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乌兹别克斯坦塔什干州克拉斯诺戈尔斯克附近的卡拉加什雷发现了硫酸钡矿床.现在,这里正在进行工业性试开采.硫酸钡精矿在工业中主要用于生产石油、天然气钻井用泥浆的加重剂(80%)及油漆、清漆、搪瓷、纸张、玻璃、塑料、橡胶的填充剂(15%~17%),以及有放射性辐射源的场所抹灰用特制水泥. 以前,乌兹别克斯坦国内没有发现过硫酸钡矿床,乌兹别克斯坦使用的硫酸钡一直靠进口.1994年,当以本国资源取代进口原料变得势在必行的时候,乌兹别克斯坦共和国地质委员会对发现有硫酸钡矿脉的地区的资料进行了汇总,发现了卡拉加什雷的硫酸钡矿床最容易被… 相似文献
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测定矿物或水中硫酸根的氧同位素组成(δ18O)能够识别物质来源及转化过程,常用的方法是将硫酸根转化为硫酸钡再用离线或在线法测试其δ18O值。目前普遍采用1420℃在线测试硫酸钡的氧同位素组成,该方法极易缩短反应炉的寿命,通过添加还原剂碳可以降低反应温度,但是已有报道对于添加还原剂后的反应温度讨论较少。本文选择镀镍碳(Ni-C)作为还原剂,将样品经Ni-C高温处理后进行一系列条件实验,确认了采用元素分析仪-稳定同位素质谱仪(EA-IRMS)测定硫酸钡中氧同位素组成的分析方法的关键技术参数:硫酸钡在线反应温度为1350℃; Ni-C与硫酸钡样品量的质量比范围选择0. 73～2. 15;为了获得更加精确的数据,硫酸钡与Ni-C用量都控制在700±100μg。在以上实验条件下,EA/HT-IRMS测定硫酸钡δ18O值的精密度为±0. 12‰～±0. 26‰,优于在线法已报道的精密度±0. 20‰～±0. 50‰。本方法在满足测试精密度的前提下,通过添加Ni-C降低了硫酸钡在线反应温度,延长了反应炉使用寿命。 相似文献
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应用改进DDARP方法纯化天然水体样品中硫酸钡固体的效果评价 总被引：2，自引：1，他引：1
二乙酸三胺五乙酸(DTPA)溶解再沉淀方法(DDARP)可去除硫酸钡沉淀过程中引入的硝酸盐杂质,但该方法对不同类型水体样品硫酸钡沉淀处理效果报道不多,特别是对有机质含量高的水体样品沉淀的硫酸钡固体是否有纯化作用尚未明确。本文选择硫酸钡高纯试剂以及水体样品沉淀的硫酸钡固体作为研究对象,采用改进DDARP方法纯化后,借助元素分析仪和稳定同位素质谱仪测定纯化前后硫酸钡固体的氧同位素值,对比分析该方法的纯化效果。结果表明:(1)改进DDARP方法主要内容为20mg硫酸钡沉淀溶于30mL DTPA-氢氧化钠混合溶液,再沉淀后超纯水洗涤2次,硫酸钡高纯试剂纯化前后氧同位素值没有明显变化,说明其杂质少,可直接作为实验室标准使用,而黄河水硫酸钡沉淀纯化前后氧同位素差异均值为0. 8‰,说明其杂质较多,需要纯化。(2)六种不同类型水体硫酸钡沉淀纯化前后氧同位素差异值范围为-0. 4‰～+1. 9‰,其中溶解性洗衣粉、地下水、河水、生活污水、溶解性化学肥料以及雨水的差异均值分别为0. 7‰、0. 2‰、0. 3‰、-0. 3‰、0. 1‰和1. 4‰。(3)雨水硫酸钡沉淀纯化前后氧同位素差异值较大(+0. 5‰～+1. 9‰),与雨水中较高NO3/SO4摩尔比值(0. 2～1. 9,均值0. 7)有关。污水纯化前后氧同位素差异值为负值(-0. 2‰～0. 4‰),说明纯化方法可以去除有机物干扰。研究认为:改进DDARP方法有效降低了硝酸盐和有机质干扰,有利于获得更准确的硫酸盐样品氧同位素组成,可以作为水体硫酸盐氧同位素标准纯化方法。 相似文献
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应用XRF可快速测定重晶石中钡元素的总量,但当测定硫酸钡含量时,由于样品中的碳酸钡计入钡量造成硫酸钡的测定结果不准确,铜、铅、锌等有色金属元素对熔样坩埚会造成损害,需要进行酸处理除去碳酸钡、铅等干扰。而样品经酸处理后不同样品的剩余量不同,造成熔剂与样品的比例不确定,也不能准确测定硫酸钡的含量,因此保证熔剂与样品比例一致是解决该问题的关键。本文优化了样品前处理、熔片制样和仪器工作条件,将一定量样品以10%盐酸和10%硝酸溶解,过滤除去碳酸钡、硫酸钙及铜、铅、锌等有色金属元素,未溶解样品在700℃下灼烧后以氧化铝补充到原取样量,实现了熔剂与样品比例一致,再以硝酸铵作氧化剂,溴化锂和碘化铵作脱模剂,1075℃熔融制片,即可用XRF准确测定硫酸钡的含量。本方法的相对标准偏差(RSD)小于0.4%,检出限为72μg/g,较ICP-OES等方法的检测周期短、干扰元素少,提高了测试效率和分析质量。 相似文献
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彭雪娇 《华东地质学院学报》2003,26(3):281-283
测定水中硫酸根的方法有重量法、容量法、硫酸钡比浊法和间接极谱法等。常用硫酸钡比浊法和容量法来测定。EDTA 铅滴定法测定水中硫酸根的含量是一种经典的容量法,通过对该法滴定条件———溶液酸度、沉淀放置时间、缓冲溶液的加入量等进行较详细的试验。提出了测定时应控制的实验条件,验证了该法的可行性,且测定结果更精确。进一步氯离子的干扰试验表明:此方法适用于氯离子含量小于600mg·L-1的水样测定。 相似文献
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测定银铅矿中的铅,常规分解方法是采用酸溶法（王水和四酸）处理样品。当银铅矿中重晶石含量为40%~80%时,酸溶法不能完全分解样品,造成铅的测定结果偏低;且样品中大量硫酸钡的存在易与铅生成铅钡复盐沉淀而影响铅的准确测定。本文采用过氧化钠碱熔法分解样品,在试液中加入氯化钡,应用电感耦合等离子体发射光谱法测定重晶石含量高的银铅矿中铅的含量,通过优化取样量与稀释倍数等参数,配合高盐雾化器的使用有效避免了基体干扰。方法检出限为0.013%,相对标准偏差（RSD）为1.1%~1.6%,回收率为97.9%~102.9%,标准样品的测定结果可靠。本法采用过氧化钠碱熔,可完全彻底地分解样品;氯化钡的加入使重晶石含量高的银铅矿样品中硫酸钡对铅的干扰被消除,而对不含重晶石的铅矿样品中铅的测定无影响。本法解决了银铅矿与高含量重晶石共生时样品难分解的问题,同时解决了硫酸钡干扰测定铅的问题。 相似文献
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硫酸钡的氧硫同位素分析方法及有关数据的地质应用实例 总被引：1，自引：0，他引：1
碳粉在高温条件下可还原硫酸钡，使其氧转入ＣＯ２及ＣＯ气体中。此ＣＯ气体在高温镍金属的催化作用下，可转化为ＣＯ２气体。两种ＣＯ２合并后，可用质谱计分析其氧同位素组成。此组成便是硫酸钡的δ（１８）Ｏ值。水体硫酸根的氧、硫同位素值在水环境研究中大有用处。例如，三山岛金矿矿井水中硫酸根的氧、硫同位素数据表明，此水是地下水及海水的混合产物。这就为矿井排水工程的设计提供出某种信息。 相似文献
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Inter-regional correlation of transgressions and regressions in the Cretaceous period 总被引：1，自引：0，他引：1
T. Matsumoto 《Cretaceous Research》1980,1(4):359-373
Well investigated platforms have been selected in each continent, and the history of Cretaceous transgressions and regressions there is concisely reviewed from the available evidence. The factual records have been summarized into a diagram and the timing of the events correlated between distant as well as adjoining areas.On a global scale, major transgressions were stepwise enlarged in space and time from the Neocomian, via Aptian-Albian, to the Late Cretaceous, and the post-Cretaceous regression was very remarkable. Minor cycles of transgression-regression were not always synchronous between different areas. Some of them were, however, nearly synchronous between the areas facing the same ocean.Tectono-eustasy may have been the main cause of the phenomena of transgression-regression, but certain kinds of other tectonic movements which affected even the so-called stable platforms were also responsible for the phenomena. The combined effects of various causes may have been unusual in the Cretaceous, since it was a period of global tectonic activity. The slowing down of this activity followed by readjustments may have been the cause of the global regression at the end of the Cretaceous. 相似文献
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The Afyon stratovolcano exhibits lamprophyric rocks, emplaced as hydrovolcanic products, aphanitic lava flows and dyke intrusions, during the final stages of volcanic activity. Most of the Afyon volcanics belong to the silica-saturated alkaline suite, as potassic trachyandesites and trachytes, while the products of the latest activity are lamproitic lamprophyres (jumillite, orendite, verite, fitztroyite) and alkaline lamprophyres (campto-sannaite, sannaite, hyalo-monchiquite, analcime–monchiquite). Afyon lamprophyres exhibit LILE and Zr enrichments, related to mantle metasomatism. 相似文献
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K.Naganjaneyulu 《地学前缘(英文版)》2014,5(1):1-2
正The Precambrian shields and associated suture zones of the globe preserve important records of continental growth and destruction,the formation and closure of ocean basins,and the early evolution of the Earth in terms of tectonics,resources,and environment.They also offer critical clues on the nature and style 相似文献
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Daniel Harlov 《地学前缘(英文版)》2014,5(5):621-625
正1.Introduction This special issue of Geoscience Frontiers is a tribute volume honoring the life and career of Jacques Touret.A set of research papers has been assembled,which broadly reflect his research interests over his 50 plus year career.These papers focus on the role that fluids play during the formation and evolution of the Earth's crust.Below I provide a brief summary of the life of Jacques Touret,along with a select bibliography of his more important papers.This is then followed by a brief introduction to the papers assembled for this special issue. 相似文献
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《地学前缘(英文版)》2014,(1):139-141
正1 AIM AND SCOPE GEOSCIENCE FRONTIERS(GSF)is a bi-monthly international journal that publishes in English high quality original research articles and timely reviews in interdisciplinary fields of Earth and Planetary Sciences.GSF aims to bridge innovative,provocative and challenging concepts and models related to various fields of research including petrology and geochemistry in understanding lithospheric architecture and mantle dynamics,global tectonics,economic geology and fuel exploration,geophysics,stratigraphy and paleontology with new 相似文献
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正The world petroleum exploration suggests that,about70%of the world’s potash resources were discovered during oil and gas exploration(Zheng et al.,2007).The Kuqa depression in the Tarim basin is abundant with petroleum exploration data,and 相似文献
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正Qarhan Salt Lake is located in the eastern part of the Qaidam Basin,which is first discovered the large potash deposit in the late 1950s.The Bieletan section is located in the west of Qarhan Salt Lake,where saline sediment 相似文献
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正With the approach of the 45th World Earth Day,China’s Ministry of Land and Resources issued the status of the Chinese geological survey and environments on 22nd April 2013.Regional geological survey in 2013 achieved new results—(why was oceanic in twice?)polar and oceanic expedition were fully completed,a national census of geography was begun,and 相似文献
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正1 Introduction The Lop Nor playa,located in the eastern end of the Tarim Basin,capped with a thick salt crust covering an area of approximately 5,500 km2(Ma 2007)that closely resembles a"Great Ear"in satellite images.Understanding the formation of the salt crust can provide important 相似文献
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In Liaoning, Hunan, Guangxi, Guizhou, Gansu, Sichuan, Anhui, Jilin and other provinces in China, there is a wide occurrence of metal quantity over 1000 tons of refractory gold ores, principally because of low gold recoveries and become ＂stay mine＂. Features of refi＇actory gold ores are： gold in micro-particles or a microscopic state that is wrapped in pyrite, presence of arsenopyrite and other sulfide minerals or disseminated in the crystal lattice of sulfide minerals; harmful impurity elements such as arsenic, carbon, mercury, antimony, copper with high content are closely related with the gold, and these elements affect the contact reaction between the gold and solvent extraction, making the recovery of the gold extraction process low. In the past 20 years, overseas countries have developed the application of the roasting oxidation method, hot acid （alkali） oxidation, bacterial oxidation and flash chlorination oxidation technology to solve this problem.Among these, biological oxidation has developed rapidly in the domestic market and gold enterprises abroad because of its low investment in infrastructure, low production costs, less environmental pollution, simple process and easy control, etc. 相似文献