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1.
A critical factor in successfully monitoring and forecasting volcanic ash dispersion for aviation safety is the height reached by eruption clouds, which is affected by environmental factors, such as wind shear and atmospheric instability. Following earlier work using the Active Tracer High Resolution Atmospheric Model for strong Plinian eruptions, this study considered a range of eruption strengths in different atmospheres. The results suggest that relatively weak volcanic eruptions in the moist tropics can trigger deep convection that transports volcanic material to 15–20 km. For the same volcanic strength there can be ~9 km difference between eruption heights in moist tropical and dry subpolar environments (a larger height difference than previously suggested), which appears consistent with observations. These results suggest that eruption intensity should not be estimated from eruption height alone for tropospheric eruptions and also that the average height of volcanic eruptions may increase if the tropical atmospheric belt widens in a changing climate. Ash aggregation is promoted by hydrometeors (particularly liquid water), so the smaller modelled eruptions in moist atmospheres, which have a relatively small ash content for their height and water content, result in a relatively small proportion of fine ash in the dispersing cloud when compared to a dry atmosphere. This in turn makes the ash clouds much more difficult to detect using remote sensing than those in dry atmospheres. Overall, a weak eruption in the tropics is more likely to produce a plume above cruising levels for civil aviation, harder to detect and track, but with a lower concentration of fine ash than a mid-latitude or polar equivalent. There is currently no defined ‘acceptable’ concentration of ash for aircraft, but as these results suggest low-grade encounters in the tropics from undetected clouds are likely, it would be desirable to explore that issue.  相似文献   

2.
The Lonquimay volcanic complex (LVC) in the high Southern Andes comprises a stratocone and NE-trending flank-cone alignments. Numerous effusive and explosive volcanic eruptions characterize its post-glacial magmatic activity. Our tephrostratigraphic record, pre-dating the four historically documented eruptions, comprises 22 dated pyroclastic deposits that are used to constrain repose time distribution and eruption probability of the LVC magmatic system. Statistical examination of the stratigraphy-based eruption time series yields probabilities of 20–50 % for at least one explosive (VEI ≥ 3) eruption within the next 100 years as of 2011. The tephra deposits are subdivided into three petrographic groups: a felsic group (Lonquimay colored-pumice tephra, LCPT), an intermediate population (Lonquimay gray pumice tephra, LGPT), and a mafic member (Lonquimay dark scoria tephra, LDST). The distribution of these petrographic groups through the LVC tephrostratigraphy is linked to the observed changes in repose times. LDST-deposits as well as deposits compositionally zoned from LCPT to LGPT dominate the lower part of the stratigraphy for which recurrence times are short (RTmean = 417 ± 169a). Deposits younger than 6,000 b2k (years before 2000 AD) have dominantly LCPT and minor LDST compositions, no longer contain LGPT, and repose times are significantly longer (RTmean = 1,350 ± 310a). We interpret the change in eruption regime to result from a rearrangement in the magma storage and plumbing system. Thermobarometric calculations based on cpx–liquid equilibria and amphibole compositions reveal three distinct magma storage levels: the mafic LDST derive from mid crustal storage (P mean = 476 ± 95 MPa, T mean = 1,073 ± 24 °C), felsic LCPT mainly erupted from upper-crustal level (P mean = 86 ± 49 MPa, T mean = 936 ± 24 °C), whereas LGPT samples yield intermediate storage depths (P mean = 239 ± 100 MPa, T mean = 1,013 ± 17 °C). Magma contributions from this intermediate reservoir are restricted to >6,000 b2k when the Lonquimay plumbing system was in a regime of short repose times; disappearance of the intermediate reservoir coincides with the change to longer repose times between eruptions.  相似文献   

3.
We present for the first time a self-consistent methodology connecting volcanological field data to global climate model estimates for a regional time series of explosive volcanic events. Using the petrologic method, we estimated SO2 emissions from 36 detected Plinian volcanic eruptions occurring at the Central American Volcanic Arc (CAVA) during the past 200,000 years. Together with simple parametrized relationships collected from past studies, we derive estimates of global maximum volcanic aerosol optical depth (AOD) and radiative forcing (RF) describing the effect of each eruption on radiation reaching the Earth’s surface. In parallel, AOD and RF time series for selected CAVA eruptions are simulated with the global aerosol model MAECHAM5-HAM, which shows a relationship between stratospheric SO2 injection and maximum global mean AOD that is linear for smaller volcanic eruptions (<5 Mt SO2) and nonlinear for larger ones (≥5 Mt SO2) and is qualitatively and quantitatively consistent with the relationship used in the simple parametrized approximation. Potential climate impacts of the selected CAVA eruptions are estimated using an earth system model of intermediate complexity by RF time series derived by (1) directly from the global aerosol model and (2) from the simple parametrized approximation assuming a 12-month exponential decay of global AOD. We find that while the maximum AOD and RF values are consistent between the two methods, their temporal evolutions are significantly different. As a result, simulated global maximum temperature anomalies and the duration of the temperature response depend on which RF time series is used, varying between 2 and 3 K and 60 and 90 years for the largest eruption of the CAVA dataset. Comparing the recurrence time of eruptions, based on the CAVA dataset, with the duration of climate impacts, based on the model results, we conclude that cumulative impacts due to successive eruptions are unlikely. The methodology and results presented here can be used to calculate approximate volcanic forcings and potential climate impacts from sulfur emissions, sulfate aerosol or AOD data for any eruption that injects sulfur into the tropical stratosphere.  相似文献   

4.
The Campi Flegrei volcanic district (Naples region, Italy) is a 12-km-wide, restless caldera system that has erupted at least six voluminous ignimbrites during the late Pleistocene, including the >300 km3 Campanian ignimbrite (CI) which originated from the largest known volcanic event of the Mediterranean region. The Breccia Museo (BM), a petrologically heterogeneous and stratigraphically complex volcanic deposit extending over 200 km2 in close proximity to Campi Flegrei, has long remained contentious regarding its age and stratigraphic relation to the CI. Here, we present crystallization and eruption ages for BM plutonic ejecta clasts that were determined via uranium decay series and (U–Th)/He dating of zircon, respectively. Despite mineralogical and textural heterogeneity of these syenitic clasts, their U–Th zircon rim crystallization ages are indistinguishable with an average age of 49.7 ± 2.5 ka (2σ errors; mean square of weighted deviates MSWD = 1.2; n = 34). A subset of these crystals was used to obtain disequilibrium-corrected (U–Th)/He zircon ages which average 41.7 ± 1.8 ka (probability of fit P = 0.54; n = 15). This age closely overlaps with published CI 40Ar/39Ar eruption ages (40.6 ± 0.1 ka) after recalibration to recently revised flux monitor ages. Concordant eruption ages for BM and CI agree with previous chemostratigraphic and paleomagnetic correlations, suggesting their origin from the same eruption. However, they are at variance with recalibrated 40Ar/39Ar ages which have BM postdate CI by 3 ± 1 ka. BM syenites show similar geochemical and Sr–Nd isotopical features of pre-caldera rocks erupted between 58 and 46 ka, but are distinctive from subsequent caldera-forming magmas. Energy-constrained assimilation and fractional crystallization modeling of Nd–Sr isotopic data suggests that pre-caldera magmas formed a carapace of BM-type intrusions in a mid-crust magma chamber (≥8 km depth) shielding the younger CI magma from contamination by Hercynian basement wall rocks. An ~41–50 ka hiatus in crystallization ages implies rapid solidification of these pre-CI intrusions. This argues against protracted pre-eruptive storage of a large volume of CI magma at shallow crustal levels.  相似文献   

5.
New geochemical and isotopic data on volcanic rocks spanning the period ~75–50 ka BP on Ischia volcano, Italy, shed light on the evolution of the magmatic system before and after the catastrophic, caldera-forming Monte Epomeo Green Tuff (MEGT) eruption. Volcanic activity during this period was influenced by a large, composite and differentiating magmatic system, replenished several times with isotopically distinct magmas of deep provenance. Chemical and isotopic variations highlight that the pre-MEGT eruptions were fed by trachytic/phonolitic magmas from an isotopically zoned reservoir that were poorly enriched in radiogenic Sr and became progressively less radiogenic with time. Just prior to the MEGT eruption, the magmatic system was recharged by an isotopically distinct magma, relatively more enriched in radiogenic Sr with respect to the previously erupted magmas. This second magma initially fed several SubPlinian explosive eruptions and later supplied the climactic, phonolitic-to-trachytic MEGT eruption(s). Isotopic data, together with erupted volume estimations obtained for MEGT eruption(s), indicate that >5–10 km3 of this relatively enriched magma had accumulated in the Ischia plumbing system. Geochemical modelling indicates that it accumulated at shallow depths (4–6 km), over a period of ca. 20 ka. After the MEGT eruption, volcanic activity was fed by a new batch of less differentiated (trachyte-latite) magma that was slightly less enriched in radiogenic Sr. The geochemical and Sr–Nd-isotopic variations through time reflect the upward flux of isotopically distinct magma batches, variably contaminated by Hercynian crust at 8–12 km depth. The deep-sourced latitic to trachytic magmas stalled at shallow depths (4–6 km depth), differentiated to phonolite through crystal fractionation and assimilation of a feldspar-rich mush, or ascended directly to the surface and erupted.  相似文献   

6.
The quantification of energy interactions among land surface, atmosphere, and surface vegetation is significant to comprehend the hydrological cycle in montane watersheds. Moreover, elevation change is an essential in causing variations in energy fluxes. Thus, estimating the major components of energy interactions is essential for better understanding of the hydrological process. The advanced land surface models (LSMs); the common land model (CLM) and variables infiltration capacity (VIC) are used to estimate accurate hydrometeorological variables. These hydrometeorological variables such as net radiation and sensible, latent, and ground heat fluxes were estimated using CLM and VIC at upper and lower meteorological stations in Sierra Nevada Mountain, California, USA. The estimated fluxes were compared with observations at each site. The estimated daily and monthly net radiation and sensible heat flux from both models showed good agreement with the observations (R ≥ 0.84). The CLM-modeled estimates showed lower trends during the rainfall periods, which occurred mainly during winter at both sites. In comparison, the estimated daily and monthly latent heat flux from CLM at both sites showed better results with lower RMSE and bias than that from VIC, which underestimated latent heat flux. Both models overestimated ground heat flux, and the variation trend was similar to observation. For sensitivity analysis, according to elevation change, all the estimated energy fluxes had slightly different values at the upper and lower met stations. In future studies, parameterization for the LSMs will be conducted for more robust estimations of hydrometeorological variables in montane watersheds.  相似文献   

7.
Diffusion couple experiments with wet half (up to 4.6 wt%) and dry half were carried out at 789–1,516 K and 0.47–1.42 GPa to investigate water diffusion in a peralkaline rhyolitic melt with major oxide concentrations matching Mount Changbai rhyolite. Combining data from this work and a related study, total water diffusivity in peralkaline rhyolitic melt can be expressed as:
$ D_{{{\text{H}}_{ 2} {\text{O}}_{\text{t}} }} = D_{{{\text{H}}_{ 2} {\text{O}}_{\text{m}} }} \left( {1 - \frac{0.5 - X}{{\sqrt {[4\exp (3110/T - 1.876) - 1](X - X^{2} ) + 0.25} }}} \right), $
$ {\text{with}}\;D_{{{\text{H}}_{ 2} {\text{O}}_{\text{m}} }} = \exp \left[ { - 1 2. 7 8 9- \frac{13939}{T} - 1229.6\frac{P}{T} + ( - 27.867 + \frac{60559}{T})X} \right], $
where D is in m2 s?1, T is the temperature in K, P is the pressure in GPa, and X is the mole fraction of water and calculated as = (C/18.015)/(C/18.015 + (100 ? C)/33.14), where C is water content in wt%. We recommend this equation in modeling bubble growth and volcanic eruption dynamics in peralkaline rhyolitic eruptions, such as the ~1,000-ad eruption of Mount Changbai in North East China. Water diffusivities in peralkaline and metaluminous rhyolitic melts are comparable within a factor of 2, in contrast with the 1.0–2.6 orders of magnitude difference in viscosities. The decoupling of diffusivity of neutral molecular species from melt viscosity, i.e., the deviation from the inversely proportional relationship predicted by the Stokes–Einstein equation, might be attributed to the small size of H2O molecules. With distinct viscosities but similar diffusivity, bubble growth controlled by diffusion in peralkaline and metaluminous rhyolitic melts follows similar parabolic curves. However, at low confining pressure or low water content, viscosity plays a larger role and bubble growth rate in peralkaline rhyolitic melt is much faster than that in metaluminous rhyolite.
  相似文献   

8.
A pyroxene with composition LiNiSi2O6 was synthesized at T = 1,473 K and P = 2.0 GPa; the cell parameters at T = 298 K are a = 9.4169(6) Å, b = 8.4465(7) Å, c = 5.2464(3) Å, β = 110.534(6)°, V = 390.78(3) Å3. TEM examination of the LiNiSi2O6 pyroxene showed the presence of h + k odd reflections indicative of a primitive lattice, and of antiphase domains obtained by dark field imaging of the h + k odd reflections. A HT in situ investigation was performed by examining TEM selected area diffraction patterns collected at high temperature and synchrotron radiation powder diffraction. In HTTEM the LiNiSi2O6 was examined together with LiCrSi2O6 pyroxene. In LiCrSi2O6 the h + k odd critical reflections disappear at about 340 K; they are sharp up to the transition temperature and do not change their shape until they disappear. In LiNiSi2O6 the h + k odd reflections are present up to sample deterioration at 650 K. A high temperature synchrotron radiation powder diffraction investigation was performed on LiNiSi2O6 between 298 and 773 K. The analysis of critical reflections and of changes in cell parameters shows that the space group is P-centred up to the highest temperature. The comparative analysis of the thermal and spontaneous strain contributions in P21/c and C2/c pyroxenes indicates that the high temperature strain in P-LiNiSi2O6 is very similar to that due to thermal strain only in C2/c spodumene and that a spontaneous strain contribution related to pre-transition features is not apparent in LiNiSi2O6. A different high-temperature behaviour in LiNiSi2O6 with respect to other pyroxenes is suggested, possibly in relation with the presence of Jahn–Teller distortion of the M1 polyhedron centred by low-spin Ni3+.  相似文献   

9.
Tephrochronology is a powerful tool for dating sedimentary sequences, especially in Patagonia, where a large number of active volcanoes have produced frequent historical eruptions. Short lacustrine sedimentary sequences were extracted from the lakes Moreno Oeste and Ton?ek (Nahuel Huapi National Park). Seventeen volcanic ash layers were identified in both cores, 210Pb and 137Cs were used for dating techniques, and historical volcanic records were employed for correlation. White pumice and glass shards from the tephras were characterised by measuring major and trace element contents by instrumental neutron activation analysis. Two volcanic sources – the Cordón Caulle and the Calbuco volcanoes – were recognised as the prevailing systems that impacted the area in the past 800–1000 a. The Calbuco volcano was mainly responsible for the nine tephras identified in the Lake Ton?ek sequence. Four of these nine tephras also contained material from the Cordón Caulle complex, and could be interpreted as composite tephras or possible reworked ones. The Calbuco volcano showed predominant influences in the Lake Moreno Oeste sequence. Six of the eight tephras identified in such a sequence were from the Calbuco volcano, and three of these six contained material from the Cordón Caulle complex. The other two were from the Cordón Caulle complex, with contributions from the Calbuco volcano in one of them. These findings show that the high frequency of volcanic events in the study region demands an accurate characterisation of the products generated by each source, as well as an evaluation of their spatial distribution, to obtain a consistent framework for dating recent environmental changes. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

10.
Mangakino, the oldest rhyolitic caldera centre delineated in the Taupo Volcanic Zone of New Zealand, generated two very large (super-sized) ignimbrite eruptions, the 1.21 ± 0.04 Ma >500 km3 Ongatiti and ~1.0 Ma ~1,200 km3 Kidnappers events, the latter of which was followed after a short period of erosion by the ~200 km3 Rocky Hill eruption. We present U/Pb ages and trace-element analyses on zircons from pumice clasts from these three eruptions by Secondary Ion Mass Spectrometry (SIMS) using SHRIMP-RG instruments to illustrate the evolution of the respective magmatic systems. U–Pb age spectra from the Ongatiti imply growth of the magmatic system over ~250 kyr, with a peak of crystallisation around 1.32 Ma, ~100 kyr prior to eruption. The zircons are inferred to have then remained stable in a mush with little crystallisation and/or dissolution before later rejuvenation of the system at the lead-in to eruption. The paired Kidnappers and Rocky Hill eruptions have U–Pb zircon ages and geochemical signatures that suggest they were products of a common system grown over ~200 kyr. The Kidnappers and Rocky Hill samples show similar weakly bimodal age spectra, with peaks at 1.1 and 1.0 Ma, suggesting that an inherited antecrystic population was augmented by crystals grown at ages within uncertainty of the eruption age. In the Kidnappers, this younger age peak is dominantly seen in needle-shaped low U grains with aspect ratios of up to 18. In all three deposits, zircon cores show larger ranges and higher absolute concentrations of trace elements than zircon rims, consistent with zircon crystallisation from evolving melts undergoing crystal fractionation involving plagioclase and amphibole. Abundances and ratios of many trace elements frequently show variations between different sectors within single grains, even where there is no visible sector zoning in cathodoluminescence (CL) imaging. Substitution mechanisms, as reflected in the molar (Sc + Y + REE3+)/P ratio, differ in the same growth zone between the sides (along a-axis and b-axis: values approaching 1.0) and tips (c-axis: values between 1.5 and 5.0) of single crystals. These observations have implications for the use of zircons for tracking magmatic processes, particularly in techniques where CL zonation within crystals is not assessed and small analytical spot sizes cannot be achieved. These observations also limit applicability of the widely used Ti-in-zircon thermometer. The age spectra for the Ongatiti and Kidnappers/Rocky Hill samples indicate that both magmatic systems were newly built in the time-breaks after respective previous large eruptions from Mangakino. Trace element variations defining three-component mixing suggest that zircons, sourced from multiple melts, contributed to the population in each system.  相似文献   

11.
Air entrainment in fragmented magmas controls the dynamics of volcanic eruptions. Pyroclast oxidation kinetics may be applied to quantify the degree of magma–air interaction. Pyrrhotite (Po) in volcanic rocks is often oxidized to form magnetite (Mt) and hematite (Hm), and its reaction mechanisms are well constrained. To test utilizing Po oxidation as a marker for magma–air interactions, we compared the occurrence of Po oxidation products from three different eruption styles during the Sakurajima 1914–1915 eruption. Pumices from the Plinian eruption include columnar-type Fe oxides (Mt with subordinate width of Hm) often accompanied by relict Po. This columnar type is also found in clastogenic lava, where it is almost completely oxidized to Hm. The effusive lava contains framboidal aggregates of subhedral to anhedral Mt crystals without Hm. The formation mechanisms of columnar and framboidal Fe oxides were estimated. The columnar type Fe oxides were formed syn-eruptively through gaseous reactions, as opposed to the melt in a magma chamber, as demonstrated by the Ti-free nature of the columnar Mt and its synchronous oxidation to Hm. By contrast, the framboidal type was formed in a melt with decreasing fS2. The calculation of Hm growth in a conductively cooling pumice clast constrains the surface temperature of pumice in the eruption column. The paragenesis and oxidation degree of Po and Fe oxides are consistent with the eruption processes in terms of magma fragmentation, air entrainment, and welding, and can, therefore, be a responsive marker for the magma–air interaction.  相似文献   

12.
A probabilistic eruption forecast is provided for seven historically active volcanoes along the Central American Volcanic Arc (CAVA), as a pivotal empirical contribution to multi-disciplinary volcanic hazards assessment. The eruption probabilities are determined with a Kaplan–Meier estimator of survival functions, and parametric time series models are applied to describe the historical eruption records. Aside from the volcanoes that are currently in a state of eruptive activity (Santa María, Fuego, and Arenal), the highest probabilities for eruptions of VEI ≥ 2 occur at Concepción and Cerro Negro in Nicaragua, which are likely to erupt to 70–85 % within the next 10 years. Poás and Irazú in Costa Rica show a medium to high eruption probability, followed by San Miguel (El Salvador), Rincón de la Vieja (Costa Rica), and Izalco (El Salvador; 24 % within the next 10 years).  相似文献   

13.
火山活动与气候变化研究进展   总被引:12,自引:1,他引:12  
综述了火山活动对气候影响的研究进展。不同岩浆成分及喷发类型的火山活动对气候的影响不同:中酸性普林尼(Pl inian)式火山喷发主要造成气候变冷和臭氧层破坏,它导致气候变化的时间较短,但空间范围较大;大火成岩省造成气候变化的时空范围及程度均较大,它能够导致地表温度、海平面大幅度变化,最终引起生物灭绝;中小规模玄武质裂隙式喷发主要造成火山盆地内气候较大幅度变化,但对气候影响的持续时间较短,主要气候效应是导致附近地区温度快速下降和形成酸雨。简要阐述了第四纪火山活动的特点。  相似文献   

14.
This retrospective study focuses on the fine silicate particles (<62 µm in diameter) produced in a large eruption that was otherwise well studied. Fine particles represent a potential hazard to aircraft, because as simple particles they have very low terminal velocities and could potentially stay aloft for weeks. New data were collected to describe the fine particle size distributions of distal fallout samples collected soon after eruption. Although, about half of the mass of silicate particles produced in this eruption of ~1 km3 dense rock equivalent magma were finer than 62 µm in diameter, and although these particles were in a stratospheric cloud after eruption, almost all of these fine particles fell to the ground near (<300 km) the volcano in a day or two. Particles falling out from 70 to 300 km from the volcano are mostly <62 µm in diameter. The most plausible explanation for rapid fallout is that the fine ash nucleates ice in the convective cloud and initiates a process of meteorological precipitation that efficiently removes fine silicates. These observations are similar to other eruptions and we conclude that ice formation in convective volcanic clouds is part of an effective fine ash removal process that affects all or most volcanic clouds. The existence of pyroclastic flows and surges in the El Chichón eruption increased the overall proportion of fine silicates, probably by milling larger glassy pyroclasts.  相似文献   

15.
There are over 100 active volcanoes in the North Pacific (NOPAC) region, most of which are located in sparsely populated areas. Dispersion models play an important role in forecasting the movement of volcanic ash clouds by complementing both remote sensing data and visual observations from the ground and aircraft. Puff is a three-dimensional dispersion model, primarily designed for forecasting volcanic ash dispersion, used by the Alaska Volcano Observatory and other agencies. Since early 2007, the model is in an automated mode to predict the movement of airborne volcanic ash at multiple elevated alert status volcanoes worldwide to provide immediate information when an eruption occurs. Twelve of the predictions are within the NOPAC region, nine more within the southern section of the Pacific ring of fire and the others are in Europe and the Caribbean. Model forecasts are made for initial ash plumes ranging from 4 to 20 km altitude above sea level and for a 24-h forecast period. This information is made available via the Puff model website. Model results can be displayed in Virtual Globes for three-dimensional visualization. Here, we show operational Puff predictions in two and three-dimensions in Google Earth®, both as iso-surfaces and particles, and study past eruptions to illustrate the capabilities that the Virtual Globes can provide. In addition, we show the opportunity that Google Maps® provides in displaying Puff operational predictions via an application programming web interface and how radiosonde data (vertical soundings) and numerical weather prediction vertical profiles can be displayed in Virtual Globes for assisting in estimating ash cloud heights.  相似文献   

16.
Protracted pre-eruptive zircon residence is frequently detected in continental rhyolites and can conflict with thermal models, indicating briefer magma cooling durations if scaled to erupted volumes. Here, we present combined U-Th and (U-Th)/He zircon ages from the Acigöl rhyolite field (Central Anatolia, Turkey), which is part of a Quaternary bimodal volcanic complex. Unlike other geochronometers, this approach dates crystallization and eruption on the same crystals, allowing for internal consistency testing. Despite the overall longevity of Acigöl rhyolite volcanism and systematic trends of progressive depletion in compatible trace elements and decreasing zircon saturation temperatures, we find that zircon crystallized in two brief pulses corresponding to eruptions in the eastern and western part of the field during Middle and Late Pleistocene times, respectively. For Late Pleistocene zircon, resolvable differences exist between interior (average: 30.7 ± 0.9 ka; 1σ error) and rim (21.9 ± 1.3 ka) crystallization ages. These translate into radial crystal growth rates of ~10?13 to 10?14 cm/s, broadly consistent with those constrained by diffusion experiments. Rim crystallization and (U-Th)/He eruption ages (24.2 ± 0.4 ka) overlap within uncertainty. Evidence for brief zircon residence at Acigöl contrasts with many other rhyolite fields, suggesting that protracted zircon crystallization in, or recycling from, long-lived crystal mushes is not ubiquitous in continental silicic magma systems. Instead, the span of pre-eruptive zircon ages is consistent with autochthonous crystallization in individual small-volume magma batches that originated from basaltic precursors.  相似文献   

17.
Quenched juvenile mafic inclusions (enclaves) are an occasional but informative component in the deposits of large felsic eruptions. Typically, the groundmasses of these inclusions rapidly crystallize as the mafic magma is chilled against a more voluminous, cooler felsic host, providing a physical and chemical record of the nature and timing of mafic–felsic interactions. We examine mafic inclusions of two compositional lineages (tholeiitic and calc-alkaline) from deposits of the 25.4 ka Oruanui eruption (Taupo, New Zealand). 2-D quantitative textural data from analysis of back-scattered electron images reveal a marked diversity in the groundmass textures of the inclusions, including median crystal sizes (amphibole: 14–45 µm; plagioclase: 21–75 µm) and aspect ratios (amphibole: 1.7–4.2; plagioclase: 2.1–4.0), area number densities (amphibole: 122–2660 mm?2; plagioclase: 117–2990 mm?2), area fractions (?) of minerals (?plag?=?23–45%, ?amph?=?0–28%, ?cpx?=?0–6%, ?oxides?=?0.6–5.5%), and the relative abundance of plagioclase and amphibole (?plag/?amph?=?1.0–4.6). Textural parameters vary more significantly within, rather than between, the two compositional lineages, and in some cases show marked variations across individual clasts, implying that each inclusion’s cooling history, rather than bulk composition, was the dominant control on textural development. Groundmass mineral compositions are also diverse both within and between inclusions (e.g. plagioclase from An34–92, with typical intra-clast variability of ~?20 mol%), and do not correlate with bulk chemistry. Diverse groundmass textures and mineral and glass chemistries are inferred to reflect complex interplay of a range of factors including the degree and rate of undercooling, bulk composition, water content and, possibly, intensive variables. Our data are inconsistent with breakup of a crystallizing ponded mafic layer at the base of the Oruanui melt-dominant body, instead implying that each inclusion partially crystallized as a discrete body with a unique cooling history. Extensive ingestion of mush-derived macro-crystals suggests that mechanical breakup of mafic feeder dikes occurred within a transition zone between the mush and melt-dominant magma body. In this zone, the mush lacked yield strength, as has been inferred from field studies of narrow (meters to few tens of meters) mush-melt transition zones preserved in composite intrusions. Evidence for plastic deformation of inclusions during eruption and the abundance of fresh residual glass in inclusions from all eruptive phases suggest that the inclusions formed syn-eruptively, and must have been formed recurrently at multiple stages throughout the eruption.  相似文献   

18.
Pb-contaminated water is a dangerous threat occurring near metallurgic and mining industries. This circumstance produces serious environment concern, due to Pb(II) high toxic effects. Several reactive materials have been reported for Pb(II) adsorption, but not all reached final Pb(II) suitable concentrations, or they are expensive and rejected in massive remediation technologies; hence, natural materials are good options. The adsorption behavior of a volcanic scoria (two sieved fractions 1425 and <425 µm) was studied toward synthetic Pb(II) water solutions in batch experiments (170.4–912.3 mg L?1) with high removal efficiencies (97%). The Langmuir model fits both fractions with high linear correlation coefficients (0.9988 and 0.9949) with high maximum capacity values (588.23 and 555.55 mg g?1). Separation factor R L parameter varies with initial concentration, and the empirical equation predicts the limits of the material usefulness, a criterion proposed in this paper for conditions’ selection. The Lagergren pseudo-second-order analysis demonstrates chemisorption; calculated rate constant (416.66 mg g?1 min?1). Weber–Morris intraparticle model proves that the adsorption phenomena occur fast on the material surface (k inst = 72 g mg?1 min?0.5). The characterization of the volcanic material afforded the elemental composition (X-ray fluorescence), and the empirical formula was proposed. X-ray diffraction patterns verify the material structure as basalt, with a plagioclase structure that matches anorthite and albite, mostly composed of quartz. The presence of oxides on the material surface explain the high Pb(II) adsorption capacity, observed on the surface by scanning electronic microscopy. The studied volcanic scoria has potential use as a Pb(II) adsorbent in water remediation technologies.  相似文献   

19.
The contents of Ti, Al and Fe 2 O 3 in a lacustrine sediment core (DY6) collected from Dongdao Island, South China Sea (SCS), were determined to be much higher than those in the three major sediment end-members (coral sand, guano and plants), and their likely sources include terrigenous dust and volcanic ash. At 61 cm (~AD 1300), the contents of Ti, Al and Fe 2 O 3 have an abnormally high spike, which cannot be explained by terrigenous dust. The Sr and Nd isotope compositions at 61 cm are in excellent agreement with those in volcanic materials, but they are significantly different from those in terrigenous dust, implying a possible material input from historical volcanic eruptions in the lacustrine sediment DY6. The documented great Samalas volcanic eruption at AD 1257 in Indonesia is likely the candidate for this volcanic eruption.  相似文献   

20.
Slunyaev  A.  Sergeeva  A.  Didenkulova  I. 《Natural Hazards》2016,84(2):549-565
The evolution of unidirectional nonlinear sea surface waves is calculated numerically by means of solution of the Euler equations. The wave dynamics corresponds to quasi-equilibrium states characterized by JONSWAP spectra. The spatiotemporal data are collected and processed providing information about the wave height probability and typical appearance of abnormally high waves (rogue waves). The waves are considered at different water depths ranging from deep to relatively shallow cases (k p h > 0.8, where k p is the peak wavenumber, and h is the local depth). The asymmetry between front and rear rogue wave slopes is identified; it becomes apparent for sufficiently high waves in rough sea states at all considered depths k p h ≥ 1.2. The lifetimes of rogue events may reach up to 30–60 wave periods depending on the water depth. The maximum observed wave has a height of about three significant wave heights. A few randomly chosen in situ time series from the Baltic Sea are in agreement with the general picture of the numerical simulations.  相似文献   

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