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1.
铜山岭铜多金属矿床是湘南W、Sn、Pb、Zn、Cu多金属矿集区的代表性矿床,本文对其不同类型岩石和矿石矿物进行了S、Pb、C同位素组成对比研究。矿石硫化物的δ34 S值变化范围为-1.9‰~5.7‰,平均值为2.6‰,硫主要来源于硫同位素组成均一化的岩浆。硫化物硫同位素平衡温度表明,矿床主要成矿温度为134~339℃。矿石铅的206 Pb/204 Pb、207 Pb/204 Pb、208 Pb/204 Pb比值分别为18.256~18.856、15.726~15.877、38.352~39.430;岩体岩石铅的206Pb/204Pb、207Pb/204Pb、208Pb/204Pb比值分别为18.617~18.805、15.721~15.786、38.923~39.073;两者铅同位素组成相同,都主要为上地壳铅,是由同一岩浆体系分异形成,可能来源于古老基底岩石。不同类型岩石、方解石矿物的δ13 CPDB值为-9.88‰~1.32‰,δ18 OSMOW值为11.67‰~17.68‰,从矽卡岩矿体到距岩体稍远的围岩地层,方解石矿物的δ13 CPDB、δ18 OSMOW值逐渐增大,成矿流体中的碳早期可能主要来源于岩浆,在成矿过程中有部分碳酸盐岩地层碳的加入。铜山岭矿床成矿物质主要来源于岩浆,赋矿地层对矿床成矿物质来源作用不显著,仅提供了少量成矿物质。  相似文献   

2.
滇西金厂河铁铜铅锌多金属矿床位于保山地块北部,是"三江"多金属成矿带内典型矿床之一。对该矿床开展硫铅同位素示踪研究,探讨成矿物质来源,并结合构造背景和成矿时代分析了矿床成矿机制。样品测试结果表明,矿石中硫化物的δ~(34)S值为+2.5‰～+11.1‰,平均值为+5.65‰,硫同位素来源为深部幔源岩浆和岩浆上侵混染壳源物质形成的多种硫源同位素组合;矿石矿物铅同位素组成中~(206)Pb/~(204)Pb为18.167～18.497,~(207)Pb/~(204)Pb为15.668～15.779,~(208)Pb/~(204)Pb为38.554～38.997,铅同位素总体较稳定,显示壳幔混染特征,以上地壳铅为主,可能来源有深部侵入岩浆及赋矿围岩。由矿床成矿物质来源表现出的多源、深源-浅源的特征推测,与成矿有关的中酸性岩体隐伏在区域深部。  相似文献   

3.
那更康切尔银矿是东昆仑造山带的大型热液脉型独立银矿床,有望达到超大型规模。以矿区地质特征为研究基础,开展硫化物硫-铅同位素、二长花岗岩和花岗闪长岩铅同位素研究,探讨成矿物质来源及两类岩体与成矿的关系。矿区硫化物样品(黄铁矿、方铅矿和闪锌矿)的δ34S值介于-6.1‰~3.9‰之间,主体δ34 S值介于-4‰~2.1‰之间,数值集中,指示成矿物质硫源具有深源岩浆硫的特征。矿石铅同位素组成中206 Pb/204 Pb、207 Pb/204 Pb、208 Pb/204 Pb的变化范围分别为18.28~18.62、15.6~15.73、38.38~39.1,矿石铅具有壳幔混合源的特点。矿区内二长花岗岩LA-ICP-MS锆石U-Pb年龄为239±1 Ma,(206Pb/204Pb)i、(207Pb/204Pb)i、(208Pb/204Pb)i值分别为18.389~18.585、15.638~15.648、38.288~38.558;花岗闪长岩LA-ICP-MS锆石U-Pb年龄为252±1 Ma,(206Pb/204Pb)i、(207Pb/204Pb)i、(208Pb/204Pb)i值分别为18.348~18.447、15.625~15.629、38.394~38.412,铅同位素组成投图显示成矿与2类岩浆岩关系较弱,与区域上鄂拉山组火山岩呈较明显的线性相关。那更康切尔银矿与邻区哈日扎铅锌银矿床具有相似的成矿物质来源,硫源具有同一性,且矿石铅同位素组成表现出很明显的线性关系,表明2个矿床的成矿物质具有相近或相似的源区或演化过程。成矿地质条件、成矿物质来源及成矿流体特征均表明两者属中-低温热液脉型矿床。综合本文及前人对那更康切尔银矿床的研究,构建了成矿模式和找矿模型,为区域内同类型银矿床的找矿工作提供了指导作用。  相似文献   

4.
广西西大明山多金属矿集区是右江褶皱带东南缘近年找矿突破的重要地区,发育凤凰山特大型银矿床、罗维中型钨锌多金属矿床、弄屯大型铅锌矿床及一些中、小型矿床等。其中罗维和弄屯矿床是近年新发现的矿床,矿体分别呈层状赋存于寒武系碎屑岩和呈脉状赋存于寒武系与泥盆系接触界面附近或断裂破碎带中。笔者对矿集区内层状和脉状矿床矿石硫化物铅同位素进行研究,并与赋矿围岩、隐伏二长花岗岩进行对比。铅同位素数据显示:罗维层状矿床矿石硫化物铅同位素组成为:~(206)Pb/~(204)Pb=18.1320~18.5980,~(207)Pb/~(204)Pb=15.5920~15.7988,~(208)Pb/~(204)Pb=38.4041~39.0461;弄屯脉状矿床矿石硫化物铅同位素组成为:~(206)Pb/~(204)Pb=18.3240~18.5060,~(207)Pb/~(204)Pb=15.7321~15.9140,~(208)Pb/~(204)Pb=38.6511~39.2311;二者具有相似的同位素组成,但弄屯矿床矿石硫化物~(207)Pb/~(204)Pb比值略高于罗维矿床矿石硫化物。罗维矿床矿石硫化物铅同位素组成与深部隐伏二长花岗岩铅同位素组成一致;而弄屯矿床矿石硫化物~(208)Pb/~(204)Pb值介于二长花岗岩和地层铅同位同位素组成之间,且矿石~(207)Pb/~(204)Pb比值指示矿石铅可能来源于上泥盆统莲花山组碎屑岩与中寒武统黄洞口组碎屑岩。渌井和大新铅锌矿床显示出异常高的~(207)Pb/~(204)Pb,暗示可能还有其他富铀的地质体为成矿提供放射成因铅,铅同位素特征值(μ值、ω值)揭示矿石硫化物和岩体都具有壳源铅的特征;从垂向上,各矿床距罗维隐伏岩体顶界距离增加,岩浆铅减少,地层铅增加。综合研究认为,西大明山多金属矿集区应属于典型的与深部燕山期岩体侵入有关的岩浆热液充填交代型矿床,成矿物质主要来源于燕山期岩浆和围岩地层。  相似文献   

5.
黔西北筲箕湾铅锌矿床成矿物质来源:Pb同位素证据   总被引：1，自引：0，他引：1  
筲箕湾铅锌矿床位于扬子地块西南缘川滇黔相邻铅锌矿集区黔西北铅锌成矿区垭都―蟒硐断裂带,是贵州省有色金属及核工业地质勘探局近年发现的中型矿床。对该矿床原生矿体中主要矿石矿物黄铁矿、方铅矿和闪锌矿进行了Pb同位素组成分析,结果表明矿床Pb同位素组成变化不大,其中206Pb/204Pb、207Pb/204Pb和208 Pb/204 Pb的分布范围分别在18.616～18.686、15.682～15.728和39.067～39.181之间,在206 Pb/204 Pb-207 Pb/204 Pb和206 Pb/204 Pb-208 Pb/204 Pb图中,样品投影在上地壳铅平均演化线附近的狭小区域和区域基底岩石的Pb同位素组成范围之内,靠近不同时代碳酸盐地层以及川滇黔相邻矿集区滇东北成矿区会泽超大型铅锌矿床和黔西北成矿区天桥铅锌矿床,与震旦纪灯影组白云岩和峨眉山玄武岩分布范围存在明显差异。推测矿床成矿物质来源以基底岩石为主,区域上不同时代碳酸盐地层可能提供了部分成矿物质。  相似文献   

6.
为了解藏南柯月铅锌多金属矿床主要矿物的标型特征及成矿物质来源,在详细野外及室内工作基础上对柯月铅锌多金属矿床进行了矿物电子探针和S-Pb同位素测定。柯月铅锌多金属矿床硫化物种类较多,电子探针分析结果显示,硫化物伴随的Cu、Ag含量较高。闪锌矿具有层控矿床特征,方铅矿及黄铁矿的标型特征表明其与沉积改造作用相关,同时也受到了岩浆及火山作用的影响。S同位素δ~(34)SCDT为4.9‰~11.2‰,与日当组地层S源范围相近,Pb同位素显示~(206)Pb/~(204)Pb比值为18.53~19.78,平均为19.589;~(207)Pb/~(204)Pb比值为15.674~15.939,平均为15.848;~(208)Pb/~(204)Pb比值为38.618~40.559,平均为40.155,与附近扎西康矿床的Pb同位素呈线性排列且放射性成因Pb较高,模式年龄均为负值,落入了北喜马拉雅和高喜马拉雅变质结晶岩系的印度地盾端元内,指示来源于上地壳。综上认为柯月铅锌多金属矿床具有沉积改造型矿床的特征;日当组地层及围岩对成矿提供矿源初始物质并且与扎西康特大型矿床成矿物质来源相似。  相似文献   

7.
针对分布于豫西南栾川地区的脉状铅锌矿床,进行铅锌矿、地层和岩浆岩的铅同位素数据对比分析研究显示:该区铅锌矿床的铅同位素组成(赤土店矿床206Pb/204Pb=17.005～17.953,207Pb/204Pb=15.414～15.587,208Pb/204Pb=37.948～39.036;冷水北沟矿床206Pb/204Pb=17.602～17.954,207Pb/204Pb=15.458～15.606,208Pb/204Pb=38.208～38.772;百炉沟矿床206Pb/204Pb=17.552～18.426,207Pb/204Pb=15.451～15.5794,208Pb/204Pb=38.264～39.637)与区内燕山期斑岩和地层的铅同位素组成(燕山期斑岩206Pb/204Pb=17.189～17.894,207Pb/204Pb=15.381～15.569,208Pb/204Pb=37.655～39.01;元古界岩石206Pb/204Pb=17.694～19.249,207Pb/204Pb=15.467～15.585,208Pb/204Pb=38.303～41.104)有一定的相似和差别。铅同位素特征值(μ值、ω值)、Δβ-Δγ、206Pb/204Pb-207Pb/204Pb、Δα-Δβ-Δγ等分析研究,揭示铅锌矿床铅与燕山期斑岩和地层铅的来源关系,综合研究,认为栾川地区脉状铅锌床为与燕山中期斑岩侵入有关的岩浆热液充填-交代型矿床,成矿物质存在燕山期岩浆和围岩地层两种来源。  相似文献   

8.
康家湾铅锌多金属矿床位于湖南水口山矿田的东部,是矿田内最大的铅锌金银矿床,以铅锌为主,共伴生金银矿。通过硫、铅、氢-氧同位素研究,显示金属硫化物硫同位素δ~(34)S(-4.3‰～+2.1‰)主要变化范围为0～+3‰,说明本区硫化物硫同位素组成具有岩浆硫的特征(δ~(34)S=0‰);矿石铅同位素组成~(206)Pb/~(204)Pb、~(207)Pb/~(204)Pb、~(208)Pb/~(204)Pb比值分别变化于18.182～18.840、15.180～15.96、37.892～39.499之间,显示具有正常铅特点;在构造分配模式图解和构造环境判别图中,本区矿石铅同位素的投点均分布于上地壳演化线、造山带演化线和地幔演化线之间,暗示其铅同位素属于壳幔混合型铅;在Δγ-Δβ成因分类图解中,本区矿石铅同位素投点均分布于岩浆作用范围内,反映本矿床的成矿流体来源于岩浆岩;而氢-氧同位素表明,康家湾铅锌矿床成矿流体是多源的,主要由大气降水和岩浆水混合而成,早期以岩浆水为主,后期混入大量的大气降水。从而证明康家湾铅锌多金属矿床的形成与岩浆侵入活动有着密切的成因关系,应属于中低温岩浆热液型铅锌多金属矿床。  相似文献   

9.
陈欣彬 《地质与勘探》2017,53(2):227-236
滇中前震旦系主要位于扬子地块西南缘,元谋-绿汁江断裂以东、普渡河-滇池断裂以西,岩浆活动强烈导致该区地壳结构复杂,具有"多层结构"的特点。据统计,赋存在昆阳群中的铅锌矿床(点)有近20处,其赋矿地层主要为:大龙口组(Pt_2d)、黑山头组(Pt_2hst)、鹅头厂组(Pt_2e)。本文优选大笑、热水塘硫铅同位素进行系统分析对比,总结指示成矿流体与指示物质来源。研究结果显示:赋存在前震旦纪铅矿矿床~(34)S值变化范围在6.33‰~14.99‰,成矿流体的总硫同位素值(δ~(34)SΣS)12.17‰。由此可见,赋存在前震旦纪地层中铅锌矿床硫化物主要为混合硫来源,硫同位素的来源具有多源性的特点。东川大笑铅锌矿:~(206)Pb/~(204)Pb变化范围为18.282~18.391,~(207)Pb/~(204)Pb变化范围为15.491~15.515,208Pb/204Pb变化范围为38.287~38.326,主要分布于地幔、造山带演化线。热水塘铅锌矿:~(206)Pb/~(204)Pb变化范围17.702~18.512,~(207)Pb/~(204)Pb变化范围15.626~15.72,~(208)Pb/~(204)Pb变化范围37.504~38.528,主要分布在造山带演化线附近。μ、ω值的变化范围表明所分析样品铅同位素均属于异常铅,说明其成矿物质多来源。因此,铅同位素主要来自地幔、上地壳和造山带,暗示成矿物质来源具有多源型特点。  相似文献   

10.
闽中梅仙铅锌多金属矿产于中—新元古代“变质基底天窗”绿片岩系中,目前对其成矿物质来源、矿床成因认识不一。对该矿区的丁家山和峰岩铅锌多金属矿床主成矿期的闪锌矿和方铅矿等金属硫化物进行S、Pb同位素分析,结果表明:丁家山和峰岩矿床的硫、铅同位素组成基本一致,其金属硫化物的δ34S值分别为0.4‰~5.0‰和1.8‰~4.2‰,平均值则分别为2.66‰和2.88‰,表明硫为幔源硫。金属硫化物的铅同位素组成206Pb/204Pb、207Pb/204Pb和208Pb/204Pb值则分别为18.326~18.496和18.378~18.646、15.658~15.817和15.619~15.746、38.724~39.257和38.365~39.009,平均值则分别为18.388和18.447、15.705和15.700、38.880和38.823,表明2矿床铅均为壳幔混合源铅。综合硫、铅同位素分析结果,认为丁家山和峰岩铅锌多金属矿床成矿物质主要来自燕山期花岗(斑)岩。结合矿床、矿体地质特征分析,丁家山和峰岩铅锌多金属矿的形成主要与燕山期花岗(斑)岩侵入接触交代作用有关。  相似文献   

11.
The large-scale Bayanbaolege Ag polymetallic deposit is situated in the Tuquan–Linxi Fe-Sn-Cu-Pb-Zn-Ag metallogenic sub-belt in eastern slopes of the southern Great Xing’an Range, NE China. The sulfide-quartz vein-type orebodies in the deposit are hosted primarily in the Early Cretaceous granodiorite porphyry and Late Permian strata. Three primary paragenetic stages of veining have been identified: (I) arsenopyrite- pyrite-quartz stage, (II) pyrite-sphalerite-quartz stage, and (III) galena-silver minerals (pyrargyrite, argentite, and pearceite)-calcite stage. The Rb–Sr dating of sulfides yielded an isochron age of 129.9 ± 2.9 Ma (MSWD = 2.1) for the sphalerite, which constrains the mineralization age to the Early Cretaceous. Rb and Sr concentrations in the sulfides ranged from 0.0940 to 1.0294 ppm and 0.0950–3.3818 ppm, respectively. The initial 87Sr/86Sr value of the sphalerite was 0.70852 ± 0.00018, indicating that the mineralized materials were derived from the mixed crust-mantle source area. S isotope analysis showed that the δ34S values of the sulfide samples varied in a narrow range, from −1.5‰ to +1.3‰ (mean −0.65‰), indicating a magmatic S source. Pb isotopic ratios of the sulfides (206Pb/204Pb = 18.306–18.416, 207Pb/204Pb = 15.524–15.605, 208Pb/204Pb = 38.095–38.479) and the granodiorite porphyry (206Pb/204Pb = 18.341–18.933, 207Pb/204Pb = 15.539–15.600, 208Pb/204Pb = 38.134–38.944) reflect that the ore-forming materials originated from contemporaneous magma with Early Cretaceous granodiorite porphyry. This study of the Bayanbaolege deposit and other hydrothermal deposits in the area provides compelling evidence that the widespread Mesozoic magmatism and mineralization in the southern Great Xing’an Range occurred in an intracontinental extensional tectonic setting, which was associated with the westward subduction of the paleo-Pacific plate.  相似文献   

12.
The western margin of the Yangtze Block hosts the giant Upper Yangtze Pb-Zn metallogenic province, with the occurrence of >400 carbonate-hosted Pb-Zn deposits. More than 50% of these deposits are hosted in carbonate rocks of late Ediacaran to early Cambrian age. Although they have attracted great attention over the past two decades, it is still unclear why such carbonate sequences host so many Pb-Zn deposits and the role that the country rocks played during mineralization. The newly-discovered Maliping Pb-Zn deposit (~6 Mt @ 4.18 wt% Pb and 9.18 wt% Zn) is hosted in early Cambrian strata composed of carbonate and phosphate rocks, black shales, as well as evaporite sulfates, of which the carbonate rocks are the direct ore-hosting rocks. Evidence from mineralogy and the concentrations of ore-forming metals indicate that the phosphate rocks played an important role in providing geochemical barriers during Pb-Zn ore formation. Homogenization temperatures of the primary fluid inclusions in sphalerite and quartz range from 185 to 282 °C, and their salinities vary from 3.39 to 17.17 wt% NaCl equiv. The REE and C-O isotopes imply that the hydrothermal carbonates were formed under relatively oxidizing conditions and that the wall rocks were involved in the Pb-Zn mineralization through dissolution. Sulfur isotopic compositions (δ34S = +7.60–+31.79‰) of sulfides reveal that S2− originated from evaporite sulfates within the ore-hosting strata, and that the black shales acted as an important reducing agent during thermo-chemical reduction (TSR). Pb isotopic ratios of galena (206Pb/204Pb = 17.856–17.973, 207Pb/204Pb = 15.668–15.689 and 208Pb/204Pb = 37.953–38.101) are similar to those of Proterozoic basement rocks in the region. This implies that the basement could be the key source of mineralizing metals. Hence, we propose that: (i) The favorable lithological combination of early Cambrian phosphate rocks, black shales, carbonates and evaporites, as well as Proterozoic basement in the area, were responsible for controlling the majority of Pb-Zn deposits in the late Ediacaran-early Cambrian carbonate sequences in the western Yangtze Block; and (ii) the Maliping Pb-Zn deposit resulted from a combination of mineralized fluids, various trap structures and favorable lithologies, of which the fluids were epigenetic with low to moderate temperatures and salinities.  相似文献   

13.
Abstract: The Dajing Cu‐polymetallic ore deposit in Linxi county, Inner Mongolia Autonomous Region, China, is economically a valuable Cu–Sn–Ag–Zn–Pb deposit in the southern section of the Da Hinggan metallogenic province. For the analyzed 23 samples of sulfide minerals, including chalcopyrite, pyrite, sphalerite and galena, the δ34S values range from –1.8 to +3.8 % with an average of +0.65 %. The narrow distributions of the δ34S values with +1 % peak value, including the published data, and the δ13C values around –5 % indicate that the sulfur and carbon of the hydrothermal fluids are derived from a hypomagmatic source, and exclude the possibility that the hosted strata, i.e., the Upper Permian Linxi Formation, provided certain amounts of sulfur and carbon. The 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios of sulfide ores range respectively within 18.257‐18.368, 15.476‐15.609, and 37.916‐38.355 with the model ages of 122–209 Ma. The black shale, however, contains higher radiogenic lead with the 206Pb/204Pb ratios of 18.473‐20.156, differing from the ores. However, the 206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb ratios of the ore, basaltic porphyrite and feldspar leads are similar, and lie on the same lines in the diagrams of 208Pb/204Pb vs. 206Pb/204Pb and 207Pb/204Pb vs. 206Pb/204Pb. The fact that these mixing lines are composed of the two end members, the mantle and orogenic belt, strongly supports that all the metallogenic elements were carried by the hypomagma mixing the matters of the mantle and orogenic belt prior to the Mesozoic. Therefore, the Dajing ore deposit is a typical mag–matic–hydrothermal vein type ore deposit associated with subvolcanic rocks.  相似文献   

14.
Qingdong Zeng    Jianming Liu    Zuolun Zhang    Changshun Jia    Changming Yu    Jie Ye    Hongtao Liu 《Resource Geology》2009,59(2):170-180
The Baiyinnuoer deposit (32.74 Mt ore with grades of 5.44% Zn, 2.02% Pb and 31.36 g t?1 Ag), the largest Zn‐Pb‐Ag deposit in northern China, is hosted by crystalline limestone and slate of the Early Permian Huanggangliang Formation. Detailed cross‐section mapping indicates stratigraphic and fold structural controls on the mineralization. The Zn‐Pb‐Ag mineralization is hosted predominantly by skarn, which occurs as bedding‐parallel lens that pinch out at the margins of the main economic zone. Three skarn stages are identified at the deposit: (i) garnet‐clinopyroxene; (ii) sulfides; and (iii) carbonate‐epidote. Lead isotopic compositions were determined for galena and sphalerite of the ores, whole rock samples of the Yanshanian granite and granodiorite, Permian marble and tuff, and Jurassic volcanic and subvolcanic rocks in and around the Baiyinnuoer area in order to discuss the sources of ore‐forming materials and the relationship between the ore formation and these whole rocks. Galena and sphalerite of the Baiyinnuoer ore have uniform isotopic ratios (206Pb/204Pb, 18.267–18.369; 207Pb/204Pb, 15.506–15.624; 208Pb/204Pb, 38.078–38.394) consistent with the granite and granodiorite (206Pb/204Pb, 18.252–18.346; 207Pb/204Pb, 15.504–15.560; 208Pb/204Pb, 38.141–38.320), whereas the ratios for Jurassic volcanic and subvolcanic rocks are variable and radiogenic (206Pb/204Pb, 18.468–18.614; 207Pb/204Pb, 15.521–15.557; 208Pb/204Pb, 38.304–38.375). These results indicate that the mineralization was not related to the Jurassic volcanism, but to the Yanshanian magmatism. The Permian strata may have a slight contribution to the mineralization. All features show that the Baiyinnuoer deposit is related to the Yanshanian granitic magmatism, and can be classified as a zinc‐lead‐silver skarn deposit.  相似文献   

15.
内蒙古白音诺尔铅锌矿铅同位素研究   总被引：1，自引：0，他引：1  
内蒙古白音诺尔铅锌矿床是大兴安岭地区储量最大的铅锌矿床,矿体主要沿花岗闪长（斑）岩与大理岩接触带产出。为了查明成矿物质来源,对矿石中的硫化物和矿区内及外围主要侵入岩开展了铅同位素示踪分析。测试结果表明：矿石中硫化物的N（206Pb）/N（204Pb）为18.266～18.372,平均值18.296,N（207Pb）/N（204Pb）为15.501～15.579,平均值15.536,N（208Pb）/N（204Pb）为38.016～38.339,平均值38.138。铅同位素年龄校正计算结果表明：矿石中硫化物的Pb同位素比值与大理岩和花岗闪长（斑）岩非常相似,表明矿石中的铅主要来自花岗闪长（斑）岩和大理岩,说明成矿物质也主要来自这两类岩石,进一步证明了白音诺尔铅锌矿床的成矿与花岗闪长（斑）岩和大理岩有关,属于矽卡岩型矿床,与喷流沉积型和火山岩块状硫化物矿床有明显的差别。与区域上其他银多金属矿床对比发现,本区银多金属矿床的Pb同位素组成非常相似,其组成范围多有重叠,暗示这些矿床的矿石铅来源也非常相似,可能表明有一个共同的富银的基底或地层为这些银多金属矿床的形成提供了成矿物质来源。  相似文献   

16.
The paper considers the results of high-precision Pb–Pb isotopic analysis of 120 galena samples from 27 Au and Ag deposits of the South Verkhoyansk Synclinorium (SVS) including large Nezhdaninsky deposit (628.8 t Au). The Pb isotopic composition is analyzed on a MC-ICP-MS NEPTUNE mass-spectrometer from solutions with an error of no more than ±0.02% (2σ). Four types of deposits are studied: (i) stratified vein gold–quartz deposits (type 1) hosted in metamorphosed Upper Carboniferous–Lower Permian terrigenous rocks and formed during accretion of the Okhotsk Block to the North Asian Craton synchronously with dislocation metamorphism and related granitic magmatism; (ii) vein gold–quartz (Nezhdaninsky type) deposits also hosted in Lower Permian metasedimentary rocks; (iii) Au–Bi deposits localized at the contact zones of the Late Cretaceous granitic plutons; and (iv) Sn–Ag polymetallic deposits related to granitic and subvolcanic rocks of the Okhotsk Zone of the SVS. The deposits of types 2, 3, and 4 are postaccretionary. The general range of 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios is 18.1516–18.5903 (2.4%), 15.5175–15.6155 (0.63%), and 38.3010–39.0481 (2.0%), respectively. In 206Pb/204Pb–207Pb/204Pb and 206Pb/204Pb–208Pb/204Pb diagrams, the data points of Pb isotopic compositions of all deposits occupy restricted, partly overlapping areas along a general elongated trend. The various SVS Au–Ag deposits can be classified according to the Pb isotopic composition in accordance with all three Pb ratios. Deposits of the same type show distinct Pb isotopic compositions that strongly exceed the scale of analytical error (±0.02%). The differences in Pb isotopic composition within specific deposits are low and subordinate and have little effect on variations in the Pb isotopic composition of the SVS deposits. The μ2 values (Stacey–Kramers model), which characterize the 238U/204Pb ratios of ore lead sources of the SVS deposits, widely vary from 9.7 to 9.38. The ω2 values (232Th/204Pb) are 39.82–36.61, whereas the Th/U ratios are 4.04–3.86. The content of all three radiogenic Pb isotopes and μ2 values of feldspars from SVS intrusive rocks are strongly distinct from those of galena of stratified gold–quartz and vein gold–quartz deposits and are identical to Pb of galena from Au–Bi and Sn–Ag polymetallic deposits, indicating a mostly magmatic origin for the Pb of these deposits. Detailed isotopic study of the Nezhdaninsky deposit shows different Pb isotopic composition of two consecutive mineral assemblages (gold–sulfide and Ag polymetallic): ~0.30, ~0.07, and ~0.22% for 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb ratios, respectively. These differences are interpreted as a result of involvement of at least two metal sources during the evolution of an ore-forming system: (i) host Lower Permian terrigenous rocks and (ii) a magmatic source similar in Pb isotopic composition to that of Sn–Ag polymetallic deposits. The Pb isotopic composition and μ2 and Th/U values show that lead of stratified gold–quartz deposits combines isotopic tracers of lower and upper crustal sources (Upper Carboniferous–Lower Permian terrigenous rocks), lead of which was mobilized by ore-bearing fluids. The high 208Pb/206Pb ratios and Th/U evolutionary parameter are common to all Pb isotopic composition of all studied Au–Ag deposits and SVS Cretaceous intrusive rocks and indicate that Pb sources were depleted in U relative to Th. Taking into account the structure of the region and conceptions on its evolution, we can suggest that the magma source was related to lower crustal subducted rocks of the Archean (~2.6 Ga) North Asian Craton and the Okhotsk terrane.  相似文献   

17.
The Hongdonggou Pb-Zn polymetallic ore deposit,located in the southwestern part of the Luanchuan Mo-W-Pb-Zn-Ag polymetallic ore mineralization in Henan Province,China,is an important part of the East Qinling metallogenic belt.The orebodies in the deposit,which are vein,bedded and lenticular,are mainly hosted in the syenite porphyry,and formed within the carbonate and clastic rocks of the Yuku and Qiumugou formations partially.The genesis of the deposit has previously been argued to be of hydrothermal-vein type or of skarn-hydrothermal type.In this study,we report the results of Rb-Sr isotopic dating based on sphalerites from the main orebody of the Hongdonggou Pb-Zn polymetallic ore deposit,which yield an isochron age of 135.7 ± 3.2 Ma,constraining the timing of mineralization as early Cretaceous.The age is close to those reported for the Pb-Zn deposits in the Luanchuan ore belt.The(~(87)Sr/~(86)Sr),values of the sphalerites(0.71127 + 0.00010) are lower than that of terrigenous silicates(0.720) and higher than the mantle(0.707),suggesting that the metallogenic components were mainly derived through crust-mantle mixing.Combining the results from this study with those from previous work,we propose that the Hongdonggou Pb-Zn polymetallic ore deposit is a hydrothermal-vein deposit associated with the early Cretaceous tectonothermal event,and the mineralization is controlled by NWand near EW-trending faults in the Luanchuan Mo-W-Pb-Zn-Ag polymetallic ore concentration belt.  相似文献   

18.
《International Geology Review》2012,54(10):1220-1238
Recently, many Mo deposits genetically related to emplacement of Early Cretaceous granites have been found in the Dabie–Qinling belt. A typical intrusion that combines magmatism and metallogenesis, the Bao'anzhai granite, yields a zircon 238U–206Pb age of 123.2 ± 1.1 Ma and a molybdenite Re–Os isochron age of 122.5 ± 2.7 Ma. This granite is characterized by high silica and alkali, but low Mg, Fe, and Ca. It is enriched with light rare earth elements (REEs) and large-ion lithophile elements (LILEs, Rb, K, Th, U) but depleted of heavy REEs, high field strength elements (HFSEs, Nb, Ta, Ti, and Y), and Sr. This high-K granite has medium initial 87Sr/86Sr ratios (0.706518–0.707116) and low initial Pb isotopic ratios [(206Pb/204Pb)i, 16.423–16.699; (207Pb/204Pb)i, 15.285–15.345; (208Pb/204Pb)i, 37.335–37.633], and is characterized by low ?Nd(t) and ?Hf(t) values (?14.92 to??14.22 and??21.67 to??19.19, respectively). These data indicate that this pluton is a high-K calc-alkaline fractionated I-type granitite. It was generated by partial melting of the Yangtze lower crust, which is probably similar to Neoproterozoic TTG-like magmatic rocks at the north Yangtze Block under a non-thickened lower crust environment (<35 km). The ores also have low radiogenic Pb isotopes (206Pb/204Pb, 16.592–17.674; 207Pb/204Pb, 15.300–15.476; 208Pb/204Pb, 37.419–37.911) and low Re content in molybdenite (5.693–10.970 ppm), suggesting a crustal magmatic source for the metallogenic minerals in the Mo deposit.  相似文献   

19.
冈底斯-念青唐古拉成矿带矿床成矿元素组合由南向北存在着Cu-Au、Cu-Mo向Pb-Zn-Cu-Fe、Pb-Zn过渡的变化规律,但引起该变化规律的原因目前少研究。本文通过对成矿带典型矿床Pb同位素特征较为系统的总结,并结合成矿年代学和区域构造演化研究成果,从成矿物质来源的角度对该分带性进行了初步探讨。研究表明成矿带由南到北成矿物质来源存在着差异:最南端Cu-Au矿床Pb同位素组成具幔源特征(207Pb/204Pb和208Pb/204Pb平均值分别为15.490和38.016),反映成矿物质来自于俯冲过程中的交代地幔楔;最北端的Pb-Zn矿床Pb同位素组成与念青唐古拉群基底片麻岩相近(207Pb/204Pb和208Pb/204Pb分别变化于15.641～15.738和38.976～39.362),反映成矿物质来自于基底片麻岩。Pb-Zn-Cu-Fe矿床Pb同位素组成介于幔源Pb和上地壳Pb之间,且具混合线特征,反映了同碰撞期成矿物质同时从俯冲板片和念青唐古拉基底片麻岩活化的混源模式;而Cu-Mo矿床不具混合线特征的造山带Pb同位素组成,反映了成矿物质来源于俯冲阶段楔形地幔部分熔融并底侵到地壳底部与地壳发生物质交换后所形成的新生下地壳源区。甲马Cu多金属矿床Pb同位素组成具幔源和造山带两个端元,推测除新生下地壳源区提供成矿物质外,叶巴组火山岩也提供了部分成矿物质。由南向北成矿物质来源的差异很大程度上与板片俯冲的"距离效应"有关,正是由于成矿物质来源的差异导致成矿带成矿元素分带性的形成。  相似文献   

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