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1.
准噶尔盆地北三台地区北 82井、北 83井和沙 10 8井湖相原油咔唑类化合物的分布特征表明,油气运移作用是影响该区原油中咔唑类化合物分布的重要因素。沿油气运移方面,咔唑类化合物具有明显的分馏效应。总的趋势是原油中咔唑类化合物、高分子量的烷基咔唑化合物和苯并咔唑化合物的含量逐渐减少,低分子量咔唑和甲基咔唑,以及具屏蔽效应的二甲基咔唑和苯并 [a]咔唑异构体的相对含量则逐渐增加。利用咔唑类化合物的分馏效应,可有效地指示油气运移方向。  相似文献   

2.
胡庆油田湖相原油咔唑类化合物的地球化学特征   总被引:1,自引:0,他引:1  
胡庆油田湖相原油成熟度低,多为低成熟原油,生物降解作用轻微,原油中含有丰富的咔唑类化合物。分析表明,原油成熟度对咔唑类化合物含量及相对组分影响明显,源岩沉积环境对其也有一定的影响,而生物降解作用对咔唑类化合物含量及相对组分影响很小。原油中咔唑类化合物含量、链基咔唑/苯并咔唑及苯并咔唑比值受原油成熟度与沉积环境影响明显,已不适合用来指示油气运移距离,而二甲基咔唑同分异构体比值所受影响小,仍可作为油气运移的有效参数。  相似文献   

3.
分析和研究了69个样品的咔唑类含氮化合物数据,认为惠民凹陷临南地区沙三段咔唑类含氮化合物中的咔唑、甲基咔唑、二甲基咔唑及苯并咔唑等.与埋藏深度、成熟度和沉积环境之间关系密切.因此今后研究过程中可以考虑部分咔唑类含氮化合物的含量和比值作为成熟度指标和指相标志.  相似文献   

4.
刘洛夫  康永尚 《地球化学》1998,27(5):475-482
在塔里木盆地塔中地区的原油中分离和检测到咔唑类含氮化合物,并成功地将其应用于油气运移研究,烷基咔唑类化合物大量存在于所分析的样品中,苯并咔唑只在部分样品检测到且含量小,而二苯并卟唑则未发现,根据C2烷基咔唑的G1,G2和G3结构类型的分布,C3-咔唑/C2-咔唑比值以及烷基咔唑与苯并烷基咔唑的相对含量可知,塔中地区石炭系C3油组的石油分别从北西和南东两个方向向塔中4号构造的高点侧向运移,研究还表明  相似文献   

5.
高邮凹陷韦庄地区原油吡咯类含氮化合物运移分馏效应   总被引:4,自引:0,他引:4  
刘小平  徐健 《地球科学》2004,29(4):461-466
高邮凹陷韦庄地区具有正常和轻微生物降解2类原油,对油气运移方向一直存在争议.根据2类原油中含氮化合物浓度、屏蔽型含氮化合物的相对含量与反映原油生物降解的地化参数C21^-/C22^ 、Pr/nC17等指标的对比研究,发现生物降解作用对该区原油中含氮化合物的相对含量及其分布影响不明显,运移作用仍然是造成含氮化合物分馏的主要因素.自东向西、东北向西南方向,韦X11井、韦6~2井、韦5—19井、韦8井原油中屏蔽型咔唑的相对含量依次增大,分别为11.62%,10.66%,12.70%,13.88%;暴露型咔唑的相对含量则表现出相反的变化趋势,分别为30.60%,28.56%,26.43%,24.62%.由此明确了本区油气自东、东北方向向西、西南方向注入,深凹带和车逻鞍槽提供了主要油源.  相似文献   

6.
塔里木塔中隆起古生界原油咔唑类化合物的分布及意义   总被引:1,自引:0,他引:1  
石油在运移过程中,极性含氮化合物与围岩(如孔隙、裂缝、断层等)表面相互作用。随着运移距离增加,其在原油中的含量不断降低,并发生石油极性含氮化合物的分馏作用。以前的研究表明,石油中咔唑类含氮化合物的分布受母质类型、沉积环境、成熟度的影响很小,而主要受石油运移的影响。本文主要运用咔唑类化合物的分布来研究石油的运移并迫踪烃源岩。文中对来自塔里木盆地塔中地区6口井的7个原油样品的咔唑类化合物的类型、含量及其分布特征作了详细的探讨。得到  相似文献   

7.
基于C30重排藿烷(C30DH)和C30藿烷(C30H)热稳定性差异,研究了C30DH/C30H作为油气运移方向和充注途径的可行性.结果发现:C30DH结构稳定性高于C30H,C30DH/C30H参数具有成熟度属性;同时对比分析C30DH/C30H参数与咔唑类参数的相关性,认为两者之间正相关性明显,表明C30DH/C30H参数不仅是良好的热成熟度参数还是良好的石油充注运移参数.M油田位于Fula凹陷东部,M油田原油为弱氧化-还原、淡水-微咸水环境下低等藻类与高等植物混源生成,属于同一族群原油.利用C30DH/C30H参数示踪Fula凹陷M油田石油充注方向,油气运移途径主要为自北向南,同时还发育自西向东的运移途径;咔唑类参数也验证了C30DH/C30H参数示踪油气运移的准确性.结果表明C30DH/C30H参数是示踪石油充注途径的有效参数.   相似文献   

8.
生物降解原油中吡咯氮化合物组成的变化   总被引:1,自引:0,他引:1  
渤海海域地区近50个原油样品中性氮组分的GC/MS定量分析资料表明,油藏中的生物降解作用对原油的吡咯氮化合物含量和分布有明显影响。经与同源未降解原油比较,各种烷基咔唑和苯并咔唑在3。4级中轻度降解油中就出现明显降解迹象,随生物降解程度增高其含量逐渐减少,在6—8级严重降解油中它们的总含量降低到原有的五分之一左右。在3—4级中轻度降解油中,裸露型甲基咔唑异构体更容易被微生物侵袭而代谢,抗生物降解能力按1-甲基咔唑〉4-甲基咔唑〉2-、3-甲基咔唑顺序递减;当降解程度更高时,这些化合物降解速率相当,1-/4-MCA等比值相对稳定。低-中等降解阶段,不同类型二甲基咔唑异构体的抗生物降解能力也存在明显差异性,呈屏蔽型〉半屏蔽型〉裸露型降低;在生物降解水平进一步增高时,这些异构体之间的相对含量变化不大。生物降解作用对苯并咔唑系列化合物分布的影响具有不确定性,且随降解程度的增加变得更为显著,降解油中【a】/[c】苯并咔唑比值或增高或降低。生物降解原油中吡咯氮化合物的组成变化,使降解油的二次运移示踪面临新的问题。  相似文献   

9.
生物标志物苯并藿烷系列的新发现及其地化意义   总被引:1,自引:0,他引:1  
蕾烷系列化合物的各类参数,已在石油地球化学研究中普遍应用,可有效地判断有机质类型及其成熟度。芳构藿烷发现有四芳和三芳藿烷,近年来又发现了一类新的单芳六环藿烷-苯并藿烷C32-C35系列,它们分别检出于碳酸盐岩和原油(G.Hussler,1984)、磷酸盐和非磷酸盐沉积物(H.Belayouni,1984)、新疆准噶尔盆地侏罗系含煤地层埋深617.7-619.7米的黑色泥岩(盛国英、傅家谟,1985)、陕甘宁盆地侏罗系、上三叠统与石炭二叠系的碳质页岩和油页岩(黄汝昌、王广玉,未发表)中。笔者在酒西盆地下白垩统黑色泥岩中检出了C32、C33、C35等苯并藿烷,更有意义的是,还首次鉴定出了C31苯并藿烷,即C29-降苯并藿烷,这进一步丰富了生物标志物的内容。  相似文献   

10.
中性含氮化合物的演化及地化意义   总被引:13,自引:0,他引:13  
通过对生油岩样品中的中性氮系列化合物含量和组成变化的系统研究。指出含氮化合物的热演化规律和形成机制。含氮化合物是沉积有机质成岩演化的产物。其含量和组成明显受控于有机质成熟度;认为1-/4-甲基咔唑,苯并[a]咔唑/苯并[c]咔唑等比值可作为成熟度参数。  相似文献   

11.
International unity is becoming ever stronger in this country owing to an increasing similarity in the development of the cultural environment. This comprises the provision of all the country's republics with a sufficient number of schools, theatres, and other institutions and cultural information media in accordance with the needs of the population. An important part is played by the rise in ‘the general educational level, as well as the level of professional qualifications and skills. Among all the Soviet nations and nationalities, this rise being more rapid among formerly backward peoples. Prominent among the factors of internationalization is the progressive development of the nationalities’ cultural resources, while professional culture is being increasingly brought within the reach of the masses.The implementation of the nationalities policy promotes the all-round development of all Soviet nations and nationalities, their drawing together, the upsurge of the individual capabilities of every Soviet citizen.  相似文献   

12.
13.
Chronological analyses of correlations between certain global repeating events (mass extinctions of marine organisms, meteorite impacts, and flashes in the frequency of geomagnetic reversals) during the Phanerozoic Eon and the motion of the solar system in the Galaxy are presented for five rotationally symmetrical models for the regular Galactic gravitational field. Thirteen of sixteen mass-extinction events can be described by a repetition interval of 183±3 million years. This is in agreement with the anomalistic period (interval between two subsequent passages of the Sun through the apocenter of its Galactic orbit) in the model of Allen and Martos. The positions of the minima and maxima in Gaussian functions approximating the frequency distribution for geomagnetic reversals also agree with the times of passage of the Sun through the apocenter and pericenter, respectively, of its Galactic orbit in this model. The maximum in the distribution of the deviations of the dates of mass extinctions from the nearest dates of impacts of large, crater-forming bodies is close to zero, providing evidence that many such events are correlated. As a rule, extinctions follow impact events. The impacts of large bodies have occurred most often when the solar system passes through the Galactic plane, while mass extinctions occur more often at some distance from the Galactic plane (about 40 pc). As a rule, intervals of increases in the frequency of geomagnetic reversals coincide with dates of impacts of large bodies. At the same time, these intervals do not show a clear correlation with the dates of mass extinctions. The intensity of mass extinctions, like the energy released by impacts, is consistently higher in periods when the Sun is moving from the apocenter toward the pericenter of its orbit, than when it is moving from the pericenter toward the apocenter. Thus, there is evidence for a variety of relationships between repeating global events in the Phanerozoic and the motion of the Sun in the Galaxy. Long-period variations in the frequency of geomagnetic reversals are correlated with the orbital motion of the Sun, and increases in the frequency of geomagnetic reversals are correlated with impacts. Mass extinctions are correlated with the impacts of large bodies, whose motions may have been perturbed by clouds of interstellar material concentrated toward the Galactic plane and by the shock front associated with the Perseus spiral arm, through which the solar system passes. The velocity of the Sun relative to the spiral pattern is estimated.  相似文献   

14.
It is known from observations that the center of mass of the Moon does not coincide with the geometric center of its figure, and the line connecting these two centers is not aligned with the direction toward the center of the Earth, instead deviating toward the Southeast. This stationary deviation of the axis of the inertia ellipsoid of the Moon to the South of the direction toward the Earth is analyzed. A system of five linear differential equations describing the physical libration of the Moon in latitude is considered, and these equations are derived using a new vector method taking into account perturbations from the Earth and partly from the Sun. The characteristic equation of this system is obtained, and all five oscillation frequencies are found. Special attention is paid to the fifth (zero) frequency, for which the solution of the latitude libration equations are stationary and represents a previously unknown additional motion of the rotational axis of theMoon in a cone with a small opening angle. In contrast to the astronomical precession of the Earth, the rotation of the angular-velocity vector is in the positive direction (counter-clockwise), with the period T 3 = 27.32 days. On this basis, this phenomenon has been named “quasi-precession.” This quasi-precession leads to a stationary inclination of the major axis of the inertia ellipsoid of theMoon to the South (for an observer on Earth), making it possible to explain one component of the observed deviation of the center of mass of the Moon from the direction toward the Earth. The opening angle of the quasiprecession cone is approximately 0.834″.  相似文献   

15.
从榴辉岩与围岩的关系论苏鲁榴辉岩的形成与折返   总被引:4,自引:1,他引:4       下载免费PDF全文
位于华北和扬子两板块碰撞带中的苏鲁榴辉岩形成的温压条件不但是超高压,而且是高温。榴辉岩的PTt轨迹表明其为陆-陆磁撞俯冲带的产物。榴辉岩的区域性围岩花岗质片麻岩为新元古代同碰撞期花岗岩,榴辉岩及其他直接围岩皆呈包体存在于其中,并见新元古代花岗岩呈脉状侵入榴辉岩包体中。区域性围岩新元古代花岗岩的锆石中发现有柯石英、绿辉石等包裹体,表明新元古代花岗岩的组成物质也经受过超高压变质作用,且榴辉岩与围岩新元古代花岗岩的锆石U-Pb体系同位素年龄基本相同。但新元古代花岗岩所记录的变质作用和变形作用期次(或阶段)却少于榴辉岩。椐上述可得如下推断:超高压榴辉岩与新元古代花岗岩岩浆是同时在碰撞带底部(俯冲板块前部)形成的;榴辉岩的第一折返阶段是由新元古代花岗岩岩浆携带上升的,其第二折返阶段是和新元古代花岗岩一起由逆冲及区域性隆起而上升,遭受剥蚀。  相似文献   

16.
某高速公路下伏煤矿采空区稳定性分析   总被引:10,自引:0,他引:10  
在论述某高速公路下伏砦脖煤矿采空区地质、采矿和工程地质特征的基础上,进行了稳定性数值模拟分析,定性与定量地分析与评价了该煤矿采空区的地表变形特征及稳定性。研究结果表明:该煤矿采空区的变形尚未完成,对拟建的高速公路将产生很大的危害,必须采取相应的工程治理措施。  相似文献   

17.
18.
摩擦桩基桩土间极限摩阻力取值问题探讨   总被引:1,自引:0,他引:1  
陈银生 《世界地质》1999,18(1):54-59
通过对广珠东线高速公路横沥大桥的试桩及土体的工程地质条件分析,总结出影响摩擦桩基桩土间极限摩阻力取值的一般问题以及解决问题的方法和措施。  相似文献   

19.
The structure of the eastern Pyrenees consists mainly of south-directed thrusts involving basement and cover rocks. An antiformal stack developed by the piling up of basement thrust sheets which outcrop in the Axial zone. These structures account for a thin-skinned thrust model rather than a vertical fault model in which the Axial zone would be essentially autochthonous, and the North-Pyrenean fault the axial plane of a fan thrust system. New data from the Eastern Pyrenees and the thin-skinned model suggest that(1) the structure east of the Pedraforca nappe is similar to that of the Central Pyrenees; (2) the cover rocks of the South-Pyrenean units and of the Axial zone-after restoration—built up a northwards-thickening prism consistent with the existence of a unique Pyrenean sedimentary basin during Mesozoic time; (3) the Axial zone is only a complex antiformal stack developed as a part of South-Pyrenean system related to the Paleogene thrusting-tectonics. The Axial zone palaeogeographic area had no special meaning during Mesozoic time.  相似文献   

20.
We first re-examined the apparent polar wander curves for stable Eurasia and Africa since the Triassic. These curves were then combined together with curves of North and South America according to the kinematics of the Atlantic ocean and a synthetic polar wander curve was given. Then, most of the paleomagnetic results from the Tethys mobile belt, from the Atlantic to the Pamirs, were analysed.Several groups of plates, microplates and blocks can be seen. First, relatively stable regions like Maghreb and Sicily, which have not moved much. Then we have a group formed by Iberia, Sardinia, Italy and, to a lesser extent, Corsica and the Western and Central Alps. For these blocks, movements are anticlockwise rotations chiefly driven by the anticlockwise rotation of Africa, but they are sometimes stronger.To the east, a major change takes place. The north of the Aegean Sea and the Ionian zone are clockwise rotated and these rotations are recent: Oligocene-Miocene for the first part, Pliocene to the present for the second part.A major problem arises in Turkey, Caucasus and Iran. Paleomagnetic results indicate a position far to the south of Eurasia, and, at the same time, geological evidence is in favour of a position close to Eurasia. We discuss these discrepancies.  相似文献   

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