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1.
The effects of small amounts of H2O (<4 wt % in the melt)on the multiply saturated partial melting of spinel lherzolitein the system CaO–MgO–Al2O3–SiO2 ±Na2O ± CO2 have been determined at 1·1 GPa inthe piston-cylinder apparatus. Electron microprobe analysisand Fourier transform infrared spectroscopy were used to analysethe experimental products. The effects of H2O are to decreasethe melting temperature by 45°C per wt % H2O in the melt,to increase the Al2O3 of the melts, decrease MgO and CaO, andleave SiO2 approximately constant, with melts changing fromolivine- to quartz-normative. The effects of CO2 are insignificantat zero H2O, but become noticeable as H2O increases, tendingto counteract the H2O. The interaction between H2O and CO2 causesthe solubility of CO2 at vapour saturation to increase withincreasing H2O, for small amounts of H2O. Neglect of the influenceof CO2 in some previous studies on the hydrous partial meltingof natural peridotite may explain apparent inconsistencies betweenthe results. The effect of small amounts of H2O on multiplysaturated melt compositions at 1·1 GPa is similar tothat of K2O, i.e. increasing H2O or K2O leads to quartz-normativecompositions, but increasing Na2O produces an almost oppositetrend, towards nepheline-normative compositions. KEY WORDS: H2O; CO2; FTIR; hydrous partial melting; mantle melting; spinel lherzolite; system CaO–MgO–Al2O3–SiO2 ± H2O ± CO2 ± Na2O 相似文献
2.
To investigate eclogite melting under mantle conditions, wehave performed a series of piston-cylinder experiments usinga homogeneous synthetic starting material (GA2) that is representativeof altered mid-ocean ridge basalt. Experiments were conductedat pressures of 3·0, 4·0 and 5·0 GPa andover a temperature range of 1200–1600°C. The subsolidusmineralogy of GA2 consists of garnet and clinopyroxene withminor quartz–coesite, rutile and feldspar. Solidus temperaturesare located at 1230°C at 3·0 GPa and 1300°C at5·0 GPa, giving a steep solidus slope of 30–40°C/GPa.Melting intervals are in excess of 200°C and increase withpressure up to 5·0 GPa. At 3·0 GPa feldspar, rutileand quartz are residual phases up to 40°C above the solidus,whereas at higher pressures feldspar and rutile are rapidlymelted out above the solidus. Garnet and clinopyroxene are theonly residual phases once melt fractions exceed 20% and garnetis the sole liquidus phase over the investigated pressure range.With increasing melt fraction garnet and clinopyroxene becomeprogressively more Mg-rich, whereas coexisting melts vary fromK-rich dacites at low degrees of melting to basaltic andesitesat high melt fractions. Increasing pressure tends to increasethe jadeite and Ca-eskolaite components in clinopyroxene andenhance the modal proportion of garnet at low melt fractions,which effects a marked reduction in the Al2O3 and Na2O contentof the melt with pressure. In contrast, the TiO2 and K2O contentsof the low-degree melts increase with increasing pressure; thusNa2O and K2O behave in a contrasted manner as a function ofpressure. Altered oceanic basalt is an important component ofcrust returned to the mantle via plate subduction, so GA2 maybe representative of one of many different mafic lithologiespresent in the upper mantle. During upwelling of heterogeneousmantle domains, these mafic rock-types may undergo extensivemelting at great depths, because of their low solidus temperaturescompared with mantle peridotite. Melt batches may be highlyvariable in composition depending on the composition and degreeof melting of the source, the depth of melting, and the degreeof magma mixing. Some of the eclogite-derived melts may alsoreact with and refertilize surrounding peridotite, which itselfmay partially melt with further upwelling. Such complex magma-genesisconditions may partly explain the wide spectrum of primitivemagma compositions found within oceanic basalt suites. KEY WORDS: eclogite; experimental petrology; mafic magmatism; mantle melting; oceanic basalts 相似文献
3.
Chromium as Cr3+ substitutes for octahedrally coordinated Alin upper-mantle minerals, thereby reducing the activity of Al2O3in the system and hence the concentration of Al2O3 in partialmelts. The effect of Cr2O3 on melt compositions multiply saturatedwith the spinel lherzolite phase assemblage has been quantifiedin the system CaO–MgO–Al2O3–SiO2–Cr2O3at 1·1 GPa as a function of 100 Cr/(Cr + Al) in the spinel(Cr#sp). The decrease of Al2O3 in the melt with increasing Cr#spis accompanied by increasing MgO and SiO2, whereas CaO remainsalmost constant. Consequently, the CaO/Al2O3 ratio of the meltincreases with Cr#sp, and the melt becomes richer in normativediopside, hypersthene and quartz. The effect may explain certainmantle melts with unusually high CaO/Al2O3 ratios. The concentrationof Cr2O3 in the melt remains low even at high Cr#sp, which meansthat the strong effect of Cr2O3 on partial melting equilibriais not readily apparent from its concentration in the melt itself.The existence of a highly refractory major component such asCr2O3 nullifies simplified conclusions from the ‘inverseapproach’ in the experimental study of basalt petrogenesis,as there is insufficient information in the composition of thepartial melt to reconstruct the conditions of melting. KEY WORDS: basalt petrogenesis; partial melting; reversal experiment; spinel lherzolite; system CMAS–Cr2O3; CaO/Al2O3 of melt; effect of Cr2O3 相似文献
4.
Using experimental results at 1·0 GPa for the systemsCaO–SiO2, MgO–SiO2, CaMgSi2O6–SiO2 and CaMgSi2O6–Mg2SiO4,and all the currently available phase equilibria and thermodynamicdata at 1 bar, we have optimized the thermodynamic propertiesof the liquid phase at 1·0 GPa. The new optimized thermodynamicparameters indicate that pressure has little effect on the topologyof the CaO–SiO2, CaMgSi2O6–SiO2, and CaMgSi2O6–Mg2SiO4systems but a pronounced one on the MgO–SiO2 binary. Themost striking change concerns passage of the MgSiO3 phase fromperitectic melting at 1 bar to eutectic melting at 1·0GPa. This transition is estimated to occur at 0·41 GPa.For the CaMgSi2O6–SiO2 and CaMgSi2O6–Mg2SiO4 pseudo-binaries,the size of the field clinopyroxene + liquid increases withincreasing pressure. This change is related to the shift ofthe piercing points clinopyroxene + silica + liquid (from 0·375mol fraction SiO2 at 1 bar to 0·414 at 1·0 GPa)and clinopyroxene + olivine + liquid (from 0·191 molfraction SiO2 at 1 bar to 0·331 at 1·0 GPa) thatbound the clinopyroxene + liquid field in the CaMgSi2O6·SiO2and CaMgSi2O6·Mg2SiO4 pseudo-binaries, respectively. KEY WORDS: CaO–SiO2; CaMgSi2O6–Mg2SiO4; CaMgSi2O6–SiO2; experiments; MgO–SiO2 相似文献
5.
Multianvil melting experiments in the system CaO–MgO–Al2O3–SiO2–CO2(CMAS–CO2) at 3–8 GPa, 1340–1800°C, involvingthe garnet lherzolite phase assemblage in equilibrium with CO2-bearingmelts, yield continuous gradations in melt composition betweencarbonatite, kimberlite, melilitite, komatiite, picrite, andbasalt melts. The phase relations encompass a divariant surfacein P–T space. Comparison of the carbonatitic melts producedat the low-temperature side of this surface with naturally occurringcarbonatites indicates that natural magnesiocarbonatites couldbe generated over a wide range of pressures >2·5 GPa.Melts analogous to kimberlites form at higher temperatures alongthe divariant surface, which suggests that kimberlite genesisrequires more elevated geotherms. However, the amount of waterfound in some kimberlites has the potential to lower temperaturesfor the generation of kimberlitic melts by up to 150°C,provided no hydrous phases are present. Compositions resemblinggroup IB and IA kimberlites are produced at pressures around5–6 GPa and 10 GPa, respectively, whereas the compositionsof some other kimberlites suggest generation at higher pressuresstill. At pressures <4 GPa, an elevated geotherm producesmelilitite-like melt in the CMAS–CO2 system rather thankimberlite. Even when a relatively CO2-rich mantle compositioncontaining 0·15 wt % CO2 is assumed, kimberlites andmelilitites are produced by <1% melting and carbonatitesare generated by even smaller degrees of melting of <0·5%. KEY WORDS: carbonatite; CO2; kimberlite; melilitite; melt generation 相似文献
6.
The equilibrium temperatures of the reaction muscovite+chlorite+quartz= cordierite+phlogopite+H2O (1) in the pure system K2O—MgO—Al2O2—SiO2—H2Owere found to be 495±10°C at 1 kb PH2O; 525±10°Cat 2 kb; 610±15°C at 5 kb; 635±10°C at6 kb. From intersection of this curve with the lower temperaturestability limit of cordierite close to 645°C, 6.5 kb PH2O,a reaction cordieritc+muscovite = phlogopite+aluminum silicate+quartz+H2O(2) is generated which has a negative slope and passes throughthe points 645°C, 6.5 kb PH2O and 700°C, 5 kb PH2O.On the high-pressure side of this reaction curve cordieriteis restricted to K2O—poor bulk compositions. Application of the experimentally determined phase relationsto more complex natural pelitic rocks suggests that reaction(1) represents maximum temperatures for the disappearance ofchlorite from pelitic assemblages containing muscovite and quartz,whereas reaction (2) gives maximum water pressures for the disappearanceof cordierite from these rocks. 相似文献
7.
Al2SiO5 reaction textures in aluminous schist and quartziteof the northern Picuris range, north-central New Mexico, recorda paragenetic sequence of kyanite to sillimanite to andalusite,consistent with a clockwise P–T loop, with minor decompressionnear the Al2SiO5 triple-point. Peak metamorphic temperaturesare estimated at 510–525°C, at 4·0–4·2kbar. Kyanite and fibrolite are strongly deformed; some prismaticsillimanite, and all andalusite are relatively undeformed. Monaziteoccurs as inclusions within kyanite, mats of sillimanite andcentimetre-scale porphyroblasts of andalusite, and is typicallyaligned subparallel to the dominant regional foliation (S0/S1or S2) and extension lineation (L1). Back-scatter electron imagesand X-ray maps of monazite reveal distinct core, intermediateand rim compositional domains. Monazite–xenotime thermometryfrom the intermediate and rim domains yields temperatures of405–470°C (±50°C) and 500–520°C(±50°C), respectively, consistent with the progradeto peak metamorphic growth of monazite. In situ, ion microprobeanalyses from five monazites yield an upper intercept age of1417 ± 9 Ma. Near-concordant to concordant analyses yield207Pb–206Pb ages from 1434 ± 12 Ma (core) to 1390± 20 Ma (rim). We find no evidence of older regionalmetamorphism related to the 1650 Ma Mazatzal Orogeny. KEY WORDS: Al2SiO5; metamorphism; monazite; thermochronometry; triple-point 相似文献
8.
We investigated phase equilibria in the six-component systemNa2O–K2O–Al2O3–SiO2–F2O–1–H2Oat 100 MPa to characterize differentiation paths of naturalfluorine-bearing granitic and rhyolitic magmas. Topaz and cryoliteare stable saturating solid phases in calcium-poor systems.At 100 MPa the maximum solidus depression and fluorine solubilityin evolving silicic melts are controlled by the eutectics haplogranite–cryolite–H2Oat 640°C and 4 wt % F, and haplogranite–topaz–H2Oat 640°C and 2 wt % F. Topaz and cryolite form a binaryperalkaline eutectic at 660°C, 100 MPa and fluid saturation.The low-temperature nature of this invariant point causes displacementof multiphase eutectics with quartz and alkali feldspar towardsthe topaz–cryolite join and enables the silicate liquidusand cotectic surfaces to extend to very high fluorine concentrations(more than 30 wt % F) for weakly peraluminous and subaluminouscompositions. The differentiation of fluorine-bearing magmasfollows two distinct paths of fluorine behavior, depending onwhether additional minerals buffer the alkali/alumina ratioin the melt. In systems with micas or aluminosilicates thatbuffer the activity of alumina, magmatic crystallization willreach either topaz or cryolite saturation and the system solidifiesat low fluorine concentration. In leucogranitic suites precipitatingquartz and feldspar only, the liquid line of descent will reachtopaz or cryolite but fluorine will continue to increase untilthe quaternary eutectic with two fluorine-bearing solid phasesis reached at 540°C, 100 MPa and aqueous-fluid saturation.The maximum water solubility in the haplogranitic melts increaseswith the fluorine content and reaches 12· 5 ±0· 5 wt % H2O at the quartz–cryolite–topazeutectic composition. A continuous transition between hydrousfluorosilicate melts and solute-rich aqueous fluids is not documentedby this study. Our experimental results are applicable to leucocraticfluorosilicic magmas. In multicomponent systems, however, thepresence of calcium may severely limit enrichment of fluorineby crystallization of fluorite. KEY WORDS: granite; rhyolite; topaz; cryolite; magmatic differentiation 相似文献
9.
Fe–Mg exchange is the most important solid solution involvedin partial melting of spinel lherzolite, and the system CaO–MgO–Al2O3–SiO2–FeO(CMASF) is ideally suited to explore this type of exchange duringmantle melting. Also, if primary mid-ocean ridge basalts arelargely generated in the spinel lherzolite stability field bynear-fractional fusion, then Na and other highly incompatibleelements will early on become depleted in the source, and themelting behaviour of mantle lherzolite should resemble the meltingbehaviour of simplified lherzolite in the CMASF system. We havedetermined the isobarically univariant melting relations ofthe lherzolite phase assemblage in the CMASF system in the 0·7–2·8GPa pressure range. Isobarically, for every 1 wt % increasein the FeO content of the melt in equilibrium with the lherzolitephase assemblage, the equilibrium temperature is lower by about3–5°C. Relative to the solidus of model lherzolitein the CaO–MgO–Al2O3–SiO2 system, melt compositionsin the CMASF system are displaced slightly towards the alkalicside of the basalt tetrahedron. The transition on the solidusfrom spinel to plagioclase lherzolite has a positive Clapeyronslope with the spinel lherzolite assemblage on the high-temperatureside, and has an almost identical position in P–T spaceto the comparable transition in the CaO–MgO–Al2O3–SiO2–Na2O(CMASN) system. When the compositions of all phases are describedmathematically and used to model the generation of primary basalts,temperature and melt composition changes are small as percentmelting increases. More specifically, 10% melting takes placeover 1·5–2°C, melt compositions are relativelyinsensitive to the degree of melting and bulk composition, andequilibrium and near-fractional melting yield similar melt compositions.FeO and MgO are the oxides that exhibit the greatest changein the melt with degree of melting and bulk composition. Theamount of FeO decreases with increasing degree of melting, whereasthe amount of MgO increases. The coefficients for Fe–Mgexchange between the coexisting crystalline phases and melt,KdFe–Mgxl–liq, show a relatively simple and predictablebehaviour with pressure and temperature: the coefficients forolivine and spinel do not show significant dependence on temperature,whereas the coefficients for orthopyroxene and clinopyroxeneincrease with pressure and temperature. When melting of lherzoliteis modeled in the CMASF system, a strong linear correlationis observed between the mg-number of the lherzolite and themg-number of the near-solidus melts. Comparison with meltingin the CMASN system indicates that Na2O has a strong effecton lherzolite melting behaviour only at small degrees of melting. KEY WORDS: CMASF; lherzolite solidus; mantle melting 相似文献
10.
The Sulfide Capacity and the Sulfur Content at Sulfide Saturation of Silicate Melts at 1400{degrees}C and 1 bar 总被引：2，自引：0，他引：2
The solubility of sulfur as S2– has been experimentallydetermined for 19 silicate melt compositions in the system CaO–MgO–Al2O3–SiO2(CMAS)± TiO2 ± FeO, at 1400°C and 1 bar, using CO–CO2–SO2gas mixtures to vary oxygen fugacity (fO2) and sulfur fugacity(fS2). For all compositions, the S solubility is confirmed tobe proportional to (fS2/fO2)1/2, allowing the definition ofthe sulfide capacity (CS) of a silicate melt as CS = [S](fO2/fS2)1/2.Additional experiments covering over 150 melt compositions,including some with Na and K, were then used to determine CSas a function of melt composition at 1400°C. The resultswere fitted to the equation 相似文献
11.
Calculated Phase Relations in the System Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O with Applications to UHP Eclogites and Whiteschists 总被引：2，自引：0，他引：2
Pressure–temperature grids in the system Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O and its subsystems have been calculatedin the range 15–45 kbar and 550–900°C, usingan internally consistent thermodynamic dataset and new thermodynamicmodels for amphibole, white mica, and clinopyroxene, with thesoftware THERMOCALC. Minerals considered for the grids includegarnet, omphacite, diopside, jadeite, hornblende, actinolite,glaucophane, zoisite, lawsonite, kyanite, coesite, quartz, talc,muscovite, paragonite, biotite, chlorite, and plagioclase. Compatibilitydiagrams are used to illustrate the phase relationships in thegrids. Coesite-bearing eclogites and a whiteschist from Chinaare used to demonstrate the ability of pseudosections to modelphase relationships in natural ultrahigh-pressure metamorphicrocks. Under water-saturated conditions, chlorite-bearing assemblagesin Mg- and Al-rich eclogites are stable at lower temperaturesthan in Fe-rich eclogites. The relative temperature stabilityof the three amphiboles is hornblende > actinolite > glaucophane(amphibole names used sensu lato). Talc-bearing assemblagesare stable only at low temperature and high pressure in Mg-and Al-rich eclogites. For most eclogite compositions, talccoexists with lawsonite, but not zoisite, in the stability fieldof coesite. Water content contouring of pressure–temperaturepseudosections, along with appropriate geotherms, provides newconstraints concerning dehydration of such rocks in subductingslabs. Chlorite and lawsonite are two important H2O-carriersin subducting slabs. Depending on bulk composition and pressure–temperaturepath, amphibole may or may not be a major H2O-carrier to depth.In most cases, dehydration to make ultrahigh-pressure eclogitestakes place gradually, with H2O content controlled by divariantor higher variance assemblages. Therefore, fluid fluxes in subductionzones are likely to be continuous, with the rate of dehydrationchanging with changing pressure and temperature. Further, eclogitesof different bulk compositions dehydrate differently. Dehydrationof Fe-rich eclogite is nearly complete at relatively shallowdepth, whereas Mg- and Al-rich eclogites dehydrate continuouslydown to greater depth. KEY WORDS: dehydration; eclogites; phase relations; THERMOCALC; UHP metamorphism; whiteschists 相似文献
12.
Calculated Phase Relations in High-Pressure Metapelites in the System NKFMASH (Na2O-K2O-FeO-MgO-Al2O3-SiO2-H2O) 总被引：6，自引：0，他引：6
Using an internally consistent thermodynamic dataset and updatedmodels of activity–composition relation for solid solutions,petrogenetic grids in the system NKFMASH (Na2O–K2O–FeO–MgO–Al2O3–SiO2–H2O)and the subsystems NKMASH and NKFASH have been calculated withthe software THERMOCALC 3.1 in the P–T range 5–36kbar and 400–810°C, involving garnet, chloritoid,biotite, carpholite, talc, chlorite, kyanite/sillimanite, staurolite,phengite, paragonite, albite, glaucophane, jadeite, with quartz/coesiteand H2O in excess. These grids, together with calculated AFMcompatibility diagrams and P–T pseudosections, are shownto be powerful tools for delineating the phase equilibria andP–T conditions of Na-bearing pelitic assemblages for avariety of bulk compositions from high-P terranes around theworld. These calculated equilibria are in good agreement withpetrological studies. Moreover, contours of the calculated phengiteSi isopleths in P–T pseudosections for different bulkcompositions confirm that phengite barometry is highly dependenton mineral assemblage. KEY WORDS: phase relations; HP metapelite; NKFMASH; THERMOCALC; phengite geobarometry 相似文献
13.
Liquidus relations in the four-component system Na2O–Al2O3–SiO2–F2O–1were studied at 0· 1 and 100 MPa to define the locationof fluoride–silicate liquid immiscibility and outlinedifferentiation paths of fluorine-bearing silicic magmas. Thefluoride–silicate liquid immiscibility spans the silica–albite–cryoliteand silica–topaz–cryolite ternaries and the haplogranite-cryolitebinary at greater than 960°C and 0· 1–100 MPa.With increasing Al2O3 in the system and increasing aluminum/alkalication ratio, the two-liquid gap contracts and migrates fromthe silica liquidus to the cryolite liquidus. The gap does notextend to subaluminous and peraluminous melt compositions. Forall alkali feldspar–quartz-bearing systems, the miscibilitygap remains located on the cryolite liquidus and is thus inaccessibleto differentiating granitic and rhyolitic melts. In peralkalinesystems, the magmatic differentiation is terminated at the albite–quartz–cryoliteeutectic at 770°C, 100 MPa, 5 wt % F and cation Al/Na =0· 75. The addition of topaz, however, significantlylowers melting temperatures and allows strong fluorine enrichmentin subaluminous compositions. At 100 MPa, the binary topaz–cryoliteeutectic is located at 770°C, 39 wt % F, cation Al/Na 0·95, and the ternary quartz–topaz–cryolite eutecticis found at 740°C, 32 wt % F, 30 wt % SiO2 and cation Al/Na 0· 95. Such location of both eutectics enables fractionationpaths of subaluminous quartz-saturated systems to produce fluorine-rich,SiO2-depleted and nepheline-normative residual liquids. KEY WORDS: silicate melt; granite; rhyolite; fluorine; liquid immiscibility 相似文献
14.
Hydrothermal investigation of the bulk composition CaO.Al2O3.4SiO2+excessH2O has been conducted using conventional techniques over thetemperature ranges 200–450 °C and 500–6000 barsPfluid. A number of reactions have been studied by employingmineral mixtures consisting of reactants and products in about9: 1 and 1: 9 ratios. The phase relations were deduced fromrelatively long experiments by observing which seeded assemblagedisappeared or decreased markedly in one of the paired run charges. Laumontite was synthesized in the laboratory, probably for thefirst time. Laumontite was grown from seeded wairakite to over99 per cent using a weak NaCl solution. The refractive indicesof the synthetic material are about = 1.504 and = 1.514. Theaverage unit cell dimensions are a0 = 14.761±0.005 Å;b0 = 13.077±0.005 Å; c0 = 7.561±0.003 Å;and ß = 112.02°±0.04°. Within the errorof measurement, the optical properties and cell parameters arein good agreement with those of natural laumontite. The equilibriumdehydration of laumontite involves two reactions: (1) laumontite= wairakite+2H2O, passing through about 230 °C at 0.5 kb,255±5 °C at 1 kb, 282±5 °C at 2 kb, 297±5°C at 3 kb and 325±5 °C at 6 kb; and (2) laumontite= lawsonite+2 quartz+2H2O, taking place at about 210 °Cat 3 kb and 275 °C at 3.2 kb. Above 300 °C, the equilibriumcurve for the solid-solid reaction (3) lawsonite+2 quartz =wairakite passes through 305 °C, 3.4 kb and 390 °C,4.4 kb. Equilibrium has been demonstrated unambiguously forthe above three reactions. The hydrothermal decomposition ofnatural laumontite above its own stability limit appears tobe a very slow process. Combined with previously published equilibria determined hydrothermallyfor wairakite, the phase relations are further investigatedby chemographic analysis interrelating the phases, laumontite,wairakite, lawsonite, anorthite, prehnite+kaolinite, and 2 pumpellyite+kaolinitein the system CaAl2Si2O8-SiO2-H2O. This synthesis allowed theconstruction of a semiquantitative petrogenetic grid applicableto natural parageneses and the delineation of the physical conditionsfor the various low-grade metamorphic facies in low µCO2environments. The similar stratigraphic zonations, consistentlyfound in a variety of environments, are recognized to be a functionof burial depth, geothermal gradient, and mineralogical andchemical composition of the parental rocks. Departures fromthe normal sequences are believed to be due to the combinationsof mineralogical variations, availability of H2O, differencesin the ratio µCO2/µH2O, and the rate of reaction.The possible P-T boundaries for diagenesis, the zeolite facies,the lawsonite-albite facies, the prehnite-pumpellyite facies,and the adjacent metamorphic facies are illustrated diagrammatically. 相似文献
15.
Fluid-saturated subsolidus experiments from 2·0 to 6·5GPa, and from 680 to 800°C have been performed on threemodel peridotites in the system Na2O–CaO–FeO–MgO–Al2O3–SiO2–H2O(NCFMASH). Amphibole and chlorite coexist up to 2·4 GPa,700°C. Chlorite persists to 4·2 GPa at 680°C.Starting from 4·8 GPa, 680°C a 10 Å phase structurereplaces chlorite in all compositions. The 10 Å phasestructure contains significant Al2O3 (up to 10·53 wt%) deviating from the MgO–SiO2–H2O 10 Å phase(MSH 10 Å phase). A mixed layered structure (chlorite–MSH10 Å phase) is proposed to account for aluminium observed.In the Tinaquillo lherzolite amphibole breakdown occurs viathe reaction
Thermal stabilityof chlorite (chlorite + orthopyroxene = forsterite + garnet+ H2O) is shifted towards lower temperatures, compared withthe system MASH. Furthermore, the chlorite thermal breakdownis also related to the degenerate reaction
Chlorite and the Al-10 Å phase structurecontribute significantly to the water budget in subduction zonesin the depth range relevant for arc magmatism, whereas amphibole-relatedfluid release is restricted to the forearc region. Chloriteand Al-10 Å phase breakdowns might explain the occurrenceof a double seismic zone by dehydration embrittlement. KEY WORDS: amphibole; chlorite; high pressure; peridotites; subduction zones 相似文献
16.
Sediment Melts at Sub-arc Depths: an Experimental Study 总被引：14，自引：0，他引：14
The phase and melting relations in subducted pelites have beeninvestigated experimentally at conditions relevant for slabsat sub-arc depths (T = 600–1050°C, P = 2·5–4·5GPa). The fluid-present experiments produced a dominant paragenesisconsisting of garnet–phengite–clinopyroxene–coesite–kyanitethat coexists with a fluid phase at run conditions. Garnet containsdetectable amounts of Na2O (up to 0·5 wt%), P2O5 (upto 0·56 wt%), and TiO2 (up to 0·9 wt%) in allexperiments. Phengite is stable up to 1000°C at 4·5GPa and is characterized by high TiO2 contents of up to 2 wt%.The solidus has been determined at 700°C, 2·5 GPaand is situated between 700 and 750°C at 3·5 GPa.At 800°C, 4·5 GPa glass was present in the experiments,indicating that at such conditions a hydrous melt is stable.In contrast, at 700°C, 3·5 and 4·5 GPa, asolute-rich, non-quenchable aqueous fluid was present. Thisindicates that the solidus is steeply sloping in P–T space.Fluid-present (vapour undersaturated) partial melting of thepelites occurs according to a generalized reaction phengite+ omphacite + coesite + fluid = melt + garnet. The H2O contentof the produced melt decreases with increasing temperature.The K2O content of the melt is buffered by phengite and increaseswith increasing temperature from 2·5 to 10 wt%, whereasNa2O decreases from 7 to 2·3 wt%. Hence, the melt compositionschange from trondhjemitic to granitic with increasing temperature.The K2O/H2O increases strongly as a function of temperatureand nature of the fluid phase. It is 0·0004–0·002in the aqueous fluid, and then increases gradually from about0·1 at 750–800°C to about 1 at 1000°C inthe hydrous melt. This provides evidence that hydrous meltsare needed for efficient extraction of K and other large ionlithophile elements from subducted sediments. Primitive subduction-relatedmagmas typically have K2O/H2O of 0·1–0·4,indicating that hydrous melts rather than aqueous fluids areresponsible for large ion lithophile element transfer in subductionzones and that top-slab temperatures at sub-arc depths are likelyto be 700–900°C. KEY WORDS: experimental petrology; pelite; subduction; UHP metamorphism; fluid; LILE 相似文献
17.
Falloon Trevor J.; Green David H.; Danyushevsky Leonid V.; McNeill Andrew W. 《Journal of Petrology》2008,49(4):591-613
We have determined the near-solidus melt compositions for peridotiteMM-3, a suitable composition for the production of mid-oceanridge basalt (MORB) by decompression partial melting, at 1 and1·5 GPa. At 1 GPa the MM-3 composition has a subsolidusplagioclase-bearing spinel lherzolite assemblage, and a solidusat 1270°C. At only 5°C above the solidus, 4% meltis present as a result of almost complete melting of plagioclase.This melting behaviour in plagioclase lherzolite is predictedfrom simple systems and previous experimental work. The persistenceof plagioclase to > 0·8 GPa is strongly dependenton bulk-rock CaO/Na2O and normative plagioclase content in theperidotite. At 1·5 GPa the MM-3 composition has a subsolidusspinel lherzolite assemblage, and a solidus at 1350°C.We have determined a near-solidus melt composition at 2% meltingwithin 10°C of the solidus. Near-solidus melts at both 1and 1·5 GPa are nepheline normative, and have low normativediopside contents; also they have the highest TiO2, Al2O3 andNa2O, and the lowest FeO and Cr2O3 contents compared with higherdegree partial melts. Comparison of these near-solidus meltswith primitive MORB glasses, which lie in the olivine-only fieldof crystallization at low pressure, indicate that petrogeneticmodels involving aggregation of near-fractional melts formedduring melting at pressures of 1·5 GPa or less are unlikelyto be correct. In this study we use an experimental approachthat utilizes sintered oxide mix starting materials and peridotitereaction experiments. We also examine some recent studies usingan alternative approach of melt migration into, and entrapmentwithin ‘melt traps’ (olivine, diamond, vitreouscarbon) and discuss optimal procedures for this method. KEY WORDS: experimental petrology; mantle melting; near-solidus; fertile peridotite; MORB 相似文献
18.
Calculated Phase Relations in the System NCKFMASH (Na2O-CaO-K2O-FeO-MgO-Al2O3-SiO2-H2O) for High-Pressure Metapelites 总被引：5，自引：0，他引：5
Petrogenetic grids in the system NCKFMASH (Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O)and the subsystems NCKMASH and NCKFASH calculated with the softwareTHERMOCALC 3.1 are presented for the P–T range 7–30kbar and 450–680°C, for assemblages involving garnet,chloritoid, biotite, carpholite, talc, chlorite, kyanite, staurolite,paragonite, glaucophane, jadeite, omphacite, diopsidic pyroxene,plagioclase, zoisite and lawsonite, with phengite, quartz/coesiteand H2O in excess. These grids, together with calculated compatibilitydiagrams and P–T and T–XCa and P–XCa pseudosectionsfor different bulk-rock compositions, show that incorporationof Ca into the NKFMASH system leads to many of the NKFMASH invariantequilibria moving to lower pressure and/or lower temperature,which results, in most cases, in the stability of jadeite andgarnet being enlarged, but in the reduction of stability ofglaucophane, plagioclase and AFM phases. The effect of Ca onthe stability of paragonite is dependent on mineral assemblageat different P–T conditions. The calculated NCKFMASH diagramsare powerful in delineating the phase equilibria and P–Tconditions of natural pelitic assemblages. Moreover, contoursof the calculated phengite Si isopleths in P–T and P–XCapseudosections confirm that phengite barometry in NCKFMASH isstrongly dependent on mineral assemblage. KEY WORDS: phase relations; metapelites; NCKFMASH; THERMOCALC; phengite geobarometry 相似文献
19.
To elaborate physicochemical models for the origin of crystalline rocks, experimental studies of the field of high-alumina assemblages of the system CaO–MgO–Al2O3–SiO2 were carried out at 10–30 kbar and 1250–1535 °C. We have determined the phase relations between the melt (L) and An, Sp, Cpx, Cor, and Ga, the slope of the rays of the monovariant reactions An + Sp = Cpx + Cor + (Ga) and L = Cpx +Ga + Cor + Sp, the position of the nonvariant point (An, Sp, Cpx, Cor, Ga, L), and the compositions of phases participating in these reactions. Based on a topological analysis of the studied segment of the system CaO–MgO–Al2O3–SiO2, we have substantiated that “eclogitization” must follow the reaction Opx + An + Sp = Cpx + Ga. A fundamental continuous series of eutectic monovariant equilibria was observed: L = Cpx + Opx + Fo + An, L = Cpx + Opx + An + Sp, L = Cpx (+ Ga) + An + Sp, and L = Cpx + Cor (+ Ga) + An. A change in the melt composition in this series of eutectic reactions depending on pressure must reflect the most likely magma genesis trend in nature. Comparision of the composition fields in which the above series of reactions is observed with the composition fields of the rocks of magmatic formations showed that this series is most similar to the alkali-earth series of rocks. The mineralogical compositions of cumulates and phenocrysts found in the effusive and dike varieties of these rocks correspond to unique sets of subsolidus phase associations and individual subsolidus phases crystallizing in this fundamental eutectic series. 相似文献
20.
Melt inclusion and host glass compositions from the easternend of the Southwest Indian Ridge show a progressive depletionin light rare earth elements (LREE), Na8 and (La/Sm)n, but anincrease in Fe8, from the NE (64°E) towards the SW (49°E).These changes indicate an increase in the degree of mantle meltingtowards the SW and correlate with a shallowing of the ridgeaxial depth and increase in crustal thickness. In addition,LREE enrichment in both melt inclusions and host glasses fromthe NE end of the ridge are compatible with re-fertilizationof a depleted mantle source. The large compositional variations(e.g. P2O5 and K2O) of the melt inclusions from the NE end ofthe ridge (64°E), coupled with low Fe8 values, suggest thatmelts from the NE correspond to a variety of different batchesof melts generated at shallow levels in the mantle melting column.In contrast, the progressively more depleted compositions andhigher Fe8 values of the olivine- and plagioclase-hosted meltinclusions at the SW end of the studied region (49°E), suggestthat these melt inclusions represent batches of melt generatedby higher degrees of melting at greater mean depths in the mantlemelting column. Systematic differences in Fe8 values betweenthe plagioclase- and the olivine-hosted melt inclusions in theSW end (49°E) of the studied ridge area, suggest that theplagioclase-hosted melt inclusions represent final batches ofmelt generated at the top of the mantle melting column, whereasthe olivine-hosted melt inclusions correspond to melts generatedfrom less depleted, more fertile mantle at greater depths. KEY WORDS: basalt; melt inclusions; olivine; plagioclase; Southwest Indian Ridge 相似文献