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1.
Collected by means of a high-altitude scientific balloon and a self-made automatic sample collector,a total of 276 dust grains were selected for the study of shape,grain size and optical property.Some of the grains were examined by X-ray diffraction and electrom microprobe techniques,The stratospheric dust grains can be classified as 6 types:cosmic dusts,cosmic dusts(?),microtektite,natural pollutants,artificial pollutants and the unknown substances.The different types of dust grains have different characters and distinguishing symbols.Widespread in the space of the solar system,cosmic dusts are the initial substances of the solar system and ,to some degree,have recorded a great wealth of information on the early history of the solar system.So they have become one of the important objects in the field of cosmochemistry at present time,Since the 1960‘s,scholars of many countries have collected cosmic dusts both in the space near the earth(using rock ets,space probes and space shuttles)and in the stratosphere (using high-altitude balloons or U-2air planes).According to the shape(the scanning electron microimage),element composition(the energy-dispersive X-ray spectrum)and optical properties of dust grains,the substances in the stratosphere can be classified as 5 types:cosmic dusts,alumina spheroids,terrestrial artificial pollutants,terrestrial natural pollutants and unknown substances(CDPET,1982). 相似文献
2.
民用燃煤烟尘特征及环境矿物材料固硫剂开发 总被引：9，自引：0，他引：9
通过对北京某地区居民炊事用型煤和散装烟煤煤岩和元素分析 ,表明烟煤和型煤含碳量分别为 70 %和 5 9% ,烟煤中可燃性高变质活性组分为 87% ,而型煤有较高的粘土成分 ,约达 2 0 %。对它们燃烧产生的烟尘进行物相分析、组分定量、粒度测试、显微形貌和微观结构等矿物学研究 ,表明型煤和烟煤的烟尘均含有较高碳质组分 ,分别占 2 5 %和 2 8% ;烟煤烟尘只有型煤烟尘含更高的烧蚀残渣 ,两者的粘土 (包括石英等矿物 )类组分均相当多 ,约占 5 0 % ;烟尘平均粒径都很小 ,型煤烟尘只有烟煤烟尘的 1/ 4左右 ,约为 6 5 μm ,而比表面积大 2倍多 ;烟煤烟尘呈碎屑状 ,型煤烟尘为粉末状 ;烟尘中均含有较多的均质体 ,并有铁质侵染现象 ;石英小颗粒在烟尘中大量存在。为促使燃煤充分燃烧 ,达到固硫、助燃和降尘的目的 ,本实验室开发研制了效果良好的民用燃煤环境矿物材料固硫添加剂 ,并对山东肥城高硫烟煤进行了型煤固硫实验 ,在 85 0℃ ,95 0℃和 10 5 0℃燃烧条件下固硫率高于目前国内同类水平 ,固硫率达 70 % 80 %。 相似文献
3.
The paper presents the results of investigations of physical and chemical properties of after reclamation dust that is generated in the foundry industry. Universally applied mechanical reclamation processes of spent moulding sands generate large amounts of after-reclamation dusts containing mainly rubbed spent binding agents and quartz dusts. An amount of after-reclamation dusts—in dependence of the reclamation system efficiency and the reclaim dedusting system—can reach 5–10 % in relation to the total reclaimed spent moulding sand. After-reclamation dusts originated from spent moulding sands with different kinds of resins mostly belong to dangerous wastes, since they contain chemo-setting binders with dangerous substances removed in the reclamation process. None of the companies producing mechanical reclamation systems offers presently the complex technology and equipment for utilisation of after reclamation dusts, which would meet technical and economic expectations of foundry plants. The paper presents the results of research carried out at the Faculty of Foundry Engineering AGH UST in Cracow which aims on the determination of possibilities of using the post-reclamation dust generated during mechanical reclamation of used moulding sands with organic resins as a source of energy. Different dusts generated in the mechanical reclamation process of used organic sands, delivered from foundries, were tested to determine their chemical composition, granular characterisation and physicochemical properties. As a result of the investigations, possible ways to utilise the dusts are presented. 相似文献
4.
François Prognon Isabelle Cojan Pascal Kindler Michel Demange 《Quaternary Research》2011,75(1):256-266
The alternation of carbonate deposits and paleosols compose the emerged part of the Bermuda archipelago. The pedological units present a complex and diversified mineralogy. Former studies demonstrated that the paleosols are not primarily a product of the unique dissolution of the surrounding carbonates, but contain a massive input of allochthonous non-carbonate detrital material. Researchers during more than the past three decades have attributed this flux of insoluble residues (IR) to Saharan dusts. We carried out systematic field and mineralogical analyses on the Quaternary paleosols from the Bermuda archipelago. Their mineralogical assemblage predominantly includes carbonates, clay minerals (kaolinite, chlorite and chlorite/vermiculite), phosphates, and aluminium and iron oxides/hydroxides. This assemblage is strikingly close to the mineralogy of the weathered volcanic substrate of Bermuda, but noticeably different from the mineralogy of Saharan dust. Moreover, we found volcanic lithoclasts in numerous paleosol profiles all over the archipelago and in all the recorded time intervals. We thus consider the volcanic seamount underlying Bermuda as the main source of non-carbonate minerals detected in the paleosols. This hypothesis further resolves the anomalous maturity of Bermudan paleosols compared to their southern counterparts in the Bahamas and Barbados. 相似文献
5.
《International Journal of Mineral Processing》2005,75(1-2):1-20
Recycling scrap iron and steel in electric arc furnaces (EAFs) generates very fine metal-containing dusts which can present major environmental problems. This paper describes experimental work on a relatively novel, simple, and inexpensive process for decreasing the chloride content and upgrading the zinc level of dust from an Australian plant, to produce saleable products and environmentally safe waste products for disposal.The dust contained about 2.1% Cl as various chlorides, 23.1% Zn as zincite and franklinite, 27.1% Fe as magnetite, franklinite, and hematite, plus small quantities of lead, cadmium, chromium, and other materials. The dust was very fine (P80 about 2 μm). Individual particles were commonly aggregates of fine spheres and other shapes.Simple water washing at ambient temperatures and natural pH (12) for 60 min extracted 99% of the chlorides, giving a residue assaying 200 ppm Cl. This residue was strongly coagulated by lime present in the dust and settled rapidly. The wash solution contained low levels of iron, zinc, lead, cadmium, and chromium, most of which could be removed by sulphide precipitation.Wet magnetic separation with a Davis tube was investigated. At the lowest field strength employed (0.6 A), 95% of the zinc was recovered in a non-magnetic product assaying 28% Zn and 24% Fe. At the highest field strength (1.6 A), 91% of the zinc was recovered in a non-magnetic product assaying 29% Zn and 25% Fe. Wet cycloning at a nominal separation size of 2–5 μm gave a cyclone overflow product assaying 31% Zn and 26% Fe, and containing 85% of the zinc. All these results fit a typical zinc grade–recovery relationship.The proposed process of water washing followed by magnetic separation or cycloning would produce a relatively high-zinc, low-iron, low-chloride product suitable for treatment in a lead–zinc smelter or electrolytic zinc plant, a high-iron, low-zinc product suitable for land fill, and a treated waste water for discharge to a sewer. 相似文献
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矿物纤维粉尘表面及体内外安全性评估研究 总被引：2，自引：0，他引：2
本项目探讨了天然纤维材料的表面化学活性—生物活性—生物持久性、生物毒性—环境安全性,试图寻求工业矿物、环境医学、材料价值的联合评估。研究工作对生物大分子静电配合物和阳离子配合物形成,对带电粉尘及其出溶阳离子的行为、粉尘及其衍生物与体液、细胞膜、胞内物质作用方式与细胞代谢有重要意义;也为粉尘毒性的可改造性及工业矿物纤维的安全处理提供了有效的途径;对阐明氨基酸蛋白质膜功能与结构,以及含有外露蛋白质的其它机体单元的粉尘溶解、反应、配合与破坏;粉尘中的硅成分在体内的残留、溶解、运移方式、硅肺的治疗和… 相似文献
8.
The entrainment, transport and deposition of æolian dust are important processes affecting soil development at the margins of deserts. To assess accurately the impact of deposited æolian dust on soil development, it is important not only to measure total dust deposition rates, but to distinguish additions of remotely and regionally sourced dust from locally derived material as well (which should not be viewed as new soil material as it is derived from æolian re‐mobilization of an existing soil). Because of the well‐established relationship between dust particle‐size and distance travelled from source, the particle‐size distribution of deposited dusts can be used to identify the distance to probable source regions, in addition to identifying matching topsoil particle populations. Three dust traps were located along a transect of semi‐arid south‐eastern Australia, to measure æolian dust deposition rates between late 2000 and late 2001. The particle‐size distributions of selected dust deposits were measured and, with the aid of meteorological data, probable dust source regions determined. Particle‐size distributions of the topsoils at each dust trap location were also measured to determine if any dust and soil particle populations matched. Although the sampling period was relatively short, and there was relatively little dust storm activity in this part of Australia during this time, a clear pattern of diminishing total dust deposition was measured downwind along the south‐east dust path. Dust deposition rates were also moderate to low by global standards. Source regions of deposited dust were interpreted as being: (i) a combination of south‐western and local sources; (ii) a combination of north‐western and local sources; and (iii) a mixed source where dust was rained‐out. The relative importance of these sources was correlated strongly with seasonal weather conditions, although the proportion of local dust in each deposit was greater at the arid (western) end of the transect. The effects of deposited dust on soil profile development are greatest at the western and central transect locations. At the western location, a fine‐grained particle population distinctive of the south‐western and north‐western regional dusts and a coarse silt‐sized particle population characteristic of local dusts, are also present in the topsoil, altering the texture of this Arenosol derived from dune sand. At the central location, where a Calcisol has formed in lacustrine lunette sediment, local dust of the same size as the dominant silt population of the topsoil continues to be deposited, while minor topsoil populations of very fine‐grained silt match regional and long‐distance dusts deposited at the site. Deposited dust appears to have been a less important soil development factor at the more humid eastern site because of the much smaller rates of dust deposition there. Nevertheless, a minor population of very fine silt particles in the Vertisol topsoil matches long‐distance dusts deposited at the site, suggesting a small input of dust to this alluvial soil. The particle‐size methodology used here has applications in other studies of dust contributions to peri‐desert soils. In particular, particle‐size distribution ‘smoothness’ may provide an indication of whether soils have simple or complex origins. 相似文献
9.
The application of mineralogical characterization to mine waste has the potential to improve risk assessment, guide appropriate mine planning for planned and active mines and optimize remediation design at closed or abandoned mines. Characterization of minerals, especially sulphide and carbonate phases, is particularly important for predicting the potential for acidic drainage and metal(loid) leaching. Another valuable outcome from mineralogical studies of mine waste is an understanding of the stability of reactive and metal(loid)-bearing minerals under various redox conditions. This paper reviews analytical methods that have been used to study mine waste mineralogy, including conventional methods such as X-ray diffraction and scanning electron microscopy, and advanced methods such as synchrotron-based microanalysis and automated mineralogy. We recommend direct collaboration between researchers and mining companies to choose the optimal mineralogical techniques to solve complex problems, to co-publish the results, and to ensure that mineralogical knowledge is used to inform mine waste management at all stages of the mining life cycle. A case study of arsenic-bearing gold mine tailings from Nova Scotia is presented to demonstrate the application of mineralogical techniques to improve human health risk assessment and the long-term management of historical mine wastes. 相似文献
10.
Morris RV Golden DC Bell JF rd Lauer HV Adams JB 《Geochimica et cosmochimica acta》1993,57(19):4597-4609
We have examined a Hawaiian palagonitic tephra sample (PN-9) that has spectroscopic similarities to Martian bright regions using a number of analytical techniques, including Mossbauer and reflectance spectroscopy, X-ray diffraction, instrumental neutron activation analysis, electron probe microanalysis, transmission electron microscopy, and dithionite-citrate-bicarbonate extraction. Chemically, PN-9 has a Hawaiitic composition with alkali (and presumably silica) loss resulting from leaching by meteoric water during palagonitization; no Ce anomaly is present in the REE pattern. Mineralogically, our results show that nanophase ferric oxide (np-Ox) particles (either nanophase hematite (np-Hm) or a mixture of ferrihydrite and np-Hm) are responsible for the distinctive ferric doublet and visible-wavelength ferric absorption edge observed in Mossbauer and reflectivity spectra, respectively, for this and other spectrally similar palagonitic samples. The np-Ox particles appear to be imbedded in a hydrated aluminosilicate matrix material; no evidence was found for phyllosilicates. Other iron-bearing phases observed are titanomagnetite, which accounts for the magnetic nature of the sample; olivine; pyroxene; and glass. By analogy, np-Ox is likely the primary pigmenting agent of the bright soils and dust of Mars. 相似文献
11.
Salt cakes, which are nominally waste products derived from aluminium dross melting furnaces, are complex mixtures of some 20 different compounds made up of many different elements. Normally they are regarded as waste products and they are disposed of in toxic waste dumps. However, it is shown here that some components are readily recoverable as high-grade products for recycling or sale and that the residues thus generated can be non-toxic. Recoverable components include metallic aluminium, salt (halite (NaCl) and sylvite (KCl)), alumina-containing compounds, and possibly hydrogen gas. 相似文献
12.
Associations between Pb, Zn, Fe and Mn in soils and indoor dusts in urban Syracuse, NY have been investigated at different levels of spatial aggregation. The concentrations of these elements of interest (EOI) in 3566 soil samples were mapped across the city to investigate variations in concentration potentially associated with specific city locations. Indoor floor dust loadings for the EOI determined at 433 residences were mapped in a similar fashion. Pearson product correlation coefficients at different levels of soil sample aggregation (individual sampling points, block group averages, and census tract (CT) averages), consistently demonstrated a strong correlation between soil Pb and Zn concentrations. Correlations between Pb and both Fe and Mn soil concentrations were also significant. However, the correlation between the Fe and Mn floor dust loadings was much stronger than that for soil, as were the correlations between the Pb and both the Fe and Mn dust loadings. The correlation between the Fe and Zn floor dust loadings was far less significant. Surprisingly, most of the correlations between the paired EOI in the dusts and soils at the individual homes were mostly not statistically significant. The two correlations of any significance, and these were between the Pb in soil and the Pb in the dust, and between Pb in dust and Zn in soil. 相似文献
13.
With the rise of shale oil and gas exploration and great success of North American shale oil and gas development in recent years, the study of gas shale reservoir pores gets more and more attention. The pore diameters of shale reservoirs are mainly in nano-scale which are different from conventional reservoirs, and they can not be evaluated by conventional methods. On the basis of the research on the classification of shale pore types and nanopore characterization techniques, qualitative and quantitative nanopore characterization methods were classified and summarized. In addition, the advantages and disadvantages of various methods as well as application scopes were summarized. Qualitative characterization methods can obtain the morphologic information, connectivity and filling conditions of shale pores directly by focused ion beam milling scanning electron microscopy, field emission scanning electron microscopy, transmission electron microscopy, broad ion beam scanning electron microscope, atomic force microscope and Nano-CT. Quantitative characterization methods can measure pore diameters, pore distribution and specific surface area by nitrogen adsorption experiments, carbon dioxide adsorption experiments, mercury injection experiments, small-angle neutron scattering, and nuclear magnetic resonance. The factors that control nanopore developments and the effects of nanopore on shale gas accumulation were discussed. The nanopore developments are related to total organic carbon content, clay minerals content, carbonate content and thermal maturity. Nanopores have influences on shale gas storage capacity, occurrences of shale gas and seepage mechanisms. Frontier research and development directions were proposed. In the aspect of nanopore characterization techniques of shales, the accuracy and efficiency of the experiments and three dimensional imaging technology should be improved constantly. Qualitative and quantitative characterization techniques should be combined. As to the evaluation of shale nanopore reservoirs, the factors that control nanopore developments, shale gas storing and producing and nanopores characterization and evaluation of continental heterogeneous shale are the key issues for further research. 相似文献
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纤粒矿物粉尘体外细胞毒性研究 总被引：6，自引：0，他引：6
采用体外细胞培养技术,观察兔肺泡巨噬细胞死亡率,用丙二醛（ＭＤＡ）的含量变化、乳酸脱氢酶（ＬＤＨ）及超氧化物歧化酶（ＳＯＤ）的活性变化来评价来自１２个矿６床的６种矿物的１２种结晶习性的矿物粉尘的细胞毒性,探讨其使巨噬细胞受损的机制。结果显示：沸石、硅灰石无细胞毒性,而其他的纤维状及片粒状矿物粉尘则表现出不同程度的细胞毒性,说明矿物粉尘的细胞毒性与矿物粉尘的形态有一定关系,但主要由矿物粉尘的特性所决 相似文献
16.
A. Zarasvandi E.J.M. Carranza F. Moore F. Rastmanesh 《Journal of Geochemical Exploration》2011,111(3):138-151
Dust storms in Khuzestan province (Iran) are causing problems in industries and human health. To mitigate the impact of those phenomena, it is vital to know the physical and chemical characteristics of airborne dusts. In this paper, we give an overview of the spatio-temporal occurrences and geochemical characteristics of airborne dusts in Khuzestan. Meteorological data from 10 stations in Khuzestan during 1996–2009 indicate (a) an average of 47 dust storm days per year, (b) a lowest annual average of 13 dust storm days in 1998, (c) a highest annual average of 104 dust storm days in 2008, and (d) an average increase of two dust storm days per year. Above-average number of dust storm days usually occurred in the cities of Dezful, Ahvaz, Masjed-e-Soleiman, Abadan and Bostan, whereas below-average number of dust storm days usually occurred in the cities of Mahshahr, Ramhormoz, Behbahan, Shoushtar and Izeh. XRD analyses of airborne dust samples collected in 2008 and 2009 show that the mineralogy of airborne dusts is dominated by calcite, followed by quartz and then kaolinite, with minor gypsum. SEM analyses of the samples indicate that airborne dusts have rounded irregular, prismatic and rhombic shapes. The sizes of airborne dusts vary from 2 to 52 μm, but 10 to 22 μm are the dominant sizes. The smallest and largest dust particles are clays, sulfates or carbonates. XRF and ICP analyses of the samples show that the most important oxide compositions of airborne dusts are SiO2, Al2O3, Fe2O3, CaO and MgO. Estimates of enrichment factors (EF) for all studied elements show that Mn, Hf, U, Sc, K, V and Sr, with EF < 10, are of natural origin, whereas Na, Ni, Co, Ba and Cr, with EF > 10, are of anthropogenic origin. Flat REE patterns with depletion in Th, V, Nb, Zr and enrichment in Al, Rb, Sr and Mn indicate that airborne dusts in Khuzestan come from the same source, which is likely an eroded sedimentary environment outside Iran. In general, airborne dusts in Khuzestan are geochemically similar to airborne dusts elsewhere in the world. 相似文献
17.
《Applied Geochemistry》2006,21(2):335-351
In this paper, the leaching behaviour of major components (Al, Ca, SO4, Mg, Si, Fe, Na and DOC) and trace elements (Ni, Zn, Cd, Cu, Pb, Mo and Sb) from MSWI bottom ash is studied as a function of time over a wide range of pH, under pH-controlled conditions. Equilibrium geochemical modelling using the modelling framework ORCHESTRA is used to enable a process-based interpretation of the results and to investigate whether ‘equilibrium’ is attained during the time scale of the experiments. Depending on the element and setpoint-pH value, net concentration increases or decreases of up to one order of magnitude were observed. Different concentration–time trends (increase or decrease) are observed in different pH ranges. The direction of the concentration–time trends depends on: (1) the shape of the ‘equilibrium’ solubility curve, and (2) the position of the setpoint-pH in the leaching test relative to the natural pH of the sample. Although the majority of the elements do not reach steady state, leached concentrations over a wide pH range have been shown to closely approach ‘equilibrium’ model curves within an equilibration time of 168 h. The different effects that leaching kinetics may have on the pH dependent leaching patterns have been identified for a wide range of elements, and can generally be explained in a mechanistic way. The results are in support of the currently prescribed equilibration time of 48 h in the European standard for the pH-static leaching test (TS14997). Finally, this study demonstrates that pH-static leaching experiments such as described in the European standards (TS14497 and TS14429), in combination with selective chemical extractions and a mechanistically based modelling approach, constitute a powerful set of tools for the characterization of leaching processes in waste materials over a wide range of conditions. 相似文献
18.
Use of rare earth element patterns to trace the provenance of the atmospheric dust near Beijing, China 总被引：3，自引：1，他引：2
Atmospheric dust is one of the important indicators of urban air quality. In this study, atmospheric dust and topsoil samples were collected monthly from four sites in Beijing and surrounding areas, and analyzed for rare earth elements (REEs). Total REE concentrations (∑REE) in the dusts ranged from 43.10 to 164.43 mg kg?1; concentrations in Beijing and Miyun were higher than those in Zhangbei and Fengning. Most of sampling sites showed the same seasonal depletion in dust ∑REE concentrations in summer, probably caused by the “dilution effect” of added organic matter in summertime samples. Most of the dusts have consistent Ce-anomaly (Ce/Ce*) values (0.91–1.00) and Eu anomaly (Eu/Eu*) values (0.93–1.36); some dusts show slight positive Eu anomalies. The REE patterns of both the dusts and topsoils (normalized to post-Archean shales from Australia, PASS) show different signatures at different sites, whereas the temporal patterns are consistent at each site. These results suggest that local topsoils are likely to be the main provenance of the dusts in the study area. 相似文献
19.
铜矿采矿废石重金属环境污染的淋溶实验研究——以安徽铜陵凤凰山矿田药园山铜矿床为例 总被引：2，自引：0，他引：2
本文基于凤凰山铜矿田药园山矿床采矿废石的淋溶实验研究,着重探索表生环境下影响重金属淋滤迁移的因素,分析重金属在采矿废石中迁移转化的机制。动态淋滤实验考查了重金属从两种采矿废石中淋出的浓度与淋溶液的pH值、淋滤时间以及淋出液酸度的关系。结果表明,采矿废石中重金属淋滤强度随酸度的增加而逐渐增强,而淋滤出的重金属浓度并不总是随时间的延长而递减,同时实验研究也表明,淋溶采矿废石的排放水不一定都是酸性的。因此,在评价矿山环境污染以及治理过程中要对当地雨水的平均pH值、所排放采矿废石的岩性以及废石的堆放时间进行综合考虑。 相似文献
20.
A. Steel K. Hawbol F. Khan 《International Journal of Environmental Science and Technology》2009,6(1):57-68
Hydrometallurgical facilities processing sulfide based ores produce waste residues in the form of sludges that contain concentrations of metals, as well as metal sulfides. As a part of the waste characterization and risk assessment process, a statistical design of experiment was used to assess the significant factors and interactions in the residue leaching process. Two shake flask experiments, a 24 factorial design and 23 central composite design were employed to evaluate the effect of mixing time, test pH, solid/liquid ratio and residue type on acidity, alkalinity, sulfate and metal concentration and pH of the resulting filtered leachate. The results indicate that the variable tested mixing time and solid/liquid ratio most strongly affect metal concentration in the filtrate from waste residue samples tested over a moderate test pH range. When tests were conducted over a longer test period and at lower test pH values, test pH and residue type were dominant factors contributing to residue filtrate metal concentration. 相似文献