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1.
文章运用Pupin的锆石群型研究方法,对滇西宝兴厂喜马拉雅期复式岩体中锆石的鉴定和统计,研究表明,本区复式岩体中的锆石有18种亚型,主要由{100}、{110}柱面和{111}、{311}锥面组成,其中柱面以{100}特优发育,锥面以{111}最为发育;众所周知,温度、酸性、碱性程度等对晶形的发育影响很大,本次研究锆石结晶速度较快,结晶温度较低,且在偏碱性的环境下形成的。锆石的结晶标型显示本区复式岩体是以壳源为主的壳幔混合成因的花岗岩,具有富水、富碱、富含成矿物质的特征,成为有利成矿的岩浆系统。  相似文献   

2.
武宁县大岭上钨矿是赣西北大湖塘矿集区的重要组成部分,矿产类型以W为主,伴生有Cu、Mo等,成矿与燕山期花岗岩密切相关。本文重点研究了大岭上燕山期黑云母花岗斑岩锆石的U-Pb年龄及其Hf同位素特征,探讨了黑云母花岗斑岩的成岩年龄、物源性质及岩石与矿化的关系。本区黑云母花岗斑岩结晶锆石的加权平均年龄为130.4±1.6Ma,代表花岗斑岩的结晶年龄,该年龄与晚白垩世前后中国东部区域构造体制从挤压缩短变形向大陆伸展转换的时期(135Ma)基本一致。黑云母花岗斑岩结晶锆石ε_(Hf)(t)值为+3.38~+8.63,二阶段模式年龄为684~1020Ma,说明大岭上黑云母花岗斑岩源岩物质主要为1020Ma之前从地幔中脱离出来的壳源物质,但有地幔物质混染。该区黑云母花岗斑岩的成岩年龄比矿集区钨矿的成矿年龄小,说明该黑云母花岗斑岩与矿区钨矿在成因上无关。黑云母花岗斑岩在空间上与矿区铜矿化密切共生,成岩物源中混染的幔源物质可能Cu元素的携载者,这些Cu叠加在早期钨矿中。大岭上矿区的钨、铜矿化是不同矿化时间和不同矿化种类叠加的产物。  相似文献   

3.
西藏青草山Cu-Au矿床是班公湖-怒江缝合带北侧新发现的具有大型远景的斑岩型矿床,但该矿床含矿斑岩的年龄、成因及源区一直未得到有效的约束.对青草山花岗闪长岩以及含矿花岗岩闪长斑岩进行了锆石年代学、Hf同位素以及岩石地球化学研究.结果显示,花岗闪长岩与含矿花岗闪长斑岩的侵入时代分别为131.2±0.3 Ma与117.9±0.8 Ma,代表了班公湖-怒江缝合带早期的成岩作用以及斑岩Cu-Au成矿作用.二者具有相似的地球化学特征,表明二者可能具有相同的岩浆源区,是不同时期同源岩浆活动的产物.结合含矿花岗闪长斑岩锆石Hf同位素组成,认为青草山含矿斑岩形成于班公湖-怒江洋壳向北俯冲过程中,是下地壳部分熔融的产物,受到了少量地幔物质的混合.   相似文献   

4.
赣南淘锡坑锡矿床中锡石晶体形态学和地球化学研究   总被引:1,自引:0,他引:1  
黄品赟  汪相  陈洁  任名华  赖光兵 《地质论评》2012,58(5):987-1000
本文对淘锡坑锡矿床的含矿石英脉中的锡石晶体开展了晶体形态学和地球化学的系统研究。按晶面组合特征,淘锡坑锡矿床中的锡石可分为三种类型:由{111}锥面+{110}柱面共2个单形构成的A型锡石、由{111}锥面+{110}柱面+{100}柱面共3个单形构成的B型锡石和由{111}锥面+{101}锥面+{110}柱面+{100}柱面共4个单形构成的C型锡石。综合各种锡石晶型与结晶条件的资料分析,本文推测A型、B型锡石的结晶温度高于C型锡石的。本文首次利用电子探针分析仪对锡石进行阴极发光(CL)成像观测,发现淘锡坑锡矿床中的锡石经历了两期结晶作用:早期锡石以CL荧光亮度较小(黑色——暗灰色)为特征,边缘有明显的溶蚀痕迹,常见典型的韵律振荡构造和砂钟构造,其晶面组合特征显示了早期锡石属于A型或B型锡石;晚期锡石以CL荧光亮度较大(白色——浅灰色)为特征,往往沿着早期锡石的溶蚀边界面充填生长,一般不显示韵律振荡构造和砂钟构造,其晶面组合特征显示了晚期锡石属于C型锡石。电子探针分析显示,淘锡坑锡矿床中锡石的FeO、Ta2O5含量较高,指示其形成于高温热液环境;HfO2含量较高,Zr/Hf比值较低,说明成矿热液来源于高度分异的花岗质岩浆。两期锡石的FeO含量和In2O3含量的对比结果显示,早期锡石相对富FeO而贫In2O3,反映了早期锡石的结晶温度和压力均高于晚期锡石的,故两期锡石的结晶作用分别与淘锡坑矿床的两期岩浆热液成矿作用相关。  相似文献   

5.
为探讨后峪地区锆石的生长条件及其与该地区岩浆岩的成因和演化的关系,对本区不同岩体中的锆石形态标型进行了系统的研究。结果表明:不同岩体中锆石的长宽比大多集中在1.5∶1~3∶1之间,按Pupin锆石晶体类型分类,岩体中的锆石可划分为R2、P1-5、S2-5、S7-10、S12-15和S20等类型,说明锆石是在碱质岩浆中结晶,且结晶温度较低;岩体的液相线的温度为850~750℃,锆石大规模结晶温度为700~650℃。锆石的结晶作用从岩浆早期开始一直持续到岩浆后期,温度跨度大,持续时间长,说明岩浆为富水岩浆,有利于斑岩型矿床Cu-Mo-Au的矿化。本区岩浆岩的化学成分分析及不同岩体中锆石群类型的演化趋势图表明:本区岩浆除了壳源成因之外还有幔源成分加入其中,岩浆岩属于钙碱性系列(偏碱性)岩石。  相似文献   

6.
贵州从江地区花岗质斑岩的地球化学特征   总被引:3,自引:1,他引:2  
王敏 《贵州地质》1999,16(4):278-281
从江地区花岗质斑岩分布于摩花岗岩体的周级,主要有二长花岗斑岩、普通花斑岩、碱长花岗斑岩、混合花岗斑岩4种类型。就岩石化学特征而言,二长花岗斑岩以壳源为主, 幔源成分的壳幔混源成因;普通花岗斑岩属壳源交代成因;而混合花岗斑岩与区内负变质岩的岩石化学成分相似。  相似文献   

7.
摘要福建建宁地区中元古代韩家、严塘二个岩体来自上地幔,其副矿物有28种。副矿物有三个结晶阶段,以富含自然铁、铬铁矿和富铪锆石为特征。锆石具高柱面指数和高锥面指数。变石英闪长岩和变英云闪长岩的锆石类型有二个主型和七个亚型。根据其副矿物标型组合及标型矿物特征,认为其物质来自幔源为主成因的岩浆。  相似文献   

8.
张倩  吴湘滨  杨牧  钱美平  刁谦  孟斐斯 《现代地质》2019,33(5):1025-1035
华南中生代花岗岩成因研究对指示华南岩石圈演化机制具有重要意义,也是成岩成矿作用研究的重要内容。利用原位LA-ICP-MS锆石U-Pb年代学、微量元素及Hf同位素组成分析,对紫金山矿田内浸铜湖铜钼矿床发育的花岗斑岩开展研究,获得其成岩年龄为(101.1±1.9)Ma,属早白垩世。浸铜湖花岗斑岩锆石Hf同位素εHf(t=101 Ma)为-6.1~0.7,两阶段Hf模式年龄(TDM2)为1.09~1.51 Ga,不支持其形成于华夏陆壳基底物质或壳源(变质)沉积岩的直接熔融。锆石Ce4+/Ce3+值指示岩浆氧逸度较低,表明其成因类似于华南分异的I型花岗岩,主要源于火成岩的部分熔融作用,可能有少量地幔物质的加入。华南晚中生代古太平洋板块受俯冲作用影响,发育大规模岩浆活动,其构造背景为活动大陆边缘环境。  相似文献   

9.
李壮  李兴怡  张鹏  郎兴海  赵枫 《地质论评》2022,68(4):1236-1260
浦桑果是近年来西藏冈底斯成矿带内发现的唯一一个富钴矽卡岩型铜多金属矿床,铜、铅、锌品位高,开发价值巨大。矿区主要出露黑云母花岗闪长岩和闪长玢岩中酸性侵入岩体,岩体形成时代均为中新世(13~14 Ma),但其岩体含矿性目前尚未查明,是否具有斑岩型铜矿成矿潜力值得进一步探讨和研究。本文主要采用LA- ICP- MS原位成分分析方法分别对黑云母花岗闪长岩和闪长玢岩中锆石展开系统的原位微量元素分析。分析结果表明,黑云母花岗闪长岩和闪长玢岩中锆石均发育典型的振荡环带结构,两种岩体具有相似的REE配分模式、Ce正异常和Eu负异常特征,锆石成因类型属于典型的岩浆锆石类,锆石主要结晶形成于陆壳环境。锆石初始饱和温度和锆石Ti结晶温度计算结果表明,黑云母花岗闪长岩锆石初始饱和温度范围为633~645℃,锆石Ti结晶温度为658~817℃;闪长玢岩锆石初始饱和温度分布在549~626℃,锆石Ti结晶温度为640~772℃,锆石初始饱和温度均低于锆石Ti结晶温度,综合指示矿区中酸性岩体形成过程中存在多期次岩浆熔体的补给作用。锆石n(Ce4+)/n(Ce3+)、EuN/Eu*N、微量元素Dy/Yb、(Ce/Nd)/Y值与氧逸度(ΔFMQ)特征表明,黑云母花岗闪长岩较闪长玢岩具有更高的氧逸度范围(ΔFMQ+0. 44 ~ ΔFMQ+3. 86)和相对高的水含量,从而更有利于浦桑果矿区铜、硫等成矿元素在岩浆中进一步富集成矿,且矿区可能发育中—大型规模的金属矿床,然而进一步发育斑岩型铜矿床的可能性较低。  相似文献   

10.
对青海南部西南三江多金属成矿带北段陆日格斑岩钼矿床开展了锆石LA-ICP-MS U-Pb和辉钼矿Re-Os同位素定年研究.研究表明,陆日格黑云母花岗斑岩、细粒花岗斑岩的锆石LA-ICP-MS 206Pb/238U加权平均年龄分别为62.1±0.4Ma、61.7±0.3Ma,所测锆石均显示岩浆成因特点,锆石U-Pb年龄可代表斑岩的结晶年龄;5件辉钼矿的Re-Os加权平均模式年龄为60.7±1.5Ma,锆石U-Pb同位素年龄与辉钼矿的Re-Os年龄非常吻合,所获年龄准确厘定了陆日格矿床的岩浆活动与矿化时限为早古新世.陆日格与三江带中北段主要斑岩型矿床成岩成矿年龄相差近20Ma,表明三江北段自古新世起,区域内至少有两期较大规模的斑岩成矿作用,作为目前已知新生代三江成矿带最早的一次岩浆成矿事件,陆日格斑岩钼矿具有非常重要的理论与找矿工作意义.  相似文献   

11.
锆石形态标型特征及标型生长机制探讨   总被引:4,自引:0,他引:4       下载免费PDF全文
本文在系统总结归纳不同研究者对锆石形态标型特征的研究成果基础上,重点从晶体生长、晶体化学和地球化学理论为重点探讨了锆石形态标型特征的生长机制。研究表明:锆石晶体结构中不同的面网方向,其平面内的原子组成、比例、化学键联结和键力以及面网间距和密度都是有差别的,由此决定了锆石晶体在不同的结晶介质条件下,不同面网的生长速度发生改变,生成相应的晶形。例如,尽管碱性元素并不进入锆石晶格,但它们可以影响Zr、Si、O离子的扩散速度,但是富钾和富钠的介质对锆石晶形发育的影响是有差别的,表现为:在富钾的介质中,将导致柱面的法向生长速度较锥面快得多,而锥面中,{111}的法向生长又较{311}快,由此决定了形成以{311}锥为主的双锥状晶体;在富钠的介质中,柱面和锥面都有一定程度的发育,但前者弱于后者,而柱面中,{100}的法向生长较{110}慢,由此决定了形成以{100}柱和{111}锥为主的短柱锥状晶体。根据类似方法,论证了其它形态标型特征的客观性,从而揭示了标型之间的内在联系和本质,展示了花岗岩研究中锆石形态标型特征应用推广的前景,也可为单颗粒锆石定年研究提供更多的分析应用价值  相似文献   

12.
Systematics of internal zircon morphology in major Variscan granitoid types   总被引:7,自引:0,他引:7  
The internal morphologies of zircon crystals from different types of granitoids (alkaline, calcalkaline and anatectic) are revealed by cathodoluminescence imaging and are described in terms of growth rates of the crystal faces relative to each other. Zircons in the alkaline granitoids are characterized by high and constant growth rates of {010} relative to the pyramidal forms and by symmetric grwoth of {011}. Zircons in the calcalkaline and anatectic granitoids are characterized by fluctuating or gradually decreasing relative growth rates of {010}, by asymmetric and highly variable growth of {011}, and by a tendency of {110} to become grwoth-inhibited. Corrosion events are interspersed during zircon growth in the calcalkaline magmas. In the calcalkaline and anatectic magmas, a discontinuity breaks the morphological evolution at late stages of crystallization. The discontinuity coincides with a sharp drop in cathodoluminescence. The growth behaviour of each crystal form is analysed and compared with predictions made by the periodic bond chain (PBC) theory. It is argued that the relative growth rate of {010} depends on supersaturation, that the growth rates of {011} faces are changed in response to different ratios of adsorbing cations (Na, K, Al), and that {110} faces become growth-inhibited by the adsorption of H2O or trace elements enriched in the residual liquid. Morphological and chemical discontinuities at late stages of crystallization are reasonably explained by the formation of larger growth units (from smaller ionic entities) in the residual liquid. Important factors controlling the zircon morphology in different types of granitoids are: high cooling rates (alkaline magmas), magma mixing (calcalkaline magmas), enrichment of H2O and trace elements in residual liquids (calcalkaline and anatectic magmas), and the major element chemistry of the magma, possibly the ratio of Na and K to Al (agpaicity).  相似文献   

13.
锆石的形态标型和成分标型可用于反演岩浆的演化过程和构造环境。为探讨西藏桑耶地区晚白垩世的石英二长闪长岩的岩浆成因、演化过程及其物理化学条件,采用成因矿物学方法对石英二长闪长岩中的锆石的形态标型、成分标型及其构造环境进行了系统研究。结果表明,锆石的延长系数多集中于1.5∶1~3.0∶1,锆石群型多为S10和P1。锆石形态标型表明岩浆为壳幔混源成因,成分标型指示锆石的Ti饱和温度为802~896℃(均值为853℃)。氧逸度结果离散度较大,其lgfO_(2)为-15.37~-4.77(平均FMQ为0.41),属中等氧逸度。锆石的Th/U值(0.76~1.38)及其微量元素成因判别图解均显示其为岩浆锆石,构造-岩浆背景判别图指示石英二长闪长岩可能来源于岛弧岩浆环境,形成于大陆弧型的构造背景。  相似文献   

14.
云南澜沧老厂隐伏花岗斑岩体地球化学特征及构造环境   总被引:4,自引:1,他引:3  
详细阐述了老厂隐伏花岗斑岩的地球化学特征,利用图解判别了其形成的构造环境,并初步探讨其成因机制。老厂花岗斑岩SiO2含量(68.09%~73.48%)与中国花岗岩平均值基本相当,富碱(Na2O+K2O为7.73%~8.51%),富钾(K2O/Na2O为1.85~25.8),属酸性偏铝质高钾钙碱性系列岩浆岩。轻稀土元素中等富集,重稀土元素相对亏损,(La/Yb)N=12.01~24.85,δEu=0.79~0.99(为弱负异常),稀土元素分布曲线为平滑的右倾曲线。通过花岗斑岩地球化学特征、图解判别、锆石标型特征等的综合研究,认为老厂隐伏花岗斑岩体是以壳源为主的壳幔源混合成因花岗斑岩,形成于青藏高原新生代碰撞造山主碰撞阶段区域挤压机制下的主碰撞构造环境。碰撞激发深部地幔局部熔融,使熔融体沿穿透性构造发育的早期裂谷带轴部上涌,成为构造-岩浆-热事件的主要驱动力;地幔物质涌入,向下地壳注入新生物质,诱发下地壳物质熔融,形成壳幔混合源富钾含矿岩浆。  相似文献   

15.
云南澜沧老厂花岗斑岩形成年龄及地质意义   总被引:4,自引:1,他引:3  
应用锆石SHRIMPU-Pb法和辉钼矿Re-Os同位素测年法对斑岩的形成时代进行精确定年。结果表明:成矿花岗斑岩体的形成年龄为44.6±1.1Ma;辉钼矿Re-Os等时线年龄为43.78±0.78Ma;成岩成矿期与滇西新生代岩浆-成矿作用高峰期吻合。结合区域地质条件和岩浆的可能源岩年龄(126.7±3.5Ma~529.3±13Ma)等资料分析,提出花岗斑岩在成因上与印支地块与滇缅泰地块陆内俯冲碰撞引发的地幔上涌及地壳重熔作用有关,岩浆来源具壳-幔混合特征。研究还证实滇西地区喜山期存在与隐伏花岗斑岩有关的大规模成矿作用。  相似文献   

16.
The relative growth rates of zircon crystal faces are recorded by growth zoning, which is recognizable in cathodoluminescence photographs of oriented crystal sections. The kinematics of zircon growth is graphically presented by the slopes of Grabahnen between crystal sectors. The relative velocities of advance of crystal faces correlate to the pattern of growth zoning. Widely spaced zoning, interrupted by surfaces of dissolution, on the one hand, and narrowly spaced uninterrupted oscillatory zoning, on the other hand, are interpreted as markers of low and high zircon-supersaturation of the melt, respectively. The following model is deduced from this correlation. The prism {110} is that crystal form, the growth rate of which reacts most sensitively to the zircon-supersaturation of the melt. The growthrate of the steep pyramid {211} is not primarily controlled by zircon-supersaturation. Instead, the growth of {211} is delayed by the adsorption of foreign atoms on its faces. The kinematics of zircon growth in anatectic, plutonic and meta-rhyolitic host rocks in the pre-Mesozoic basement of the Tauern Window (Eastern Alps) is explained by this model. Results show that the kinematics of zircon growth carry a much greater petrogenetic significance than has been previously suggested for the final shape of crystals alone.  相似文献   

17.
As the main objective of the present study, the morphological development of accessory zircons from four granitoids (pearl gneiss, fine-grained granite, coarse-grained gneiss, and Weinsberg granite) of the South-western Bohemian Massif was described in detail. On the one hand, this was realized by the classical approach, including a statistical evaluation of external zircon morphologies with the typology scheme. On the other hand, direct insight into the growth of single crystals was established by the production of crystal sections parallel and perpendicular to the crystallographic c-axis and by their subsequent imaging with the electron microprobe. Regarding the second method, eventual morphological trends were represented as a function of the growth rates of single crystal forms. Except for the coarse-grained gneiss, zircon crystals of the investigated granitoids show similar morphological trends according to both methods, starting with a dominant {1 0 0} prism and equally sized pyramids. Final crystal habit, however, is marked by the predominance of {1 1 0} and {2 1 1}. Zircon crystals from the coarse-grained gneiss run through a completely different development with a change of the prism habit from {1 1 0} to {1 0 0} and a more or less static growth of {1 0 1} with only slight modifications in size. Comparison of the results with data from the literature underlines the role of magma chemistry, magma temperature, and cooling rate as the main factors responsible for growth trends of accessory zircon.  相似文献   

18.
云南澜沧老厂斑岩钼矿成岩成矿时代研究   总被引:10,自引:1,他引:9  
2008年以来,滇西澜沧老厂矿区深部新发现巨厚斑岩型钼矿体,找矿取得重大突破。在对矿区矿化系统结构研究的基础上,应用锆石SHRIMP U-Pb法和辉钼矿Re-Os同位素测年法对成岩和成矿进行精确定年。结果表明:成矿花岗斑岩体的形成年龄为(44.6±1.1)Ma;辉钼矿Re Os等时线年龄为(43.78±0.78)Ma。证实矿区喜山期存在与隐伏花岗斑岩有关的大规模成矿作用,斑岩钼矿的成岩成矿期与滇西新生代岩浆作用高峰期吻合,老厂斑岩钼矿形成于陆内碰撞造山环境。  相似文献   

19.
Tin deposits are often closely associated with granitic intrusions. In this study, we analyzed tin partition coefficients between different fluids and melts (\({\text{D}}_{Sn}^{aq.fl./melt}\)) as well as various crystals and melts \({\text{D}}_{Sn}^{aq.fl./melt}\)(\({\text{D}}_{Sn}^{crystal/melt}\)) from the Furong tin deposit associated with the Qitianling A-type granite. Our experimental results indicate that tin partition behavior is affected by the chemical compositions of fluids, melts, and minerals. Tin is prone to partitioning into the residual magma in fractional crystallization or other differential magmatic processes if the magma originated from crustal sources with high alkali content, high volatile content, and low oxygen fugacity. Highly evolved residual peralkaline granitic magma enriched in tin can lead to tin mineralization in a later stage. Furthermore, the volatiles F and Cl in the magma play important roles in tin partitioning behavior. Low F contents in the melt phase and high Cl content in the aqueous fluid phase are favorable factors for tin partitioning in the aqueous fluid phase. High Cl content in the aqueous fluid catalyzes water–rock interaction and leads to the extraction of tin from tin-bearing minerals. All these findings support a hydrothermal origin for the tin deposits. In light of the geotectonic setting, petrochemical characteristics, and mineralizing physicochemical conditions of the Furong tin deposit, it is inferred that the ore-forming fluid of the Furong tin ore deposit could have derived from the Qitianling peralkaline intrusion.  相似文献   

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