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1.
藏北羌塘盆地东部地区三叠系巴贡组之上沉积超覆了一套火山岩-火山碎屑岩．该套地层下部玄武岩的锆石SHRIMPu—Pb年龄明显可以分为2组,一组年龄相对年轻（220．4Ma±2．3Ma）,代表了羌塘东部地区鄂尔陇巴组火山岩的喷发年龄;另外一组年龄相对较老（241．4Ma±3．6Ma）,可能与中三叠世羌塘地区普遍存在的碰撞隆升事件有关。羌塘中生代（晚三叠世-早白垩世）盆地演化早期的沉积作用经历了由陆相至海相的超覆过程,沉积超覆作用从冲洪积相开始,伴随着岩浆侵入、火山爆发及火山碎屑沉积作用,总体上表现为一个向上变深的海侵序列,显示裂谷盆地的特征。 相似文献
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羌塘中生代(T3-K1)盆地演化新模式 总被引：4，自引：0，他引：4
在羌塘盆地上三叠统那底岗日组陆相火山岩—沉火山碎屑岩及冲洪积相砂砾岩之下,作者发现了一个十分重要的古风化壳。该风化壳穿时超覆于肖茶卡组(T3上三叠统?)及其以下的二叠系及石炭系地层之上,沉积超覆于古风化壳之上的那底岗日组陆相火山岩—沉火山碎屑岩及冲洪积相砂砾岩代表了羌塘中生代(T3—K1,晚三叠世卡尼期至早白垩世时期)新一轮沉积作用的开启。采用SHRIMP锆石U-Pb同位素定年方法,作者在羌塘盆地胜利河地区和望湖岭地区分别获得了一组那底岗日组玻屑凝灰岩和晶屑凝灰岩的年龄,其值为216.8±2.1 Ma和217.3±2.5 Ma;这些同沉积年龄证据证实了羌塘中生代盆地的开启时间应该为晚三叠世卡尼—若利期。羌塘中生代盆地早期沉积作用经历了一个由陆相至海相的沉积超覆过程。伴随着岩浆侵入、火山爆发及火山碎屑沉积作用,沉积超覆作用是从冲洪积相开始。总体上,表现为一个向上由浅变深的海侵序列,显示为被动陆缘裂陷盆地特征。 相似文献
3.
康托组在羌塘南部地区分布广泛,是青藏高原始新世大规模隆升以后首先接受的陆相碎屑和火山沉积,以往根据时代跨度较大的生物化石将其时代确定为中新世,但一直存在争议。羌南走构由茶错康托组中呈层状出露的火山岩面积约120km2,主要岩性为玄武质粗面安山岩,保存有完好的火山口和火山颈。40Ar-39Ar积分年龄为30.5Ma±0.6Ma,K-Ar法年龄为33.3Ma±0.5Ma、29.3Ma±0.4Ma、32.3Ma±0.5Ma、28.4Ma±0.4Ma,为渐新世早期。结合区域上康托组与伴生火山岩的相互关系,确定走构由茶错、康托、鱼鳞山和纳丁错等地的火山岩是康托组的组成部分。根据走构由茶错火山岩同位素定年结果将康托组的时代由中新世厘定为渐新世,羌塘地区大规模隆升以后接受沉积的时间前推了大约10Ma。 相似文献
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1∶25万玛依岗日幅区域地质调查期间,在藏北戈木错北部发现了一套新生代钾质火山岩。对保存较好的3处火山岩的样品进行40Ar/39Ar年代学研究,获得了30.6Ma±0.4Ma、30.0Ma±0.2Ma和29.8Ma±0.3Ma三个坪年龄,代表该地区火山岩的喷溢时代。戈木错北部火山岩的地球化学特征与钾质火山岩的类似,它与鱼鳞山、走构由茶错、多格错仁等地区的新生代火山岩共同构成了羌塘地区钾质—超钾质火山岩带,它们的形成与印度大陆同亚洲大陆的碰撞和青藏高原的隆升密不可分。 相似文献
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最新地质调查与研究表明,赣东北江南次级盆地新元古界南华系是一套沉积超覆于基底变质岩系之上的裂谷系“楔状地层”。桃源组陆相火山岩及火山碎屑岩是该“楔状地层”的最低层位,代表了南华裂谷系江南次级盆地新一轮沉积旋回的起点。取自桃源组流纹岩样品的结晶锆石SHRIMP U Pb同位素年龄为803±9 Ma,这一年龄值基本上代表了该次级盆地新元古代盆地的开启时间。沉积相研究表明,江南次级盆地沉积作用主要由四个沉积相组合构成:（1）陆相火山岩组合;（2）冲洪积相及河湖相组合;（3）滨浅海-次深海相组合;（4）冰碛岩相组合。与扬子东南缘其它次级盆地相比,江南次级盆地沉积作用以陆相为主,但两者的剖面沉积演化序列非常相似,都经历了一个由陆相至海相的沉积超覆演化过程,代表了新元古代南华期华南古大陆解体之后扬子地块东南缘典型的裂谷盆地演化特征。 相似文献
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藏北北羌塘盆地那底岗日组时代归属的新证据 总被引：17，自引：9，他引：17
藏北北羌塘盆地那底岗日组是一套角度不整合于三叠系肖茶卡组灰岩之上、假整合伏于侏罗系雀莫错组陆源碎屑岩之下的一套陆相火山岩夹火山碎屑岩及陆源碎屑岩地层,现有的资料都将其时代归属于早侏罗世。取自北羌塘盆地不同地区的2个那底岗日组流纹质晶屑凝灰岩和1个流纹质英安岩样品的SHRIMP锆石U-Pb定年结果分别为205Ma±4Ma、208Ma±4Ma和210Ma±4Ma,它们代表了那底岗日火山岩的形成时代,即那底岗日组的时代应为晚三叠世中期(诺利期)。那底岗日组形成时代的重新确定,对于重新认识羌塘盆地中生代火山喷发事件、羌塘盆地的性质与沉积构造演化具有重要意义。 相似文献
8.
黔东南1∶5万高武幅、宰便幅区域地质调查结果表明,新元古界下江群是一套沉积超覆于中元古界四堡群之上的裂谷系楔状地层,其底部甲路组沉积底砾岩高角度(不整合)沉积超覆于四堡群复理石浊积岩之上,或沉积超覆于侵入四堡群之中的摩天岭花岗岩之上。取自该地区沉积超覆面之下摩天岭花岗岩样品的TIMS锆石U-Pb同位素年龄为825.0±2.4Ma,表明该地区新元古代裂谷系开始接受沉积的时间应该晚于825±2.4Ma;而取自沉积超覆面之上甲路组底部同沉积基性火山岩样品的TIMS锆石U-Pb同位素年龄为814±13Ma,这一年龄大致代表了该地区新元古代沉积超覆的开启时间,且与目前已获得的华南其它地区新元古代裂谷系沉积超覆的开启时间(820Ma)十分接近。本项研究成果支持华南裂谷系沉积超覆的开启时间为820Ma左右的观点。 相似文献
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东天山企鹅山群火山岩锆石U-Pb年代学 总被引：24，自引：2，他引：24
企鹅山群是指分布于东天山觉罗塔格地区康古尔塔格断裂和大草滩断裂之间的一套火山-沉积岩系。新近发现的土屋-延东大型斑岩型铜矿含矿斑岩的围岩为企鹅山群第二组的火山岩系,同时由于该火山岩系与其上覆和下伏岩系均呈断层接触,因而企鹅山群火山岩的形成时代备受关注。对该火山岩系组合中的基性火山岩和酸性火山岩进行锆石U-Pb同位素年龄测定,测得基性火山岩的成岩年龄为322.6Ma±2.0Ma,酸性火山岩的成岩年龄为319.9Ma±1.6Ma。该年龄对认识东疆地区石炭纪构造演化历史和成矿作用具有重要价值。 相似文献
10.
内蒙古林西地区上二叠统林西组砂岩碎屑锆石的年龄及其大地构造意义 总被引：1，自引：0，他引：1
林西地区林西组的主体岩性以碎屑岩为主,对其中代表性岩石组合——长石石英砂岩进行了年代学研究。 50粒碎屑锆石样品的LA-ICP-MS U-Pb年代学测试结果显示2个主要年龄区间：(256±2～322±3)Ma,峰值年龄为279Ma±2Ma;(357±7～497±4)Ma,峰值年龄为441Ma±3Ma。另有3颗锆石的年龄分别为797Ma±6Ma、1413Ma±38Ma、1661Ma±24Ma。其中256 Ma±2Ma的年龄限定了林西组原岩年龄应为晚二叠世;第二组年龄(357±7～497±4)Ma,峰期年龄441Ma±3Ma,与东北地区的主要泛非期事件年龄一致,表明主要的物源区为东北地块(佳蒙地块)。而797Ma±6Ma、1413Ma±38Ma、1661Ma±24Ma等年龄反映了东北地块基底年龄的信息。这些年龄数据表明, 林西组应为东北地块的一部分,并进一步限制了华北与西伯利亚两大板块的缝合线应位于林西组发育地区的南部,即西拉木伦河断裂,而拼合时代应晚于晚二叠世,可能为早三叠世。 相似文献
11.
E. M. Prasolov S. A. Sergeev B. V. Belyatsky E. S. Bogomolov K. A. Gruzdov I. N. Kapitonov R. Sh. Krymsky V. O. Khalenev 《Geochemistry International》2018,56(1):46-64
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others. 相似文献
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奥地利安东帕有限公司 《岩矿测试》2009,28(3):306-306
最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提 相似文献
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S. Viswanathan K. Surya Prakash Rao B. Mahabaleswar 《Journal of the Geological Society of India》2013,82(6):621-627
Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours. 相似文献
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《Applied Geochemistry》2001,16(2):137-159
Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km2 area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population). 相似文献
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《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l− 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2. 相似文献
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S. M. Moosavirad J. Rasouli M. R. Janardhana M. R. Moghadam M. Shankara 《Arabian Journal of Geosciences》2013,6(10):3623-3634
This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds. 相似文献
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Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations. 相似文献