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1.
卫河是海河流域污染最严重的河流之一,该河如何影响附近浅层地下水的水质是长期受到重视但缺乏定量研究的关键问题。为探讨这一问题,利用Hydrus 2d模型模拟河流非饱和带氮素的迁移转化,以GMS软件中的RT3D模块模拟氮素在饱和含水层中的运移,将包气带底部淋滤出的污染物浓度定为饱和带溶质运移模型的上边界条件,首次实现了河流非饱和带饱和含水层氮素运移的联合模拟,得到河流线状污染源对浅层地下水的影响程度及范围。研究结果表明：由于吸附作用、硝化反硝化作用的存在,从河流上游到下游,包气带厚度加大,运移至含水层中的NH4-N、NO2-N浓度呈下降趋势,而NO3-N浓度则呈上升趋势。随着入渗时间的增长,进入饱和含水层中的NH4-N、NO2-N、NO3-N的浓度逐渐升高并最终保持稳定。污染的河流对浅层地下水的影响呈带状分布,污染物随入渗水流在包气带中垂直入渗;在饱和含水层中以水平运移为主,污染羽偏向地下水流动的方向,其影响距离不超过500 m。 相似文献
2.
3.
The present research aims to derive the intrinsic vulnerability of groundwater against contamination using the GIS platform. The study applies DRASTIC model for Ahmedabad district in Gujarat, India. The model uses parameters like depth, recharge, aquifer, soil, topography, vadose zone and hydraulic conductivity, which depict the hydrogeology of the area. The research demonstrates that northern part of district with 46.4% of area is under low vulnerability, the central and southern parts with 48.4% of the area are under moderate vulnerability, while 5.2% of area in the south-east of district is under high vulnerability. It is observed from the study that lower vulnerability in northern part may be mostly due to the greater depth of vadose zone, deeper water tables and alluvial aquifer system with minor clay lenses. The moderate and high vulnerability in central and southern parts of study area may be due to lesser depth to water tables, smaller vadose zone depths, unconfined to semi-confined alluvial aquifer system and greater amount of recharge due to irrigation practices. Further, the map removal and single-parameter sensitivity analysis indicate that groundwater vulnerability index has higher influence of vadose zone, recharge, depth and aquifer parameters for the given study area. The research also contributes to validating the existence of higher concentrations of contaminants/indicators like electrical conductivity, chloride, total dissolved solids, sulphate, nitrate, calcium, sodium and magnesium with respect to groundwater vulnerability status in the study area. The contaminants/indicators exceeding the prescribed limits for drinking water as per Indian Standard 10500 (1991) were mostly found in areas under moderate and high vulnerability. Finally, the research successfully delineates the groundwater vulnerability in the region which can aid land-use policies and norms for activities related to recharge and seepage with respect to existing status of groundwater vulnerability and its quality. 相似文献
4.
Tiziana Di Lorenzo Mauro Brilli Dina Del Tosto Diana M. P. Galassi Marco Petitta 《Environmental Earth Sciences》2012,67(8):2383-2398
The aim of this study is to apply an integrated approach to determine nitrate sources and fate in the alluvial aquifer of the River Vibrata (Abruzzi, central Italy) by coupling the Isotope and the Component approaches. Collected data include concentration and nitrogen isotope composition of groundwater samples from the alluvial aquifer and nitrogen loads arising from agricultural and non-agricultural sources. The adopted methodology identified synthetic fertilizers as main sources of nitrate in the Vibrata alluvial aquifer. At the catchment scale, two different zones have been identified: the Upper Valley, where infiltration to groundwater is dominant and nitrogen easily migrates into the aquifer; in this area, nitrate content in groundwater is stable and normally higher than EU requirements. Moreover, streamwaters are fed by groundwater with a nitrate content likely lowered by denitrification processes occurring in the hyporheic zone. In the Lower Valley, runoff processes dominate and the nitrate content in surface waters is higher. Nevertheless, groundwater is locally affected by denitrification that breaks down the nitrate content, which often reaches values consistent with law limits. 相似文献
5.
受气候变化和人类活动等因素的综合影响,地下水超采和含水层水量亏空已成为备受关注的全球性问题。为了弥补含水层水量亏空和促进地下水资源涵养,已探索出多种人为干预地下水补给的措施,其中通过河道开展地下水人工补给由于具有明显优势而受到重视。已有实践表明,受渗漏补给潜力和包气带调蓄能力等的限制,并不是所有河流或河段都适宜开展地下水人工补给工作。目前缺乏为大家广泛接受的适宜性评估方法。本研究以永定河生态补水为契机,以北京平原段河道和下伏含水层为研究区开展了案例研究,并用实测数据对研究结果进行了检验。应用指标体系法建立的适宜性评估模型（LMBGITSC模型）包括河床土地利用类型、河床介质类型、河床宽度、河床地形坡度、包气带介质类型、包气带厚度、包气带给水度、包气带水平渗透性等8个指标。案例研究结果表明,沿河流流向,通过河道渗漏补给地下水的适宜性由好变差（防渗河段除外）。该规律主要受渗漏补给潜力和包气带调蓄能力控制,因此适宜性也呈现出“阶梯式”演变规律。检验结果表明所建的评估方法适用性较好。该方法具有可移植性,因此也可为其他同类地区提供参考。 相似文献
6.
地下水防污性能评价方法探讨 总被引：52，自引：0，他引：52
地下水防污性能评价是环境规划和决策的有用工具,国外已有许多研究,也提出了各种计算防污性能指数模型。文中着重介绍使用最广泛的DRASTIC模型,并指出其不足之处。根据中国情况,提出用DRTA模型评价潜水的防污性能,用DLCT模型评价承压含水层的防污性能。DRTA模型包含有地下水埋深、包气带评分介质、包气带评分介质的厚度和含水层厚度4 个因子;DLCT模型包含有承压含水层埋深、隔水层岩性、隔水层的连续性和隔水层厚度4个因子。 相似文献
7.
Non-point pollution of groundwater from agricultural activities in Mediterranean Spain: the Balearic Islands case study 总被引：3，自引：0，他引：3
Mediterranean Spain is a region with intensive agricultural production combined with an important seasonal water demand for
water supply. High application rates of inorganic nitrogen fertiliser, input of plant protection products and intensive irrigation,
sometimes with treated wastewater, is a common practice. As a result, most aquifers show nitrate contamination problems of
agricultural origin. Data on pesticide residues is scarce, as systematic monitoring is not currently done. In Majorca Island,
values up to 700 mg/l of nitrate in groundwater have been observed. To analyse the current situation derived from non-point
pollution, several actions have been taken at different scales: declaration of a nitrate vulnerable zone, field experiments
to evaluate nitrogen transport to the aquifer and the development of a GIS-simulation model to generate nitrate risk maps. 相似文献
8.
Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA 总被引：1，自引：0，他引：1
Joseph L. Domagalski Steven P. Phillips E. Randall Bayless Celia Zamora Carol Kendall Richard A. WildmanJr Janet G. Hering 《Hydrogeology Journal》2008,16(4):675-690
Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N2 in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area. 相似文献
9.
Gernot Klammler Hans Kupfersberger Gerhard Rock Johann Fank 《Environmental Earth Sciences》2013,69(2):663-678
The aquifer Westliches Leibnitzer Feld, Austria, is a significant resource for regional and supraregional drinking water supply for more than 100,000 inhabitants, but the region also provides excellent agricultural conditions. This dual use implicates conflicts (e.g., non-point source groundwater pollution by nitrogen leaching), which have to be harmonized for a sustainable coexistence. At the aquifer scale, numerical models are state-of-the-art tools to simulate the behavior of groundwater quantity and quality and serve as decision support system for implementing groundwater protecting measures. While fully and iteratively coupled simulation models consider feedback between the saturated and unsaturated zone, sandy soil conditions and groundwater depths beneath the root zone allow the use of a unidirectional sequential coupling of the unsaturated water flow and nitrate transport model SIMWASER/STOTRASIM with FEFLOW for the investigation area. Considering separated inputs of water and nitrogen into groundwater out of surface water bodies, agricultural, residential and forested areas, first simulation results match observed groundwater tables, but underestimate nitrate concentrations in general. Thus, multiple scenarios assuming higher nitrogen inputs at the surface are simulated to converge with measured nitrate concentrations. Preliminary results indicate that N-input into the groundwater is strongly dominated by contributions of agricultural land. 相似文献
10.
Assessment of Groundwater Vulnerability in Upper Betwa River Watershed using GIS based DRASTIC Model
Groundwater, the most vital water resource being used for irrigation, domestic and industrial purposes is nowadays under severe threat of contamination. Groundwater contamination risk assessment is an effective tool for groundwater management. In the study, a DRASTIC model which is based on the seven hydrogeological parameters viz: depth of water, net-recharge, aquifer media, soil media, topography, impact of vadose zone and hydraulic conductivity was used to evaluate the groundwater pollution potentiality of upper Betwa watershed. ArcGIS was used to create the ground water vulnerability map by overlaying the seven layers. Based on groundwater vulnerability map, the watershed has been divided in three vulnerable zones viz; low vulnerability zone with 42.83 km2 of area, moderate with 369.21 km2 area and high having 270.96 km2 of area. Furthermore, the DRASTIC model has been validated by nitrate concentration over the area. Results of validation have shown that in low vulnerable zone, no nitrate contamination has been recorded. While in the moderate zone nitrate has been found in the range of 1.6-10ppm. However, in high vulnerable zone 11-40ppm of nitrate concentration in groundwater has been recorded, which proves that the DRASTIC model is applicable for the prediction of groundwater vulnerability in the watershed and in similar areas too. 相似文献
11.
Nitrogen isotope studies of nitrate contamination of the thick vadose zones in the wastewater-irrigated area 总被引：1，自引：0，他引：1
Cui-Yun Zhang Sheng Zhang Mi-Ying Yin Lin-Na Ma Ze He Zhuo Ning 《Environmental Earth Sciences》2013,68(5):1475-1483
The objective of this study was to investigate natural abundance and the distribution of nitrogen isotopic compositions to assess denitrification in two ~30 m thick vadose zones beneath the different land uses in the wastewater-irrigated area located in southern Shijiazhuang, China. Sediment samples were collected from cores of boreholes drilled in the vegetable growth plot and the wastewater-irrigated farmland for analyses of nitrogen isotopes, physical and chemical properties, respectively. The profile of borehole A drilled in the vegetable growth plot only applied animal wastes had lower δ15N values of mean +7.5 ‰ in the upper vadose zone, but higher values of mean +10.9 ‰ in the lower vadose zone. δ15N values in each part varied little with depth, indicating no or little denitrification occurred in the deep vadose zone below the soil zone. The profile of borehole B drilled in the wastewater-irrigated farmland had low δ15N values of mean +5.7 ‰ below the soil zone and little variations of δ15N values with depth, indicating no or little denitrification occurred in the deep vadose zone below the soil zone. This was also verified by consistent variations of NO3 ? and SO4 2? contents with Cl? contents. Our results suggested most of leachable nitrate from the soil zone was hardly subjected to biological attenuation into groundwater. 相似文献
12.
典型岩溶包气带洞穴滴水水文过程研究——以桂林硝盐洞为例 总被引：1，自引：0，他引：1
选取桂林丫吉试验场硝盐洞为研究对象,通过示踪试验和高分辨率水文水化学监测,确定滴水补给来源,研究典型岩溶包气带洞穴滴水对降雨响应的水文过程。研究结果表明,硝盐洞XY5滴水主要受到两种径流成分补给,即集中补给的管道流和弥散流。硝盐洞上部包气带中可能存在表层岩溶带含水层,长期维持滴水流量。滴水流量、电导率和示踪剂浓度的峰值均出现在强降雨时段,表现出快速响应的管道流特征,存在降雨阈值引起硝盐洞滴水降雨响应。降雨前岩溶含水层水分条件是包气带水文响应差异的主要原因,雨季滴水对降雨响应迅速,XY5滴水对降雨响应的滞后时间为10 h;而旱季对降雨的响应滞后明显,滞后时间达9.8天,体现了土壤和表层岩溶带的调蓄作用。74.4 mm降雨量是旱季转雨季滴水响应的降雨阈值。借助于洞穴滴水的水文动态变化和示踪试验技术对于研究包气带水文过程,深入了解岩溶含水层结构及特征,揭示岩溶区降雨入渗补给机制具有重要作用。 相似文献
13.
Khaled S. Gemail Mohamed El Alfy Mohamed F. Ghoneim Ahmed M. Shishtawy Moheb Abd El-Bary 《Environmental Earth Sciences》2017,76(9):350
DRASTIC indexing and integrated electrical conductivity (IEC) modeling are approaches for assessing aquifer vulnerability to surface pollution. DRASTIC indexing is more common, but IEC modeling is faster and more cost-effective because it requires less data and fewer processing steps. This study aimed to compare DRASTIC indexing with IEC modeling to determine whether the latter is sufficient on its own. Both approaches are utilized to determine zones vulnerable to groundwater pollution in the Nile Delta. Hence, assessing the nature and degree of risk are important for realizing effective measures toward damage minimization. For DRASTIC indexing, hydrogeological factors such as depth to aquifer, recharge rate, aquifer media, soil permeability, topography, impact of the vadose zone, and hydraulic conductivity were combined in a geographical information system environment for assessing the aquifer vulnerability. For IEC modeling, DC resistivity data were collected from 36 surface sounding points to cover the entire area and used to estimate the IEC index. Additionally, the vulnerable zones identified by both approaches were tested using a local-scale resistivity survey in the form of 1D and 2D resistivity imaging to determine the permeable pathways in the vadose zone. A correlation of 0.82 was obtained between the DRASTIC indexing and IEC modeling results. For additional benefit, the obtained DRASTIC and IEC models were used together to develop a vulnerability map. This map showed a very high vulnerability zone, a high-vulnerability zone, and moderate- and low-vulnerability zones constituting 19.89, 41, 27, and 12%, respectively, of the study area. Identifying where groundwater is more vulnerable to pollution enables more effective protection and management of groundwater resources in vulnerable areas. 相似文献
14.
Aquifer vulnerability assessment using the DRASTIC model at Russeifa landfill,northeast Jordan 总被引：1，自引：0，他引：1
Groundwater is inherently susceptible to contamination from anthropogenic activities and remediation is very difficult and expensive. Prevention of contamination is hence critical in effective groundwater management. In this paper an attempt has been made to assess aquifer vulnerability at the Russeifa solid waste landfill. This disposal site is placed at the most important aquifer in Jordan, which is known as Amman-Wadi Sir (B2/A7). The daily-generated leachate within the landfill is about 160 m3/day and there is no system for collecting and treating this leachate. Therefore, the leachate infiltrates to groundwater and degrades the quality of the groundwater. The area is strongly vulnerable to pollution due to the presence of intensive agricultural activity, the solid waste disposal site and industries. Increasing groundwater demand makes the protection of the aquifer from pollution crucial. Physical and hydrogeological characteristics make the aquifer susceptible to pollution. The vulnerability of groundwater to contamination in the study area was quantified using the DRASTIC model. The DRASTIC model uses the following seven parameters: depth to water, recharge, aquifer media, soil media, topography, impact on vadose zone and hydraulic conductivity. The water level data were measured in the observation wells within the disposal site. The recharge is derived based on precipitation, land use and soil characteristics. The aquifer media was obtained from a geological map of the area. The topography is obtained from the Natural Resources Authority of Jordan, 1:50,000 scale topographic map. The impact on the vadose zone is defined by the soil permeability and depth to water. The hydraulic conductivity was obtained from the field pumping tests. The calculated DRASTIC index number indicates a moderate pollution potential for the study area. 相似文献
15.
Karst groundwater is one of the important water resources for people in the world. There is an estimate that by 2028 karst
groundwater will supply more than 80% of people in the world. However, several areas in the world are characterized by high
nitrate concentrations in karst aquifers. In China, karst groundwater is also threatened by extensive use of fertilizer and
pesticides, industry waste, septic systems and poultry, hog or cattle manure. In order to understand the water quality of
a subterranean river in south China, especially the dynamic variation of nitrate, nitrogen input and output were determined
via auto-monitored apparatus, manual observation and samples from 2004 to 2008 in Guancun subterranean river drainage area.
Land use and anthropogenic activities were also investigated frequently. The results showed the range of nitrate variation
was 2.56–15.40 mg l−1, with an average value of 6.60 mg l−1. Spatial variation of nitrate concentrations showed nitrate rose where there were villages and agriculture distribution.
Long series of nitrate and discharge monitoring revealed there was a nitrate peak in spring just before the beginning of rainy
season. Three rainfall events were selected for analysis of relations among hydrological process, water chemistry, and nitrate
of the spring. The flood processes of the spring were divided into three or four phases according to change of water level
and water chemistry. They were dominated by initial condition of aquifer, piston flow in soil and vadose, piston flow in conduit,
diffuse recharge, and bypass recharge. The original condition of aquifer and rainfall pulse controlled recharge flow and changes
of nitrate and hydro-chemical graphs of the spring. The quantity of nitrogen input in a year was 66.61 t, and the output was
21.24 t. Nitrogen leaching loss in base flow accounted for 76.11% in a year. Some measures should be taken to protect karst
water in the very near future, so that health risks to the local people can be decreased. 相似文献
16.
An aquifer vulnerability assessment of the Benin Formation aquifer,Calabar, southeastern Nigeria,using DRASTIC and GIS approach 总被引：2，自引：1，他引：1
Aniekan Edet 《Environmental Earth Sciences》2014,71(4):1747-1765
An aquifer vulnerability of the Benin Formation aquifer (Calabar, southern Nigeria) has been assessed using a combination of DRASTIC index and GIS technology. The assessment was necessitated by the fact that uncontrolled disposal of domestic, industrial and agricultural wastes have caused groundwater contamination. Therefore, prevention of contamination, monitoring and management of the aquifer was urgently required to increase the efficient use of the current water supplies. The DRASTIC method uses seven parameters (depth to groundwater table, net recharge, aquifer media, soil media, topography, influence of vadose zone and hydraulic conductivity), which were used to produce vulnerability maps. The drastic vulnerability index ranged between 124 and 170. The vulnerability map shows that the aquifer is highly vulnerable in southeastern parts of the area covering about 22 %. The medium vulnerability area covers about 56.8 % of Calabar extending from the southwest to northern parts. 21.2 % of the area covering the central and northern parts the area lies within the low vulnerability zone. The present industrial and activities are located in the eastern and western parts, which falls within the low-medium vulnerability areas. Documented nitrate concentration in hand-dug wells and boreholes are in agreement with vulnerability zones. Sensitivity analysis was performed to evaluate the sensitivity of each parameter between map layers such that subjectivity can be reduced to an extent and new weights computed for each DRASTIC parameter. As management options sensitive areas, especially in the southern parts of Calabar area, should be protected from future development. 相似文献
17.
Jinlong Zhou Guomin Li Feng Liu Yiping Wang Xiaojing Guo 《Environmental Earth Sciences》2010,60(5):1055-1063
According to the characteristics of groundwater in arid area, this paper proposes DRAV model for groundwater vulnerability
assessment, where D is groundwater depth, R is the net recharge of aquifer, A is the aquifer characteristics, and V is the lithology of vadose zone. As a case study, the paper assesses the vulnerability of pore phreatic water in Tarim Basin
of Xinjiang, China by using the DRAV model. The results indicate that the areas of phreatic water with vulnerability index
ranges of 2–4, 4–6, 6–8 and >8 accounting for 10.1, 80.4, 9.2 and 0.2% of the total plain area of the Tarim Basin respectively,
and the areas with the latter two vulnerability ranges (6–8 and >8) are mainly located in the irrigation districts with thin
soil layer (20–30 cm thick surface soil of vadose zone, mainly with underlying sandy gravel) and with silty and fine sand
layer. Such vadose zone generally lacks sandy loam and clayey soil and has larger recharge by infiltration of irrigation water. 相似文献
18.
为了识别石家庄市南部污灌区地下水硝酸盐污染来源, 采集5种潜在污染源和19组地下水样用于化学和氮同位素分析.灌溉污水NH4+的δ15N值较低(4.0‰), 施化肥土壤和粪堆下土壤NO3-的δ15N值分别为1.4‰和12.4‰; 仅施厩肥的蔬菜种植区下伏近30 m厚包气带沉积物NO3-的δ15N分布显示, 来自动物粪便的NO3-已运移到11.5 m以下包气带, 均值10.9‰; 污水灌溉农田下伏厚层包气带沉积物样品分析结果指示, 土壤层下伏包气带沉积物δ15N值变幅较小, 均值5.7‰.污灌区内除一深井外, 其他水井地下水硝酸盐浓度变化在52.6~124.5 mg/L之间, 均值79.72 mg/L, δ15N值变化在5.3‰~8.3‰之间, 均值7.0‰.污灌区地下水的δ15N值较污灌区土壤层下伏包气带沉积物的δ15N值高, 表明地下水NO3-除了来自灌溉的污水外, 还有δ15N值更高的其他来源, 这些来源主要是人和动物粪便.利用线性混合模型计算, 污灌区地下水NO3-来自灌溉的污水, 约占76%, 而来自人和动物粪便的NO3-约占24%.为控制污灌区地下水NO3-浓度进一步增长, 不仅要加强污水灌溉管理, 还要加强人和动物粪便的管理. 相似文献
19.
在地表等量氮输入条件下,包气带中硝酸盐含量分布是其抗污染能力的直接表征。阐明不同包气带中硝酸盐分布的差异并分析其成因对于评价下覆含水层的硝酸盐污染脆弱性、保护地下水资源免遭硝酸盐污染,具有重要意义。本文基于太行山山前冲洪积扇上栾城和正定两个16m深包气带硝酸盐含量数据,指出两个剖面上包气带中硝酸盐分布特征的差异性。分析研究区的施肥历史、大气降水的入渗补给强度及土壤有机质含量,认为包气带水分运移速度和反硝化能力是导致包气带硝酸盐分布差异的两个关键因素。在分析N同位素测试技术进步的基础上,指出利用同位素技术对包气带中的反硝化能力的定量化研究有望取得新进展。 相似文献
20.
Pharmaceuticals and personal care products (PPCPs) are a new kind of contaminant widely existing in the surface water and groundwater environment. In recent years, PPCPs have been received widely attention from many researchers. The migration and transformation of PPCPs are mainly photolysis, biodegradation, adsorption and hydrolysis in aquifer environment. The influencing factors of PPCPs migration include PPCPs' own physical and chemical properties, types and contents of organic matter, pH, lithology, geotechnical structure and the thickness of vadose zone, etc. At present, the research of PPCPs in China is still in the primary stage, especially on the contaminant in aquifer system. Therefore, the research in this field needs to be further strengthened. 相似文献