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1.
Shales of the ca. 3.0 Ga Buhwa Greenstone Belt, Zimbabwe, were derived from a compositionally diverse provenance whose ages, determined by ion probe analyses of detrital zircons in interbedded sandstones, range from 3.8 to 3.1 Ga. Geochemical data for the shales were previously interpreted to indicate that sediments had been derived from an intensely weathered source. REE concentrations in the shales were interpreted to suggest that the provenance was compositionally mixed, with components of felsic (tonalite and alkalic granitoid) and mafic rocks. Sm/Nd and Nd isotopic compositions of these rocks can be used to model initial Nd isotopic ratios at the time of sedimentation (εNdsed), as well as model crustal formation ages (TDM). The former, at the age of sedimentation, range from +0.6 to −10.8, consistent with a range of provenance ages. The latter range from 4.46 Ga to 2.99 Ga. The oldest crustal formation ages, up to 0.7 Ga older than known detrital components, are interpreted here to indicate that the Sm-Nd system of the sediments experienced open system behavior. The implied alteration would have included an increase in Sm/Nd by about 20-25 percent, probably in the form of preferential loss of Nd with respect to Sm. The Pb isotopic compositions of whole rock samples are quite radiogenic, with a range of 206Pb/204Pb from 25.5 to 154. An array of ten samples lies scattered about a line with a 207Pb/204Pb -206Pb/204Pb slope age of about 2.73 Ga. Five individual samples were sequentially leached to further test the timing and characteristics of this U-Th-Pb alteration event. These arrays of a whole rock, three leach steps, and a residue also form linear Pb-Pb arrays (one is more scattered) with ages ranging from 2260 ± 360 Ma to 2824 ± 170 Ma, suggesting that all samples experienced a latest Archean to earliest Proterozoic enrichment in U/Pb. This age range also may be the approximate age of Sm/Nd enrichment for the shales. All samples, both whole rocks and leached samples, lie grouped on a 208Pb/204Pb - 206Pb/204Pb diagram around a line with 232Th/238U = 3.5 (2.9 to 3.9). Because of the lack of large differences in the Th/U of the samples through large ranges of U/Pb, we interpret this consistency in Th/U to mean that the shales of the Buhwa belt experienced Pb loss, rather than U and Th gain. Circumstances that may be responsible for Pb loss in a sedimentary basin include loss of saline fluids during basin dewatering. Such an event would likely have been related to folding associated with the thrusting and magmatic intrusion of the adjacent Limpopo Belt, suggesting that uplift, dewatering, and geochemical and isotopic alteration can be genetically related.  相似文献   

2.
The Jurassic to Early Cretaceous magmatic arc of the Andes in northern Chile was a site of major additions of juvenile magmas from the subarc mantle to the continental crust. The combined effect of extension and a near stationary position of the Jurassic to lower Cretaceous arc favoured the emplacement and preservation of juvenile magmatic rocks on a large vertical and horizontal scale. Chemical and Sr, Nd, and Pb isotopic compositions of mainly mafic to intermediate volcanic and intrusive rock units coherently indicate the generation of the magmas in a subduction regime and the dominance of a depleted subarc mantle source over contributions of the ambient Palaeozoic crust. The isotopic composition of the Jurassic (206Pb/204Pb: ∼ 18.2; 207Pb/204Pb: ∼ 15.55; 143Nd/144Nd: ∼ 0.51277; 87Sr/86Sr: ∼ 0.703–0.704) and Present (206Pb/204Pb: ∼ 18.5; 207Pb/204Pb: ∼ 15.57; 143Nd/144Nd: ∼ 0.51288; 87Sr/86Sr: ∼ 0.703–0.704) depleted subarc mantle beneath the Central and Southern Andes (18°–40°S) was likely uniform over the entire region. Small differences of isotope ratios between Jurassic and Cenozoic to Recent of subarc mantle-derived could be explained by radiogenic growth in a still uniform mantle source.Electronic Supplementary Material Supplementary material is available to authorised users in the online version of this article at .  相似文献   

3.
《地学前缘(英文版)》2020,11(5):1621-1634
The Izu-Bonin arc system is sediment-poor(~400 m thick with no accretionary prism) and,therefore,the influence of the altered oceanic crust(AOC) is most likely the source of the documented along-arc lava compositional variations,especially in Pb isotopes.Izu-Bonin arc lava geochemistry suggests an influx of subduction component from an Indian-type AOC.However,samples drilled from the western Pacific geochemical reference site at Integrated Ocean Drilling Program Site 1149 implies subduction of a Pacific-type AOC.To solve the apparent discrepancy of slab input versus arc output in this arc system,samples of the AOC were dredged from vertical fault scarps of the subducting Pacific Plate along a transect from 27.5°N to 34.50 N.Samples range from tholeiitic to mildly alkalic mid-ocean ridge basalts as well as trachybasalts,basaltic trachyandesites,tephrites,and phono-tephrites.Isotope ratios also exhibit a range of values(~(87)Sr/~(86)Sr=0.70282-0.70673,143 Nd/144 Nd=0.512552-0.513174,~(206)Pb/204 Pb=18.43-20.00,207 Pb/204 Pb=15.40-15.67,~(208)Pb/~(204)Pb=37.75-39.55).Our results suggest that there is a geochemical variation in the AOC that is neither completely due to seawater or hydrothermal alteration,nor to petrogenetic processes.Rather,this variation is the result of the Pacific-Izanagi Ridge system tapping into a heterogeneous,plume-polluted mantle source during the Mid-Cretaceous volcanic event.The observed Pacific-type AOC is not responsible for the Indian-type Pb isotopic signature of Izu-Bonin arc lavas.This leads us to propose an alternative scenario where the Izu-Bonin arc lava Indian-type Pb isotopic signature originates from slab-derived fluids interacting and adsorbing Pb from an Indian-type mantle wedge through zone-refining.  相似文献   

4.
Four volcanoes in the Pantar Strait, the westernmost part of the extinct sector of the east Sunda arc, show remarkable across-arc variation in elemental abundances (K2O: 1.2 to 4.3%), trace element ratios (Pb/Ce: 0.4 to 0.18; Ce/Yb: 20 to 55) and isotope ratios (143Nd/144Nd: 0.51263 to 0.51245; 87Sr/86Sr: 0.7053 to 0.7068; 206Pb/204Pb: 19.29 to 19.15). Pb isotopes are decoupled from Sr and Nd isotopes, with the frontal volcanoes showing the higher Nd and Pb and lower Sr isotopic ratios. The isotopic and trace element ratios of the volcanic samples are best explained by modification of a MORB-type source (with Indian Ocean island basalt-type Pb isotopic characteristics) by a fluid and a partial melt of subducted continental material (SCM). The frontal volcano contains the highest proportion of the fluid component, with a small contribution of partial melt. The source of the rear-arc volcano is strongly influenced by a partial melt of SCM that had undergone a previous dehydration event, by which it lost most of its fluid-mobile elements such as Pb. The SCM partial melt was in equilibrium with both rutile and garnet, whereas mantle melting took place in the presence of residual mica. The relatively large across-arc increase in incompatible elements can be explained by a combination of increasing addition of SCM partial melt, changing mantle wedge fertility and smaller degrees of partial melting toward the rear of the arc. Comparison with a more westerly across-arc transect shows that the relatively low 143Nd/144Nd ratios of the frontal volcano, and the decoupling of Pb from Sr and Nd isotopes are unique to the Pantar Strait volcanoes. This is likely to reflect magma generation in a collisional environment, where the leading edge of the Australian continent, rather than subducted sediment, contributes to the magma source.  相似文献   

5.
《Gondwana Research》2006,9(4):529-538
Sr, Nd and Pb isotopic compositions of the Cenozoic basalts were analyzed from Baengnyeongdo Island, Jeongok, Ganseong, and Jejudo Island of Korea. They reveal relatively enriched Sr and Nd isotopic compositions (87Sr/86Sr = 0.70330∼0.70555, 143Nd/144Nd = 0.51298∼0.51256) compared with MORB.207Pb/204Pb and 208Pb/204Pb values of all the analyzed Korean basalts lie above the Northern Hemisphere Reference Line (NHRL) defined by Hart (1984). Pb isotopic compositions of basalts from Jejudo Islands (206Pb/204Pb = 18.61∼19.12, 207Pb/204Pb = 15.54∼15.69, 208Pb/204Pb = 38.98∼39.72) are significantly more radiogenic than the rest (206Pb/204Pb = 17.72∼18.03, 207Pb/204Pb = 15.44∼15.58, 208Pb/204Pb = 37.77∼38.64). The Cenozoic Korean basalts thus can be divided into two groups based on their Sr, Nd and Pb isotopic compositions. The north group reveals mixing between DMM and EM1 while the south group displays DMM-EM2 mixing. Such a distribution is the same as Chinese Cenozoic basalts and it can be interpreted that the subcontinental lithospheric mantle under Korea represents simple lateral continuation of the South and North China Blocks. We suggest that Korean continental collision zone cross the Korean Peninsula through the region between the north and south basalt groups of Korea.  相似文献   

6.
Recent statistical analyses on the isotopic compositions of oceanic, arc, and continental basalts have revealed that the Earth's mantle is broadly divided into eastern and western hemispheres. The present study aimed to characterize the isotopically defined east–west geochemical hemispheres using trace-element concentrations. Basalt data with Rb, Sr, Nd, Sm, Pb, Th, and U in addition to the isotopic ratios 87Sr/86Sr, 143Nd/144Nd, 206Pb/204Pb, 207Pb/204Pb, and 208Pb/204Pb were selected mostly from the GEOROC and PetDB databases. A total of 4787 samples were used to investigate the global geochemical variations. The results show that the wide trace-element variations are broadly explained by the melting of melt-metasomatized and fluid-metasomatized mantle sources. The larger amount of the fluid component derived from subducted plates in the eastern hemisphere than that in the western hemisphere is inferred from the basalts. These characteristics support the hypothesis that focused subduction towards the supercontinent created the mantle geochemical hemispheres.  相似文献   

7.
The basaltic basement of the large igneous province formed bythe Kerguelen Plateau and Broken Ridge in the southeastern IndianOcean has been sampled by three Ocean Drilling Program cruises(Legs 119, 120 and 183). Although the Cretaceous parts of thisplateau formed in the embryonic Indian Ocean basin, presumablyby melting associated with the Kerguelen plume, trace elementabundances and isotopic ratios of Sr, Nd and Pb of Cretaceousbasalt from several drill sites indicate that continental lithospherewas involved in their petrogenesis. On the basis of relativedepletions in Nb, Ta and Th, and isotopic characteristics similarto those of EMI ocean island basalt, lavas from Leg 120 Site747 in the Central Kerguelen Plateau contain a component derivedfrom lower continental crust. On the basis of relative abundancesof Sr and Eu and EMI-like Pb isotopic ratios, the source ofbasalt from Leg 120 Site 750 in the northeastern part of theSouthern Kerguelen Plateau also contained a component derivedfrom lower continental crust; in this case, the crustal componentformed as a plagioclase-rich, clinopyroxene-bearing cumulate.Basalts from Leg 120 Site 749 define two distinct isotopic (Sr,Nd and Pb) groups which differ from the isotopic fields forSite 747 and 750 basalts. Among Site 749 lavas, there is subtleevidence for a continental component, broadly similar (i.e.moderate 206Pb/204Pb  相似文献   

8.
Pb, Sr and Nd isotopic compositions have been analyzed in recent granites from Northern Africa, Northern Italy and Greece. Lead isotope compositions of K-feldspars are rather homogeneous, and cluster close to the modern lead of Stacey and Kramers (1975) but with slightly higher207Pb/204Pb and208Pb/204Pb ratios. The Cyclades samples, however, have higher206Pb/204Pb ratios. Addition of mantle-derived lead was probably very limited, which supports a quasi-closed system evolution of this element in the continental crust. The Sr, Nd data fall in the enriched part of the143Nd/144Nd vs.87Sr/86Sr diagram and define a smooth hyperbolic mixing curve. Over a wide area, straddling different orogens, most granites may be accounted for by a binary mixture between a recycled crustal component and a depleted mantle-like component. No correlation is observed between either Pb and Sr or Nd isotopic ratios, or any isotopic ratio and major element contents. Quantitative modelling suggests that two cases fit the Sr and Nd characteristics of these granites: they both require anatexis of the crust on a scale large enough to average the isotopic properties of heterogeneous terranes. In the first case, the mantle-derived component may be represented by differentiated Island Arc-type magmas, and the granites result from mixing these magmas with anatectic melts. In the second case, mantle-derived igneous rocks, such as obducted ophiolites, are part of the crustal source and their variable involvement in the anatectic process causes isotopic variations.CRPG Contribution n 630.  相似文献   

9.
The Denizli region of the Western Anatolia Extensional Province (WAEP) includes a typical example of intra-plate potassic magmatism. Lamproite-like K-rich to shoshonitic alkaline rocks erupted in the Upper Miocene-Pliocene in a tensional tectonic setting. The absence of Nb and Ta depletion, low Th/Zr and high Nb/Zr ratios and distinct isotopic values (i.e. low 87Sr/86Sr, 0.703523–0.703757; high 143Nd/144Nd, 0.512708–0.512784; high 206Pb/204Pb, 19.079–19.227, 207Pb/204Pb, 15.635–15.682, 208Pb/204Pb, 39.144–39.302) mark an anorogenic geochemical signature of the Denizli volcanics. All of the lavas are strongly enriched in large-ion-lithophile elements (e.g. Ba 1,100–2,200 ppm; Sr 1,900–3,100 ppm; Rb 91–295 ppm) and light rare-earth elements (e.g. LaN?=?319–464), with a geochemical affinity to ocean-island basalts and lack of a recognizable subduction signature or any evidence for crustal contamination. The restricted range of isotopic (Sr, Nd, Pb) ratios in both near-primitive (Mg# 66.7–77.2) and more evolved (Mg# 64.6–68.7) members of the Denizli volcanics signify their evolution from an isotopically equilibrated parental mantle source. Their high Dy/Yb and Rb/Sr values also suggest that garnet and phlogopite were present in the mantle source. Their strong EM-II signature, very low Nd model ages (0.44–049 Ga) and isotopic (Sr-Nd-Pb) values analogous to those of the Nyiragongo potassic basanites and kimberlites from the African stable continental settings, suggest that the parental melts that produced the Denizli volcanics are associated with very young and enriched mantle sources, which include both sublithospheric and enriched subcontinental lithospheric mantle melts. Mantle-lithosphere delamination probably played a significant role in the generation of these melts, and could be related to roll-back of the Aegean arc, lithospheric extension and asthenospheric mantle upwelling.  相似文献   

10.
Seven hundred and twenty-five Sr, two hundred and forty-three Nd and one hundred and fifty-one Pb isotopic ratios from seven different Mexican magmatic provinces were compiled in an extensive geochemical database. Data were arranged according to the Mexican geological provinces, indicating for each province total number of analyses, range and mean of values and two times standard deviation (2σ). Data from seven provinces were included in the database: Mexican Volcanic Belt (MVB), Sierra Madre Occidental (SMO), Baja California (BC), Pacific Ocean (PacOc), Altiplano (AP), Sierra Madre del Sur (SMS), and Sierra Madre Oriental (SMOr). Isotopic values from upper mantle and lower crustal xenoliths, basement outcrops and sediments from the Cocos Plate were also compiled. In the MVB the isotopic ratios range as follows:87Sr/86Sr 0.703003-0.70841;143Nd/144Nd 0.512496-0.513098;206Pb/204Pb 18.567-19.580;207Pb/204Pb 15.466-15.647;208Pb/204Pb 38.065-38.632. The SMO shows a large variation in87Sr/86Sr ranging from ∼0.7033 to 0.71387.143Nd/144Nd ratios are relatively less variable with values from 0.51191 to 0.51286. Pb isotope ratios in the SMO are as follows:206Pb/204Pb 18.060-18.860;207Pb/204Pb 15.558-15.636;208Pb/204Pb 37.945-38.625. PacOc rocks show the most depleted Sr and Nd isotopic ratios (0.70232-0.70567 for Sr and 0.512631-0.513261 for Nd). Pb isotopes for PacOc show the following range:206Pb/204Pb 18.049-19.910;207Pb/2047Pb 15.425-15.734;208Pb/204Pb 37.449-39.404. The isotopic ratios of the AP rocks seem to be within the range of those from the PacOc. Most samples with reported Sr and Nd isotopic data are spread within and around the “mantle array”. The SMO seems to have been formed by a mixing process between mantle derived magmas and continental crust. The MVB appears to have a larger mantle component, with AFC as the dominant petrogenetic process for the evolved rocks. There is still a need for Pb isotopic data in all Mexican magmatic provinces and of Nd isotopes in BC, AP, SMS, and SMOr.  相似文献   

11.
Ordovician faunal data from the Scandinavian Caledonides is tested with new geochemical information from zircons to give U/Pb ages and source origins of volcanic arc and ophiolite sequences. Early Ordovician (Arenig-Llanvirn), low latitude, Toquima-Table Head faunas from the upper Upper Allochthon are associated with an island arc system formed adjacent to Laurentia. Contemporaneous mafic magmas were contaminated by crustal material during subduction and associated granites contain inherited zircons of Archaean age. The nearest source for such rocks is on the Laurentian rather than the Baltic side. Higher latitude Celtic province faunas from the upper Upper Allochthon are from one insular site accessible to forms from both Laurentia and Baltica.
The late Ordovician low-latitude Holorhynchus and subtropical Hirnantia faunas occur in overstep sequences above deeply eroded early Ordovician arc complexes. The transgression appears to be coeval with a second generation of spreading-related complexes. Single detrital zircons from sediments show sources from Archaean, Proterozoic and early Ordovician terranes. This suggests that deposition was in a basin situated along the same continental margin (Laurentia) to which the early Ordovician ophiolite/arc sequences had already become accreted. The late Ordovician faunas link both Laurentia and Baltica at a time of narrowing of lapetus.
The new geochemical data together with the faunal information is supported by recent palaeomagnetic studies.  相似文献   

12.
The Cadomian basement and the Cambro-Ordovician overstep sequence in Saxo-Thuringia is characterized by clastic sedimentation from the Late Neoproterozoic to the Ordovician. Magmatism in the Avalonian–Cadomian Arc preserved in Saxo-Thuringia occurred between ca. 570 and 540 Ma. Peri-Gondwanan basin remnants with Cadomian to Early Palaeozoic rocks are exposed as very low-grade metamorphosed rocks in six areas (Schwarzburg Anticline, Berga Anticline, Doberlug Syncline, North Saxon Anticline, Lausitz Anticline, and Elbe Zone). A hiatus in sedimentation between 540 and 530 Ma (Cadomian unconformity) is related to the Cadomian Orogeny. A second gap in sedimentation occurred during the Upper Cambrian (500 to 490 Ma) and is documented by a disconformity between Lower to Middle Cambrian rocks and overlying Tremadocian sediments. Major and trace-element signatures of the Cadomian sediments reflect an active margin (“continental arc”), those of the Ordovician sediments a passive margin. The Cambrian sediments have inherited the arc signature through the input of relatively unaltered Cadomian detritus. Initial Nd and Pb isotope data from the six Saxo-Thuringian areas demonstrate that there is no change in source area with time for each location, but that there are minor contrasts among the locations. (1) Cadomian sediments from the Lausitz Anticline, the Doberlug Syncline and the Elbe Zone have lower 207Pb/204Pb than all other areas. (2) The core of the Schwarzburg Anticline, which is overprinted by greenschist facies conditions and detached, is isotopically heterogeneous. One part of its metasedimentary units has less radiogenic Nd than sediments from other low-grade units of similar age in the same area. (3) Cadomian sediments from the Schwarzburg Anticline show an input of younger felsic crust. (4) The Rothstein Group shows distinct input of young volcanic material. Also, (5) Cadomian sediments from the Lausitz Anticline, the Elbe Zone and parts of the North Saxon Anticline are characterized by input from an old mafic crust. Nd isotope data of the remaining areas yield average crustal residence ages of the sediment source of 1.5–1.9 Ga, which suggests derivation from an old craton as found for other parts of the Iberian–Armorican Terrane Collage. Similarly, the Pb isotope data of all areas indicate sediment provenance from an old craton.The rapid change of lithologies from greywacke to quartzite from the Late Neoproterozoic (Cadomian basement) to the Ordovician does not reflect changes in sediment provenance, but is essentially due to increased reworking of older sediments and old weathering crusts that formed during various hiatus of sedimentation. This change in sediment maturity takes its chemical expression in lower overall trace-element contents in the quartzite (dilution effect by quartz) and relative enrichment of some trace-elements (Zr, MREE, HREE due to detrital zircon and garnet). The Rb–Sr systematics of the quartzites and one Ordovician tuffite was disturbed (most likely during the Variscan Orogeny), which suggests a lithology-controlled mobility of alkali and calc-alkali elements. By comparison with available data, it seems unlikely that only Nd TDM model ages are useful to distinguish between West African and Amazonian provenance. Nd TDM model ages of 1.5 to 1.9 Ga in combination with paleobiogeographic aspects, age data from detrital zircon, and palaeogeographic constraints, especially through tillites of the Saharan glaciation in the Hirnantian, strongly indicate a provenance of Saxo-Thuringia from the West African Craton.  相似文献   

13.
The Takaka Terrane in New Zealand is one of the best exposed arc fragments of the early Paleozoic Australian-Antarctic convergent margin and constitutes one of the most outboard terranes of this margin in paleogeographic reconstructions. Pb-Nd isotope compositions of clinopyroxenes from the Cambrian Devil River Volcanics of the Takaka Terrane enable identification of the location of the terrane in the Paleo-Pacific Ocean. The Devil River Volcanics, a suite of primitive arc and back-arc rocks, are interbedded with the partly continent-derived Haupiri Group sediments. Extremely radiogenic Pb and unradiogenic Nd compositions in the arc rocks cannot be explained by assimilation of the Haupiri Group sediments or a continental basement of such a composition. Pb isotope compositions of the Takaka Terrane sediments are much less radiogenic and overlap with crustal compositions of the Lachlan Fold Belt in Australia, suggesting that both units are derived from one source, the Australian-Antarctic Pacific margin. Pb-Nd isotope compositions in the Devil River Volcanics reflect contamination of their mantle sources by subducted sediments derived from Archean provinces in either Antarctica or Laurentia. Both provinces show characteristically high 207Pb/204Pb500 and were located at the Pacific rim in the Cambrian. Mixing between mantle and Proterozoic continental material from present western South America or eastern Laurentia cannot explain the high 207Pb/204Pb500 in the New Zealand rocks. As in New Zealand, extreme spreads in Pb-Nd isotope compositions in other Cambrian volcano-sedimentary sequences in southeast Australia and Tasmania can be explained by the same model, suggesting that all these fragments originated along the Australian-Antarctic Gondwana margin. Pb isotope compositions of arc rocks, therefore, provide a new tool for terrane analysis in the early Paleozoic Pacific ocean.  相似文献   

14.
The Sr,Nd and Pb isotopic characteristics of the Wudang basic dyke swarms and basic volcanics of the Yaolinghe Group show that they were derived from the same multi-component mixing source in the mantle.The Wudang basic dyke swarms have(^87Sr/^86Sr)i=0.6905-0.7061,εNd(t)=-1.9-5.0,△^208Pb/^204Pb=35.49-190.26,△^207Pb/^204Pb=Th/Ta and a wide range of La/Yb ratios;and the basic volcanics of the Yaolinghe Group have(^87Sr/^86Sr)i=0.6487-0.7075,εNd(t)=0.11-3.94,△^208Pb/^204Pb=-81.58-219.95,△^207Pb/^204Pb=4.44-16.68and higher Th/Ta and La/Yb ratios,indicating that their source is a mixture of DM and EMⅡ,and the basic volcanics of the Yaolinghe Group were contaminated by crust materials en rout to the surface.Based on the geochemical features of continental tholeiitic basalts and being products of differen tacies derived from the same source,it can be concluded that an important rifting event in the South Qinling basement block occurred during Neoproterozoic,followed by a setting of oceanic basic in the Early Paleozoic.  相似文献   

15.
The Pb and Sr isotope ratios of Plio-Pleistocene volcanic rocks from the Aleutian volcanic arc are used as tracers of the lithospheric subduction process at the converging Pacific and Bering plates. Aleutian arc lavas do not have the same Pb isotopic compositions as volcanic rocks of the subducted Pacific ocean crust or the nearby Pribilof Islands, but appear to contain an ‘old continental crustal component’ with high 207Pb/204Pb ratio, as has been found in some other volcanic arcs.87Sr/86Sr ratios in the Aleutian volcanic arc rocks average 0.70322, slightly higher than fresh volcanic rocks from normal ridge segments, but within the range of values from ‘Icelandic’ ridge segments, oceanic islands and the Pribolof Islands. The Pb and Sr isotopic compositions of Aleutian lavas show a positive correlation and the range of values does not change for volcanoes distributed along strike in the arc, even though the crustal type in the hanging wall of the Benioff zone changes from oceanic in the west to continental in the east. Since the basement of the continental arc segment is older than the basement of the oceanic segment, and probably has a different isotopic character, the constancy of isotopic ratios along the arc argues against contamination by wall rocks of the type exposed in the arc.A sufficient explanation for the isotopic data is the mixture of several per cent of continent-derived sediment with melt derived from the underthrust oceanic crust and overlying mantle. This small amount of contaminant is difficult to document by geophysical observations. Such a model implies extensive recycling of Ba, Pb, K and Rb through volcanism at convergent plate margins like the Aleutians.  相似文献   

16.
There has been little research on geochemistry and isotopic compositions in tholeiites of the Northern region from the Paraná Continental Flood Basalts (PCFB), one of the largest continental provinces of the world. In order to examine the mantle sources involved in the high-Ti (Pitanga and Paranapanema) basalt genesis, we studied Sr, Nd, and Pb isotopic systematics, and major, minor and incompatible trace element abundances. The REE patterns of the investigated samples (Pitanga and Paranapanema magma type) are similar (parallel to) to those of Island Arc Basalts' REE patterns. The high-Ti basalts investigated in this study have initial (133 Ma) 87Sr/86Sr ratios of 0.70538–0.70642, 143Nd/144Nd of 0.51233–0.51218, 206Pb/204Pb of 17.74–18.25, 207Pb/204Pb of 15.51–15.57, and 208Pb/204Pb of 38.18–38.45. These isotopic compositions do not display any correlation with Nb/Th, Nb/La or P2O5/K2O ratios, which also reflect that these rocks were not significantly affected by low-pressure crustal contamination. The incompatible trace element ratios and Sr–Nd–Pb isotopic compositions of the PCFB tholeiites are different to those found in Tristan da Cunha ocean island rocks, showing that this plume did not play a substantial role in the PCFB genesis. This interpretation is corroborated by previously published osmium isotopic data (initial γOs values range from +1.0 to +2.0 for high-Ti basalts), which also preclude basalt generation by melting of ancient subcontinental lithospheric mantle. The geochemical composition of the northern PCFB may be explained through the involvement of fluids and/or small volume melts related to metasomatic processes. In this context, we propose that the source of these magmas is a mixture of sublithospheric peridotite veined and/or interlayered with mafic components (e.g., pyroxenites or eclogites). The sublithospheric mantle (dominating the osmium isotopic compositions) was very probably enriched by fluids and/or magmas related to the Neoproterozoic subduction processes. This sublithospheric mantle region may have been frozen and coupled to the base of the Parana basin lithospheric plate above which the Paleozoic subsidence and subsequent Early Cretaceous magmatism occurred.  相似文献   

17.
We report here new field and analytical data from Precambrian rocks on Hainan Island of the Cathaysia Block, south China, and examine its probable connection to Laurentia. Granitoids and newly discovered felsic volcanic rocks dated at 1433 ± 6 Ma and 1439 ± 9 Ma (SHRIMP U‐Pb zircon) on Hainan Island are coeval with, and isotopically similar to the 1500–1350 Ma trans‐continental granite‐rhyolite province in southern Laurentia. Quartzites unconformably overlying the ca. 1430 Ma volcaniclastic rocks on Hainan Island are interpreted as locally‐sourced Grenvillian foreland basin deposits that can be correlated with the Deer Trail Group of south‐western Laurentia. The detrital provenance of the quartzites contains age populations comparable to the 1610–1490 Ma, westerly‐sourced non‐Laurentian detrital grains reported in the Belt Basin of south‐western Laurentia. Our new data thus make Cathaysia the most likely continental block next to western Laurentia before and during the late Mesoproterozoic assembly of Rodinia.  相似文献   

18.
Lead isotope analyses were performed on 26 polymetallic massive sulphide deposits of the Iberian Pyrite Belt, as well as on overlying gossans and associated volcanic rocks. All the massive sulphide deposits (except for Neves-Corvo), and nearly all the volcanic rocks show very similar isotopic compositions grouped around 18.183 (206Pb/204Pb), 15.622 (207Pb/204Pb) and 38.191 (208Pb/204Pb), indicating that most of the ore deposit lead was derived from the same continental crust environment as the associated volcanic rocks. The isotopic compositions are representative of the average south Iberian crust during the Devonian to Early Carboniferous (Dinantian), and their constancy implies a homogenization of the mineralizing fluids before the deposition of the massive sulphides from hydrothermal fluids circulating through interconnected regional fracture systems. This isotopic constancy is incompatible with multiple, small, independent hydrothermal cells of the East Pacific Rise type, and fits much better with a model of hydrothermal convections driven by “magmatic floor heating”. Neves-Corvo is the only south Iberian massive sulphide deposit to have a heterogeneous isotopic composition with, in particular, a highly radiogenic stanniferous ore (206Pb/204Pb of the cassiterite is >18.40). A model of lead mixing with three components is proposed to explain these variations: (1) one derived from the Devonian to Early Carboniferous (Dinantian) continental crust that generated all the other massive ores; (2) an Eohercynian stanniferous mineralization partly remobilized during the formation of the massive sulphides, but independent of them; and (3) a Precambrian continental crust component. The juxtaposition of three different sources places Neves-Corvo in a specific paleogeographic situation that could also explain its mineralogical specificity. The geodynamic context that best explains all the obtained isotopic results is one of an accretionary prism. The fact that lead isotope signatures of the gossans are almost identical to those of the underlying massive sulphides means that this technique could be a useful exploration tool for the Iberian Pyrite Belt.  相似文献   

19.
Sediment provenance analysis remains a powerful method for testing hypotheses on the temporal and spatial evolution of uplifted source regions, but issues such as recycling, nonunique sources, and pre- and post-depositional modifications may complicate interpretation of results from individual provenance techniques. Convergent retroarc systems commonly contain sediment sources that are sufficiently diverse (continental magmatic arc, fold–thrust belt, and stable craton) to enable explicit provenance assessments. In this paper, we combine detrital zircon U–Pb geochronology, heavy mineral identification, Nd isotopic analyses, conventional sandstone petrography, and paleocurrent measurements to reconstruct the clastic provenance history of a long-lived sedimentary basin now exposed in an intermontane zone of the northern Andean hinterland of Colombia. The Middle Magdalena Valley basin, situated between the Central Cordillera and Eastern Cordillera, contains a 5–10 km-thick succession of Upper Cretaceous to Quaternary fill. The integrated techniques show a pronounced change in provenance during the Paleocene transition from the lower to upper Lisama Formation. We interpret this as a shift from an eastern cratonic source to a western Andean source composed of magmatic-arc rocks uplifted during initial shortening of the Central Cordillera. The appearance of detrital chloritoid and a shift to more negative εNd(t=0) values in middle Eocene strata of the middle La Paz Formation are attributed to shortening-related exhumation of a continental basement block (La Cira–Infantas paleohigh), now buried, along the axis of the Magdalena Valley. The diverse provenance proxies also show distinct changes during middle to late Eocene deposition of the Esmeraldas Formation that likely reflect initial rock uplift and exhumation of the fold–thrust belt defining the Eastern Cordillera. Upsection, detrital zircon U–Pb ages and heavy mineral assemblages for Oligocene and younger clastic deposits indicate that the Mesozoic sedimentary cover of the Eastern Cordillera was recycled during continued Cenozoic shortening. Our multidisciplinary provenance study refines the tectonic history of the Colombian Andes and demonstrates that uncertainties related to sediment recycling, nonunique sources, source heterogeneity, and climate in interpreting provenance data can be minimized via an integrated approach.  相似文献   

20.
We have investigated the petrography, geochemistry, and detrital zircon U–Pb LA-ICPMS dating of sandstone from the Gorkhi Formation of the Khangai–Khentei belt in the Ulaanbaatar area, central Mongolia. These data are used to constrain the provenance and source rock composition of the accretionary complex, which is linked to subduction of the Paleo-Asian Ocean within the Central Asian Orogenic Belt during the Middle Devonian to Early Carboniferous. Field and microscopic observations of the modal composition of sandstone and constituent mineral chemistry indicate that the sandstone of the Gorkhi Formation is feldspathic arenite, enriched in saussuritized plagioclase. Geochemical data show that most of the sandstone and shale were derived from a continental margin to continental island arc setting, with plutonic rocks being the source rocks. Detrital zircon 206Pb/238U ages of two sandstones yields age peaks of 322 ± 3 and 346 ± 3 Ma. The zircon 206Pb/238U age of a quartz–pumpellyite vein that cuts sandstone has a weighted mean age of 339 ± 3 Ma. Based on these zircon ages, we infer that the depositional age of sandstone within the Gorkhi Formation ranges from 320 to 340 Ma (i.e., Early Carboniferous). The provenance and depositional age of the Gorkhi Formation suggest that the evolution of the accretionary complex was influenced by the intrusion and erosion of plutonic rocks during the Early Carboniferous. We also suggest that spatial and temporal changes in the provenance of the accretionary complex in the Khangai–Khentei belt, which developed aound the southern continental margin of the Siberian Craton in relation to island arc activity, were influenced by northward subduction of the Paleo-Asian Ocean plate.  相似文献   

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