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1.
Twenty-eight samples of peat, peaty lignites and lignites (of both matrix and xylite-rich lithotypes) and subbituminous coals have been physically activated by pyrolysis. The results show that the surface area of the activated coal samples increases substantially and the higher the carbon content of the samples the higher the surface area.The adsorption capacity of the activated coals for NO, SO2, C3H6 and a mixture of light hydrocarbons (CH4, C2H6, C3H8 and C4H10) at various temperatures was measured on selected samples. The result shows a positive correlation between the surface area and the gas adsorption. In contrast, the gas adsorption is inversely correlated with the temperature. The maximum recorded adsorption values are: NO = 8.22 × 10− 5 mol/g at 35 °C; SO2 = 38.65 × 10− 5 mol/g at 60 °C; C3H6 = 38.9 × 10− 5 mol/g at 35 °C; and light hydrocarbons = 19.24 × 10− 5 mol/g at 35 °C. Adsorption of C3H6 cannot be correlated with either NO or SO2. However, there is a significant positive correlation between NO and SO2 adsorptions. The long chain hydrocarbons are preferentially adsorbed on activated lignites as compared to the short chain hydrocarbons.The results also suggest a positive correlation between surface area and the content of telohuminite maceral sub-group above the level of 45%.  相似文献   

2.
The 1.27 Ga old Ivigtut (Ivittuut) intrusion in South Greenland is world-famous for its hydrothermal cryolite deposit [Na3AlF6] situated within a strongly metasomatised A-type granite stock. This detailed fluid inclusion study characterises the fluid present during the formation of the cryolite deposit and thermodynamic modelling allows to constrain its formation conditions.Microthermometry revealed three different types of inclusions: (1) pure CO2, (2) aqueous-carbonic and (3) saline-aqueous inclusions. Melting temperatures range between − 23 and − 15 °C for type 2 and from − 15 to − 10 °C for type 3 inclusions. Most inclusions homogenise between 110 and 150 °C into the liquid.Stable isotope compositions of CO2 and H2O were measured from crushed inclusions in quartz, cryolite, fluorite and siderite. The δ13C values of about − 5‰ PDB are typical of mantle-derived magmas. The differences between δ18O of CO2 (+ 21 to + 42‰ VSMOW) and δ18O of H2O (− 1 to − 21.7‰ VSMOW) suggest low-temperature isotope exchange. δD (H2O) ranges from − 19 to − 144‰ VSMOW. The isotopic composition of inclusion water closely follows the meteoric water line and is comparable to Canadian Shield brines. Ion chromatography revealed the fluid's predominance in Na, Cl and F. Cl/Br ratios range between 56 and 110 and may imply intensive fluid–rock interaction with the host granite.Isochores deduced from microthermometry in conjunction with estimates for the solidification of the Ivigtut granite suggest a formation pressure of approximately 1–1.5 kbar for the fluid inclusions. Formation temperatures of different types of fluid inclusions vary between 100 and 400 °C. Thermodynamic modelling of phase assemblages and the extraordinary high concentration in F (and Na) may indicate that the cryolite body and its associated fluid inclusions could have formed during the continuous transition from a volatile-rich melt to a solute-rich fluid.  相似文献   

3.
Organic inclusions could be formed at the stages of either primary or secondary migration of hydrocarbons so long as mineral crystallization or recrystallization takes place in the sediments, presenting a direct indicator of oil/gas evolution, migration and abundance. Based on the study of organic inclusions in carbonate-type reservoir beds of commercial importance from North China, Xingjing, North Jiangsu, Jianghan, Sichuan and Guizhou in China, many inclusion parameters for oil/gas potential assessment of carbonate reservoir beds are summarized in this paper, including: 1) Types of organic inclusion: Commercially important oil beds are characterized by inclusions consisting of either pure liquid hydrocarbons or liquid plus minor gaseous hydrocarbons, while commercially important gas reservoirs are characterized by inclusions consisting of either pure gaseous hydrocarbons or gas plus minor liquid hydrocarbons. 2) Quantity of organic inclusions: The number of organic inclusions in commercially important oil/gas reservoirs is over 60% of the total inclusion percentage. 3) Temperature of saline inclusions: The homogenization temperatures of contemporaneous saline inclusions in oil reservoirs range from 91–161 °C, while in gas reservoirs from 150–250 °C). 4) Inclusion composition: In commercially important oil reservoirs, C1/C2=2−10, C1/C3=2−4, C1/C4=2−21, (C2−C4)/(C1−C4)(%)>20, (CH4+CO+H2)/CO2 (molecules/g)=0.5−1.0, and in C2−C3−nC4 triangle diagram there should be an upside-down triangle with the apex within the ellipse, while in commercial gas reservoirs, C1/C2=10−35, C1/C3=14−82, C1/C4=21−200, (C2−C4)/(C1−C4)(%)<20, (CH4+CO+H2)/CO2>1, and there would be an upright triangle with the apex within the ellipse. The above-mentioned parameters have been used to evaluate a number of other unknown wells or regions and the results are very satisfactory. It is valid to use organic inclusions as an indicator to assess the oil/gas potential during oil/gas exploration and prospecting. This approach is effective, economic, rapid, and easy to popularize.  相似文献   

4.
CSA mine exploits a ‘Cobar-type’ Cu–Pb–Zn±Au±Ag deposit within a cleaved and metamorphosed portion of the Cobar Supergroup, central New South Wales. The deposit comprises systems of ‘lenses’ that encompass veins, disseminations and semi-massive to massive Cu–Pb–Zn ores. The systems and contained lenses truncate bedding, are approximately coplanar with regional cleavage and similarly oriented shear zones and plunge parallel to the elongation lineation. Systems have extreme vertical continuity (>1000 m), short strike length (400 m) and narrow width (100 m), exhibit vertical and lateral ore-type variation and have alteration haloes. Models of ore formation include classical hydrothermalism, structurally controlled remobilisation and polymodal concepts; syntectonic emplacement now holds sway.Fluid inclusions were examined from quartz±sulphide veins adjacent to now-extracted ore, from coexisting quartz–sulphide within ore, and from vughs in barren quartz veins. Lack of early primary inclusions precluded direct determination of fluids associated with D2–D3 ore and vein emplacement. Similarly, decrepitation (by near-isobaric heating) of the two oldest secondary populations precluded direct determination of fluid phases immediately following D2–D3 ore and vein emplacement. Post-decrepitation outflow (late D3 to early post-D3) is recorded by monophase CH4 inclusions. Entrained outflow of deeply circulated meteoric fluid modified the CH4 system; modification is recorded by H2O+CH4 and H2O+(trace CH4) secondary populations and by an H2O+(trace CH4) primary population. The contractional tectonics (D2–D3) of ore emplacement was superseded by relaxational tectonics (D4P) that facilitated meteoric water penetration and return flow.Under D2 prograde metamorphism, entrapment temperatures (Tt) and pressures (Pt) for pre-decrepitation secondary inclusions are estimated as Tt300–330 °C and Pt1.5–2 kbar≈Plith (the lithostatic pressure). Decrepitation accompanied peak metamorphism (T350–380 °C) in mid- to late-D3, while in late-D3 to early post-D3, essentially monophase CH4 secondary inclusions were entrapped at Tt350 °C and Pt=1.5–2 kbar≈Plith. Subsequently, abundant CH4 and entrained meteoric water were entrapped as H2O+CH4 secondaries under slowly decreasing temperature (Tt330–350 °C) and constant pressure (Pt1.5–2 kbar). Finally, with increasingly dominant meteoric outflow, H2O+(trace CH4) populations record decreasing temperatures (Tt>300 to <350 down to 275–300 °C) at pressures of Phydrostatic<Pt (1 kbar) <Plith (1.5 kbar).The populations of inclusions provide insight into fluid types, flow regimes and P–T conditions during parts of the deposit's evolution. They indirectly support the role of basin-derived CH4 fluids in ore formation, but provide no insight into a basement-sourced ore-forming fluid. They fully support post-ore involvement of meteoric water. The poorly constrained entrapment history is believed to span 10 Ma from 395 to 385 Ma.  相似文献   

5.
The quartz grains from the sandstone of Jaisalmer, Pariwar and Goru Formations of the Jaisalmer basin, Rajasthan, India, exhibits a variety of primary and secondary fluid inclusions. Most of them are hydrocarbon bearing fluid inclusions. Laser Raman studies indicate that the primary fluid inclusions were mostly having aliphatic hydrocarbons with lower degree of maturity, while the secondary fluid inclusions were generally with aliphatic as well as aromatic hydrocarbons with higher degree of maturity. This inference was consistent with their fluorescence characteristics. The homogenization temperatures of primary monophase CH4 rich fluid inclusions varied from ?80°C to ?100°C, whereas the primary biphase fluid inclusions (CH4-CO2) homogenized between +80°C and +150°C. The secondary petroleum rich monophase fluid inclusions were having homogenization temperature between ?80°C to ?90°C, whereas the secondary biphase fluid inclusions homogenized between +130°C and +180°C. Most of the secondary biphase fluid inclusions were having the mixtures of H2O-CO2-NaCl, and were identified on the basis clathrate formation and they got homogenized between +140°C and + 250 °C. The three past events of migration of petroleum inferred in the host rock which were marked by the presence of characteristic secondary fluid inclusions. They were identified on the basis of cross-cutting relationships of different trails of fluid inclusions in the quartz. The cement generation in the basin might have been occurred in two stages as per the fluid inclusion petrography.  相似文献   

6.
The Changkeng Au and Fuwang Ag deposits represent an economically significant and distinct member of the Au–Ag deposit association in China. The two deposits are immediately adjacent, but the Au and Ag orebodies separated from each other. Ores in the Au deposit, located at the upper stratigraphic section and in the southern parts of the orefield, contain low Ag contents (< 11 ppm); the Ag orebodies, in the lower stratigraphic section, are Au-poor (< 0.2 ppm). Changkeng is hosted in brecciated cherts and jasperoidal quartz and is characterized by disseminated ore minerals. Fuwang, hosted in the Lower Carboniferous Zimenqiao group bioclastic limestone, has vein and veinlet mineralization associated with alteration comprised of quartz, carbonate, sericite, and sulfides. Homogenization temperatures of fluid inclusions from quartz veinlets in the Changkeng and Fuwang deposits are in the range of 210 ± 80 °C and 230 ± 50 °C, respectively. Salinities of fluid inclusions from the two deposits range from 1.6 to 7.3 wt.% and 1.6 to 2.6 wt.% equiv. NaCl, respectively. The δDH2O, δ18OH2O, δ13CCO2 and 3He/4He values of the fluid inclusions from the Changkeng deposit range from − 80‰ to − 30‰, − 7.8‰ to − 3.0‰, − 16.6‰ to − 17.0‰ and 0.0100 to 0.0054 Ra, respectively. The δDH2O, δ18OH2O, δ13CCO2 and 3He/4He values of fluid inclusions from the Fuwang deposit range from − 59‰ to − 45‰, − 0.9‰ to 4.1‰, − 6.7‰ to − 0.6‰ and 0.5930 to 0.8357 Ra, respectively. The δDH2O, δ18OH2O, δ13CCO2 and 3He/4He values of the fluid inclusions suggest the ore fluids of the Changkeng Au-ore come from the meteoric water and the ore fluids of the Fuwang Ag-ore are derived from mixing of magmatic water and meteoric water. The two deposits also show different Pb-isotopic signatures. The Changkeng deposit has Pb isotope ratios (206Pb/204Pb: 18.580 to 19.251, 207Pb/204Pb: 15.672 to 15.801, 208Pb/204Pb: 38.700 to 39.104) similar to those (206Pb/204Pb: 18.578 to 19.433, 207Pb/204Pb: 15.640 to 15.775, 208Pb/204Pb: 38.925 to 39.920) of its host rocks and different from those (206Pb/204Pb: 18.820 to 18.891, 207Pb/204Pb: 15.848 to 15.914, 208Pb/204Pb: 39.579 to 39.786) of the Fuwang deposit. The different signatures indicate different sources of ore-forming material. Rb–Sr isochron age (68 ± 6 Ma) and 40Ar–39Ar age (64.3 ± 0.1 Ma) of the ore-related quartz veins from the Ag deposit indicate that the Fuwang deposit formed during the Cenozoic Himalayan tectonomagmatic event. Crosscutting relationships suggests that Au-ore predates Ag-ore. The adjacent Changkeng and Fuwang deposits could, however, represent a single evolved hydrothermal system. The ore fluids initially deposited Au in the brecciated siliceous rocks, and then mixing with the magmatic water resulted in Ag deposition within fracture zones in the limestone. The deposits are alternatively the product of the superposition of two different geological events. Age evidence for the Fuwang deposit, together with the Xiqiaoshan Tertiary volcanic-hosted Ag deposit in the same area, indicates that the Pacific Coastal Volcanic Belt in the South China Fold Belt has greater potential for Himalayan precious metal mineralization than previous realized.  相似文献   

7.
The barium deposits in Ankang and Xunyang counties,Shaanxi Province,China,occur in the northernmost part of the world-class barium metallogenic belt in south Qinling.The deposits are hosted by the Lower Silurian carbonaceous siliceous rocks,with a unique combination of barite and witherite.The homogenization temperatures of fluid inclusions in the barite are mainly concentrated between 135 and 155 ℃,whereas those from the witherite have two peaks of 165-175 ℃,and 215-225℃,respectively.Laser Raman analysis of fluid inclusions indicates that the vapor phase of fluid inclusions in barite is dominated by H_2O,although some contains N_2,H_2S,and CH_4.The compositions of the vapor and liquid phases of fluid inclusions in witherite can be divided into two end-members,one dominated by H_2O without other volatiles,and the other containing CH_4,C_2H_6,C_3H_8,C_2H_4,and C_6H_6 in addition to H_2O.CO_2,H_2S,and some CH_4 are interpreted as products of chemical reactions during mineralization.Organic gases(CH_4,C_2H_6,C_3H_8,C_2H_4,and C_6H_6) in the fluids were critical in the formation of barium sulfate versus carbonate.The δ~(34)S values of barite range from 38.26‰ to54.23‰(CDT),the δ~(34)S values of sulfides coexisting with barium minerals vary from 22.44‰ to25.11‰(CDT),and those in the wall rock from 11.60‰ to 19.06‰(CDT).We propose that the SO_4~(2-)generally experienced bacterial sulfate reduction in seawater before mineralization,and some SO_4~(2-)also experienced thermochemical sulfate reduction in hydrothermal system during mineralization.The δ~(13)C values of witherite range from-27.30‰ to-11.80‰(PDB),suggesting that carbon was sourced from organic substances(like CH_4,C_2H_4,and C_2H_6).The formation of witherite was possibly associated with thermochemical sulfate reduction,which caused the consumption of the organic gases and SO_4~(2-) in the hydrothermal solutions,consequently inhibiting barite formation.The important conditions for forming witherite include high fluid temperatures,high Ba~(2+) concentrations,CO_2 in the fluids,low HS~- concentrations,and the subsequent rapid diffusion of H_2S during thermochemical sulfate reduction of the fluids.  相似文献   

8.
The calcite cement in the Lower Ordovician Majiagou Formation in the Ordos basin in northern China can be subdivided into three groups based on preliminary results of oxygen and carbon isotopes and fluid inclusion microthermometry. Group 1 has low oxygen isotopes (− 14‰ to − 18‰), low Th values (92–103 °C), and low salinities (1.7–4.9 wt.% NaCl equivalent) and is interpreted to have precipitated during early burial from porewater influenced by meteoric water. Group 2 has much higher oxygen isotope values (− 5‰ to − 8‰), which, coupled with the higher Th values (136–151 °C), suggest that the calcite was precipitated from fluids that were significantly enriched in 18O, possibly resulting from fluid–rock reaction during burial. Group 3 occurring along fractures is characterized by high salinities (21–28 wt.% NaCl equivalent) and is interpreted to have been precipitated from locally preserved residual evaporitic brines. The occurrence of primary hydrocarbon inclusions and its low carbon isotopes (− 11‰ to − 15‰) suggest that precipitation of group 3 calcite took place in the presence of hydrocarbons.  相似文献   

9.
We report fluid inclusion data for skarn, formed at the contact between Hercynian granitoids and dolomite of the Proterozoic Bayan Obo Group, in the vicinity of Bayan Obo REE–Nb–Fe deposit, Inner Mongolia, China. Three types of fluid inclusions are identified: two-phase CH4-rich, three-phase liquid–vapour–solid and two-phase aqueous inclusions. Using microthermometry and laser Raman microprobe analysis to calculate isochores for CH4-bearing inclusions, we estimate fluid trapping conditions at T=280 to 344 °C and P<1 to 2.3 kbar. Such conditions are compatible with formation of CH4 inclusions as a result of reaction between graphite in the country rocks (black slate sequence) and fluids derived from magma. The lack of carbonaceous material in the inclusions supports the hypothesis that CH4 was generated during fluid migration rather than by in situ reaction. In contrast to the skarn, and despite the fact that similar graphite-bearing slates are found in the host rocks, no CH4-bearing inclusions have been so far reported from Bayan Obo REE ores. We therefore conclude that the skarn-forming fluids in the contact aureole of the Hercynian granitoids were not involved at any stage in the formation of the Bayan Obo deposit.  相似文献   

10.
The relative chronology and detailed chemistry of paleofluids circulating at the base of the Kombolgie Sub-basin were investigated in the East Alligator River district (Northern Territory, Australia), where world-class unconformity-type uranium deposits are located. The chemistry of fluid inclusions was determined using in-situ analysis (Raman microprobe and laser-induced breakdown spectroscopy [LIBS]) and by observing the melting sequences by microthermometry. This study revealed the occurrence of three distinct fluids: (i) a sodium-rich brine that corresponds to a diagenetic fluid percolating at the bottom of the Kombolgie sandstones at a temperature close to 150±15 °C; (ii) a calcium-rich brine, probably corresponding to a residual brine in evaporitic environment that has evolved by fluid–rock interactions with the basement lithologies; and (iii) a low salinity fluid, heated in the basement, injected into the base of the sandstone cover. H2 and O2 and/or traces of CH4 were detected in the vapor phase of some fluid inclusions, especially in the low salinity ones in quartz breccia samples taken above mineralized areas. Hydraulic brecciation of the sandstone was associated with a pressure decrease favoring fluid mixing and the subsequent cementation of breccias. According to the fluid inclusion study and other geologic constrains, the minimum thickness of the Sub-Kombolgie Basin is estimated at 4 km. Drusy quartz breccias with evidence of fluid mixing are quite common at the base of the Kombolgie Basin, but not necessarily linked to U-mineralization. However, it is proposed that the presence of gases such as H2 and O2 in fluid inclusions, which results from water radiolysis, constitutes an indicator of gas linked to significant U concentrations deeper in the basement rocks.  相似文献   

11.
Fluid inclusion microthermometry and structural data are presented for quartz vein systems of a major dextral transcurrent shear zone of Neoproterozoic–Cambrian age in the Ribeira River Valley area, southeastern Brazil. Geometric and microstructural constraints indicate that foliation–parallel and extensional veins were formed during dextral strike–slip faulting. Both vein systems are formed essentially by quartz and lesser contents of sulfides and carbonates, and were crystallized in the presence of CO2–CH4 and H2O–CO2–CH4–NaCl immiscible fluids following unmixing from a homogeneous parental fluid. Contrasting fluid entrapment conditions indicate that the two vein systems were formed in different structural levels. Foliation–parallel veins were precipitated beneath the seismogenic zone under pressure fluctuating from moderately sublithostatic to moderately subhydrostatic values (319–397 °C and 47–215 MPa), which is compatible with predicted fluid pressure cycle curves derived from fault–valve action. Growth of extensional veins occurred in shallower structural levels, under pressure fluctuating from near hydrostatic to moderately subhydrostatic values (207–218 °C and 18–74 MPa), which indicate that precipitation occurred within the near surface hydrostatically pressured seismogenic zone. Fluid immiscibility and precipitation of quartz in foliation–parallel veins resulted from fluid pressure drop immediately after earthquake rupture. Fluid immiscibility following a local pressure drop during extensional veining occurred in pre-seismic stages in response to the development of fracture porosity in the dilatant zone. Late stages of fluid circulation within the fault zone are represented dominantly by low to high salinity (0.2 to 44 wt.% equivalent NaCl) H2O–NaCl–CaCl2 fluid inclusions trapped in healed fractures mainly in foliation–parallel veins, which also exhibit subordinate H2O–NaCl–CaCl2, CO2–(CH4) and H2O–CO2–(CH4)–NaCl fluid inclusions trapped under subsolvus conditions in single healed microcracks. Recurrent circulation of aqueous–carbonic fluids and aqueous fluids of highly contrasting salinities during veining and post-veining stages suggests that fluids of different reservoirs were pumped to the ruptured fault zone during faulting episodes. A fluid evolution trending toward CH4 depletion for CO2–CH4–bearing fluids and salinity depletion and dilution (approximation of the system H2O–NaCl) for aqueous–saline fluids occurred concomitantly with decrease in temperature and pressure related to fluid entrapment in progressively shallower structural levels reflecting the shear zone exhumation history.  相似文献   

12.
The small Pirilä gold deposit, which is located in the southeastern part of the Svecofennian complex near the Archean/Proterozoic boundary, is hosted by quartz veins and lenses occurring in mica schist. The rocks of the area were metamorphosed under conditions of amphibolite facies. Gold is invariably associated with sulphides. Microthermometry of fluid inclusions in quartz indicates four types of inclusions: (1) weakly saline H2O-CO2 (< 4.0 eq.wt% NaCl) with small amounts of CH4 (< 10 mole% CH4); (2) CO2 (< 10 mole% CH4); (3) CH4; and (4) H2O (< 25 eq.wt% NaCl) with less than 0.85 mole% CO2 in the vapour phase. Texturally these inclusion types are classified as primary (H2O-CO2) and secondary (H2O, CO2 and CH4). Leachate analysis shows that, in addition to Na, the aqueous fluids contain Ca and Fe with minor amounts of K and Mg. The primary H2O-CO2 and the secondary H2O inclusions contain sulphide and unidentified opaque grains, respectively. The secondary CH4 inclusions are often associated with short trails of arsenopyrite grains. Fluid inclusion and geological data suggest ore mineral mobilization, crystallization of host quartz, and deposition of sulphides controlled by the D2 and D3 structures in the presence of a H2O-CO2 fluid mainly during the plastic D3 deformation and during the amphibolite facies metamorphism (i.e. 3.4 kbars/540–670°C). During ductile-brittle deformation (probably D4), precipitation of tectonic remobilized gold from sulphides in fractures occurred in the presence of CH4 and H2O fluids at lowered temperature (< 440°C) and pressure (< 2 kbars).  相似文献   

13.
The Daenam mine, which produced over 9250 tons of iron oxide ore from 1958 to 1962, is situated in the Early Cretaceous Yeongyang subbasin of the Gyeongsang basin. It consists of two lens-shaped, hematite-bearing quartz veins that occur along faults in Cretaceous leucocratic granite. The hematite-bearing quartz veins are mainly composed of massive and euhedral quartz and hematite with minor amounts of pyrite, pyrrhotite, mica, feldspar and chlorite.Fluid inclusions in quartz can be divided into three main types: CO2-rich, CO2–H2O, and H2O-rich. Hydrothermal fluids related to the formation of hematite are composed of either H2O–CO2–NaCl ± CH4 (homogenization temperature: 262–455 °C, salinity <7 eq. wt.% NaCl) or H2O–NaCl (homogenization temperature: 182–266 °C, and salinity <5.1 eq. wt.% NaCl), both of which evolved by mixing with deeply circulating meteoric water. Hematite from the quartz veins in the Daenam mine was mainly deposited by unmixing of H2O–CO2–NaCl ± CH4 fluids with loss of the CO2 + CH4 vapor phase and mixing with downward percolating meteoric water providing oxidizing conditions.  相似文献   

14.
Fluid inclusions in quartz globules and quartz veins of a 3.8-3.7 Ga old, well-preserved pillow lava breccia in the northeastern Isua Greenstone Belt (IGB) were studied using microthermometry, Raman spectrometry and SEM Cathodoluminescence Imaging. Petrographic study of the different quartz segregations showed that they were affected by variable recrystallization which controlled their fluid inclusion content. The oldest unaltered fluid inclusions found are present in vein crystals that survived dynamic and static recrystallization. These crystals contain a cogenetic, immiscible assemblage of CO2-rich (+H2O, +graphite) and brine-rich (+CO2, +halite, +carbonate) inclusions. The gas-rich inclusions have molar volumes between 44.8 and 47.5 cm3/mol, while the brine inclusions have a salinity of ∼33 eq. wt% NaCl. Modeling equilibrium immiscibility using volumetric and compositional properties of the endmember fluids indicates that fluid unmixing occurred at or near peak-metamorphic conditions of ∼460 °C and ∼4 kbar. Carbonate and graphite were precipitated cogenetically from the physically separated endmember fluids and were trapped in fluid inclusions.In most quartz crystals, however, recrystallization obliterated such early fluid inclusion assemblages and left graphite and carbonate as solid inclusions in recrystallized grains. Intragranular fluid inclusion trails in the recrystallized grains of breccia cementing and crosscutting quartz veins have CO2-rich assemblages, with distinctly different molar volumes (either between 43.7 and 47.5 cm3/mol or between 53.5 and 74.1 cm3/mol), and immiscible, halite-saturated H2O-CO2-NaCl(-other salt) inclusions. Later intergranular trails have CH4-H2 (XH2 up to ∼0.3) inclusions of variable density (ranging from 48.0 to >105.3 cm3/mol) and metastable H2O-NaCl(-other salt?) brines (∼28 eq. wt% NaCl). Finally, the youngest fluid inclusion assemblages are found in non-luminescent secondary quartz and contain low-density CH4 (molar volume > 105.33 cm3/mol) and low-salinity H2O-NaCl (0.2-3.7 eq. wt% NaCl). These successive fluid inclusion assemblages record a retrograde P-T evolution close to a geothermal gradient of ∼30 °C/km, but also indicate fluid pressure variations and the introduction of highly reducing fluids at ∼200-300 °C and 0.5-2 kbar. The quartz globules in the pillow fragments only contain sporadic CH4(+H2) and brine inclusions, corresponding with the late generations present in the cementing and crosscutting veins. We argue that due to the large extent of static recrystallization in quartz globules in the pillow breccia fragments, only these relatively late fluid inclusions have been preserved, and that they do not represent remnants of an early, seafloor-hydrothermal system as was previously proposed.Modeling the oxidation state of the fluids indicates a rock buffered system at peak-metamorphic conditions, but suggests a change towards fluid-graphite disequilibrium and a logfH2/fH2O above the Quartz-Fayalite-Magnetite buffer during retrograde evolution. Most likely, this indicates a control on redox conditions and on fluid speciation by ultramafic rocks in the IGB.Finally, this study shows that microscopic solid graphite in recrystallized metamorphic rocks from Isua can be deposited inorganically from a fluid phase, adding to the complexity of processes that formed reduced carbon in the oldest, well-preserved supracrustal rocks on Earth.  相似文献   

15.
The pressure-volume-temperature-composition (PVTX) properties of H2O-CH4 were determined from the bubble point curve to 500 °C and 3 kbar for compositions ?4 mol.% CH4 using the synthetic fluid inclusion technique. H2O-CH4 inclusions were produced by loading known amounts of Al3C4 and H2O into platinum capsules along with pre-fractured and inclusion-free quartz cores. During heating the Al3C4 and H2O react to produce CH4, and the H2O-CH4 homogeneous mixture was trapped as inclusions during fracture healing at elevated temperature and pressure. The composition of the fluid in the inclusion was confirmed using the weight loss technique after the experiment and by Raman spectroscopic analysis of the inclusions.Homogenization temperatures of the inclusions were determined and the results were used to construct iso-Th lines, defined as a line connecting the formation temperature and pressure with the homogenization temperature and pressure. The pressure in the inclusion at the homogenization temperature was calculated from the Duan equation of state (EOS). The slope (ΔP/ΔT) of each iso-Th line was calculated and the results fitted to a polynomial equation using step-wise multiple regression analysis to estimate the slope of the iso-Th line as a function of the homogenization temperature and composition according to:
(ΔP/ΔT)=a+b·m+c·m4+d·(Th)2+e·m·Th+f·m·(Th)4,  相似文献   

16.
Fluid inclusions in mineralized graphite-sillimanite-mica schist from the Rampura-Agucha Pb-Zn-(Ag) deposit, Rajasthan, northwest India, have been investigated by microthermometry and Raman microspectrometry. Three different main types of fluid inclusions in quartz can be distinguished: (1) gaseous (CO2, partially mixed with CH4-N2), (2) low salinity aqueous inclusions (0–8 eq. wt% NaCl) and (3) high salinity aqueous inclusions (NaCl ± MgCl2-CaCl2). Low density CO2-rich and low salinity H2O inclusions are contemporaneous and occur, together with CH4-N2 inclusions, in close association with sulfide mineral inclusions. This indicates immiscibility between the gaseous and aqueous phase and participation of these fluids during the deposition or remobilization of the ore, which occurred over a wide P (1220 to 200 bar) and T (450 to 250 °C). Raman spectra of graphite indicate upper greenschist-facies metamorphic conditions, although host rocks have been metamorphosed at upper amphibolite-facies metamorphic conditions. This indicates that graphite re-equilibrated with the CO2-rich phase during retrograde metamorphism.  相似文献   

17.
Petroleum and aqueous fluid inclusions from the Encantada–Buenavista fluorite mineralized zone in northern Mexico were analyzed by microthermometry, UV fluorescence, Raman Spectroscopy, Fourier Transform Infrared Spectroscopy (FTIR) and Confocal Scanning Laser Microscopy (CSLM) to evaluate the geochemical evolution of the mineralizing fluids. Two-phase (petroleum or brine+vapor) and three-phase (petroleum+brine+vapor) inclusions are described. Aqueous and petroleum-rich inclusions commonly occur in the same plane. Vapor-decrepitated and stretched fluid inclusions are present. A low-salinity methane-saturated fluid and a high salinity-fluid with highly variable methane contents are recognized. H2S is not quantified but is always detected in close association with methane. Petroleum inclusions are of two types: a low methane petroleum fluid (20 mol%) with low Th (60 °C) and a petroleum fluid with a methane of content near 30 mol% and a Th of 90 °C.Pressure and temperature diagrams for the aqueous and petroleum inclusions show three main intersects that allow P–T–X reconstruction of fluid evolution at La Encantada–Buenavista. A CH4- and H2S-rich low-salinity brine was mixed with oil that migrated under hydrostatic conditions with a thermal gradient of 70 °C/km. The arrival and mixing of a high-salinity aqueous fluid produced overpressure to 300 bars. A return to hydrostatic conditions was accompanied by an increase in the thermal gradient.The brine related to the fluorite orebodies appears to have a genetic relationship with the brines reported from the Jurassic petroleum basins located west of the fluorite bodies and similarities with reported fluids from Mississippi Valley type deposits. It is interpreted that the fluorine-rich fluids migrated toward the platform margins during the mid-Tertiary (30 to 32 Ma) using extension zones related to Basin and Range tectonism. Mixing of two different brines was responsible for precipitation and mineralization. Heat from magmas, related to tectonic extension, caused decrepitation and changes in the shape of fluid inclusions near the contact zones.  相似文献   

18.
The Junction gold deposit, in Western Australia, is an orogenic gold deposit hosted by a differentiated, iron‐rich, tholeiitic dolerite sill. Petrographic, microthermometric and laser Raman microprobe analyses of fluid inclusions from the Junction deposit indicate that three different vein systems formed at three distinct periods of geological time, and host four fluid‐inclusion populations with a wide range of compositions in the H2O–CO2–CH4–NaCl ± CaCl2 system. Pre‐shearing, pre‐gold, molybdenite‐bearing quartz veins host fluid inclusions that are characterised by relatively consistent phase ratios comprising H2O–CO2–CH4 ± halite. Microthermometry suggests that these veins precipitated when a highly saline, >340°C fluid mixed with a less saline ≥150°C fluid. The syn‐gold mineralisation event is hosted within the Junction shear zone and is associated with extensive quartz‐calcite ± albite ± chlorite ± pyrrhotite veining. Fluid‐inclusion analyses indicate that gold deposition occurred during the unmixing of a 400°C, moderately saline, H2O–CO2 ± CH4 fluid at pressures between 70 MPa and 440 MPa. Post‐gold quartz‐calcite‐biotite‐pyrrhotite veins occupy normal fault sets that slightly offset the Junction shear zone. Fluid inclusions in these veins are predominantly vapour rich, with CO2?CH4. Homogenisation temperatures indicate that the post‐gold quartz veins precipitated from a 310 ± 30°C fluid. Finally, late secondary fluid inclusions show that a <200°C, highly saline, H2O–CaCl2–NaCl–bearing fluid percolated along microfractures late in the deposit's history, but did not form any notable vein type. Raman spectroscopy supports the microthermometric data and reveals that CH4–bearing fluid inclusions occur in syn‐gold quartz grains found almost exclusively at the vein margin, whereas CO2–bearing fluid inclusions occur in quartz grains that are found toward the centre of the veins. The zonation of CO2:CH4 ratios, with respect to the location of fluid inclusions within the syn‐gold quartz veins, suggest that the CH4 did not travel as part of the auriferous fluid. Fluid unmixing and post‐entrapment alteration of the syn‐gold fluid inclusions are known to have occurred, but cannot adequately account for the relatively ordered zonation of CO2:CH4 ratios. Instead, the late introduction of a CH4–rich fluid into the Junction shear zone appears more likely. Alternatively, the process of CO2 reduction to CH4 is a viable and plausible explanation that fits the available data. The CH4–bearing fluid inclusions occur almost exclusively at the margin of the syn‐gold quartz veins within the zone of high‐grade gold mineralisation because this is where all the criteria needed to reduce CO2 to CH4 were satisfied in the Junction deposit.  相似文献   

19.
The composition and potential diamond productivity of C–O–H fluids that could exist in the reduced regions of the Earth’s upper mantle and in the mantles of Uranus and Neptune were studied in experiments at 6.3 GPa and 1400–1600 °C and durations of 15–48 h. Hydrogen fugacity in the fluid phase was controlled by the Mo–MoO2 or Fe–FeO buffers, using a specially modified double-capsule method. The oxygen fugacity in the samples was controlled by adding different amounts of water, stearic acid, anthracene, and docosane to a graphite charge. At high P–T conditions, the degree of decomposition of the heavy hydrocarbons added to the charge was 99.9%. The composition of the fluids coexisting with graphite/diamond in the buffered experiments varied from H2O  H2 > CH4 (at fO2 somewhat lower than the “water maximum”) to H2 > CH4 > (C2H4 + C2H6)>C3H8 (in C–H system). In the C–H system the maximum concentrations of major species in the synthesized fluid were: H2 = 79 mol.% and CH4 = 21 mol.%. The composition of the H2-rich fluids, which were synthesized at 6.3 GPa and 1400–1600 °C for the first time, differs considerably from that of the ultra-reduced CH4-rich fluids stable at 2.0–3.5 GPa and 1000–1300 °C. Thermodynamic calculations of the reduced C–O–H fluids at the P–T conditions of the experiments revealed CH4-rich compositions (CH4  H2 > (C2H4 + C2H6)>C3H8), which however drastically differed from the synthesized compositions. The rates of diamond nucleation and growth in the experiments depended on the fluid composition. Diamond crystallization had a maximum intensity in the pure aqueous fluids, while in the H2-rich fluids no diamond formation was observed. Only metastable graphite precipitated from the ultra-reduced fluids. The type of the initial hydrocarbon used for the fluid generation did not affect this process.  相似文献   

20.
 Incorporation of hydrocarbons (CH4, C2H6, C3H8, C4H10) in cordierite channels was experimentally studied at 700 °C and at pressures from 200 to 1000 MPa, (avoiding recrystallization). The maximum concentrations of hydrocarbons determined by gas chromatographic analysis are CH4=78.3, C2H6=134, C2H4 + C2H6=26, C3H8=28, C4H10=32, C5H12=23, and C6H14=7 × 10−3 wt%). According to IR spectroscopy data, the channel forms of hydrocarbons differ from the forms on the surface. As a result of interactions with the framework oxygen, normal hydrocarbons are converted to saturated oligomers and their fragments. Small amounts of water molecules of the first and second types (up to 0.3 wt%) are formed in the same way. As pressure grows from 200 to 1000 MPa, the total content of structural hydrocarbons is nearly doubled. Special runs on cordierite saturation in mixtures of hydrocarbons with water showed that low contents of hydrocarbons in natural cordierites correspond to their large concentrations in fluid. Received: 7 May 2001 / Accepted: 17 July 2001  相似文献   

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