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1.
This work reports new hydrochemical data on the two types of cold high p CO2 groundwaters from the Mukhen deposit (Khabarovsk district). The first type is classed with HCO3-Ca-Mg waters with a relatively low TDS (up to 1.7 g/l) and high concentrations of Fe2+, Mn2+, Ba2+, and SiO2. The second type is of HCO3-Na composition with high TDS (up to 14 g/l) and elevated Li+, B, Sr2+, Br?, and I?. New oxygen (δ18O) and hydrogen (δD) isotopic data on the waters and carbon (δ13C) isotopic data on the gas phase, together with a detailed geological and hydrogeological analysis of the study area, allowed us to decipher the origin of both the mineral waters. Based on the tritium content (3H) in the ground and surface waters of the area, the duration of the mineral water circulation was estimated. It was established that the both types of groundwaters were formed during interaction of meteoric water with bedrock under active influence of CO2, however HCO3-Na groundwaters have longer residence time than HCO3-Ca-Mg groundwaters.  相似文献   

2.
With depleted coal resources or deteriorating mining geological conditions, some coal mines have been abandoned in the Fengfeng mining district, China. Water that accumulates in an abandoned underground mine (goaf water) may be a hazard to neighboring mines and impact the groundwater environment. Groundwater samples at three abandoned mines (Yi, Er and Quantou mines) in the Fengfeng mining district and the underlying Ordovician limestone aquifer were collected to characterize their chemical and isotopic compositions and identify the sources of the mine water. The water was HCO3·SO4-Ca·Mg type in Er mine and the auxiliary shaft of Yi mine, and HCO3·SO4-Na type in the main shaft of Quantou mine. The isotopic compositions (δD and δ18O) of water in the three abandoned mines were close to that of Ordovician limestone groundwater. Faults in the abandoned mines were developmental, possibly facilitating inflows of groundwater from the underlying Ordovician limestone aquifers into the coal mines. Although the Sr2+ concentrations differed considerably, the ratios of Sr2+/Ca2+ and 87Sr/86Sr and the 34S content of SO42? were similar for all three mine waters and Ordovician limestone groundwater, indicating that a close hydraulic connection may exist. Geochemical and isotopic indicators suggest that (1) the mine waters may originate mainly from the Ordovician limestone groundwater inflows, and (2) the upward hydraulic gradient in the limestone aquifer may prevent its contamination by the overlying abandoned mine water. The results of this study could be useful for water resources management in this area and other similar mining areas.  相似文献   

3.
Recent (<50 years old) freshwater cyanobacterial carbonates from diverse environments (streams, lakes, waterfalls) throughout Britain and Ireland were analysed for their stable carbon and oxygen isotope compositions. The mean δ18O value of ?5–9‰ PDB for river and stream data represents calcite precipitation in equilibrium with the mean oxygen isotopic composition of precipitation in central Britain (?7–5‰SMOW) assuming a mean water temperature of 9°C. The mean δ18O of lake data, ?4–5‰ PDB, is statistically different, reflecting the effects of residence time and/or variations in the oxygen isotopic composition of rainfall. Carbon isotopes have wide variations in both fluviatile and lake data sets (+ 3 to ?12‰ PDB). These variations are principally controlled in the fluviatile samples by contribution of isotopically light ‘soil zone’ carbon relative to isotopically heavier carbon from limestone aquifer rock dissolution. Lake samples have the heaviest carbon isotope values, reflecting a trend toward isotopic equilibrium between atmospheric CO2 and aqueous HCO?3. We infer that isotopic compositions of ancient cyanobacterial carbonates should also record environmental information, although the effects of stabilization and diagenesis on primary δ18O values will need careful consideration. Primary carbon isotope compositions should be well preserved, although in marine samples values will be buffered by the isotopic composition of aqueous marine bicarbonate.  相似文献   

4.
178 groundwater and surface waters have been sampled from April to September 1994 in an endoreic basin located in the N of Mexico (Comarca Lagunera). In this area, groundwater has been exploited over the past century mainly for irrigation and cattle supply. Recent intensive pumping has caused the lowering of the water table at a rate of 1 m a−1 Chemical analyses have been performed on all collected samples and 37 of them have been selected for isotopic measurements (18O,2H,13C and14C). Water stable isotope contents (18O,2H) show an increasing evaporation of the groundwater towards the Nazas river. They also indicate that the recharge occurs from the Nazas river and from the mountains surrounding the depression (Sierra Madre Occidental). Water presents a large spatial variability of the chemical facies (SO4Ca, SO4ClNa, HCO3-Ca and HCO3-Na) which is in relation with (i) their interaction with the geological formations of the basin (carbonates, gypsum and various silicates) and (ii) evaporation. This evaporation occurs in the upper part of the unsaturated zone during infiltration especially for the groundwater sampled near the Nazas river. The14C activity varies between 110.4 (± 1.1) and 4.0 (±0.2) pmc. The13C contents of the total dissolved inorganic C (TDIC) range between −11.0 and −3.6‰. The calculated13C contents of the CO2 in equilibrium with the TDIC, varying between −18.4%0 to −10.9% indicate two origins of C in solution: the carbonate matrix (δ13C= +0.9‰) and the soil CO2 (δ13C from −27.7‰ to −21.7‰ for the cultivated areas). Mean residence times have been determined after correction of the initial activities for dead C from the rock matrix. The mean residence times confirm a modern recharge of the groundwater from the Nazas and indicate the presence of palaeowaters in the northern and southern parts of the basin (up to 30 ka BP).  相似文献   

5.
We present the chemical and isotope compositions of the water and gas phases of the unique Mukhen cold high-pCO2 spa. Estimated 518O, 5D, and 513Ctic values and data on geology and hydrogeology of the studied area indicate that the source of the groundwaters is meteoric waters, whereas carbon dioxide is of deep genesis and numerous regional faults are gas-feeding channels. Calculations of equilibrium reactions in the water-rock system show that the upper-aquifer waters (HCO3-Ca-Mg) with low TDS are undersaturated with carbonate minerals, montmorillonites, and aluminosilicates but are oversaturated with kaolinite, whereas the lower-aquifer waters (HCO3-Na) with high TDS are oversaturated with calcite, dolomite, and clay minerals but are undersaturated with main aluminosilicates. We propose a new concept of the formation of these groundwaters, demonstrating that long interaction between rocks and groundwaters in the presence of CO2 and considerable precipitation of secondary minerals are responsible for the high TDS of the lower-aquifer waters (up to 14 g/L) and their geochemical type (HCO3-Na) and unusual isotope composition (518O = -25.2%c, 5D = -69.0%c).  相似文献   

6.
This paper reports new geochemical data on the low temperature nitric thermal waters of Sikhote Alin. The studied alkaline waters belong to the HCO3-Na type with significant trace element variations. The waters demonstrate an increase in temperature and TDS from the south northward of Sikhote Alin. The oxygen and hydrogen isotopic data suggest their infiltration origin. The chemical composition of these waters was formed by water-rock interaction.  相似文献   

7.
The present research aims to identify sources of ions and factors controlling the geochemical evolution of groundwater in an intermountain basin, comprising hill and valley fill region, of Outer Himalaya in Himachal Pradesh, India. The groundwater samples collected from 81 tubewells and handpumps are analyzed for major ions, trace metals and stable isotopes (δ18O and δD). Geochemically the dominant hydrochemical facies in the Una basin are Ca–HCO3, Ca–Mg–HCO3 and Na–Cl types at few locations. A relatively lower ionic concentration in the valley fills indicates dilution and low residence time of water to interact with the aquifer mass due to high porosity and permeability. The ionic ratios of 0.9, 0.8 and 3.8 to 5.7, respectively, for (Ca?+?Mg): HCO3, (Ca?+?Mg): (HCO3?+?SO4) and Na: Cl, suggests that ionic composition of groundwater is mainly controlled by rock weathering of, particularly by dissolution/precipitation of calcrete and calcite hosted in rock veins and Ca–Na feldspar hosted in conglomerate deposits derived from the Higher and Lesser Himalaya during the formation of Siwalik rocks. Although Na, K, NO3 and SO4 are introduced in the groundwater through agricultural practices, Na has also been introduced through ion exchange processes that have occurred during water–rock interaction, as indicated by negative CAI values. Factor analysis further suggests three major factors affecting the water chemistry of the area. The first two factors are associated with rock weathering while the third is anthropogenic processes associated with high nitrate and iron concentration. High concentrations of Fe and Mn ions that are exceeded that of WHO and BIS standards are also present at few locations. The recharge of groundwater in the Outer Himalaya is entirely through Indian Southwest Monsoon (ISM) and depleted ratios of δ18O/δD in valley region indicate infiltration from irrigation in recharging the groundwater and fractionation of isotopes of precipitation due to evaporation before infiltration. High d-excess values and inverse relation with δ18O are indicative of secondary evaporation of precipitation during recharge of groundwater.  相似文献   

8.
This paper summarizes a new outlook on the conceptual model of Melgaço–Messegães CO2-rich cold (≈18 °C) mineral water systems, issuing in N of Portugal, based on their isotopic (2H, 3H, 13C, 14C and 18O) and geochemical features. Stable isotopes indicate the meteoric origin of these CO2-rich mineral waters. Based on the isotopic fractionation with the altitude, a recharge altitude between 513 up to 740 m a.s.l. was estimated, corroborating the tritium results. The lowest 3H content (0 TU) is found in the groundwater samples with the highest mineralization. The mineral waters circulation are mainly related to a granitic and granodioritic environment inducing two different groundwater types (Ca/Na–HCO3 and Na/Ca–HCO3), indicating different underground flow paths. Calcium dissolution is controlled by hydrolysis of rock-matrix silicate minerals (e.g. Ca-plagioclases) and not associated to anthropogenic sources. The shallow dilute groundwaters exhibit signatures of anthropogenic origins (e.g. NO3) and higher Na/Ca ratios. The stable isotopes together with the geochemistry provided no indication of mixing between the regional shallow cold dilute groundwater and mineral water systems. The heavy isotopic signatures identified in the δ13C data (δ13C = 4.7 ‰, performed on the total dissolved inorganic carbon (TDIC) of CO2-rich mineral waters) could be derived from a deep-seated (upper mantle) source or associated to methanogenesis (CH4 source). The negligible 14C content (≈2 pmC) determined in the TDIC of the mineral waters, corroborates the hypothesis of a mantle-derived carbon source to the mineral groundwater systems or dissolution of carbonate layers at depth.  相似文献   

9.
The study reported here is a part of an attempt to establish a comprehensive hydrochemical and isotopic baseline for a tropical wetland system as background data for a range of applications. Surface water samples of Vembanad Lake were collected from 20 stations in three seasons during the period 2007–2009. The analytical results were subjected to different chemical classification techniques to understand processes affecting the chemical concentration of waters. The Piper diagram classified the water samples as 100% alkali group in pre-monsoon followed by 15% in monsoon and 85% in post-monsoon, and for anions 100% samples were of strong acids followed by 90% in monsoon and 100% in post-monsoon season. The plot to decipher the mechanism controlling water chemistry placed the Vembanad Lake in the region of precipitation and rock dominance in the monsoon season and in the field of saline water dominance in pre-monsoon and post-monsoon season. The positive values for the chloro-alkaline indices in pre and post-monsoon season promoted cation exchange in the system. The stable isotopes of water samples ranged from ?20.21 to +17.0‰ and ?5.6 to +3.34‰ for δ 2H and δ 18O, respectively. The most depleted δ values observed in the monsoon are due to the amount effect. The high enrichment observed in pre-monsoon is primarily due to evaporation and salinity mixing. The variation of isotopes in the whole system point toward the fact that salinity mixing can be indicated by the δ 18O variation and δ 2H indicates the evaporation effect. The plot of δ 18O with chloride concentration showed precipitation dominance in the monsoon season, mixing of saline water and evaporation in pre-monsoon season, whereas the post-monsoon samples plot in both fresh and saline region.  相似文献   

10.
Hundreds of precipitation samples collected from meteorological stations in the Ordos Basin from January 1988 to December 2005 were used to set up a local meteoric water line and to calculate weighted average isotopic compositions of modern precipitation. Oxygen and hydrogen isotopes, with averages of ?7.8‰ and ?53.0‰ for δ18O and δD, respectively, are depleted in winter and rich in spring, and gradually decrease in summer and fall, illustrating that the seasonal effect is considerable. They also show that the isotopic difference between south portion and north portion of the Ordos Basin are not obvious, and the isotope in the middle portion is normally depleted. The isotope compositions of 32 samples collected from shallow groundwater (less than a depth of 150 m) in desert plateau range from ?10.6‰ to ?6.0‰ with an average of ?8.4‰ for δ18O and from ?85‰ to ?46‰ with an average of ?63‰ for δD. Most of them are identical with modern precipitation. The isotope compositions of 22 middle and deep groundwaters (greater than a depth of 275 m) fall in ranges from ?11.6‰ to ?8.8‰ with an average of ?10.2‰ for δ18O and from ?89‰ to ?63‰ with an average of ?76‰ for δD. The average values are significantly less than those of modern precipitation, illustrating that the middle and deep groundwaters were recharged at comparatively lower air temperatures. Primary analysis of 14C shows that the recharge of the middle and deep groundwaters started at late Pleistocene. The isotopes of 13 lake water samples collected from eight lakes define a local evaporation trend, with a relatively flat slope of 3.77, and show that the lake waters were mainly fed by modern precipitation and shallow groundwater.  相似文献   

11.
Ma  Bin  Liang  Xing  Liu  Shaohua  Jin  Menggui  Nimmo  John R.  Li  Jing 《Hydrogeology Journal》2017,25(3):675-688

Subsurface-water flow pathways in three different land-use areas (non-irrigated grassland, poplar forest, and irrigated arable land) in the central North China Plain were investigated using oxygen (18O) and hydrogen (2H) isotopes in samples of precipitation, soils, and groundwater. Soil water in the top 10 cm was significantly affected by both evaporation and infiltration. Water at 10–40 cm depth in the grassland and arable land, and 10–60 cm in poplar forest, showed a relatively short residence time, as a substantial proportion of antecedent soil water was mixed with a 92-mm storm infiltration event, whereas below those depths (down to 150 cm), depleted δ18O spikes suggested that some storm water bypassed the shallow soil layers. Significant differences, in soil-water content and δ18O values, within a small area, suggested that the proportion of immobile soil water and water flowing in subsurface pathways varies depending on local vegetation cover, soil characteristics and irrigation applications. Soil-water δ18O values revealed that preferential flow and diffuse flow coexist. Preferential flow was active within the root zone, independent of antecedent soil-water content, in both poplar forest and arable land, whereas diffuse flow was observed in grassland. The depleted δ18O spikes at 20–50 cm depth in the arable land suggested the infiltration of irrigation water during the dry season. Temporal isotopic variations in precipitation were subdued in the shallow groundwater, suggesting more complete mixing of different input waters in the unsaturated zone before reaching the shallow groundwater.

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12.
The formation of authigenic Ca-rich rhodochrosite (ACR) in sapropelic sediments of the Gotland Basin, Baltic Sea, is governed by deepwater renewal processes whereby saline water from the North Atlantic flushes the brackish anoxic Baltic Deeps. The carbon and oxygen isotopic compositions of these Mn-carbonates suggest that ACR formation takes place just below the sediment surface and that dissolved compounds from the deepwater column, such as water and bicarbonate molecules, were incorporated in ACR during authigenesis. Porewaters near the sediment surface display δ18O values of −5.4‰ (VSMOW) and are generally depleted in 18O, compared to the oxygen isotopic composition of water in equilibrium with Mn-carbonate solid solutions (ACR δ18O values are −4.6‰). This suggests that early burial diagenetic processes significantly modify the initial isotopic composition of water during Mn-carbonate formation. The reduction of sulfate having δ18O values of +8.4‰ accounts for a permanent enrichment of porewater 18O and observed δ18O values at depth equal to −4.6‰. However, this process does not explain the observed disequilibrium in the oxygen isotopic composition between water and ACR close to the sediment surface where Mn-carbonate formation takes place. Based on isotopic mass balance calculations, we suggest that MnO2 with δ18O values of +8.9‰ released oxygen enriched in 18O into the anoxic porewaters close below the sediment surface. This process should occur after oxygenation events during deepwater renewal when MnO2 accumulates at the surface of anoxic sediments. Manganese carbonates formed in these waters display δ18O values of ∼1.0‰ heavier than values expected solely from the initial deepwater composition. This quantitatively explains the discrepancy between paleosalinities calculated from ACR δ18O based on Mn-carbonate/water isotopic equilibrium fractionation and direct observations for the same period. Our results emphasize the important role of microbial MnO2 reduction during rhodochrosite authigenesis and suggest that Mn(II) activity, rather than alkalinity, is the limiting component for sedimentary Mn-carbonate formation.  相似文献   

13.
In light of recent studies that show oxygen isotope fractionation in carbonate minerals to be a function of HCO3− and CO32− concentrations, the oxygen isotope fractionation and exchange between water and components of the carbonic acid system (HCO3−, CO32−, and CO2(aq)) were investigated at 15°, 25°, and 40°C. To investigate oxygen isotope exchange between HCO3−, CO32−, and H2O, NaHCO3 solutions were prepared and the pH was adjusted over a range of 2 to 12 by the addition of small amounts of HCl or NaOH. After thermal, chemical, and isotopic equilibrium was attained, BaCl2 was added to the NaHCO3 solutions. This resulted in immediate BaCO3 precipitation; thus, recording the isotopic composition of the dissolved inorganic carbon (DIC). Data from experiments at 15°, 25°, and 40°C (1 atm) show that the oxygen isotope fractionation between HCO3− and H2O as a function of temperature is governed by the equation:
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14.
To interpret correctly the isotopic composition of metmorphic rocks and minerals, the effect of nettransfer reactions must be quantitatively evaluated. Such evaluation requires a complete set of linearly independent, net-transfer reactions that fully describe the reacting system. The set of net-transfer reactions is then coupled with mass-balance equations for stable isotopes. Reaction spaces can be contoured with isopleths of °18O, °13C, and D of minerals which allows evaluation of the effect of different reactions and bulk compositions on the stable isotopic composition of minerals and rocks. Using this approach, we examined the effect of fractionation of isotopes due to net-transfer reactions at the biotite and second-sillimanite isograds in northern New England. Our analysis shows that the shift in °13C and °18O at an isograd depends strongly upon the overall net-transfer reaction at the isograd and the bulk composition of the rock. The use of model isograd reactions to determine isotopic shifts, therefore, can lead to serious errors in the interpretation of isotopic data. At the second-sillimanite isograd °18O qtz (quartz), °18O kspar (K feldsdpar), and °18O wr (whole rock) decrease by 0.5, 1.0, and 0.8 per mil, respectively. Quantitative evaluation of the effect of fractionation of isotopes by net-transfer reactions shows that: (1) the relative changes in oxygen isotopes across the isograd could be caused by distillation of fluids during develatilization reactions; (2) the magnitude of the observed isotopic shifts often differs by a factor of 2 from the calculated shifts due to reaction progress alone. The difference between observed and calculated shifts is attributed to either, differences in bulk composition between individual rocks, or, to isotopic exchange between minerals after peak metamorphism. At the biotite isograd the shifts in carbon and oxygen isotope values are different from predicted shifts caused by net-transfer reactions alone. This discrepancy suggests that fluids infiltrated the rocks during the formation of the biotite isograd.  相似文献   

15.
《Applied Geochemistry》1997,12(3):333-343
Deep formation waters were sampled from boreholes on the S-E slopes of the Bohemian Massif. They are NaClHCO3 waters with TDS in the range 6–52 g L−1. Some of them are associated with gas and oil deposits. The waters are rich in Br and I and their δDandδ180 isotope compositions vary from −12 to −77‰ and + 4.6 to −10‰ respectively.The processes of concentration and dilution have been discussed based on deuterium and conservative element contents of the waters. Three regional groups can be identified in the plots Br vs I and Cl vs I: the Vienna Basin samples (VB), southern (S) and northern (N) flanks of the Bohemian Massif (BM). The VB samples have as an end member brackish water with about 7 g L−1 Cl (about 40% marine component) enriched in Br and I. This water has been later diluted by meteoric water of recent isotopic composition. Only 3 VB samples can be considered as derived from the dissolution of evaporites. The salt content of the S and N end members is very close to or higher than sea water with an isotopic composition similar to the brackish water. Subaerial evaporation of diluted sea water is suggested as the process increasing salt content. The evaporative enrichment of primary brackish solution can be estimated from extrapolation of Cl vs I and Br vs I plots to zero I (about 25 mg L−1 Br and 6 g L−1 Cl for the southern flanks of the BM). Evaporated solutions were later diluted by meteoric waters with δD in the range from −50 to −80‰ (southern flanks) and about −80‰ (northern flanks).  相似文献   

16.
Understanding the relationship between stable isotope signals recorded in speleothems (δ13C and δ18O) and the isotopic composition of the carbonate species in the soil water is of great importance for their interpretation in terms of past climate variability. Here the evolution of the carbon isotope composition of soil water on its way down to the cave during dissolution of limestone is studied for both closed and open-closed conditions with respect to CO2.The water entering the cave flows as a thin film towards the drip site. CO2 degasses from this film within approx. 10 s by molecular diffusion. Subsequently, chemical and isotopic equilibrium is established on a time scale of several 10-100 s. The δ13C value of the drip water is mainly determined by the isotopic composition of soil CO2. The evolution of the δ18O value of the carbonate species is determined by the long exchange time Tex, between oxygen in carbonate and water of several 10,000 s. Even if the oxygen of the CO2 in soil water is in isotopic equilibrium with that of the water, dissolution of limestone delivers oxygen with a different isotopic composition changing the δ18O value of the carbonate species. Consequently, the δ18O value of the rainwater will only be reflected in the drip water if it has stayed in the rock for a sufficiently long time.After the water has entered the cave, the carbon and oxygen isotope composition of the drip water may be altered by CO2-exchange with the cave air. Exchange times, , of about 3000 s are derived. Thus, only drip water, which drips in less than 3000 s onto the stalagmite surface, is suitable to imprint climatic signals into speleothem calcite deposited from it.Precipitation of calcite proceeds with time constants, τp, of several 100 s. Different rate constants and equilibrium concentrations for the heavy and light isotopes, respectively, result in isotope fractionation during calcite precipitation. Since Tex ? τp, exchange with the oxygen in the water can be neglected, and the isotopic evolution of carbon and oxygen proceed analogously. For drip intervals Td < 0.1τp the isotopic compositions of both carbon and oxygen in the solution evolve linearly in time. The calcite precipitated at the apex of the stalagmite reflects the isotopic signal of the drip water.For long drip intervals, when calcite is deposited from a stagnant water film, long drip intervals may have a significant effect on the isotopic composition of the DIC. In this case, the isotopic composition of the calcite deposited at the apex must be determined by averaging over the drip interval. Such processes must be considered when speleothems are used as proxies of past climate variability.  相似文献   

17.
Applications of speleothem calcite geochemistry in climate change studies require the evaluation of the accuracy and sensitivity of speleothem proxies to correctly infer paleoclimatic information. The present study of Harrison’s Cave, Barbados, uses the analysis of the modern climatology and groundwater system to evaluate controls on the C and O isotopic composition of modern speleothems. This new approach directly compares the δ18O and δ13C values of modern speleothems with the values for their corresponding drip waters in order to assess the degree to which isotopic equilibrium is achieved during calcite precipitation. If modern speleothems can be demonstrated to precipitate in isotopic equilibrium, then ancient speleothems, suitable for paleoclimatic studies, from the same cave environment may also have been precipitated in isotopic equilibrium. If modern speleothems are precipitated out of isotopic equilibrium, then the magnitude and direction of the C and O isotopic offsets may allow specific kinetic and/or equilibrium isotopic fractionation mechanisms to be identified.Carbon isotope values for the majority of modern speleothem samples from Harrison’s Cave fall within the range of equilibrium values predicted from the combined use of (1) calcite-water fractionation factors from the literature, (2) measured temperatures, and (3) measured δ13C values of the dissolved inorganic carbon of drip waters. Calcite samples range from ∼0.8‰ higher to ∼1.1‰ lower than predicted values. The 13C depletions are likely caused by kinetically driven departures in the fractionation between HCO3− (aq) and CaCO3 from equilibrium conditions, caused by rapid calcite growth. 13C enrichments can be accounted for by Rayleigh distillation of the HCO3− (aq) reservoir during degassing of 13C-depleted CO2.Modern speleothems from Harrison’s Cave are not in O isotopic equilibrium with their corresponding drip waters and are 0.2‰ to 2.3‰ enriched in 18O relative to equilibrium values. δ18O variations in modern calcite are likely controlled by kinetically driven changes in the fractionation between HCO3− (aq) and CaCO3 from equilibrium conditions to nonequilibrium conditions, consistent with rapid calcite growth. In contrast to δ13C, δ18O values of modern calcite may not be affected by Rayleigh distillation during degassing because CO2 hydration and hydroxylation reactions will buffer the O isotopic composition of the HCO3− (aq) reservoir. If the effects of Rayleigh distillation manifest themselves in the O isotopic system, they will result in 18O enrichment in the HCO3− (aq) reservoir and ultimately in the precipitated CaCO3.  相似文献   

18.
It is important to have qualitative as well as quantitative understanding of the hydraulic exchange between lake and groundwater for effective water resource management. Dal, a famous urban fresh water lake, plays a fundamental role in social, cultural and economic dynamics of the Kashmir Valley. In this paper geochemical, isotopic and hydrological mass balance approaches are used to constrain the lake water–groundwater interaction of Dal Lake and to identify the sources of lake water. Water samples of precipitation (n = 27), lake water (n = 18) and groundwater (n = 32) were collected across the lake and its catchment for the analysis of δ18O and δ2H. A total of 444 lake water samples and 440 groundwater samples (springs, tube wells and dug wells) were collected for the analysis of Ca2+, Mg2+, HCO3 ?, SO4 2?, Cl?, NO3 ?, Na+ and K+. Water table and lake water level were monitored at 40 observation locations in the catchment. Water table map including pH and EC values corroborate and verify the gaining nature of the Dal Lake. Stable isotopes of lake water in Boddal and Gagribal basins showed more deviation from the global meteoric water line than Hazratbal and Nigeen basins, indicating the evaporation of lake water. The isotopic and geochemical mass balance suggested that groundwater contributes a significant proportion (23–40%) to Dal Lake. The estimated average groundwater contribution to Dal Lake ranged from 31.2 × 103 to 674 × 103 m3 day?1 with an average of 276 × 103 m3 day?1. The study will be useful to delineate the possible sources of nutrients and pollutants entering the lake and for the management of lake water resources for sustainable development.  相似文献   

19.
Ayadi  Rahma  Trabelsi  Rim  Zouari  Kamel  Saibi  Hakim  Itoi  Ryuichi  Khanfir  Hafedh 《Hydrogeology Journal》2018,26(4):983-1007

Major element concentrations and stable (δ18O and δ2H) and radiogenic (3H and 14C) isotopes in groundwater have proved useful tracers for understanding the geochemical processes that control groundwater mineralization and for identifying recharge sources in the semi-arid region of Sfax (southeastern Tunisia). Major-ion chemical data indicate that the origins of the salinity in the groundwater are the water–rock interactions, mainly the dissolution of evaporitic minerals, as well as the cation exchange with clay minerals. The δ18O and δ2H relationships suggest variations in groundwater recharge mechanisms. Strong evaporation during recharge with limited rapid water infiltration is evident in the groundwater of the intermediate aquifer. The mixing with old groundwater in some areas explains the low stable isotope values of some groundwater samples. Groundwaters from the intermediate aquifer are classified into two main water types: Ca-Na-SO4 and Ca-Na-Cl-SO4. The high nitrate concentrations suggest an anthropogenic source of nitrogen contamination caused by intensive agricultural activities in the area. The stable isotopic signatures reveal three water groups: non-evaporated waters that indicate recharge by recent infiltrated water; evaporated waters that are characterized by relatively enriched δ18O and δ2H contents; and mixed groundwater (old/recent) or ancient groundwater, characterized by their depleted isotopic composition. Tritium data support the existence of recent limited recharge; however, other low tritium values are indicative of pre-nuclear recharge and/or mixing between pre-nuclear and contemporaneous recharge. The carbon-14 activities indicate that the groundwaters were mostly recharged under different climatic conditions during the cooler periods of the late Pleistocene and Holocene.

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20.
The Ganges River water and riverbank shallow groundwater were studied during a single wet season using the hydrochemical and isotopic composition of its dissolved load. The dissolved concentrations of major ions (Cl?, SO4 2?, NO3 ?, HCO3 ?, Ca2+, Na+, Mg2+, and K+), trace elements (barium (Ba) and strontium (Sr)) and stable isotopes (O and D) were determined on samples collected from the Ganges River and its riverbank shallow aquifers. In the present study, the shallow groundwater differs significantly from the Ganges River water; it shows distinct high concentrations of Ca2+, Mg2+, HCO3 ?, Ba, and Sr due to water–rock interaction and this in particular suggests that the Ganges River may not contribute significantly to the riverbank shallow aquifers during wet season. Besides, the sum of the total cationic charge (∑+, in milliequivalents per liter) in the groundwater shows high values (2.48 to 13.91 meq/L, average 9.12 meq/L), which is much higher than the sum of the cations observed in the Ganges water (1.36 to 3.10 meq/L, average 1.94 meq/L). Finally, the more depleted stable isotopic (δ 18O and δ 2H) compositions of the Ganges River water are in contrast to those of the riverbank aquifer having enriched stable isotopic values during the wet season and the riverbank groundwater thus has a purely local origin from precipitation.  相似文献   

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