting an increase in metamorphic P–T conditions. Glaucophane exhibits a compositional variation in X(gl) (= Fe2+/(Fe2+ + Mg)) and F(gl) (= Fe3+/(Fe3+ + Al) in M2 site), which decrease from the inclusions in garnet to crystals in the matrix, consistent with an increase in P–T conditions. However, for zoned matrix crystals, the X(gl) and F(gl) increase from core to rim, is interpreted to reflect a late‐stage decompression. Using composition isopleths for garnet rim and phengite in P–T pseudosections, peak P–T conditions for three samples Q5–45, Q5–01 and Q7–28 were estimated as 530–540 °C at 2.10–2.25 GPa, 580–590 °C at 2.30–2.45 GPa and 575–590 °C at 2.50–2.65 GPa, respectively, for the same assemblage garnet + omphacite + glaucophane + lawsonite (+ phengite + quartz + rutile) at the peak stage. The eclogites suggest similar P–T ranges to their surrounding felsic–pelitic schists. During post‐peak decompression of the eclogites, the most distinctive change involves the transformation of lawsonite to epidote, releasing large amount of water in the rock. The released fluid promoted further growth of glaucophane at the expense of omphacite and, in appropriate bulk‐rock compositions, paragonite formed. The decompression of eclogite did not lead to pronounced changes in garnet and phengite compositions. Peak P–T conditions of the North Qilian eclogite are well constrained using both the average P–T and pseudosection approaches in Thermocalc. Generally, the conventional garnet–clinopyroxene geothermometer is too sensitive to be used for constraining the temperature of low‐T eclogite because of the uncertainty in Fe3+ determination in omphacite and slight variations in mineral compositions because of incomplete equilibration.  相似文献   

19.
A section of the orogenic middle crust (Orlica‐?nie?nik Dome, Polish/Czech Central Sudetes) was examined to constrain the duration and significance of deformation (D) and intertectonic (I) phases. In the studied metasedimentary synform, three deformation events produced an initial subhorizontal foliation S1 (D1), a subsequent subvertical foliation S2 (D2) and a late subhorizontal axial planar cleavage S3 (D3). The synform was intruded by pre‐, syn‐ and post‐D2 granitoid sheets. Crystallization–deformation relationships in mica schist samples document I1–2 garnet–staurolite growth, syn‐D2 staurolite breakdown to garnet–biotite–sillimanite/andalusite, I2–3 cordierite blastesis and late‐D3 chlorite growth. Garnet porphyroblasts show a linear Mn–Ca decrease from the core to the inner rim, a zone of alternating Ca–Y‐ and P‐rich annuli in the inner rim, and a Ca‐poor outer rim. The Ca–Y‐rich annuli probably reflect the occurrence of the allanite‐to‐monazite transition at conditions of the staurolite isograd, whereas the Ca‐poor outer rim is ascribed to staurolite demise. The reconstructed P–T path, obtained by modelling the stability of parageneses and garnet zoning, documents near‐isobaric heating from ~4 kbar/485 °C to ~4.75 kbar/575 °C during I1–2. This was followed by a progression to 4–5 kbar/580–625 °C and a subsequent pressure decrease to 3–4 kbar during D2. Pressure decrease below 3 kbar is ascribed to I2–3, whereas cooling below ~500 °C occurred during D3. In the dated mica schist sample, garnet rims show strong Lu enrichment, oscillatory Lu zoning and a slight Ca increase. These features are also related to allanite breakdown coeval with staurolite appearance. As Lu‐rich garnet rims dominate the Lu–Hf budget, the 344 ± 3 Ma isochron age is ascribed to garnet crystallization at staurolite grade, near the end of I1–2. For the dated sample of amphibole–biotite granitoid sheet, a Pb–Pb single zircon evaporation age of 353 ± 1 Ma is related to the onset of plutonic activity. The results suggest a possible Devonian age for D1, and a Carboniferous burial‐exhumation cycle in mid‐crustal rocks that is broadly coeval with the exhumation of neighbouring HP rocks during D2. In the light of published ages, a succession of telescoping stages with time spans decreasing from c. 10 to 2–3 Ma is proposed. The initially long period of tectonic quiescence (I1–2 phase, c. 10 Ma) inferred in the middle crust contrasts with contemporaneous deformation at deeper levels and points to decoupled P–T–D histories within the orogenic wedge. An elevated gradient of ~30 °C km?1 and assumed high heating rates of c. 20 °C Ma?1 are explained by the protracted intrusion of granitoid sheets, with or without deformation, whereas fast vertical movements (2–3 Ma, D2 phase) in the crust require the activity of deformation phases.  相似文献   

20.
Prograde P–T–t paths of eclogites are often ambiguous owing to high variance of mineral assemblages, large uncertainty in isotopic age determinations and/or variable degree of retrograde equilibration. We investigated these issues using the barroisite eclogites from the Lanterman Range, northern Victoria Land, Antarctica, which are relatively uncommon but free of retrogression. These eclogites revealed three stages of prograde metamorphism, defining two distinctive P–T trajectories, M1–2 and M3. Inclusion minerals in garnet porphyroblasts suggest that initial prograde assemblages (M1) consist of garnet+omphacite+barroisite/Mg‐pargasite+epidote+phengite+paragonite+rutile/titanite+quartz, and subsequent M2 assemblages of garnet+omphacite+barroisite+phengite+rutile±quartz. The inclusion‐rich inner part of garnet porphyroblasts preserves a bell‐shaped Mn profile of the M1, whereas the inclusion‐poor outer part (M2) is typified by the outward decrease in Ca/Mg and XFe (=Fe2+/(Fe2++Mg)) values. A pseudosection modelling employing fractionated bulk‐rock composition suggests that the eclogites have initially evolved from ~15 to 20 kbar and 520–570°C (M1) to ~22–25 kbar and 630–650°C (M2). The latter is in accordance with P–T conditions estimated from two independent geothermobarometers: the garnet–clinopyroxene–phengite (~25 ± 3 kbar and 660 ± 100°C) and Zr‐in‐rutile (~650–700°C at 22–27 kbar). The second segment (M3A–B) of prograde P–T path is recorded in the grossular‐rich overgrowth rim of garnet. Apart from disequilibrium growth of the M3A garnet, ubiquitous overgrowth of the M3B garnet permits us to estimate the P–T conditions at ~26 ± 3 kbar and 720 ± 80°C. The cathodoluminescence (CL) imaging of zircon grains separated from a barroisite eclogite revealed three distinct zones with bright rim, dark mantle and moderately dark core. Eclogitic phases such as garnet, omphacite, epidote and rutile are present as fine‐grained inclusions in the mantle and rim of zircon, in contrast to their absence in the core. The sensitive high‐resolution ion microprobe U–Pb dating on metamorphic mantle domains and neoblasts yielded a weighted mean 206Pb/238U age of 515 ± 4 Ma (tσ), representing the time of the M2 stage. On the other hand, overgrowth rims as well as bright‐CL neoblasts of zircon were dated at 498 ± 11 Ma (tσ), corresponding to the M3. Average burial rates estimated from the M2 and M3 ages are too low (<2 mm/year) for cold subduction regime (~5–10°C/km), suggesting that an exhumation stage intervened between two prograde segments of P–T path. Thus, the P–T–t evolution of barroisite eclogites is typified by two discrete episodes with an c. 15 Ma gap during the middle Cambrian subduction of the Antarctic Ross Orogeny.  相似文献   

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