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1.
在夏日多矿区识别出始新世黑云母二长花岗斑岩和石英闪长玢岩,确定其结晶年龄分别为41.6±0.3～41.7±0.3Ma和41.1±0.2～41.2±0.2Ma。首次在夏日多矿区厘定出始新世岩浆活动事件,并认为该矿区铜-钼成矿作用与该期构造-岩浆活动事件有关。岩石地球化学特征显示,黑云母二长花岗岩与石英闪长玢岩具有较一致的地球化学特征,均具有略高的SiO_2、富K_2O和Na_2O、较高的K_2O/Na_2O值及较低的TFeO含量,属于弱过铝质的高钾钙碱性-钾玄岩系列;相对亏损K、Ba、Nb、P、Ti,富集Th、U、Sr、Hf,具有高分异I型花岗岩特征;具高的Zr/Hf、Rb/Sr值和较低的Ti/Eu值。夏日多斑岩的形成与印度-亚洲大陆的陆-陆碰撞诱发大规模走滑系统引起下地壳拆沉,使软流圈物质上涌,引发富集地幔的部分熔融,产生的富集地幔岩浆上升底侵,并发生壳幔物质混染有关。  相似文献   

2.
马厂箐矿集区铜、钼、金矿化之间的关系对于认识该矿床的成矿作用过程及地质勘查具有重要意义。利用40Ar-39Ar同位素定年方法对乱硐山矿段夕卡岩型铜钼金矿化和人头箐矿段蚀变岩型金矿石中热液白云母进行同位素定年,得到夕卡岩化矿石中白云母样品(B119)40Ar-39Ar坪年龄为35.25±0.36Ma,等时线年龄为35.0±1.8Ma,反等时线年龄为34.8±1.9Ma。蚀变岩型金矿化矿石中白云母样品(B118)40Ar-39Ar坪年龄为35.35±0.32Ma,等时线年龄为34.44±0.99Ma,反等时线年龄为34.4±1.2Ma。这与正长斑岩(35.6±0.3Ma)、花岗斑岩(35.0±0.2Ma)、斑岩型铜钼矿化成矿年龄(35.8±1.6Ma)和(33.9±1.1Ma)较为一致,显示马厂箐铜钼金矿床与正长(斑)岩+二长(斑)岩+花岗斑岩+斑状花岗岩岩性组合有关,铜钼金成矿属于同一个构造—岩浆—成矿系统的产物。  相似文献   

3.
对永甸地区的辽吉花岗岩进行年代学和地球化学分析。锆石U-Pb定年结果表明,永甸花岗岩形成于(2 180.4±5.3)Ma。永甸花岗岩富Si(SiO_2=72.20%~73.54%),富碱(K_2O+Na_2O=7.83%~8.35%),贫Ca、Mg、Al(CaO=0.28%~1.37%,MgO=0.07%~0.14%,Al_2O_3=12.22%~12.88%)。稀土配分模式曲线为右倾型,有较强的负Eu异常(Eu/Eu*=0.38~0.69)和较高的Ga/Al比值,而且岩体富集Zr、U、Y等高场强元素以及Rb、K等大离子亲石元素,贫Ba、Sr等元素,这些特征表明永甸花岗岩属于A_2型花岗岩。根据岩石地球化学特征,认为永甸花岗岩形成于弧后盆地环境,来源于减薄下地壳岩石的部分熔融。  相似文献   

4.
马厂箐矿集区铜、钼、金矿化之间的关系对于认识该矿床的成矿作用过程及地质勘查具有重要意义.利用40 Ar-39 Ar同位素定年方法对乱硐山矿段夕卡岩型铜钼金矿化和人头箐矿段蚀变岩型金矿石中热液白云母进行同位素定年,得到夕卡岩化矿石中白云母样品( B119)40 Ar-39 Ar坪年龄为35.25±0.36 Ma,等时线年龄为35.0±1.8 Ma,反等时线年龄为34.8±1.9 Ma.蚀变岩型金矿化矿石中白云母样品(B118)40 Ar-39 Ar坪年龄为35.35±0.32 Ma,等时线年龄为34.44±0.99Ma,反等时线年龄为34.4±1.2 Ma.这与正长斑岩(35.6±0.3 Ma)、花岗斑岩(35.0 ±0.2 Ma)、斑岩型铜钼矿化成矿年龄(35.8 ±1.6 Ma)和(33.9土1.1 Ma)较为一致,显示马厂箐铜钼金矿床与正长(斑)岩+二长(斑)岩+花岗斑岩+斑状花岗岩岩性组合有关,铜钼金成矿属于同一个构造—岩浆—成矿系统的产物.  相似文献   

5.
滇西剑川富碱岩浆岩位于青藏高原东南缘的三江南段,是金沙江-红河富碱岩浆岩带的重要组成部分。剑川富碱岩浆岩包括花岗岩和正长岩两类岩石,前者主要有花岗斑岩和石英二长斑岩,后者主要是正长斑岩和粗面岩。本文对剑川富碱岩浆岩进行了主微量元素、锆石U-Pb年代学和Sr-Nd-Hf同位素特征研究。锆石U-Pb测年结果显示,剑川花岗岩结晶年龄为35. 1～36. 1Ma,正长岩结晶年龄为35. 7～35. 8Ma,均形成于始新世。花岗斑岩和石英二长斑岩的SiO_2含量为67. 92%～69. 93%,K_2O/Na_2O比值介于0. 86～1. 22,具有高钾钙碱性特征;正长斑岩和粗面岩的SiO_2含量为53. 94%～63. 51%,K_2O/Na_2O比值介于1. 30～2. 68,属于钾玄质岩石系列。两类岩石都富集轻稀土元素(LREE)和大离子亲石元素(LILE),相对亏损高场强元素(HFSE)。其中,花岗斑岩和石英二长斑岩有着较高的Sr、Sr/Y、La/Yb值和低的Y、Yb含量,具有埃达克质岩浆属性。结合Sr-Nd-Hf同位素研究认为,滇西剑川地区花岗岩起源于增厚的镁铁质新生下地壳部分熔融,正长岩是由交代富集的岩石圈地幔熔融产生的基性岩浆演化而来的产物。滇西剑川新生代富碱岩浆活动是对印度与欧亚板块晚碰撞阶段,岩石圈地幔发生对流减薄和软流圈物质上涌过程的响应。  相似文献   

6.
打古贡卡斑岩型铜钼矿位于青海省南部三江北段,属青海省重要的斑岩型铜钼矿成矿带中。本文对打古贡卡含矿花岗斑岩体进行了LA-ICP-MS U-Pb测年,获得(240.1±0.89)Ma的年龄值,属中三叠世。含矿斑岩的SiO_2含量为65.18%～70.43%,K_2O为3.05%～6.76%,Na_2O为1.99%～3.47%,富SiO_2、K2O、Na_2O为特点,相对贫Fe、Mg、Ca,里特曼指数为1.09～4.29,铝饱和指数ASI=1.01～1.23,总体表现为弱过铝质到强过铝质高钾钙碱性系列岩石的特征;微量元素配分曲线总体呈右倾型,大离子亲石元素(LILE)富集,高场强元素(HFSE)亏损,具有较弱的Eu负异常。通过岩体地质特征、岩石学及岩石地球化学特征结合区域构造演化特点初步确定打古贡卡中三叠世花岗斑岩形成于俯冲阶段。该岩体的发现具有较为重要的科学意义,为重新认识"三江"北段斑岩型矿床的成矿时代和形成背景提供了新的线索和依据。  相似文献   

7.
张翔  于文修  刘利超 《矿产与地质》2016,(4):561-567,597
岩石地球化学分析表明小龙潭斑岩高钾(K_2O/Na_2O=0.85~8.39)、富碱(K_2O+Na_2O=9.05%~12.45%),总体属于钾玄岩系列的岩石。岩石富集Rb、Ba、Th、LREE等大离子亲石元素而亏损Ti、Nb、Ta、HREE等高场强元素,具有较高的ΣLREE/ΣHREE比值和(La/Yb)N比值,具中等程度Eu负异常。从岩石地球化学特征分析,小龙潭富碱斑岩起源于金沙江洋壳俯冲交代作用形成的富集地幔,富碱斑岩可能与Cu、Mu、Ag成矿作用密切相关。  相似文献   

8.
位于东准噶尔北缘的索尔库都克铜钼矿床,一直以来被认为属于一个与辉石闪长玢岩有关的层控夕卡岩型矿床。笔者在矿区露天采场及勘探钻孔调查中发现该矿床的成矿母岩可能为粗面英安斑岩,粗面英安斑岩多发育脉状和浸染状铜、钼矿化,且由浅部到深部热液活动逐渐加强,显示其与成矿关系密切：粗面英安斑岩的K2O＋N2O为9．38％～10．3％、K2O／Na2O为2．63～3．17、A／CNK为0．89～0．98,属准铝质、富钾碱性岩系列,为I型花岗岩：微量元素方面,相对富集Rb、Ba和K等大离子亲石元素和强不相容元素（如U和Xh）,有明显Sr、Ti、Nb和Ta的亏损,与岛弧型花岗岩的特征一致：粗面英安斑岩的（87Sr／86Sr）i为0．70100～0．70384,（143Nd／144Nd）j为0．512387～0．512436,CNd（t）为（＋4．8～＋5．8）,T2DM为663～741Ma,显示其可能源于地幔楔部分熔融。  相似文献   

9.
三岔口铜矿床位于新疆东天山大南湖岛弧带的东北缘。目前对于三岔口铜矿床的成因类型及成矿年代还存在争议。三岔口铜矿床中赋矿岩体为闪长岩-花岗闪长岩,发育黑云母化、硅化、绢英岩化、青磐岩化等。测得三岔口铜矿床辉钼矿Re-Os年龄为416Ma±6.4 Ma,含矿闪长岩中锆石LA-ICP-MS U-Pb年龄为425 Ma±3.9 Ma,反映该矿床形成于中志留世。矿区内闪长岩-花岗闪长岩w(Na_2O+K_2O)为3.88%~4.68%,A/NCK值均大于1,为铝饱和岩石。岩体贫钾(w(K_2O)0.47%~1.18%)富钠(w(Na_2O)_2.83%~4.23%),w(TiO_2)偏低(0.41%~0.46%),多属于低钾拉斑系列。岩体富集w(Ba)(260×10~(-6)~4 810×10~(-6)),w(Sr)(644×10~(-6)~797×10~(-6))等大离子亲石元素,亏损w(Nb)(2.1×10~(-6)~2.6×10~(-6)),w(Ta)(0.1×10~(-6)),w(Zr)(11.2×10~(-6)~13.1×10~(-6))等高场强元素,具岛弧岩浆岩的特征。岩体富Na贫K,K_2O/Na_2O0.42,且具有高w(Al_2O_3)(≥16.65%),w(SiO_2)(≥61.3%),w(Sr)(≥644×10~(-6))以及较低的w(Y)(≤13.7×10~(-6))和w(Yb)(≤1.41×10~(-6)),具O型埃达克岩的特征,表明三岔口铜矿床形成于俯冲岛弧环境。结合研究区域内铜(钼)矿床的成矿时代及矿床类型,得出东天山地区有三期斑岩型矿床成矿作用:志留纪的三岔口、玉海斑岩型铜矿床,石炭纪的土屋-延东、延西等斑岩型铜矿床,以及三叠纪的东戈壁、白山斑岩型钼矿床。  相似文献   

10.
北金齐地区出露一套英安斑岩,内部及周缘发育钾化到青磐岩化蚀变带,部分地段见孔雀石化,指示深部可能存在斑岩型铜矿化。为进一步评价该区找矿潜力,对该区英安斑岩进行锆石U-Pb年代学、微量元素、Hf同位素和全岩地球化学研究,结果显示,英安斑岩锆石~(206)Pb/~(238)U加权平均年龄为(305.6±1.3)Ma;岩石富Si O_2、Al_2O_3,贫Mg O、Ca O、Ti O_2,属准铝质-过铝质高钾钙碱性岩石。英安斑岩整体上富集轻稀土和大离子亲石元素,亏损高场强元素,具弱负铕异常和较高ε_(Hf)(t)值(15.7～19.5)。综合研究表明,英安斑岩应源于后碰撞伸展环境下新生地壳的部分熔融。锆石微量元素结果指示,英安斑岩氧逸度高于铁橄榄石-磁铁矿-石英缓冲线两个对数单位,该岩体有利于斑岩型矿床的形成。综合研究区矿化-蚀变及英安斑岩地球化学特征,认为北金齐地区具较大的斑岩型矿床找矿潜力。  相似文献   

11.
The physico-chemical conditions under which the pegmatite dyke No.3 was formed were discussed in the light of fluid-melt inclusion evidence.Our results lend support to the fractionation of hydrothermal solutions from magma,For the pegmatite dike No.3,the magmaderived hydrothermal solutions are dominated by NaCl CO2 H2O.  相似文献   

12.
Abstract The metamorphic history of the Archaean Superior Province crystalline basement in the Palaeoproterozoic Ungava Orogen attests to the importance of structural and geohydrological controls on a retrograde amphibolite-granulite transition. Two distinct metamorphic suites, separated in age by nearly one billion years, are recognized in extensively exposed tonalitic to dioritic metaplutonic gneisses. The older suite comprises c. 2.7-Ga granulite facies assemblages (orthopyroxene-clinopyroxene-hornblende-plagioclase-ilmenite ± biotite ± quartz) that record moderate pressures (±5 kbar) and high temperatures (±800° C). A younger, c. 1.8-Ga suite resulted from amphibolitization of the granulites and is characterized by regionally extensive amphibolite facies mineral zones that broadly parallel the basal décollement of the overlying Proterozoic Cape Smith Thrust Belt. Deformation/mineral growth relationships in the amphibolitized basement indicate that extensive hydration and re-equilibration of the Archaean granulites occurred during thrust belt deformation. The transition from granulite facies to amphibolite facies assemblages is characterized by the growth of garnet-hornblende-quartz ° Cummingtonite coronas between plagioclase and orthopyroxene-clinopyroxene, as well as titanite coronas on ilmenite. Multi-equilibrium thermobarometry on the coronitic assemblages documents re-equilibration of the granulitic gneiss to 7.7 kbar at 644° C in the south and 9.8 kbar at 700° C in the north. The variably deformed, amphibolite facies domain sandwiched between the coronitic garnet zone and the basal décollement is marked by significant metasomatic changes in major element concentrations within tonalite. These changes are compatible with equilibrium flow of an aqueous-chloride fluid down a temperature gradient. The source of fluids for basement hydration/metasomatism is interpreted to be dehydrating clastic rocks in the overlying thrust belt, with fluid flow probably focused along the basal décollement.  相似文献   

13.
西藏南部聂拉木—定日地区沉积地层记录着侏罗纪被动大陆边缘到白垩纪前陆盆地的盆—山转换演化历史。侏罗纪发育巨大的海侵—海退沉积序列，晚侏罗世喜马拉雅特提斯海底扩张速度明显加快，从0.32 cm/a上升为1.24 cm/a。前陆盆地演化分为早期深水复理石和晚期海相磨拉石两个阶段。前陆早期发育向上急剧加深的深水砂泥质复理石建造、黑色页岩建造和岛弧型火山岩建造沉积；前陆晚期海相磨拉石沉积总体表现为向上变粗、变浅的沉积序列。  相似文献   

14.
Footwall rocks of the northern Snake Range detachment fault (Hampton and Hendry's Creeks) offer exposures of quartzite mylonites (sub-horizontal foliation) that were permeated by surface fluids. An S–C–C′ mylonitic fabric is defined by dynamically recrystallized quartz and mica. Electron backscatter diffraction analyses indicate a strong preferred orientation of quartz that is overprinted by two sets of sub-vertical, ESE and NNE striking fractures. Analyses of sets of three perpendicular thin sections indicate that fluid inclusions (FIs) are arranged according to macroscopic fracture patterns. FIs associated with NNE and ESE-striking fractures coevally trapped unmixed CO2 and H2O-rich fluids at conditions near the critical CO2–H2O solvus, giving minimum trapping conditions of T = 175–200 °C and ∼100 MPa H2O-rich FIs trapped along ESE-trending microcracks in single crystals of quartz may have been trapped at conditions as low as 150 °C and 50 MPa indicating the latest microfracturing and annealing of quartz in an overall extensional system. Results suggest that the upper crust was thin (4–8 km) during FI trapping and had an elevated geotherm (>50 °C/km). Footwall rocks that have been exhumed through the brittle-ductile transition in such extensional systems experience both brittle and crystal-plastic deformation that may allow for circulation of meteoric fluids and grain-scale fluid–rock interactions.  相似文献   

15.
九瑞地区中生代岩浆活动及其大地构造意义   总被引：2，自引：0，他引：2  
通过对该地区中生代不同时期形成的花岗岩的研究,认为该区主成矿期前(160~200 Ma)形成C型埃达克岩,这时的地壳是增厚的地壳(>40 km),随后在该地区的软流圈地幔上涌和岩石圈的伸展减薄作用过程中,形成I型花岗岩(130~160 Ma)及其有关矿床,达到该地区铜金成矿高峰期,随着地壳减薄作用进一步加强,岩浆活动和成矿作用减弱。不但强调I型花岗岩的成矿专属性,而且也强调成矿时间、大地构造环境转换期成矿。  相似文献   

16.
Electronic and magnetic properties of tennantite subfamily of tetrahedrite-group minerals have been studied by copper nuclear quadrupole resonance (NQR), nuclear magnetic resonance (NMR) and SQUID magnetometry methods. The temperature dependences of copper NQR frequencies and line-width, nuclear spin-lattice relaxation rate T 1−1 and nuclear spin-echo decay rate T 2−1 in tennantite samples in the temperature range 4.2–210 K is evidence of the presence of field fluctuations caused by electronic spins hopping between copper CuS3 positions via S2 bridging atom. The analysis of copper NQR data at low temperatures points to the magnetic phase transition near 65 K. The magnetic susceptibility in the range 2–300 K shows a Curie–Weiss behavior, which is mainly determined by Fe2+ paramagnetic substituting ions.  相似文献   

17.
高岭石,铝土矿共生及相变的热力学讨论   总被引：1，自引：0，他引：1  
李明德 《矿物岩石》1991,11(2):85-88
根据热力学计算,在常温常压下,铝土矿物能与石英自发反应生成高岭石;硬水铝石和三水铝石都能自发转变为勃姆石,三者可以共生;硬水铝石会自发相变为勃姆石,可能为原生的;在沉积和成岩期的环境下,SiO_2和铝土矿均能化合生成高岭石。  相似文献   

18.
The heat capacity of synthetic ferrosilite, Fe2Si2O6, was measured between 2 and 820 K. The physical properties measurement system (PPMS, Quantum Design®) was used in the low-temperature region between 2 and 303 K. In the temperature region between 340 and 820 K measurements were performed using differential scanning calorimetry (DSC). The C p data show two transitions, a sharp λ-type at 38.7 K and a small shoulder near 9 K. The λ-type transition can be related to collinear antiferromagnetic ordering of the Fe2+ spin moments and the shoulder at 10 K to a change from a collinear to a canted-spin structure or to a Schottky anomaly related to an electronic transition. The C p data in the temperature region between 145 and 830 K are described by the polynomial $C_{p} {\left[ {\hbox{J\,mol}^{{ - 1}}\,{\hbox{K}}^{{ - 1}} } \right]} = 371.75 - 3219.2T^{{ - 1/2}} - 15.199 \times 10^{5} T^{{ - 2}} + 2.070 \times 10^{7} T^{{ - 3}} $ The heat content [H 298 – H 0] and the standard molar entropy [S 298 – S 0] are 28.6 ± 0.1 kJ mol?1 and 186.5 ± 0.5 J mol?1 K?1, respectively. The vibrational part of the heat capacitiy was calculated using an elastic Debye temperature of 541 K. The results of the calculations are in good agreement with the maximum theoretical magnetic entropy of 26.8 J mol?1 K?1 as calculated from the relationship 2*Rln5.  相似文献   

19.
This paper considers the impact of the Younger Dryas on the prehistoric inhabitants of Pont d'Ambon, a site in the Dordogne region of southwestern France, through an examination of the zooarchaeological remains from this site. An investigation of patch choice indicates that patch choice evenness declines during the Younger Dryas due to increasing local dominance of the grassland patch. Analyses of demographic composition, cutmark frequency, and marrow processing in the wild European rabbit (Oryctolagus cuniculus) assemblage suggest intensified rabbit use during this period. This study thus supports the hypothesis that changing climate had significant impacts on the prehistoric inhabitants of Pont d'Ambon. However, the traditional climate hypothesis—that changing climate negatively impacted the availability of larger fauna, forcing a switch to smaller, lower-ranked prey items—is not supported here. The inhabitants of Pont d'Ambon seem to have adapted to changing climate by efficiently exploiting the new species available to them, and possibly, during the Younger Dryas, by intensifying their use of one of these new species, the European rabbit.  相似文献   

20.
The first pressure derivatives of the second-order elastic constants have been calculated for brucite, Mg(OH)2 from the second- and third-order elastic constants. The deformation theory and finite strain elasticity theory have been used to obtain the second- and third-order elastic constants of Mg(OH)2 from the strain energy of the lattice. The strain energy ϕ is calculated by taking into account the interactions up to third nearest neighbors in the Mg(OH)2 lattice. ϕ is then compared with the strain dependent lattice energy from continuum model approximation to obtain the expressions of elastic constants. The complete set of six second-order elastic constants C IJ of brucite exhibits large anisotropy. Since C 33 (= 21.6 GPa), which corresponds to the strength of the material along the c-axis direction, is less than the longitudinal mode C 11 (= 156.7 GPa), the interlayer binding forces are weaker than the binding forces along the basal plane of Mg(OH)2. The 14 nonvanishing components of the third-order elastic constants, C IJK , of brucite have been obtained. All the C IJK of brucite are negative except the values of C 114 (= 230.36 GPa), C 124 (= 75.45 GPa) and C 134 (= 36.98 GPa). The absolute values of the C IJK are, in general, one order of magnitude greater than the C IJ ’s in the Mg(OH)2 system as usually expected for a crystalline material. To our knowledge, no previous data are available to compare the pressure derivatives of brucite. The pressure derivatives of the two components viz., C 14 and C 33 become negative indicating an elastic instability in brucite while under pressure. This may be related to the phase transition of brucite largely involving rearrangements of H atoms revealed in the Raman spectroscopic, powder neutron diffraction and synchrotron X-ray diffraction studies.  相似文献   

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