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1.
粘土矿物研究在塔里木盆地石油勘探中的应用 总被引：2，自引：1，他引：1
以塔里木盆地粘土矿物的分布特征及其组合形式、演化与形成机理为依据,探讨了粘土矿物在地层划分对比中的应用及其与有机质热演化、成岩阶段的关系和对储层物性的影响。研究表明,在侏罗系和白垩系两个不同古环境中形成的粘土矿物及其组合特征,为地层对比提供了一定的证据。泥岩中伊利石／蒙皂石间层中蒙皂石含量的纵向变化与有机质热演化及成岩阶段的关系不大。对储层物性影响不大但有利于储集性能的是以高岭石为主的粘土矿物组合类型及粘土矿物的早期自生（伊利石／蒙皂石间层矿物）衬垫式以及非自生（伊利石）衬垫式产状。 相似文献
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纳岭沟铀矿床位于鄂尔多斯盆地东北部,含铀岩系为中侏罗统直罗组。文章通过薄片鉴定、扫描电镜、X射线衍射
等分析测试手段,对纳岭沟地区直罗组砂岩粘土矿物的镜下特征、成分及含量进行了系统的观察和研究,探讨了直罗组砂
岩粘土的矿物特征,并初步与伊犁盆地及二连盆地做了对比。研究表明,纳岭沟地区直罗组砂岩的粘土矿物主要为蒙皂
石,其次为高岭石、绿泥石,少量伊利石 。蒙皂石与高岭石存在相互转化现象,部分绿泥石由蒙皂石和高岭石转化而来,
成岩过程中蒙皂石并未大规模自发的向伊利石转化。砂岩的粘土总量较高,与伊犁盆地相比,富含蒙皂石,高岭石含量较
低,粘土矿物的吸附能力较强。在直罗组砂岩的成岩过程中,粘土矿物的吸附作用为直罗组富集了大量的铀,这是鄂尔多
斯盆地东北部地区能形成众多铀矿床乃至超大型铀矿床的重要条件。 相似文献
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安徽龙河口水库流域沉积物中粘土矿物分析及其环境意义 总被引：5，自引：0，他引：5
龙河口水库是巢湖上游的重要水源地,对水库钻孔ALE的粘土矿物进行定性和半定量分析,发现水库沉积的粘土矿物主要是绿泥石(含绿泥石/蛭石混层矿物),多年平均含量达40%,其次是高岭石和伊利石及少量的蒙皂石,伊利石的多年平均含量只有21%,远低于该流域中晓天河(54%)和滑石河(63.5%)的表层样。水库和龙潭河粘土矿物的含量组成较相似,与晓天河和滑石河差别较大。表层样中粘土矿物的差异主要受流域的地质地貌的影响,水库沉积物中粘土矿物的特征主要与环境动力和粘土矿物的结晶习性有密切的关系。 相似文献
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基于有孔虫AMS14C年龄年代框架,通过冲绳海槽中南部的OKT12孔沉积物黏土矿物的分析,探讨了16 ka以来冲绳海槽细颗粒沉积物的物源变化及其对源区气候的响应。研究结果显示,10 ka时黏土矿物组成发生明显变化,伊利石、绿泥石含量增加,高岭石、蒙皂石含量减少,指示物源由之前的长江和东海陆架源转变为台湾源。受到海平面上升影响,长江河口和冲绳海槽距离增加,夏季风增强,黑潮增强,既搬运台湾来源物质,又阻碍长江物质跨陆架输运,在这些因素综合作用下,长江物质减少、台湾物质增加。高岭石/（伊利石+绿泥石）和绿泥石/（伊利石+蒙皂石）比值在4 ka以来增加指示全新世晚期台湾源区侵蚀强度发生变化。4 ka前后物源判别显示,OKT12孔沉积物来源由台湾东北部河流变为台湾东南部河流,反映了该时期季风降雨导致源区台湾不同区域的侵蚀差异,可能与ITCZ南移、ENSO活动增强有关。 相似文献
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澄湖SC7孔沉积物粘土矿物特征及其古地理意义 总被引：1，自引：0，他引：1
苏州澄湖湖底残留有一条NNW—SSE延伸且已被淤平的古河道。通过对湖心区古河道段SC7孔沉积物的粘土矿物XRD分析及与湖底硬粘土（Q3）、湖岸区沉积（Q4）和长江口滩地现代沉积的比较,表明古河道充填沉积中的粘土矿物主要为伊利石,其次为高岭石、绿泥石、蛭石,还有少量蒙皂石及蛭石/绿泥石混层矿物;其中的伊利石和绿泥石含量均明显偏高,高岭石含量则偏低,伊利石结晶度也较高。粘土矿物组合兼具太湖流域地带性粘土矿物和长江口沉积物的特点,表明古河道充填沉积既有来自本流域表层物质和澄湖扩大过程中的湖岸崩积,也受到长江物源的影响。这一沉积过程也说明古河道在最大海侵时涨潮流和洪水引起海水和江水的频繁倒灌,直至淤塞和淹废。 相似文献
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以皂石、高岭石、绿泥石和伊利石为原材料,分别与赖氨酸进行反应,研究赖氨酸在上述粘土矿物上的吸附行为,
并运用粉末X-射线衍射技术（XRD）、傅里叶变换红外吸收光谱术（FTIR）和热重（TG）等分析方法,表征反应前后粘土
矿物的变化。实验结果表明,不同粘土矿物对赖氨酸的吸附等温线均符合Freundlich等温方程,且不同粘土矿物对赖氨酸的
饱和吸附量大小顺序为：皂石>蒙脱石>绿泥石>高岭石>伊利石;XRD结果表明皂石对赖氨酸的吸附发生在矿物层间,而绿
泥石、高岭石和伊利石对赖氨酸的吸附主要在矿物表面进行;FTIR和TG结果表明赖氨酸主要取代粘土矿物层间吸附水,以
氢键的形式与Si-O-Si(IVAl)键合。实验结果将有助于进一步探明环境中粘土矿物对有机质的吸附机理。 相似文献
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滇东黔西上二叠统含煤岩系形成于陆相到海陆过渡相环境中,其泥岩的粘土矿物组成可以反映这种环境背景。该区泥岩粘土矿物类型以高岭石和伊利石/蒙皂石间层矿物为主,伊利石次之,局部层段见较少绿泥石及蒙皂石。垂向上,高岭石在富源后所矿区、盘县盘关矿区剖面中下部（即宣威组中、下段和龙潭组）含量偏高;伊利石在织金矿区剖面上部（长兴组）和下部（龙潭组下段）含量明显偏高,而在剖面中部（龙潭组上段）偏低;伊利石/蒙皂石间层矿物在后所矿区、盘关矿区、纳雍矿区占绝对优势,而在织金矿区仅在剖面中部含量较高,并与伊利石呈明显的负相关关系;蒙皂石含量很少,仅出现于盘关矿区和织金矿区剖面的上部和下部。粘土矿物的上述分布特征可大致反映出龙潭早期为海侵期,龙潭晚期为海退期,长兴期为新的更大的海侵期。平面上,从陆到海,即从滇东的冲积平原河流体系,向东经盘关向斜的上三角洲平原、纳雍的过渡带三角洲平原,到织金的下三角洲平原及潮汐平原,高岭石含量急剧减少,伊利石含量逐渐增加。最为明显的是从滇东河流体系到黔西三角洲—潮坪体系之间高岭石含量骤然减少。 相似文献
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大庆油田齐家-古龙地区扶余油层储层敏感性分析和预测 总被引：10，自引：0，他引：10
通过X射线和扫描电等方法，分析了扶余油层的敏感性和造成敏感性的原因，查明了储层中粘土矿物的含量，产状及分布特征。研究目的是为储层保护和改造提供依据。扶余油层中的粘土矿物主要有4种类型，即伊利石，高岭石，绿泥石以及不量混层粘土矿的，蒙皂石极少见。在相同的实验条件下，储层的速敏，水敏除与粘土矿物组成有关外，还受渗透视率制约。扶余油层速敏程度以中，强速敏为主，水敏程度以强水敏为主，其次为中水敏。 相似文献
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We analyzed the clay mineral assemblages, content and mineralogical characteristics of Hole U1438A sediment recovered from Amami Sankaku Basin during International Ocean Discovery Program (IODP) expedition 351. The results show that the clay minerals are mainly composed of illite (average 57%), smectite (average 26%), chlorite (average 14%) and minor kaolinite(average 3%). The crystallinity of illite in all samples are good (<0.4 Δ° 2θ), and the chemical indexes of illite in all samples are low (<0.4). Both indicate that illite in Hole U1438A formed in cold and dry climate. By comparing clay mineral assemblages of hole U1438A and the potential sediment sources, we suggest that smectite be mainly derived from the volcanic materials around Amami Sankaku Basin. Illite, chlorite and kaolinite are mainly derived from the Asian dust. The ratios of (illite+chlorite)/smectite show a phased increase over the last 350 ka, which is consistent with the cold and drying trend of the Asian continent since late Pleistocene. The high ratios of (illite+chlorite)/smectite and (illite+chlorite)/kaolinite during glacial period indicate that much more Asian dust was input into the Amami Sankaku Basin, which are responded to the aridity of Asian continent and strengthened east Asian Monsoon during glacial period. 相似文献
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Youko Miyoshi Jun‐ichiro Ishibashi Kazuhiko Shimada Hiroyasu Inoue Seiichiro Uehara Katsuhiro Tsukimura 《Resource Geology》2015,65(4):346-360
Iheya‐North‐Knoll is one of the small knolls covered with thick sediments in the Okinawa Trough back‐arc basin. At the east slope of Iheya‐North‐Knoll, nine hydrothermal vents with sulfide mounds are present. The Integrated Ocean Drilling Program (IODP) Expedition 331 studied Iheya‐North‐Knoll in September 2010. The expedition provided us with the opportunity to study clay minerals in deep sediments in Iheya‐North‐Knoll. To reveal characteristics of clay minerals in the deep sediments, samples from the drilling cores at three sites close to the most active hydrothermal vent were analyzed by X‐ray diffraction, scanning electron microscope and transmission electron microscope. The sediments are classified into Layer 0 (shallow), Layer 1 (deep), Layer 2 (deeper) and Layer 3 (deepest) on the basis of the assemblage of clay minerals. Layer 0 contains no clay minerals. Layer 1 contains smectite, kaolinite and illite/smectite mixed‐layer mineral. Layer 2 contains chlorite, corrensite and chlorite/smectite mixed‐layer mineral. Layer 3 is grouped into three sub‐layers, 3A, 3B and 3C; Sub‐layer 3A contains chlorite and illite/smectite mixed‐layer mineral, sub‐layer 3B contains chlorite/smectite and illite/smectite mixed‐layer minerals, and sub‐layer 3C contains chlorite and illite. Large amounts of di‐octahedral clay minerals such as smectite, kaolinite, illite and illite/smectite mixed‐layer mineral are found in Iheya‐North‐Knoll, which is rarely observed in hydrothermal fields in mid‐ocean ridges. Tri‐octahedral clay minerals such as chlorite, corrensite and chlorite/smectite mixed‐layer mineral in Iheya‐North‐Knoll have low Fe/(Fe + Mg) ratios compared with those in mid‐ocean ridges. In conclusion, the characteristics of clay minerals in Iheya‐North‐Knoll differ from those in mid‐ocean ridges; di‐octahedral clay minerals and Fe‐poor tri‐octahedral clay minerals occur in Iheya‐North‐Knoll but not in mid‐ocean ridges. 相似文献
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应用X射线衍射(XRD)对南海北部陆架海域225个站位表层沉积物黏土组分进行分析,结果表明,研究区黏土矿物总体以伊利石和绿泥石为主,高岭石和蒙脱石质量分数少,绿泥石、高岭石与蒙脱石质量分数呈明显的负相关关系。根据南海北部陆架海域表层沉积物中黏土矿物空间分布特征,结合邻近河流的黏土矿物组分以及洋流搬运作用,雷州半岛东部海域伊利石主要来源于广东沿海河流和珠江,绿泥石来自台湾岛,蒙脱石主要由吕宋河流提供,高岭石则由广东沿海河流和海南岛入海河流提供;雷州半岛西部海域伊利石来源于珠江,绿泥石和高岭石由红河提供,蒙脱石可能受广西入海河流携带的沉积物影响。 相似文献
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利用X射线衍射，对东海东北部海域80个表层沉积物样品进行黏土矿物的相对含量分析.结果表明:东海东北部海域表层沉积物黏土矿物中伊利石（65.1%）含量最高，其次为绿泥石（26.6%）、高岭石（8.9%）和蒙皂石（4.3%）；矿物组合中伊利石-绿泥石-高岭石-蒙皂石型占绝对优势，伊利石-绿泥石-高岭石型较少.由外陆架至冲绳海槽，伊利石含量分布呈低-高-低-高；绿泥石呈低-高-低；高岭石分布趋势明显异于伊利石和绿泥石，含量值分布出现由高到低的趋势；蒙皂石在个别区域缺失，高值区呈斑块状分布在水深小于100 m的外陆架.快速聚类分析显示，黏土矿物可分为“类长江”、“类黄河”和“类台湾”3种类型，呈4个区域相间展布.“类黄河”型黏土矿物主要由黄海沿岸流将黄河、废黄河等物质再悬浮搬运而来，分布于29.5°N以北、127°E以西的外陆架区，并未越过东海外陆架进入冲绳海槽.外陆架区“类长江”型黏土矿物主要为低海平面时期古长江物质，并混有少量现代长江源悬浮物质；冲绳海槽区“类长江”型黏土矿物主要来自低海平面时期古长江物质.“类台湾”型黏土矿物主要由黑潮控制，由台湾经冲绳海槽南部搬运而来，沿陆坡附近沉积. 相似文献
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The results of the study of clay mineral alterations in Upper Pleistocene sediments of the southern trough in the Guaymas Basin (Gulf of California) due to the influence of hydrothermal solutions and heat produced by sill intrusions are discussed. Core samples from DSDP Holes 477 and 477A were taken for the analysis of clay minerals. Application of the method of modeling X-ray diffraction patterns of oriented specimens of the finely dispersed particles made it possible to establish the phase composition of clay minerals, determine their structural parameters, and obtain reliable quantitative estimates of their contents in natural mixtures. The modeling data allowed us to characterize reliably the transformation of clay minerals in sediments of the hydrothermally active southern trough in the Guaymas Basin. In Upper Pleistocene sandy–clayey sediments of the southern trough, changes in the composition of clay minerals occurred under the influence of a long-living hydrothermal system. Its lower part (interval 170.0–257.5 m) with maximum temperatures (~300°C) was marked by the formation of chlorite. Terrigenous clay minerals are not preserved here. Saponite appears at a depth of 248 m in the chlorite formation zone. Higher in the sedimentary section, the interval 146–170 m is also barren of terrigenous clay minerals. Sediments of this interval yielded two newly formed clay minerals (chlorite and illite), which were formed at lower temperatures (above 180°C and below 300°C, approximately up to ~250°C), while the relatively low-temperature upper part (110–146 m) of the hydrothermal system (from ~140°C to ~180°C) includes the mixture of terrigenous and newly formed clay minerals. Terrigenous illite is preserved here. Illitization of the mixed-layer illite–smectite was subjected to illitization. The terrigenous montmorillonite disappeared, and chlorite–smectite with 5–10% of smectite layers were formed. In the upper interval (down to approximately 110 mbsf), the composition of terrigenous clay minerals remains unchanged. They are composed of the predominant mixed-layer illite–smectite and montmorillonite, the subordinate illite, mixed-layer chlorite–smectite with 5% of smectite layers, mixed-layer kaolinite–smectite with 30% of smectite layers, and kaolinite. This composition of clay minerals changed under the influence of sill intrusions into the sedimentary cover at 58–105 m in the section of Hole 477. The most significant changes are noted in the 8-m-thick member above the sill at 50–58 m. The upper part of this interval is barren of the terrigenous mixed-layer illite–smectite, which is replaced by the newly formed trioctahedral smectite (saponite). At the same time, the terrigenous dioctahedral smectite (montmorillonite) is preserved. The composition of terrigenous clay minerals remains unchanged at the top of the unit underlying the sill base. 相似文献
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SONG Eping ZHANG Kexin CHEN Jiangjun WANG Chaowen JIANG Gaolei YIN Ke HONG Hanlie CHURCHMAN Jock Gordon 《《地质学报》英文版》2014,88(5):1579-1591
This study collected the early Oligocene to middle Miocene sediments from the Gerze Basin of Tibet, and used X-Ray diffraction （XRD） and Scanning Electron Microscope （SEM） to discuss their clay mineralolgy, clay indices, better understand the clay mineralogy and its paleoclimatic significance. The results show that clay minerals of the Gerze Basin sediments are mainly composed of iilite and chlorite, with minor amounts of smectite and kaolinite, and their relative content varies along the section. Variations of relative contents and clay indices suggest that the Gerze Basin has experienced three-stage evolution of paleoclimate： I ） high ilUte and chlorite contents, with fluctuant smectite and low （I＋Ch）/（K＋S） ratio, indicative of a dominant seasonal arid climate from the early Oligoeene to late Oligocene; Ⅱ） higher illite and chlorite contents and larger （I＋Ch）/（K＋S） ratio but absence of kaolinite, indicating a colder and drier climate from the late Oligocene to early Miocene; Ⅲ） high iilite and chlorite contents with fluctuant （I＋Ch）/（K＋S） ratios and occasional occurrence of kaolinite, suggesting that the climate became warmer and more humid compared with that of stage Ⅱ in the mid-Miocene. These conclusions were also reinforced by the clay morphology, which suggests that physical weathering dominated in stage Ⅱ, while relatively strong chemical weathering was dominant in stages Ⅰ and Ⅲ Clay minerals of the sediments mainly consist of illite and chlorite, indicating that the source rock played a significant role in clay origin. It is inferred that global cooling and the enhancement of denudation and obstruction of northward moisture due to the uplift of the Qinghai-Tibet Plateau were responsible for the provenance of iUite and chlorite under weak chemical weathering. Though the Qinghai-Tibet Plateau reached a certain elevation by the mid-Miocene, yet the mid-Miocene widespread warming might have largely impacted the Gerze climate. 相似文献
17.
对伊豆-小笠原海脊(ODP 782A孔)上新世以来沉积物中黏土矿物的组成、含量及矿物学特征进行了分析,结果表明:黏土矿物以伊利石(42%)和蒙皂石(42%)为主,绿泥石的平均含量为14%,高岭石的含量最低,平均仅为2%。伊利石的结晶度较好,平均为0.25°Δ2θ;化学指数较低,平均为0.31;表明伊利石主要形成于干冷的气候环境。通过将ODP 782A孔黏土矿物组合特征和含量与周边可能源区对比,并结合伊利石和蒙皂石的矿物学参数特征,我们认为蒙皂石主要来源于伊豆-小笠原海脊周边岛弧火山物质;伊利石、绿泥石和高岭石主要来自亚洲大陆风尘。上新世以来(伊利石+绿泥石)/蒙皂石比值总体上呈增加的趋势,并且在5.3~3.6、3.6~1.6、1.6~0 Ma的三个阶段表现出不同的变化特征,该比值与全球深海δ18O值所记录的全球变冷、北太平洋ODP 885/886孔风尘通量和灵台黄土沉积速率,以及日本海U1430站伊利石/蒙皂石比值所指示的亚洲内陆干旱变化的总体变化趋势和阶段性变化的时间点大致同步,表明该比值敏感地响应了全球变冷和亚洲内陆的干旱。上新世以来(伊利石+绿泥石)/高岭石比值表现为高/低交替变化,分别与中国灵台黄土磁化率高/低变化相对应,由于黄土磁化率记录了亚洲内陆干/湿变化,因此该黏土矿物比值敏感地响应了亚洲内陆的古气候变化,因而可以作为可靠的亚洲大陆干/湿变化示踪指标。 相似文献
18.
南海北部中新世以来粘土矿物特征及东亚古季风记录 总被引：4，自引：0，他引：4
应用X射线衍射(XRD)、扫描电子显微镜(SEM) 和X射线能谱(EDS) 分析技术对南海北部ODP1146站中新世以来(~20 Ma) 粘土矿物的组成、结晶学特征、微形貌和化学成分进行了研究, 分析了粘土矿物的物质来源及其记录的东亚季风演化历史.1146站粘土矿物组合的总体特点是以伊利石和蒙脱石为主, 高岭石和绿泥石含量较低.物源分析表明, 1146站蒙脱石主要来自于吕宋岛, 伊利石和绿泥石来自于珠江和台湾(长江), 而高岭石则主要来自于珠江.1146站的粘土矿物不仅被南海周围物源的同时代气候所控制, 而且为相互消长的不同传输作用(表层洋流) 的强度所影响.1146站(伊利石+绿泥石) /蒙脱石比值可以用来作为东亚季风演化的矿物学标志.指标变化显示出东亚冬季风强度和冬季风相对夏季风的强度在15 Ma、8 Ma和3 Ma左右发生了3次显著加强, 结果可以与黄土、北太平洋风尘沉积、南海微体古生物记录等很好对比.青藏高原的阶段性隆升可能促进了东亚季风的这3次加强. 相似文献
19.
通过X射线衍射系统分析了杭州湾地区SE2孔全新世沉积物的黏土矿物组成,结果显示研究层段黏土矿物主要由伊利石、绿泥石、高岭石和蒙脱石组成;伊利石结晶度较好,化学风化指数普遍大于0.5,表明以化学风化为主,且风化趋势自下而上呈递减趋势。通过对比中国东南部主要河流沉积物的黏土矿物组成,认为钱塘江下切河谷全新世沉积物的黏土矿物组成具有较好的物源指示意义: 全新世 Ⅰ 段(即古河口湾和河漫滩)沉积物主要来自钱塘江上游,特征黏土矿物为高岭石,河口外物质贡献不大;Ⅱ 段(即现代河口湾和近岸浅海)沉积物包含较多蒙脱石,表明不仅包括钱塘江上游物质,河口外长江物质也开始进入钱塘江河口。黏土矿物中,高岭石对气候有较好的指示作用:中全新世高岭石含量达到最高值,反映气候最为湿热,化学风化程度最高;晚全新世含量逐渐降低,反映气候逐渐回冷,化学风化强度降低。 相似文献
20.
通过X射线衍射系统分析了杭州湾地区SE2孔全新世沉积物的黏土矿物组成,结果显示研究层段黏土矿物主要由伊利石、绿泥石、高岭石和蒙脱石组成;伊利石结晶度较好,化学风化指数普遍大于0.5,表明以化学风化为主,且风化趋势自下而上呈递减趋势。通过对比中国东南部主要河流沉积物的黏土矿物组成,认为钱塘江下切河谷全新世沉积物的黏土矿物组成具有较好的物源指示意义: 全新世 Ⅰ 段(即古河口湾和河漫滩)沉积物主要来自钱塘江上游,特征黏土矿物为高岭石,河口外物质贡献不大;Ⅱ 段(即现代河口湾和近岸浅海)沉积物包含较多蒙脱石,表明不仅包括钱塘江上游物质,河口外长江物质也开始进入钱塘江河口。黏土矿物中,高岭石对气候有较好的指示作用:中全新世高岭石含量达到最高值,反映气候最为湿热,化学风化程度最高;晚全新世含量逐渐降低,反映气候逐渐回冷,化学风化强度降低。 相似文献