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1.
油页岩中的稀土元素（REE）研究不仅可以用于解决岩石地质成因,提供物质来源信息,而且可以对REE含量进行资源评价,有利于油页岩的综合开发利用,具有重要的理论和现实意义。本研究测试并分析了银额盆地巴格毛德凹陷中生界白垩系下统巴音戈壁组（K1b）巴格毛德油页岩REE地球化学特征,分析结果表明,油页岩中的REE总量（∑REE）为94．8×10^-6～178×10^-6,平均值为126×10^-6,低于其围岩的∑REE;轻、重稀土元素含量比值（∑LREE／∑HREE）为2．60～3．45,平均值为3．10。（La／Yb）w为0．57～1．02,平均值为0．89,表明油页岩中LREE、HREE分异不明显,LREE相对HREE富集,属于LREE低度富集型。Eu表现为明显负异常,Ce表现为微弱的正异常,表明了油页岩形成于还原的古湖泊环境。油页岩样品∑REE与其微量元素的聚类分析结果表明,油页岩中的REE主要来自陆源碎屑沉积。油页岩样品δCe与δEu、δCe与∑REE均无明显的相关关系,表明成岩作用对REE的影响十分有限,研究区油页岩的成岩阶段处于未成熟阶段。 相似文献
2.
东营凹陷原油单体烃碳同位素特征及其在油源识别中的应用 总被引：4，自引：4，他引：0
为揭示东营凹陷部分复杂成因油气的来源,对该区原油、烃源岩单体烃碳同位素进行精细特征分析与油源追踪。东营凹陷不同成因原油具有不同正构烷烃单体烃碳同位素特征。沙三段淡水成因原油碳同位素曲线分别以nC15、nC32为主峰,碳同位素总体偏重、前峰极其富集13C;沙四段咸水成因原油一般以nC23为分界线,近似呈对称的双峰分布,δ13C值较沙三段成因原油的轻。沙三段、沙四段成因原油碳同位素分别与沙三段、沙四段烃源岩的聚类相关。牛庄洼陷沙三中段透镜体岩性油气藏原油单体烃碳同位素值介于沙三段、沙四段烃源岩之间,与沙四段烃源岩及相关原油具有更好的相关性,验证以往关于牛庄洼陷沙三中段隐蔽油气藏原油为沙三段、沙四段成因的混源油观点。东营凹陷南斜坡孔店组原油碳同位素总体相对较轻、近直线型分布,与孔店组烃源岩、黄骅坳陷孔店组成因原油的碳同位素曲线聚类相关,指示其与孔店组烃源岩具有成因联系。在正常油窗范围内,成熟度对东营凹陷烃源岩及相关原油碳同位素的影响较小,后者主要受控于母源与古沉积环境。单体烃碳同位素可以很好地应用于东营凹陷油气成因与油源研究,该方法是对以往生物标志物地球化学研究的补充与深化。 相似文献
3.
东营凹陷沙河街组湖相碳酸盐岩碳氧同位素组分及其古湖泊学意义 总被引：27，自引：2，他引：25
湖相碳酸盐岩的碳、氧稳定同位素分析能提供重要的环境信息。山东东营凹陷沙河街组湖相碳酸盐岩主要分布在沙一段和沙四段。对47个碳酸盐岩样品碳、氧同位素组分的分析表明:沙一段、沙四中和沙四上亚段下部沉积时期东营湖均是程度不同的封闭型湖泊。古盐度和蒸发／降雨:沙四中亚段和沙四上亚段下部沉积时期＞沙一段沉积时期＞沙四上亚段上部沉积时期;古湖水面:沙四上亚段上部沉积时期＞沙一段沉积时期＞沙四中亚段和沙四上亚段下部沉积时期;古生产力:沙一段沉积时期＞沙四上亚段上部沉积时期＞沙四中亚段和沙四上亚段下部沉积时期。 相似文献
4.
5.
贵州织金新华含稀土磷矿床稀土元素地球化学及生物成矿基本特征 总被引：15，自引：0，他引：15
对贵州织金新华含稀土磷矿床进行的稀土元素及微量元素分析结果表明，磷块岩中普遍富集稀土元素，稀土总量∑REE较高，并富集Y元素及La，Nd等轻稀土元素。LREE／HREE比值较高。含稀土磷块岩普遍具Ce负异常，显示其对源区的继承性。指示成磷环境处于氧化程度相对较高状态。稀土元素球粒陨石标准化模式曲线、北美页岩标准化模式曲线、Ce元素异常、LREE／HREE比值、微量元素特征及岩石矿物特征表明，织金新华含稀土磷矿床具以正常海相生物-化学沉积等为主伴有海相热水沉积混合成因的特征。在磷矿成矿过程中沉积物沉积时，活体生物及死亡残骸不同程度地摄取和富集了La，Nd，Ce等稀土元素、Y元素及其他微量元素，沉积在含磷层位，构成大量的含稀土、含生物碎屑白云质磷块岩。 相似文献
6.
浙江萤石矿床的稀土元素地球化学特征木 总被引：2，自引：1，他引：2
文章根据浙江14个萤石矿床(点)的94个萤石和49个赋矿岩石样品的稀土元素分布特征,将萤石矿床分为两种类型:即轻稀土富集型(萤石的∑REE=30×10~(-6)～80×10~(-6),Y=10×10~(-6)～50×10~(-6),∑Ce/∑Y≥1,La/Yb>6);重稀土富集型(萤石的∑REE=40×10~(-6)～70×10~(-6),Y=30×10~(-6)～110×10~(-6),∑Ce/∑Y<1,La/Yb<3)。前者从早阶段到晚阶段,萤石的∑REE及Y含量趋于减小,LREE/HREE及La/Yb值增大;后者从早期到晚期,萤石的∑REE和Y含量以及LREE/HREE和La/Yb比值变化则相反。轻稀土富集型萤石的矿床规模越大,萤石与未蚀变围岩的REE含量差值越大;重稀土富集型萤石的矿床规模越大,萤石与未蚀变围岩的REE含量差值越小。 相似文献
7.
东昆仑山清水泉镁铁质-超镁铁质岩的地球化学特征 总被引：12，自引：0，他引：12
东昆仑清水泉地区发育—套镁铁质—超镁铁质岩块组合，玄武岩Ti2O含量平均为2．11％，∑LREE／∑HREE=4．64～7．58，(La/Lu)N平均值705，稀土配分曲线平缓右倾，δEu平均值1．08；玄武岩大离子亲石元素(K、Rb、Ba、Th)富集，Sr相对亏损，高场强元素(Nb、Ta、Zr、Hf、Yb)为负异常，Th／Ta平均值51．03，(La／Nb)N=1．44～4．25，Zr／Nb=14．53～17．71，Zr／Y=4．68～6．79，Th／Yb、Ta／Yb和Ce／Yb平均值分别为6．50、0．20和23．61。这些特征显示大陆拉斑玄武岩的特征。不是蛇绿岩组成单元。 相似文献
8.
塔里木盆地塔北东部下奥陶统基质白云岩的稀土元素特征及其成因 总被引：2，自引：0，他引：2
白云岩成因机制的核心问题之一是白云石化流体的来源.本文选择塔北东部地区下奥陶统蓬莱坝组白云岩、云质灰岩作为研究对象,在沉积学和岩石学基础上对基质白云岩的稀土元素地球化学特征进行了分析研究.结果表明,白云岩、云质灰岩中Sc、Th、Hf、Zr等元素的含量远远低于这些元素在陆源沉积物中的含量,并且Th、Zr的含量与Y/Ho比值间不具有明显的正相关关系,La的正异常、较高的Y/Ho比值等特征均表明塔北东部下奥陶统蓬莱坝组碳酸盐岩形成的环境为未受陆源物质混染的浅海相沉积.而白云岩负Ce异常、正La异常、轻微富集的Gd正异常以及La正异常与Y异常的正相关性等典型稀土元素特征均反映了白云石化流体具有典型的海水来源特征;而基质白云岩与白云质灰岩之间的ΣREE+Y,ΣLREE和∑HREE含量差异表明,在白云石化过程中稀土元素发生了一定程度的流失,且HREE较之于LREE更易于发生流失,因此白云石化过程中成岩流体对HREE的移出量大于LREE的移出量是塔北东部下奥陶统白云岩具有相对富集的LREE及相对较低的Y/Ho比值的主要原因.结合岩石学、沉积学、微量元素以及稳定同位素特征的综合分析认为,塔北东部地区下奥陶统蓬莱坝组基质白云岩是海水白云石化作用的结果.个别白云岩样品的Eu正异常以及同层位构造裂隙方解石的δ~(18O) 、~(87)Sr/~(86)Sr以及流体包裹体均表明下奥陶统蓬莱坝组受到后期热液流体的影响,但其对研究样品基质白云岩的影响程度比较弱. 相似文献
9.
通过对五台地区高凡矿田高凡银金矿床中的脉石英、石英斑岩中的石英斑晶、铜钼矿化脉石英和变辉绿岩脉中脉石英的中子活化稀土成分分析,并结合苏联有关研究资料表明:石英中微量稀土元素的地球化学特征基本上反映了其形成时初始溶液或岩浆的稀土元素地球化学行为,可利用来判断金矿床的成因及成矿物质来源.浅成金矿床脉石英显示∑REE、∑Y/∑S_c、∑LREE/∑HREE、Eu/Sm较小,La/Yb处于地壳岩石计算值范围,稀土配分模式基本与酸性岩类的一致;深成金矿床脉石英则显示∑REE、∑Y/∑S_c、∑LREE/∑HREE、Eu/Sm较大,La/Yb低于地壳岩石计算值,稀土配分模式与超基性岩类相似. 相似文献
10.
广西南丹大厂石炭系黄龙组碳酸盐岩对探讨右江盆地石炭系古沉积环境和古海水氧化还原特征具有重要的意义。本文对研究区碳酸盐岩样品进行全岩地球化学分析,结果显示:碳酸盐岩的Mn/Sr值均小于3,表明样品能够反映原始海相化学性质;Si O2、Al2O3和Ti O2等陆源元素的平均含量低,Zr、Th的含量较低且与∑REE相关性不明显、Y/Ho值变化大但Nd含量相对稳定,说明样品受到陆源碎屑影响有限;碳酸盐岩的Ce异常,揭示了样品形成于次氧化环境,δEu接近于现代海水值,反映样品基本不受热液活动影响。根据古水深、古气候、古盐度等特征元素指标综合判别,研究区黄龙组下段沉积期为离岸距离相对较近的浅水沉积环境,总共经历了2次相对较大的海侵和海退旋回,但海水总体呈下降趋势,整体上属温暖潮湿的气候。这也进一步反映了石炭纪右江盆地为海相沉积环境。 相似文献
11.
萤石经常以脉石矿物存在于各类金属矿床中,但以矿石矿物与金属矿物共存较为少见。布拖小洞子铅锌矿体和萤石矿体是赋存在震旦系灯影组不同部位的典型矿床,受四开-交际河断裂的次级断层带控制,是该区较为特殊,研究程度较低的一类矿床。其中萤石矿床产于与黑色燧石条带白云岩相关的断裂构造,矿石矿物以萤石为主。本文通过对震旦系灯影组下部萤石矿床开展稀土元素地球化学研究,结果表明轻稀土元素富集,重稀土元素略亏损,LREE/HREE介于0.96~1.61,(La/Yb)_N为1.19~3.23,稀土元素配分图表现出略微右倾的特征,具Eu正异常和Ce负异常特征。Tb/Ca-Tb/La、Y/Ho-La/Ho及La/Yb-∑REE等图解表明小洞子萤石矿床主要为同一体系不同阶段的热液产物,破碎带充填交代型矿床成因,其成矿物质来源与灯影组地层和峨眉山玄武岩热液有关。 相似文献
12.
B. Bühn 《Mineralogy and Petrology》2008,92(3-4):453-470
Summary Two bimodal carbonatite complexes in Namibia of Cretaceous age are explored as to the presence and composition of a coexisting
carbonatitic fluid. The Kalkfeld and Ondurakorume complexes contain both Ca- and Mg/Fe-carbonatites, composed of calcite alone
or calcite with ferroan dolomite, fluorapatite and strontianite. The major element evolution in the bulk rocks from s?vites
to beforsites is due to crystallization of calcite and fluorapatite. All carbonatites show a negative Y anomaly in normalised
REE plots. Fractionation is accompanied by successively lower HREE contents between Tb and Yb, expressed by the ratios Nd/Ho
and Ho/Lu. The evolution of this downward-facing hump goes along with decreasing Y contents in bulk rocks and minerals. All
this requires an additional phase coexisting with the carbonate liquid during fractionation. Comparison between the bulk rocks
and the expelled fluid shows that the latter had preferentially accumulated the HREE and Y. Further evidence for this process
are hydrothermal, HREE, Y-rich fluorites in other carbonatite complexes which reflect the composition of the expelled fluid.
The high strength of fluoride complexes suggests that fluoride complexing in the carbonatitic fluid is the process responsible
for extracting HREE and Y from the carbonatite magma, leaving fractionated carbonatite rocks depleted in these elements. The
geochemical evolution of carbonatite magmas along fractionation has therefore to be considered in a melt-mineral-fluid system.
Correspondence: B. Bühn, Instituto de Geociências, Universidade de Brasilia, Campus Universitário Darcy Ribeiro, Brasilia
70910-900, Brazil 相似文献
13.
《International Geology Review》2012,54(12):1541-1552
The Mt Vulture carbonatites are the only carbonatite occurrence in the southern Apennines. We present new trace element data for these rocks in order to evaluate the factors influencing rare earth element (REE) and other trace element fractionations and their REE grade. This study focuses on massive hyalo-alvikites from two lava flows and one dike, which have different relative abundances of silicate and carbonate (i.e. Si/Ca). These differences are also evident from CaO/(CaO + MgO + FeO(T) + MnO) and Sr/Ba ratios. The REE grade of the Mt Vulture carbonatites is very similar to that of the global average for calcio-carbonatites. R-mode factor analysis shows that most of the trace element variance reflects the relative roles of carbonate and silicate minerals in influencing trace element distributions. Silicates largely control heavy rare earth element (HREE), transition metal, Zr, and Th abundances, whereas carbonate minerals control light rare earth element (LREE), Ba, and Pb abundances. In addition, apatite influences LREE concentrations. Increasing silica contents are accompanied by decreases in (La/Yb)N and (La/Sm)N ratios and less marked LREE enrichment. In contrast, higher carbonate contents are associated with increases in (La/Yb)N and (La/Sm)N. The Si/Ca ratio has little influence on Eu anomalies and middle rare earth element (MREE) to HREE fractionations. Apatite has a negligible effect on inter-REE fractionations amongst the carbonatites. 相似文献
14.
Stephen Roberts Martin R. Palmer Matthew J. Cooper Peter Buchaus Drew Sargent 《Mineralium Deposita》2009,44(8):881-891
Carbonate, largely in the form of dolomite, is found throughout the host rocks and ores of the Nchanga mine of the Zambian
Copperbelt. Dolomite samples from the hanging wall of the mineralization show low concentrations of rare-earth elements (REE)
and roof-shaped, upward convex, shale-normalized REE patterns, with positive Eu*SN anomalies (1.54 and 1.39) and marginally negative Ce anomalies (Ce*SN 0.98,0.93). In contrast, dolomite samples associated with copper and cobalt mineralization show a significant rotation of
the REE profile, with HREE enrichment, and La/LuSN ratios <1 (0.06–0.42). These samples also tend to show variable but predominantly negative Eu*SN and positive cerium anomalies and an upwardly concave MREE distribution (Gd-Er). Malachite samples from the Lower Orebody
show roof-tile-normalized REE patterns with negative europium anomalies (Eu*SN 0.65–0.80) and negative cerium anomalies (Ce*SN 0.86–0.9). The carbonate 87Sr/86Sr signature correlates with the associated REE values. The uppermost dolomite samples show Neoproterozoic seawater-like 87Sr/86Sr ratios ranging from 0.7111 to 0.7116, whereas carbonate from Cu–Co mineralized samples show relatively low concentrations
of strontium and more radiogenic 87Sr/86Sr, ranging between 0.7136–0.7469. The malachite samples show low concentrations of strontium, but give a highly radiogenic
87Sr/86Sr of 0.7735, the most radiogenic 87Sr/86Sr ratio. These new data suggest that the origin and timing of carbonate precipitation at Nchanga is reflected in the REE
and Sr isotope chemistry. The upper dolomite samples show a modified, but essentially seawater-like signature, whereas the
rotation of the REE profile, the MREE enrichment, the development of a negative Eu*SN anomaly and more radiogenic 87Sr/86Sr suggests the dolomite in the Cu–Co mineralized samples precipitated from basinal brines which had undergone significant
fluid–rock interaction. Petrographic, REE, and 87Sr/86Sr data for malachite are consistent with the original sulfide Lower Orebody being subject to a later oxidizing event. 相似文献
15.
青海东昆仑阿斯哈金矿床含金黄铁矿微量元素地球化学特征及其地质意义 总被引：1，自引：0，他引：1
阿斯哈金矿床是青海东昆仑造山带东段金矿床的典型代表.金矿体主要赋存于闪长岩和花岗闪长岩体的构造破碎带内,受NNE向和NNW向-NW向断裂构造控制.与金矿化密切相关的蚀变类型为黄铁矿化、硅化、绢云母化和黄铜矿化.矿石矿物主要为黄铁矿,其次是黄铜矿、方铅矿、毒砂、自然金和银金矿.据矿脉穿插关系、矿石矿物共生组合和结构构造特... 相似文献
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碳酸盐岩是地球表层岩石圈的重要组成部分,其化学组成可提供沉积环境与海洋水体演化等信息,然而,前人对碳酸盐岩中稀土等元素的分布与变化特征关注不足。本文选择穿越中国东部6个一级大地构造单元的3条地球化学走廊带,系统采集了582件碳酸盐岩地层样品,并准确分析了包括稀土元素(REE)在内的81项指标的含量。结果表明,中国东部地球化学走廊带碳酸盐岩稀土元素(REE＋Y)总量为(0.59～183)×10-6,均值为24.0×10-6,纯净碳酸盐岩(CMC含量≥99％)均值为4.80×10-6。PAAS标准化后其显示具有轻稀土相对于中稀土和重稀土略亏损、δEu轻微正异常、δCe中度负异常等特征。白云岩中稀土含量、LREE/HREE值一般低于石灰岩;砂泥质含量相近时,前中生代各时代碳酸盐岩稀土分布模式相差不大,各构造单元稀土分布特征基本相似;与其他时代相比,中生代及中新元古代碳酸盐岩具有相对较平坦的稀土分布模式。研究表明,碳酸盐岩中稀土分布受碎屑物质影响明显,表现为稀土元素含量与碳酸根负相关,与碎屑物质相关元素(Si、Ti、Rb、Cs、Th、Zr等)、黏土相关元素(Al、Fe、K等)等正相关。成岩过程及白云化过程对较纯净碳酸盐岩中稀土分布特征影响不明显。我国古生代纯净碳酸盐岩分布模式受控于海相环境,其分布模式与现今海水相近;中生代纯净石灰岩受到陆相或海陆交互相的影响,具有较平坦的稀土分布模式。氧化还原条件对δCe的影响较δEu更为明显,δCe值受海相环境控制,极端正异常值(δCe＞1.3)受到还原环境或/和热液影响。若假定海水中REE自中元古代至今无太大变化,各时代稀土元素分配系数均值介于103.55～102.39,分配系数差异是造成碳酸盐岩中轻稀土亏损、Ce负异常及Y正异常的主要原因。微生物(席)可富集稀土等金属元素并改变沉积环境,这可能是造成中新元古界碳酸盐岩较平坦的稀土分布模式的主要原因。 相似文献
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The sediments from three stratigraphic levels in the Bababudan schist belt of Dharwar craton exhibit great diversity in major,
trace and rare earth element (REE) geochemistry and thus interpreted to represent significant compositional variation in the
source rocks. Detailed geological and geochemical studies have been carried out on clastic rocks constituting the Archaean
Sargur supracrustals and the Bababudan belt of Dharwar craton (DC), southern India for understanding the geochemical characteristics
and to define the Archaean-Proterozoic Boundary (APB/QPC) in southern India. There is significant contrast in the geochemical
signatures for the sediments from these stratigraphic levles. The Sargur enclave population is characterised by slight LREE
enrichment with (La/Sm)N ranging from 1.45 to 3.58, almost flat HREE with (Gd/Yb)N ranging from 0.65 to 1.29 with Eu/Eu* ranging from 0.49 to 0.91 suggesting mafic-ultramafic source rocks in the provenance.
On the other hand, the Post QPC (PQPC) rocks are characterised by LREE enrichment with (La/Sm)N ranging from 2.66 to 7.07, nearly flat HREE with (Gd/Yb)N ranging from 0.58 to 0.95 and significant depletion of Eu with Eu/Eu* ranging from 0.34 to 0.85, indicating felsic province
in the source area. The conglomerates and quartzites representing the QPC are showing mixed nature of these, reflecting the
transitional character in depositional environment. Increase in abundance of REE, K2O/Na2O, Th/Sc, La/Sc, Th/U, Hf/Ta and Zr/Y ratios are characteristic of the QPC. The PQPC sediments are enriched in Th, U and HFSE
like Hf, Nb, Zr and Y, and depleted in Co and Eu than their older counterparts. These geochemical signatures signify the dominance
of mafic-ultramafic rocks in the source area for Sargur rocks and the existence of granite-granodiorite for PQPC clastics.
Thus, the unconformity related oligomictic quartz pebble conglomerates (QPC) and quartzites at the base of Bababudan Group
resembling the QPC of Witswaterand, South Africa signifies that a stable continental crust had already developed in southern
India prior to ∼3.0Ga. 相似文献
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广州市增城地质公园发育有大量的燕山期安山岩和流纹岩,由于缺少详细的岩石地球化学研究,这些火山岩的成因和所代表的大地构造意义一直未明确。文章对上述火山岩进行了较为系统的全岩地球化学以及同位素地球化学分析。研究结果显示,安山岩具有安第斯型火山岩特点,显示Nb、Ta、Sr和Ti的亏损,Isr值介于0.70332~0.7144,平均值0.7092,岩石稀土总量较低(ΣREE=158.9×10^-6~215.0×10^-6),平均值186.8×10^-6,轻重稀土元素分异较弱((La/Yb)N5.06~9.87),平均值7.01,Eu负异常不明显(δEu=0.80~1.38),平均值δEu=0.94。流纹岩具有高钾特点,有明显的Ba、Sr、P、Eu、Ti负异常和Pb、Yb正异常,其Isr值介于0.71393~0.73650,平均值0.72615,岩石稀土总量较低(ΣREE=93.4×10^-6~481.5×10^-6),平均值285.7×10^-6,轻重稀土元素分异弱((La/Yb)N=0.65~9.51),平均值4.35,Eu负异常很明显(δEu=0.01~0.03),平均值δEu=0.02,全岩Rb-Sr同位素年龄为(112±12)Ma。综合的地球化学研究表明,增城地质公园安山质-流纹质火山岩均属壳幔混合成因,其中安山岩以幔源为主,而流纹岩则以壳源为主,分别形成于早侏罗世和早白垩世太平洋板块俯冲碰撞挤压的构造背景下。这对华南地区中生代构造演化的深入认识具有重要的地质意义。 相似文献
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Comparative study of yttrium and rare-earth element behaviours in fluorine-rich hydrothermal fluids 总被引：16，自引：0，他引：16
The mineral fluorite is utilized as a probe to investigate the behaviour of the pseudolanthanide yttrium with respect to the lanthanides (rare-earth elements, REE) in fluorine-rich hydrothermal solutions. Hydrothermal vein fluorites are characterized by the close association of Y and REE, but in contrast to igneous and clastic rocks they show variable and nonchondritic Y/Ho ratios of up to 200. This suggests that Y and Ho, although similar in charge and size, may be fractionated in fluorine-rich medium-temperature aqueous fluids. In such solutions Y acts as a pseudolanthanide heavier than Lu. Y/Ho ratios of hydrothermal siderites are slightly below those of chondrites, suggesting that in (bi)carbonate-rich siderite-precipitating solutions Y may act as a Sm-like light pseudolanthanide. This indicates that Y-Ho fractionation is not a sourcerelated phenomenon but depends on fluid composition. Based on these results it is strongly recommended that discussions of normalized REE patterns in general should be extended to normalized Rare-Earth-and-Yttrium (REY) patterns (Y inserted between Dy and Ho), because the slightly variable behaviour of the pseudolanthanide yttrium with respect to the REE may provide additional geochemical information. Available thermodynamic data suggest a negative correlation between Y/Ho and La/Ho during migration of a fluoriteprecipitating hydrothermal solution. Cogenetic fluorites, therefore, should display either similar Y/Ho and similar La/Ho ratios, or a negative correlation between these ratios. This criterion may help to choose samples suitable for Sm-Nd isotopic studies prior to isotope analysis. However, in cogenetic hydrothermal vein fluorites the range of Y/Ho ratios is often almost negligible compared to the range of La/Ho ratios. This may be explained by modification of REE distributions by post-precipitation processes involving (partial) loss of a separate LREE-enriched phase. The presence of variable amounts of such an accessory phase in most fluorite samples is revealed by experiments employing stepwise incomplete fluorite decomposition. Fluorites derived from and deposited near to igneous rocks apparently display chondritic Y/Ho ratios close to those of their igneous source-rocks. However, a positive YSN anomaly is likely to develop as the distance between sites of REY mobilization and deposition increases. 相似文献