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1.
通过对南岭西段花山和姑婆山花岗岩基地质-岩石地球化学特征研究,判明它们的侵位深度(5.5km)、围岩温度(196℃)及岩浆初始温度(950℃),建立起花山和姑婆山岩基的数学计算模型,计算得出:花山-姑婆山花岗岩熔体侵位后,其初始温度降低至结晶温度所需的时间(△tco1)分别为4.14 Ma(花山)和4.36Ma(姑婆山);由于结晶潜热释放而使结晶过程延长的时间(△tL)为2.67Ma,2.81 Ma;由于花山和姑婆山花岗岩基放射性元素含量(U 13.5×10-6,Th 56.1×10- 6,K2O 5.79%(花山);U13.7×10-6,Th 52.4×10-6,K2O 5.28%(姑婆山))高于世界平均花岗岩放射性元素含量(U5×10-6,Th 20×10-6,K2O 2.66%),花山和姑婆山花岗岩浆侵位后产生的放射成因热使结晶过程延长的时间(△tA)分别为37.6 Ma和45.1 Ma,远长于按世界平均花岗岩放射性元素含量计算得出的△tA(3.17 Ma,花山).花山和姑婆山花岗岩基的侵位-结晶时差(△tECTD)分别为44.41Ma和52.27Ma,结合锆石U-Pb年龄值(162 Ma(花山),163Ma(姑婆山)),通过反演计算得出花山、姑婆山花岗岩基侵位年龄值(tE)分别为206Ma和215Ma,从而为花山-姑婆山花岗岩基属于印支期侵位提供了重要的岩浆动力学佐证.  相似文献   

2.
桂东北里松花岗岩中暗色包体的岩浆混合成因   总被引:25,自引:0,他引:25  
在桂东北姑婆山地区的里松花岗岩中,暗色包体广泛分布,包体的形貌、结构构造和矿物学特征表明,它们是岩浆快速冷凝结晶产物;主元素和微量元素组成说明它们属钾玄岩系列,其源岩具OIB型微量元素特征;包体与寄主花岗岩中锆石U-Pb年龄的相同性,排除了来源于深部固体岩石熔融残留体或浅部围岩捕虏体的可能性,而两种岩石化学成分、岩石结构暗色包体和寄主花岗岩在岩石结构和全岩Sr-Nd同位素组成方面的明显差别性,又排除了同源包体或析离体、堆积体的可能性。里松花岗岩在很多地质-地球化学特征上都介于里松暗色包体和姑婆山主体花岗岩之间,里松暗色包体的总体特征显示了岩浆混合成因,是里松暗色包体岩浆与姑婆山主体花岗岩岩浆发生混合时不完全混合的残留物。  相似文献   

3.
广西珊瑚钨锡矿田位于桂东北姑婆山-花山岩体南缘,以发育石英脉型钨矿为特征。盐田岭岩体是矿区内唯一出露的小岩株,但是其成岩时代及其与珊瑚钨锡矿床的关系还不十分清楚。本文利用锆石LA-ICP-MS U-Pb法和绢云母Ar-Ar法对盐田岭岩体进行了岩体侵位及热液活动年代学研究。结果显示,盐田岭花岗岩锆石U-Pb加权平均年龄为106±13 Ma,热液蚀变绢云母Ar-Ar坪年龄为103.6±1.2 Ma,等时线年龄为103.9±2.1 Ma,表明岩体侵位和岩浆期后热液活动事件均发生于早白垩世晚期,为姑婆山-花山地区岩浆演化的末期,与珊瑚矿田内长营岭钨锡矿床热液蚀变绢云母Ar-Ar年龄一致。本文认为珊瑚钨锡矿田的形成可能与盐田岭岩体的侵位有关。  相似文献   

4.
弓虎军  朱赖民  孙博亚  李犇  郭波  王建其 《岩石学报》2009,25(11):3029-3042
东江口花岗岩体位于商丹与勉略缝合带之间的南秦岭中部,其中存在大量基性暗色微粒包体.锆石的LA-MCICPMS联机U-Pb年代学分析表明,东江口岩体的形成年龄为223Ma,其包体锆石的结晶年龄为222Ma,与寄主岩体大致同时形成,指示秦岭造山带印支晚期岩石圈构造体制属性从挤压.伸展转变发生在220Ma左右.锆石的Lu-Hf同位素原位分析结果表明,南秦岭晚三叠纪花岗岩是壳幔混合作用的产物,亏损的幔源岩浆与南秦岭(或扬子)的基底地壳物质可能为南秦岭地区晚三叠纪花岗岩的源区物质,它们的形成起因于秦岭造山带在主造山期后发生的岩石圈拆沉作用.大约220Ma开始,南秦岭岩石圈构造应力性质从挤压向伸展构造体制转变,岩石圈发生拆沉作用,地幔软流圈物质上涌并底侵于下地壳,诱发下地壳物质的部分熔融,当岩浆沿构造薄弱带上升过程中,幔源岩浆与寄主岩浆发生成份的交换,两种岩浆混合过程中不完全混溶,最终形成寄主岩体和暗色基性微粒包体.  相似文献   

5.
通过对南岭西段花山和姑婆山花岗岩基地质-岩石地球化学特征研究,判明它们的侵位深度(5.5km)、围岩温度(196℃)及岩浆初始温度(950℃),建立起花山和姑婆山岩基的数学计算模型,计算得出:花山-姑婆山花岗岩熔体侵位后,其初始温度降低至结晶温度所需的时间(△tco1)分别为4.14 Ma(花山)和4.36Ma(姑婆山...  相似文献   

6.
LA-ICP-MS锆石U-Pb同位素年龄测定表明,组成广西姑婆山花岗岩的东、西岩体和里松岩体的年龄分别为160.8±1.6Ma、165.0±1.9Ma、163.0±1.3Ma,在误差范围内基本一致,说明整个姑婆山岩体是同一时代的产物,是燕山中期第一阶段华南大规模陆壳重熔型花岗岩浆活动的产物。姑婆山花岗岩中的各个岩体虽然形成于同一时代,但它们之间在岩石学、地球化学特征方面有一定的差异。除了主微量元素、稀土元素特征有所不同外,Rb-Sr、Sm-Nd同位素特征研究表明姑婆山西岩体的粗粒花岗岩、东岩体、里松岩体及其包体的平均(87Sr/86Sr)i=0.7064、εNd(t)平均为-3.03,反映它们的源区有较多地幔物质组分参与;而姑婆山西岩体的细粒花岗岩的(87Sr/86Sr)i=0.7173、εNd(t)平均为-5.00,具强烈的Eu亏损、高Rb/Sr值等特征,它的源区可能是由一个相对古老地壳组分和年轻地幔组分组成的混合源区。此外,姑婆山东岩体(GP-1)中发现的继承锆石的206Pb/238U年龄为806.4Ma,与杭州—诸广山—花山花岗岩带(HZH)上的赣北九岭堇青石花岗岩、广西英桥混合花岗岩的年龄相似,为HZH带新元古代的岩浆活动提供了锆石年代学方面的依据。  相似文献   

7.
青藏高原北部风火山花岗斑岩与逆冲推覆构造存在密切关系,岩浆侵位发生在区域地质构造演化的重要历史时期。对风火山北麓花岗斑岩及暗色包体,在显微观测和矿物鉴定的基础上,通过单颗粒锆石离子探针U-Pb同位素测年,获得高精度的测年资料。测得早期岩浆锆石结晶平均年龄为(34.5±1.4)Ma,对应于岩浆源区地壳局部熔融时代;晚期岩浆锆石结晶平均年龄为(27.6±0.5)M a,对应于岩浆向上侵入雅西错群的岩浆侵位时代。风火山北麓花岗斑岩属青藏高原北部出露的最年轻花岗岩,岩体内部不同类型锆石的U-Pb同位素测年为区域地层、区域构造和高原隆升的研究提供了重要的年代学约束。  相似文献   

8.
龙新岩体和夏郢岩体位于扬子地块与华夏地块拼合带的西南端,岩体中的Ⅰ型花岗岩成因研究对揭示桂东南地区早古生代的地球动力学背景及其构造演化具有重要的地质意义.对龙新岩体的寄主岩和其暗色微粒包体,以及夏郢岩体岩石进行了LA-ICP-MS锆石U-Pb定年、Lu-Hf同位素和全岩地球化学研究.锆石U-Pb定年结果显示,龙新岩体的寄主岩(花岗闪长岩)的年龄为440±2 Ma;龙新岩体的暗色包体(闪长岩)的年龄为441±1 Ma,寄主岩与暗色包体为同期岩浆作用的产物.夏郢岩体花岗闪长岩和二长花岗岩年龄分别为447±3 Ma和436±3 Ma,说明夏郢岩体至少发生了2期岩浆侵入事件.Hf同位素研究表明,龙新岩体寄主岩和暗色微粒包体的锆石εHf(t)值分别为-3.32~-5.83和-17.89~-1.82,二阶段模式年龄(TDM2)分别为1.62~1.76 Ga和1.57~2.54 Ga;夏郢岩体早期花岗岩闪长岩和晚期二长花岗岩的锆石εHf(t)值分别为-15.43~3.03和-4.79~6.82,TDM2分别为1.59~1.99 Ga和0.97~1.70 Ga,指示物源主要来自古-中元古代的地壳物质.地球化学特征表明龙新岩体寄主岩为准铝质高钾钙碱性Ⅰ型花岗岩,寄主岩和暗色微粒包体均富集轻稀土元素和大离子亲石元素,亏损重稀土元素及高场强元素;夏郢岩体早期的花岗闪长岩为弱过铝质高钾钙碱性Ⅰ型花岗岩,晚期的二长花岗岩则为强过铝质高钾钙碱性Ⅰ型花岗岩,主微量元素特征均与龙新岩体寄主岩相似.根据研究区花岗岩和镁铁质包体的岩相学、年代学、地球化学及Hf同位素组成特征,表明龙新岩体的暗色包体(闪长岩)为岩浆混合成因,而龙新岩体寄主岩(花岗闪长岩)和夏郢岩体(早期花岗岩闪长岩和晚期二长花岗岩)具有一致的岩石源区和岩石成因,但在后期的成岩过程中存在岩浆混合和结晶分异程度的差异.综合以往对华南地区构造背景的研究,认为龙新和夏郢岩体是在扬子地块和华夏地块陆内造山期后,岩石圈伸展减薄,热的幔源岩浆上涌底侵,中-下地壳受到地幔热影响发生部分熔融,形成的酸性岩浆在源区和基性岩浆经历了不均一且不强烈的壳-幔混合作用形成的.   相似文献   

9.
对德令哈市石底泉地区宗务隆构造带内花岗闪长岩进行了锆石U-Pb测年和岩石地球化学分析。岩石地球化学分析结果显示,其具有岛弧或活动大陆边缘花岗岩的属性,原岩可能为新元古代早期(870.0±4.5Ma左右)硅铝地壳或地壳物质熔融的产物,它们的形成与板块的俯冲作用有关LA-ICP-MS锆石U-Pb测年显示2组年龄,分别为870.0±4.5Ma和443.3±2.3Ma。其中870.0±4.5Ma代表源区继承锆石的年龄,反映了新元古代时期的构造岩浆事件;443.3±2.3Ma代表花岗闪长岩岩浆锆石的结晶年龄,即花岗闪长岩侵位于晚奥陶世。综合分析可以确定,宗务隆构造带内花岗闪长岩与柴达木盆地北缘加里东期的板块汇聚碰撞造山作用有关,证实了宗务隆构造带内岩体形成时代并非全部是海西期一印支期。  相似文献   

10.
在中国东南沿海地区广泛发育的中生代中酸性岩浆岩中多处发现了暗色包体,被认为是大规模壳幔相互作用和岩浆混合作用的产物。本文获得了浙东新昌地区小将岩体的花岗岩及暗色闪长质包体的锆石U-Pb年代学和和地球化学新结果。锆石U-Pb定年表明寄主花岗岩(121.1±0.9Ma)与暗色闪长质包体(117.6±1.0Ma)近于同期形成于早白垩纪。寄主花岗岩为高硅、富碱、富钾、准铝质或弱过铝质的钙碱性花岗岩,具有较强的铕负异常(δEu=0.23~0.30)和Sr、Ba、P和Ti等元素的亏损,属于高分异的I型花岗岩;暗色闪长质包体具有重稀土亏损的特征,与寄主花岗岩在主量和微量元素上呈现混合作用趋势。小将岩体的上述特征与浙东晚中生代和福建沿海同期的岩浆岩特征一致,它们可能都是在早白垩纪伸展构造背景下,起源于俯冲交代的岩石圈地幔部分熔融产生的基性岩浆或者演化为闪长质成分,并与壳源花岗质岩浆发生混合作用的结果。本文研究为浙东及浙闽沿海地区晚中生代壳-幔作用和岩浆混合作用提供了新的证据。  相似文献   

11.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

12.
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提  相似文献   

13.
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.  相似文献   

14.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations.  相似文献   

15.
The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.  相似文献   

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This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds.  相似文献   

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《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2.  相似文献   

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