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1.
新疆布尔克斯岱金矿床含金矿物标型特征及其地质意义 总被引：1，自引：2，他引：1
对布尔克斯岱金矿床的主要含金矿物采用多种测试手段进行研究：如重砂、化学分析、Ｘ射线衍射分析、电子探针、ＥＰＲ谱、数学地质和包裹体分析等。对矿物特征及其与金矿化的关系作了较详细的研究。对确定矿床成因、找矿标志和成矿预测有一定意义。为矿床外围和深部找矿提供了依据。 相似文献
2.
本文对桂西北典型的微细浸染型金矿床的代表之一——高龙金矿床产出的地质背景作了说明,对该金矿床的矿区地质、矿体形态与规模、矿石类型及矿物共生组合特征等进行了较为详细的描述,对高龙式金矿床氧化机理的室内研究及其实验测试结果从矿区矿体的地球化学特征角度进行了分析,提出了高龙式金矿床氧化矿体的成因模式,认为:在中三叠时期形成的桂西北微细浸染型金矿床,系由水下岩浆的大量喷出沉积的火山物质,经成岩作用和地下热液不断淋滤淬取围岩物质而形成的矿床。金主要以徽细浸染的形式赋存于各种硫化物中。由内生成矿作用形成的原生矿体,由于构造运动的影响而暴露地表后,受温度、水,CO2、pH、Eh值、氧化铁疏杆菌等的影响,含金硫化物的结构遭到严重破坏,形成地表条件下可稳定存在的氧化物类及氧化矿体。桂西北中三叠系氧化带中的高龙金矿属-成矿循环周期中晚期阶段的产物。 相似文献
3.
Accessory phases and minor components in minerals are commonly ignored in thermodynamic modelling. Such an approach seems unwarranted, as accessory phases can represent a significant element reservoir and minor components can substantially change their host mineral's stability field. However, a lack of thermodynamic data prohibits assessment of these effects. In this contribution, the polyhedron method is used to estimate the thermodynamic properties of tourmaline, a common and widespread accessory phase, stable over a range of P–T–X conditions. The polyhedron method allows Δ H , S , V , C P and V m ( T , P ) properties to be estimated from a linear stoichiometric summation over the fractional properties of its polyhedron constituents. To allow for estimates of tourmaline, fractional thermodynamic properties for BIII and BIV polyhedra were derived. Mixing contributions to molar volume were evaluated and symmetrical mixing parameters derived for Al-Mg, Al-Fe and Al-Li interaction on tourmaline's Y-site and T-site Al-Si interaction. Evaluation of the estimated properties using experimental and natural equilibria between tourmaline and melts, minerals and hydrothermal fluids, shows that reliable semi-quantitative results are obtained. The boron contents in fluids coexisting with tourmaline are calculated to within an order of magnitude of measured content, and where anchor-points are available, agreement improves to within a factor of 2. Including tourmaline in petrogenetic modelling of metamorphic rocks indicates that its presence leads to disappearance of staurolite and garnet, among others, and modifies the X Mg of coexisting phases, in line with observations on natural rocks. 相似文献
4.
Lithological maps have been proved to be a useful tool to evaluate regional and global matter fluxes from chemical weathering. However, lithological classes provide aggregated information of mineralogical, geochemical, sedimentary or diagenetic properties. Thus, using a limited number of lithological classes introduces by their definition a bias to the analysis of weathering fluxes, specifically in the case of multilithological catchments. Here it is shown that the coupling of geochemical with lithological information may help to better identify the sources of the weathering fluxes, using the example of dissolved Ca to better distinguish weathering rates of silicate and non-silicate minerals. 相似文献
5.
杭州湾潮滩沉积物黏土矿物空间差异与物源指示 总被引：4，自引：1，他引：3
通过对杭州湾潮滩沉积物中主要黏土矿物成分及组合类型的研究,分析了杭州湾潮滩沉积物黏土矿物的空间分布特征。借助聚类分析等手段,同时结合杭州湾水动力特征,探讨了研究区黏土矿物的来源和成因。研究结果表明,杭州湾潮滩表层沉积物主要为黏土质粉砂,其余为砂质粉砂。本区沉积物黏土矿物成分复杂,主要为伊利石,其次是高岭石和绿泥石;还有少量蒙皂石和蛭石及1.4 nm过渡矿物。根据其相对含量可分为3种组合类型:Ⅰ型为伊利石-高岭石-绿泥石-蛭石类-蒙皂石型,Ⅱ型为伊利石-绿泥石-高岭石-蒙皂石-蛭石类型,Ⅲ型为伊利石-高岭石-绿泥石-蒙皂石-蛭石类型。在空间上,北岸的蒙皂石和绿泥石平均含量高于南岸,而伊利石、高岭石和蛭石(含1.4 nm过渡矿物)平均含量则低于南岸。高潮滩和中潮滩黏土矿物对比,除了蒙皂石含量高潮滩大于中潮滩外,其他矿物含量均无明显规律。表层沉积物黏土矿物的分布特征与水动力条件和物质来源密切相关,杭州湾北岸乍浦以东潮滩受潮流和长江沿岸流影响明显,沉积物主要为长江和东海源的;南岸由于曹娥江和甬江两条河流的注入,流域物质所占比例明显比北岸高。柱状岩芯样品中各黏土矿物含量自下而上的变化则反映了物源区风化强度的波动特征。 相似文献
6.
长石类矿物是地壳中最常见的硅酸盐矿物,其风化作用对地球表面环境有显著影响,因而是风化作用研究的重点矿物之一。文中以长石为例,对硅酸盐矿物的风化作用研究现状从矿物的自然风化、模拟矿物化学风化和矿物的生物风化3个方面进行阐述;对影响矿物风化的各种因素及其在风化过程中所起的作用,以及长石微生物风化作用的机理和过程进行分析;指出目前硅酸盐矿物风化研究中存在的问题,并对未来的发展方向提出建议,指出对微生物-矿物复合体微环境物理化学性质的深入研究可能成为揭示微生物-矿物相互作用机理的一个突破口。 相似文献
7.
Long-term rates of chemical weathering and physical erosion from cosmogenic nuclides and geochemical mass balance 总被引：1，自引：0，他引：1
Quantifying long-term rates of chemical weathering and physical erosion is important for understanding the long-term evolution of soils, landscapes, and Earth's climate. Here we describe how long-term chemical weathering rates can be measured for actively eroding landscapes using cosmogenic nuclides together with a geochemical mass balance of weathered soil and parent rock. We tested this approach in the Rio Icacos watershed, Puerto Rico, where independent studies have estimated weathering rates over both short and long timescales. Results from the cosmogenic/mass balance method are consistent with three independent sets of weathering rate estimates, thus confirming that this approach yields realistic measurements of long-term weathering rates. This approach can separately quantify weathering rates from saprolite and from overlying soil as components of the total. At Rio Icacos, nearly 50% of Si weathering occurs as rock is converted to saprolite; in contrast, nearly 100% of Al weathering occurs in the soil. Physical erosion rates are measured as part of our mass balance approach, making it particularly useful for studying interrelationships between chemical weathering and physical erosion. Our data show that chemical weathering rates are tightly coupled with physical erosion rates, such that the relationship between climate and chemical weathering rates may be obscured by site-to-site differences in the rate that minerals are supplied to soil by physical erosion of rock. One can normalize for variations in physical erosion rates using the “chemical depletion fraction,” which measures the fraction of total denudation that is accounted for by chemical weathering. This measure of chemical weathering intensity increases with increasing average temperature and precipitation in data from climatically diverse granitic sites, including tropical Rio Icacos and six temperate sites in the Sierra Nevada, California. Hence, across a wide range of climate regimes, analysis of chemical depletion fractions appears to effectively account for site-to-site differences in physical erosion rates, which would otherwise obscure climatic effects on chemical weathering rates. Our results show that by quantifying rates of physical erosion and chemical weathering together, our mass balance approach can be used to determine the relative importance of climatic and nonclimatic factors in regulating long-term chemical weathering rates. 相似文献
8.
Pegmatites and aplites share the common major constituents with the granitoid suite as well as various gneissic lithologies, e.g., orthogneisses, aplitic gneisses. Not surprising, the pegmatitic landscape has landforms resembling some found in landscapes derived from metamorphic and granitic rocks that genetically next of kin of pegmatites. The wealth of rare minerals, the peculiar shape, the zonation into a rim extremely vulnerable to weathering and a hard silica core renders pegmatites strikingly different from the afore-mentioned crystalline rocks and account for a landscape type of its own. The primary features of pegmatites, shape and composition, the key elements of the CMS classification scheme (Chemical composition-Mineral assemblage-Structural geology) also are critical for the secondary alteration of these rocks and the evolution of a pegmatitic landscape. The 1st order landscape formation, involving geomorphology sensu stricto and weathering contributes to the built-up of five morphological types (erosional type I, alteration type II, mixed type III, composite type IV (erosion-transport-deposition), hidden type V (under an intact roof rock or under clastic overburden)). The minerals produced by chemical weathering are accountable for type II and III, whereas the relic minerals are accountable for type I, III, IV and V. Morphological type IV leads to different placer deposits. The 2nd order landscape formation is governed by the climate giving rise to discrete zones arranged from the pole to the equator and two genetic types, the plain and valley types. Both types can genetically be correlated with the wet-and-dry and the tropical humid climates. Placers developed a clastic apron around pegmatites abundant in relic minerals whereas minerals newly formed during chemical weathering lead to clay deposits resting immediately on top of pegmatites. In terms of applied geomorphology, reading and understanding a pegmatitic landscape means creating an “ore guide” to the pegmatites, to their argillaceous supergene deposits in the apical part and their cogenetic placer deposits around. The current overview is a supplement to the review Dill (2015a). 相似文献
9.
南极松散沉积物粒度分形研究 总被引：7，自引：0，他引：7
利用分形理论, 研究了南极纳尔逊冰盖前缘发育的沉积物、风成沉积物及湖泊沉积物的粒度分布分形结构特征. 结果表明: 不同沉积环境下的沉积物粒度分形结构具有明显的差异, 冰盖前缘沉积物具有显著的分形结构特征, 而湖泊沉积物和风成沉积物不具有分形结构特征, 这为识别南极地区松散沉积物沉积环境提供了一种新的判别依据. 对纳尔逊冰盖前缘沉积物粒度分维特征的研究结果表明, 其粒度分布主要与冰川搬运的动力学过程有关, 分维值的大小与当时形成沉积物的动力学过程、沉积环境、冰盖进退及古气候环境的演化密切相关. 相似文献
10.
We present a numerical approach which accounts for nucleation, growth and/or resorption of particles of fixed composition in aqueous solutions, and which involves functionalities suited to the formation of simple clay minerals in weathering processes, such as: formation of non-spherical particles, heterogeneous/homogeneous nucleation, several growth laws, precipitation resulting from the dissolution of primary minerals. The overall model is now embedded into a new numerical code called NANOKIN, in which several optimization procedures have been introduced in order to allow long dynamics to be followed. NANOKIN was applied to the precipitation of Al- bearing minerals from aqueous solutions: halloysite, kaolinite and Ca-montmorillonite. It allowed us to propose a stable scheme for the competitive precipitation of halloysite and kaolinite under two different types of initial conditions: (1) a given initial super-saturation state of the aqueous solution; (2) progressive super-saturation resulting from the kinetic dissolution of the minerals from a granitic rock under weathering conditions. Both yield particle sizes in the micron range, but with distinct crystal size distribution functions. The interplay between kinetic and thermodynamic effects is discussed. 相似文献
11.
Hari B. Srivastava Prakash K. Shrivastava Sandip K. Roy M. Javed Beg Rajesh Asthana Pawan Govil Kamlesh Verma 《Journal of the Geological Society of India》2018,91(6):651-663
The lacustrine sediments are one of the best sources to provide information on climate change, specially in peri-glacial climatic region. Schirmacher Oasis, located on the Princess Astrid Coast in Queen Maud Land, is one of the few areas in East Antarctica that provides valuable information on paleoclimate of the region with various depositional features formed due to deglaciation process. This Oasis is dotted with more than 100 lakes of proglacial, land-locked and epi-shelf type. The multi-proxy sedimentological data, generated from the sediment cores from land-locked lakes and grab sample from a proglacial lake, lying in the same drainage line in the central part of Schirmacher region has provided better insight into the paleoclimatic evolution of the region. The immature and chemically unaltered lake sediments have shown restricted drainage pattern. Different phases of warmer and cooler intervals are highlighted by the patterns of fluctuations in different sedimentological and statistical parameters. The dominance of glacial signatures is very clear on the lake sediments as revealed by the surface textures of quartz grains. Physical weathering has mainly controlled the overall sediments and the composition of clay fraction. The clay minerals indicate a gradual shift in the weathering regime and therewith in climate from strongly glacial to fluvioglacial specially around 42 ka. This indicates beginning of warming of the area much before the LGM. But the warm period is not strong enough to alter the overall clay chemistry. Proxy records indicate short-period climatic oscillations during late Quaternary. 相似文献
12.
下庄铀矿为一花岗岩型铀矿，矿田地处湿热气候条件下，沥青铀矿普遍产于破碎带中，这种特定的产出环境致使该区沥青铀矿经受了强烈的风化，形成种类繁多、数量丰富的铀酰矿物；而我国高放废物地质处置库拟建在花岗岩体中。因此，下庄铀矿田是开展核废料氧化的天然类比研究的理想地区，并对我国的高放废物地质处置库的安全性评价有重要的指导作用。下庄铀矿田的铀酰矿物组合为铀酰氢氧化物、铀酰硅酸盐和铀酰磷酸盐，包括柱铀矿、黄钙铀矿、calciouranoite、红铀矿、富硅铀酰相、硅钙铀矿、钙铀云母和盈江铀矿等。根据它们的空间分布特征可划分成两个风化系列，即硅酸盐风化系列和磷酸盐风化系列，其共生次序分别为：沥青铀矿→铀酰氢氧化物（氧化物）→富硅铀酰相→硅钙铀矿和沥青铀矿→铀酰氢氧化物（氧化物）→钙铀云母→盈江铀矿。在该矿田中，铀酰氢氧化物是亚稳定相矿物，常常被铀酰硅酸盐或磷酸盐取代，因此，铀酰氢氧化物仅出现在少数样品中，而铀酰硅酸盐和铀酰磷酸盐矿物则非常普遍。矿田中的铀酰矿物在化学成分上以富钙为其显著特征，由于核废料地质处置库近场地下水中的Ca^2＋含量应该明显比下庄矿田地下水中的高，因此，我们预测含Ca的铀酰硅酸盐和铀酰磷酸盐矿物等热力学上的稳定物相很可能是地质处置系统中最主要的铀酰矿物，处置库内放射性核素的迁移主要是由这些矿物控制的。 相似文献
13.
Bacillus mucilaginosus is a common soil bacterium,and usually used as a model bacterium in studying microbe-mineral interactions.Several reaction mechanisms of B.mucilaginosus weathering silicate minerals were proposed.However,the molecule mechanisms and detailed processes were still unclear.In this paper,bacterium-mineral interactions were studied in terms of variations in pH value over the experimental period,variations in mineral composition,weathering rates of silicate minerals and volatile metabolites in the culture medium,etc.,to further explore the bacterium-mineral interaction mechanisms.The results showed that B.mucilaginosus could enhance silicate mineral weathering obviously.The weathering rates were quite different for various kinds of silicate minerals,and the weathering rate of weathered adamellite could reach 150 mg/m2/d.Although B.mucilaginosus produced little acidic substance,pH in the microenvironment of bacterium-mineral complex might be far lower than that of the circumjacent environment;a large amount of acetic acid was found in the metabolites,and was likely to play an important role as a ligand.These results appear to suggest that acidolysis and ligand degradation are the main mechanisms of B.mucilaginosus dissolving silicate minerals,the formation of bacterium-mineral complexes is the necessary condition for the bacteria weathering silicate minerals,and extracelluar polysaccharides played important roles in bacterium-mineral interaction processes by forming bacterium-mineral complexes and maintaining the spe-cial physicochemical properties of microenvironment. 相似文献
14.
微生物对生命元素如碳、氮、硫、氧和金属离子的代谢作用能显著的改变微生物周边的外部环境和其内部环境。在一系列的生物地球化学过程中,微生物参与了矿产的沉积(生物成矿)或参与了矿石和岩石的溶解(生物风化)。生物成矿作用有两个途径：一个叫生物诱导成矿,通过这个过程,微生物分泌出代谢产物导致了之后的矿物颗粒的沉积;另一个叫生物控制成矿,在这个过程中,微生物在控制矿物成核和生长上起到了显著作用。微生物成因的矿物总体来说颗粒都很小和／或有着独特的同位素特征。最普遍的生物成因矿物有碳酸盐、硫化物和铁的氧化物。细胞表面和其分泌的胞外聚合物的结构可以为离子的浓缩、聚合和矿化提供模板,并起到重要作用。地球材料的仿生合成帮助我们了解了在人工条件下的生物成矿机制。此外,在地质环境中生物成因的矿物还可以作为一种生物信号,用来重建地球和其他行星的起源和演化。 相似文献
15.
蚯蚓肠道内小分子有机酸与摄入的土壤矿物相互作用,加速矿物溶解。摄入的土壤在蚯蚓肠道内平均停留时间约为12 h,不足以使土壤矿物产生显著的溶解特征,因此这一过程难以在蚯蚓体内进行评估。本研究通过体外实验控制pH值和有机酸浓度,模拟蚯蚓肠道中有机酸对土壤中常见矿物的溶解反应,探讨了方解石和钾长石在蚯蚓肠道环境中的初始溶解动力学。研究发现,矿物在混合有机酸中的溶解速率比在纯水中高一个数量级,说明有机配体和质子促进了矿物溶解。溶解速率及粒度分析表明,方解石(CaCO3)溶解速率不受溶解过程中粒度变化的影响,而钾长石(KAlSi3O8)粒度在溶解期间未出现显著变化。在此基础上,采用初始速率法模拟了钾长石的初始溶解动力学,计算得出的溶解速率表明钾长石在溶解初期主要为表面K~+的释放。使用缩核模型(shrink core model)和Hixson-Crowell模型对方解石溶解过程进行动力学解析,发现方解石的溶解主要受溶液中反应物内扩散的速率影响。这定量描述了两种矿物在有机酸溶液和纯水中的溶解差异。现有研究表明,有机配体和质子协同促... 相似文献
16.
《Applied Geochemistry》2000,15(2):235-243
Sulfide mineral weathering is a major source of acid generation in mining environments. Oxidation and hydrolysis reactions in soil and geologic material under earth surface conditions causes weathering of reduced sulfide minerals resulting in liberation of weathering products including acid. Pyrite and marcasite are minerals common in mine environments that cause acid generation. Many other sulfide minerals are present in mining environments which may or may not form acid upon weathering. Characterization of complex mineral assemblages containing S compounds is therefore critically important to pre-mine planning and postmine waste characterization. Despite the importance of mineral weathering behavior, little is known about the acid generation characteristics of common sulfide and sulfate minerals. To assess the response of common sulfide and sulfate minerals to oxidizing conditions, 13 minerals were subjected to treatment with 10% H2O2. The resulting leachate was analyzed for pH, electrical conductivity, S and titratable acidity. The sulfide minerals arsenopyrite, pyrite, chalcopyrite, pyrrhotite, marcasite and sphalerite demonstrated significantly elevated levels of titratable acidity and are acid generating in contrast to galena, chalcocite and all the sulfates. The sulfate minerals barite, anhydrite, gypsum, anglesite and jarosite were included in experimentation and were found not to form acid under strongly oxidizing conditions. Remediation strategies for disturbed lands containing reduced S minerals must therefore consider not only the total quantity of sulfide minerals present, but the specific mineralogy of the S compounds. 相似文献
17.
The aim of this contribution is to explore the relationship among some concepts, often considered to be unrelated, such as weathering reactions, compositional data and fractals by means of distribution analysis.Weathering reactions represent the necessary transfer of heat and entropy to the environment in geochemical cycles. Compositional data express the relative abundance of chemical elements/species in a given total (i.e. volume or weight). Fractals are temporal or spatial objects with self-similarity and scale-invariance, so that internal structures repeat themselves over multiple levels of magnification or scales of measurement.Gibbs's free energy and the application of the Law Mass Action can be used to model weathering reactions, under the hypothesis of chemical equilibrium. Compositional data are obtained in the analytical phase after the determination of the concentrations of chemicals in sampled solid, liquid or gaseous materials. Fractals can be measured by using their fractal dimensions.In this paper, the presence of fractal structures is observed when the frequency distribution of isometric log-ratio coordinates is investigated, showing the logarithm of the cumulative number of samples exceeding a certain coordinate value plotted against the coordinate value itself. Isometric log-ratio coordinates (or balances) were constructed by using the sequential binary partition (SBP) method. The balances were identified to maintain, as far as possible, the similarity with a corresponding weathering reaction affecting the Arno river catchment (Tuscany, central Italy) as described by the Law of Mass Action. The emergence of fractal structures indicates the presence of dissipative systems, which require complexity, large numbers of inter-connected elements and stochasticity. 相似文献
18.
含U副矿物的地质年代学研究综述 总被引：11，自引：0，他引：11
简要介绍了目前已经发展起来的各种微区原位测年技术的特点和研究矿物内部结构的技术。微区原位测年技术有离子探针、激光探针同位素测年技术、电子探针、质子探针和X射线荧光探针Th U 全Pb化学等时线年龄技术。综述了锆石、独居石、磷钇矿、榍石、磷灰石、金红石、斜锆石等含U副矿物在U Th Pb年代学研究方面的应用及进展，并介绍了锆石、独居石、磷钇矿、榍石等具有多世代性的矿物的成因判别方法，概括了用于岩浆过程、变质过程和沉积过程年代学研究常用的含U副矿物，及其相应的年代学研究需要注意及可解决的地质问题和适用性。总结了岩石年代学研究的主要进展和提取贮存在副矿物中有价值的年龄和成因信息需要解决的问题。 相似文献
19.