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1.
《Precambrian Research》2007,152(1-2):27-47
Metasomatism above subduction zones is an important process that produces heterogeneous mantle and thus a diversity of igneous rocks. In the Panzhihua district, on the western margin of the Yangtze Block (SW China), two Neoproterozoic mafic intrusions, one olivine gabbro and one hornblende gabbro, have identical ages of 746 ± 10 and 738 ± 23 Ma. Both of the gabbros are tholeiitic in composition and have arc-like geochemical compositions. The hornblende gabbros have K2O concentrations ranging from 0.70 to 1.69 wt.% and show enrichment of Rb, Ba, U, Th and Pb and depletion of Nb,Ta and Ti. They have variable 87Sr/86Sr ratios (0.7045–0.7070) with constant ɛNd(t) values (−0.12 to −0.93). The olivine gabbros have relatively low K2O (0.19–0.43 wt.%), are depleted in Rb and Th relative to Ba and U, and have obvious negative Nb–Ta and Zr–Hf anomalies on primitive mantle-normalized trace element diagrams. Their ɛNd(t) values range from −0.64 to −1.73 and initial 87Sr/86Sr ratios from 0.7070 to 0.7075. Both types of gabbro experienced fractional crystallization of clinopyroxene, plagioclase, amphibole and minor Fe–Ti oxide. The parental magmas of the olivine and hornblende gabbros were formed by about 20% partial melting of garnet–spinel lherzolite and spinel lherzolite, respectively. According to trace elemental ratios, the hornblende gabbros were probably derived from a source strongly modified by subducted slab fluids, whereas the olivine gabbros came from a mantle source modified by subducted slab melts. The close association of the olivine gabbros and hornblende gabbros suggests that a steep subduction zone existed along the western margin of the Yangtze Block during Neoproterozoic time. Thus, the giant Neoproterozoic magmatic event in South China was subduction-related. 相似文献
2.
The East-Ujimqin complex, located north of the Erenhot–Hegenshan fault, North China, is composed of mafic–ultramafic and granitic rocks including peridotite, gabbro, alkali granite, and syenite. We investigated the tectonic setting, age, and anorogenic characteristics of the Xing’an–Mongolian Orogenic Belt (XMOB) through field investigation and microscopic and geochemical analyses of samples from the East-Ujimqin complex and LA-MC-ICP-MS zircon U–Pb dating of gabbro and alkali granite. Petrographic and geochemical studies of the complex indicate that this multiphase plutonic suite developed through a combination of fractional crystallization, assimilation processes, and magma mixing. The mafic–ultramafic rocks are alkaline and have within-plate geochemical characteristics, indicating anorogenic magmatism in an extensional setting and derivation from a mantle source. The mafic–ultramafic magmas triggered partial melting of the crust and generated the granitic rocks. The granitic rocks are alkali and metaluminous and have high Fe/(Fe + Mg) characteristics, all of which are common features of within-plate plutons. Zircon U–Pb geochronological dating of two samples of gabbro and alkali granite yielded ages of 280.8 ± 1.5 and 276.4 ± 0.7 Ma, placing them within the Early Permian. The zircon Hf isotopic data give inhomogeneous εHf(t) values of 8.2–14.7 for gabbroic zircons and extraordinary high εHf(t) values (8.9–12.5) for the alkali granite in magmatic zircons. Thus, we consider the East-Ujimqin mafic–ultramafic and granitic rocks to have been formed in an extensional tectonic setting caused by asthenospheric upwelling and lithospheric thinning. The sources of mafic–ultramafic and granitic rocks could be depleted garnet lherzolite mantle and juvenile continental lower crust, respectively. All the above indicate that an anorogenic magma event may have occurred in part of the XMOB during 280–276 Ma. 相似文献
3.
The Xiaohuangshan ophiolite of the Beishan (Inner Mongolia) is located in the southern margin of the Central Asian Orogenic Belt. It consists of several blocks composed dominantly of serpentinized ultramafic rocks, cumulative gabbros and basalts. The geochemical data of gabbros and basalts obtained from the Xiaohuangshan ophiolite are similar to tholeiitic rocks. They all have low TiO2 and high Al2O3 contents. Their light rare earth elements are slightly enriched, (La/Yb)N = 3.62–6.80, similar to the typical enriched mid-ocean ridge basalts. The mafic rocks display enrichments in large ion lithophile elements and depletions in high field strength elements, as well as significant Nb–Ta–Ti negative anomalies, similar to subduction-derived rocks. All these geochemical characteritics indicate that the Xiaohuangshan ophiolite would form in a subduction zone from a slightly enriched mantle source. Ion microprobes (SHRIMP) U–Pb dating were conducted on zircons from the basalt and gabbro. The weighted mean ages are 336.4 ± 4.1 Ma and 345 ± 14 Ma, which are considered as the crystallization ages of the basalt and gabbro, respectively. Together with other two units, the Dongqiyishan arc belt and the Yueyashan–Xichangjing ophiolite, the Xiaohuangshan ophiolite forms a Late Paleozoic arc-basin system, indicating that the Paleo-Asian Ocean did not close in the early Carboniferous. Based on the geochemical characteristics of adjacent geological bodies and their settings, the Xiaohuangshan ophiolite is considered as an indicator of a suture zone between the different epicontinental belts in the Beishan region. 相似文献
4.
The Beiligaimiao magmatic Ni-Cu sulfide deposit is located in the northern rim of the North China Block, which was an active continental margin related to the southward subduction of the Paleo-Asian oceanic plate to the north in the Paleozoic. This deposit has never been studied before but is an excellent example of sulfide mineralization in arc settings that have been commonly overlooked by exploration geologists worldwide. Sulfide mineralization in the deposit is hosted in a mafic-ultramafic complex that consists of a small ultramafic body surrounded by an older and much larger gabbroic intrusion. Disseminated sulfide zones are present in both intrusive bodies but only those close to the surface within the ultramafic body have been mined in the past. The sulfide-mineralized ultramafic body is composed of olivine websterite and orthopyroxenite with a gradational contact between them. SIMS U-Pb dating of zircon crystals from a large olivine websterite sample yields a crystallization age of 269.4 ± 2.1 Ma, which is ∼25 Ma younger than the Erbutu subduction-related magmatic Ni-Cu sulfide deposit that occurs ∼50 km to the north. Orthopyroxene crystals in the Beiligaimiao ultramafic rocks have Mg# [100 Mg/(Mg + Fe), molar] of 77–78, significantly lower than those in the ultramafic rocks of the Erbutu deposit. Olivine crystals in the Beiligaimiao ultramafic rocks have forsterite (Fo) contents from 72 to 75 mol%, which are also significantly lower than those in the ultramafic rocks of the Erbutu deposit (Fo, 86–88 mol%). The mineral chemical data indicate a more fractionated parental magma for the former. Ca-depletion in olivine (i.e., <1000 ppm Ca), which is common for ultramafic cumulates in arc settings worldwide, is present in both deposits. Like Erbutu, the host rocks of the Beiligaimiao deposit are characterized by enrichments in light rare earth elements (REE) relative to heavy REE and pronounced negative Nb-Ta anomalies, consistent with ultramafic rocks in arc settings. The δ34S values of sulfide separates from the Beiligaimiao deposit are 1.7 to 2.5‰, significantly lower than those for the Erbutu deposit but still slightly higher than the MORB value (−1.5 to 0.5‰). Olivine websterites in the Beiligaimiao deposit have εNd from −8.9 to −9.5 and (87Sr/86Sr)i close to 0.7075, which are similar to those of an enriched lithospheric mantle. An orthopyroxenite sample from the deposit has much lower εNd (−12.6) coupled with much higher (87Sr/86Sr)i ratio (0.7132), indicating ∼25% crustal contamination. The Sr-Nd-S isotope data support the premise that both crustal contamination and addition of crustal sulfur played a role in triggering sulfur saturation in the parental magma of the Beiligaimiao deposit. Since the immediate country rocks are exclusively gabbros, these processes likely took place at depth. The close temporal and spatial association of the Beiligaimiao and Erbutu deposits points to the possibility that more Permian arc-type magmatic sulfide deposits are yet to be discovered in the region. 相似文献
5.
《Gondwana Research》2014,25(2):842-858
The northern margin of the Alxa block (NMAB), located in the southernmost part of the Altaids, is important for understanding the tectonic processes associated with the closure of the Paleo-Asian ocean. In this study, we report results from our studies on two ophiolitic belts (the Enger Us and Quagan Qulu ophiolitic belts) to constrain the tectonic evolution of the Altaids. The tectonic blocks in the Enger Us ophiolite are mainly composed of ultramafic and mafic rocks, with a matrix comprising highly deformed Carboniferous clastic rocks and tuffs. Zircons from a pillow lava sample yielded SHRIMP zircon U–Pb age of 302 ± 14 Ma. Massive and pillow basalts in the Enger Us ophiolite exhibit N-MORB geochemical affinities, displaying high TiO2 and low K2O contents with tholeiitic signatures. They are characterized by depletion of light rare earth elements (LREEs) without fractionation of high field strength elements (HFSEs) and negative Nb–Ta anomalies. It is inferred that the magmas of these rocks were derived from a depleted mantle source in a mid-ocean ridge setting. The Quagan Qulu ophiolite is composed of tectonic blocks, including ultramafic, gabbros and siliceous rocks, and matrix, including deformed clastic rocks and limestones. Zircons in a gabbro sample from the Quagan Qulu ophiolite yielded SHRIMP zircon U–Pb age of 275 ± 3 Ma. The gabbros show high MgO contents, compatible elements (Ni, Co, Sc, and V), and Al2O3/TiO2 ratios, but low TiO2 and SiO2 contents. They are enriched in large-ion lithophile elements (LILEs) and depleted in LREEs and HFSEs, indicating that they were derived from an extremely depleted mantle source which was infiltrated by a subduction-derived fluid or melt. Our geochemical data suggest that gabbros in the Quagan Qulu ophiolite were formed in a back-arc basin setting. A synthesis of evidence from geochemistry, regional geology, and paleobiogeography support the notion that the Enger Us ophiolitic belt represents the major suture of the Paleo-Asian Ocean in the NMAB and the Quagan Qulu ophiolitic belt represents a back-arc basin. These two ophiolitic belts, together with the Zongnaishan–Shalazhashan arc have been suggested to be a late Paleozoic ocean-arc–back-arc basin system in the southernmost part of the Altaids. The geochronological data suggest that the subduction process occurred even in the early Permian, indicating that the final closure of the Paleo-Asian Ocean might have taken place later than the early Permian. 相似文献
6.
Eclogites and associated high-pressure (HP) rocks in collisional and accretionary orogenic belts preserve a record of subduction and exhumation, and provide a key constraint on the tectonic evolution of the continents. Most eclogites that formed at high pressures but low temperatures at > 10–11 kbar and 450–650 °C can be interpreted as a result of subduction of cold oceanic lithosphere. A new class of high-temperature (HT) eclogites that formed above 900 °C and at 14 to 30 kbar occurs in the deep continental crust, but their geodynamic significance and processes of formation are poorly understood. Here we show that Neoarchaean mafic–ultramafic complexes in the central granulite facies region of the Lewisian in NW Scotland contain HP/HT garnet-bearing granulites (retrogressed eclogites), gabbros, lherzolites, and websterites, and that the HP granulites have garnets that contain inclusions of omphacite. From thermodynamic modeling and compositional isopleths we calculate that peak eclogite-facies metamorphism took place at 24–22 kbar and 1060–1040 °C. The geochemical signature of one (G-21) of the samples shows a strong depletion of Eu indicating magma fractionation at a crustal level. The Sm–Nd isochron ages of HP phases record different cooling ages of ca. 2480 and 2330 Ma. We suggest that the layered mafic–ultramafic complexes, which may have formed in an oceanic environment, were subducted to eclogite depths, and exhumed as HP garnet-bearing orogenic peridotites. The layered complexes were engulfed by widespread orthogneisses of tonalite–trondhjemite–granodiorite (TTG) composition with granulite facies assemblages. We propose two possible tectonic models: (1) the fact that the relicts of eclogitic complexes are so widespread in the Scourian can be taken as evidence that a > 90 km × 40 km-size slab of continental crust containing mafic–ultramafic complexes was subducted to at least 70 km depth in the late Archaean. During exhumation the gneiss protoliths were retrogressed to granulite facies assemblages, but the mafic–ultramafic rocks resisted retrogression. (2) The layered complexes of mafic and ultramafic rocks were subducted to eclogite-facies depths and during exhumation under crustal conditions they were intruded by the orthogneiss protoliths (TTG) that were metamorphosed in the granulite facies. Apart from poorly defined UHP metamorphic rocks in Norway, the retrogressed eclogites in the central granulite/retrogressed eclogite facies Lewisian region, NW Scotland have the highest crustal pressures so far reported for Archaean rocks, and demonstrate that lithospheric subduction was transporting crustal rocks to HP depths in the Neoarchaean. 相似文献
7.
《Precambrian Research》2005,136(1):67-106
A new lithotectonic framework for the northwestern Reindeer Zone of the Trans-Hudson Orogen divides rocks into five northwest- to north-dipping volcano-sedimentary assemblages: (1) at the structural base, the 1.92–1.87 Ga largely sedimentary Levesque Bay Assemblage (partly equivalent to former ‘MacLean Lake gneisses’), which lies within the confines of the Kisseynew Domain and is tectonically imbricated with metasedimentary rocks of the <1.85 Ga McLennan and Burntwood groups; (2) the turbiditic Duck Lake Assemblage, also located along the northern edge of the Kisseynew Domain; it contains detrital zircons ranging in age between 1.92 and 1.87 Ga; (3) the ?1.92 Ga mafic–ultramafic volcano-plutonic Lawrence Point Assemblage of the La Ronge Domain; (4) the ≥1.88 Ga felsic to intermediate volcano-plutonic Reed Lake Assemblage of the La Ronge Domain; and (5) the turbiditic Milton Island Assemblage of the Rottenstone Domain, which contains detrital zircons ranging in age between 2.83 and 1.86 Ga. The assemblages are intruded by a variety of 1.91–1.78 Ga mafic to felsic plutons.The Lawrence Point Assemblage is interpreted as a dismembered supra-subduction zone ophiolite. High-MgO refractory harzburgite (‘Group 1’ ultramafic rocks), at the structural base of the assemblage, is geochemically identical to the upper mantle section of selected supra-subduction zone ophiolites and mantle tectonites. Chromite and olivine compositions of the ‘Group 1’ ultramafic rocks are also comparable to those of ophiolitic harzburgite and mantle tectonite. Mafic metavolcanic rocks of the assemblage are classified as subalkaline tholeiitic basalts. Their trace element patterns and Hf, Ta, Th, Y, Nb, and La element ratios resemble those of modern back-arc basin basalts. The Reed Lake Assemblage represents a subduction-generated arc complex that was built on top of the Lawrence Point Assemblage; its mafic metavolcanic rocks are subalkaline basalts, with calc-alkaline trends, and elevated Th and Ce concentrations and negative Nb anomalies. Feldspar porphyry dykes intruding the Lawrence Point and Duck Lake assemblages constrain timing of Lawrence Point ophiolite emplacement onto the Duck Lake Assemblage to 1.86–1.84 Ga. The trace element geochemistry of the dykes suggests continued arc volcanism after ophiolite emplacement. Mafic metavolcanic rocks of the Levesque Bay Assemblage are geochemically similar to those of the Lawrence Point Assemblage. Other ultramafic rocks (peridotite to pyroxenite) are abundant in the Lawrence Point Assemblage, but have similar geochemistry to small ultramafic bodies intruding the Reed Lake, Duck Lake and Levesque Bay Assemblages. They represent a separate, later phase (?1.86 Ga) of ultramafic plutonism, which post-dates ophiolite emplacement.Timing of Lawrence Point ophiolite emplacement (between 1.86 and 1.84 Ga) and geochemistry of later felsic and mafic/ultramafic volcanism suggest that the Lawrence Point ophiolite and overlying Reed Lake arc assemblage were not accreted to the Hearne Craton prior to 1.86 Ga, but were first accreted to the Flin Flon–Glennie Complex after 1.86 Ga. 相似文献
8.
The Jiangnan orogenic belt (JOB) has been interpreted as a suture zone between the Yangtze craton and Cathaysian terranes in South China. The Neoproterozoic mafic–ultramafic rocks are extensively exposed in the western JOB, providing an ideal opportunity to study the Neoproterozoic assembly and tectonic evolution of South China. We present integrated field and geochemical studies including LA-ICP-MS zircon U–Pb dating, and whole-rock major and trace element and Sm–Nd isotope analyses of the Neoproterozoic mafic–ultramafic rocks exposed in the northern Guangxi Province, South China. Geochronological results show that the magmatic events took place in two distinct periods: the early Neoproterozoic (861–834 Ma) and the late Neoproterozoic (770–750 Ma). Early Neoproterozoic ultramafic rocks of the Sibao Group have positive εNd(t) values (+ 2.7 to + 6.6) whereas mafic rocks exhibit negative εNd(t) values (− 5.8 to − 0.9). The basaltic rocks show TiO2 contents of 0.62–0.69 wt.% and Mg-number of 59–65, and also display an enrichment of light rare earth elements (LREEs) and pronounced negative Nb, Ta and Ti anomalies on chondrite- and primitive mantle-normalized diagrams, consistent with subduction-related geochemical signatures. Late Neoproterozoic rocks of the Danzhou Group show εNd(t) values (− 1.23 to + 3.19) for both ultramafic and mafic rocks. The basaltic rocks have TiO2 contents of 1.01–1.33 wt.% and Mg-number of 57–60, and have a mixture of MORB- and arc-like geochemical affinities, inferred to have formed in an extensional arc environment. Geochemical signatures suggest that all rock types in this study were derived from subarc mantle wedge sources and underwent various degrees of crustal contamination. Thus, we suggest that subduction may have continued to ca. 750 Ma in the western JOB, implying that the amalgamation event between the Yangtze craton and Cathaysian terranes was later than 750 Ma. 相似文献
9.
The time of termination of orogenesis for the southern Altaids has been controversial. Systematic investigations of field geology, geochronology and geochemistry on newly discriminated mafic–ultramafic rocks from northern Alxa in the southern Altaids were conducted to address the termination problem. The mafic–ultramafic rocks are located in the Bijiertai, Honggueryulin, and Qinggele areas, stretching from west to east for about 100 km. All rocks occur high-grade gneisses as tectonic lenses that are composed of peridotite, pyroxenite, gabbro, and serpentinite, most of which have undergone pronounced alteration, i.e., serpentinization and chloritization. Geochemically, the rocks are characterized by uniform compositional trends, i.e., with low SiO2-contents (42.51–52.21 wt.%) and alkalinity (Na2O + K2O) (0.01–5.45 wt.%, mostly less than 0.8 wt.%), and enrichments in MgO (7.37–43.36 wt.%), with Mg# = 52.75–91.87. As the rocks have been strongly altered and have a wide range of loss-on-ignition (LOI: 0.44–14.07 wt.%) values, they may have been subjected to considerable alteration by either seawater or metamorphic fluids. The REE and trace element patterns show a relatively fractionated trend with LILE enrichment and HFSE depletion, similar to that of T-MORB between N-MORB and E-MORB, indicating that the parental melt resulted from the partial melting of oceanic lithospheric mantle overprinted by fluid alteration of island-arc origin. The ultramafic rocks are relics derived from the magma after a large degree of partial melting of oceanic lithospheric mantle with superposed island arc processes under the influence of mid-ocean-ridge magmatism. LA-ICP MS U–Pb zircon ages of gabbros from three spots are 274 ± 3 Ma (MSWD = 0.35), 306 ± 3 Ma (MSWD = 0.49), 262 ± 5 Ma (MSWD = 1.2), respectively, representing the formation ages of the mafic–ultramafic rocks. Therefore, considering other previously published data, we suggest that the mafic–ultramafic rocks were products of south-dipping subduction, most probably with a slab window caused by ridge subduction, of the Paleo-Asian Ocean plate beneath the Alxa block in the Late Carboniferous to Late Permian before the Ocean completely closed. This sheds light on the controversial tectonic history of the southern Altaids and supports the concept that the termination of orogenesis was in the end-Permian to Triassic. 相似文献
10.
Sherif Kharbish 《Chemie der Erde / Geochemistry》2010,70(3):257-266
Wadi El-Markh gabbro–diorite complex is composed of pyroxene hornblende gabbros, hornblende gabbros, diorites and quartz diorites. According to their bulk rock geochemistry and mineral chemistry, the gabbroic and dioritic rocks represent fractionates along a single line of descent and crystallized from a calc-alkaline mafic magma. When compared to the primitive mantle, all members of the gabbroic–dioritic rock suite are enriched in the large ion lithophile elements relative to the high field strength elements and display distinctive negative Nb and P2O5 anomalies. This signals an arc setting. Fractionation modeling involving the major elements reveals that the hornblende gabbros were generated from the parent pyroxene hornblende gabbros by 61.86% fractional crystallization. The diorites were produced from the hornblende gabbros by fractional crystallization with a 58.97% residual liquid, whereas the quartz diorites were formed from the diorites by 26.58% fractional crystallization. According to geothermobarometry based on amphibole mineral chemistry, the most primitive pyroxene hornblende gabbros crystallized at ～830 °C/～5 kbar. The crystallization conditions of the quartz diorites were estimated at ～570 °C/～2 kbar. In consequence the Wadi El-Markh gabbro–diorite complex represents a single magmatic suite of which fractionates crystallized in progressively shallower levels of an arc crust. 相似文献
11.
In situ zircon U–Pb ages and Hf isotope data, major and trace elements and Sr–Nd–Pb isotopic compositions are reported for coeval syenite–granodiorites–dacite association in South China. The shoshonitic syenites are characterized by high K2O contents (5.9–6.1 wt.%) and K2O/Na2O ratios (1.1–1.2), negative Eu anomalies (Eu/Eu* = 0.65 to 0.77), enrichments of Rb, K, Nb, Ta, Zr and Hf, but depletion of Sr, P and Ti. The adakitic granodiorite and granodiorite porphyry intrusions are characterized by high Al2O3 contents (15.0–16.8 wt.%), enrichment in light rare earth elements (LREEs), strongly fractionated LREEs (light rare earth elements) to HREEs (heavy rare earth elements), high Sr (438–629 ppm), Sr/Y (29.2–53.6), and low Y (11.7–16.8 ppm) and HREE contents (e.g., Yb = 1.29–1.64 ppm). The calc-alkaline dacites are characterized by LREE enrichment, absence of negative Eu anomalies, and enrichment of LILEs such as Rb, Ba, Th, U and Pb, and depletion of HFSEs such as Nb, Ta, P and Ti.Geochemical and Sr–Nd–Hf isotopic compositions of the syenites suggest that the shoshonitic magmas were differentiated from parental shoshonitic melts by fractional crystallization of olivine, clinopyroxene and feldspar. The parent magmas may have originated from partial melting of the lithospheric mantle with small amount contribution from crustal materials. The adakitic granodiorite and granodiorite porphyry have Sr–Nd–Pb isotopic compositions that are comparable to that of the mafic lower crust. They have low Mg# and MgO, Ni and Cr contents, abundant inherited zircons, low εNd(t) and εHf(t) values as well as old whole-rock Nd and zircon Hf model ages. These granodiorites were likely generated by partial melting of Triassic underplated mafic lower crust. The Hf isotopic compositions of the dacites are relatively more depleted than the Cathaysia enriched mantle, suggesting those magmas were derived from the partial melting of subduction-modified mantle sources. The coeval shoshonitic, high-K calc-alkaline and calc-alkaline rocks in Middle to Late Jurassic appear to be associated with an Andean-type subduction. This subduction could have resulted in the upwelling of the asthenosphere beneath the Cathaysia Block, which induced partial melting of the mantle as well as the mafic lower crust, and formed an arc regime in the coastal South China during Middle to Late Jurassic. 相似文献
12.
The geology of Northern Vietnam offers critical clues on the convergence history between the South China and Indochina blocks. We constrain the tectonic evolution of the South China and Indochina blocks using geochemical, mineral chemical and geochronological data collected from mafic–ultramafic rocks exposed in the Cao Bang area, Northeastern Vietnam. These rocks show significant enrichment in large ionic lithophile elements (LILEs) such as Cs, Rb, Ba, Th, U, and Pb and depletion in high field strength elements (HFSEs) such as Nb, Ta, Zr, and Ti showing [Nb/La]N between 0.28–0.41, [La/Yb]N = 3.94–10.00 and Zr/Y = 2.0–4.4. These geochemical features as well as the petrology and mineral chemistry of the Cao Bang mafic–ultramafic magmas are comparable to those of magmatic complexes formed in a back-arc environment. The basalts yield Rb–Sr whole rock ages of 263 ± 15 Ma, that are consistent with the zircon U–Pb and K–Ar ages reported in previous studies from the same area. The spatial and temporal distribution of the arc magmas within the Indochina block and along the southern margin of the South China block suggest that the Permo-Triassic mafic–ultramafic magmas formed during a tectonic event that is different from the subduction and collision event between the Indochina and South China blocks. 相似文献
13.
《Journal of South American Earth Sciences》2007,24(4):271-289
The major and trace element characteristics of black shales from the Lower Cretaceous Paja Formation of Colombia are broadly comparable with those of the average upper continental crust. Among the exceptions are marked enrichments in V, Cr, and Ni. These enrichments are associated with high organic carbon contents. CaO and Na2O are strongly depleted, leading to high values for both the Chemical Index of Alteration (77–96) and the Plagioclase Index of Alteration (86–99), which indicates derivation from a stable, intensely weathered felsic source terrane. The REE abundances and patterns vary considerably but can be divided into three main groups according to their characteristics and stratigraphic position. Four samples from the lower part of the Paja Formation (Group 1) are characterized by LREE-enriched chondrite-normalized patterns (average LaN/YbN = 8.41) and significant negative Eu anomalies (average Eu/Eu1 = 0.63). A second group of five samples (Group 2), also from the lower part, have relatively flat REE patterns (average LaN/YbN = 1.84) and only slightly smaller Eu anomalies (average Eu/Eu1 = 0.69). Six samples from the middle and upper parts (Group 3) have highly fractionated patterns (average LaN/YbN = 15.35), resembling those of Group 1, and an identical average Eu/Eu1 of 0.63. The fractionated REE patterns and significant negative Eu anomalies in Groups 1 and 3 are consistent with derivation from an evolved felsic source. The flatter patterns of Group 2 shale and strongly concave MREE-depleted patterns in two additional shales likely were produced during diagenesis, rather than reflecting more mafic detrital inputs. An analysis of a single sandstone suggests diagenetic modification of the REE, because its REE pattern is identical to that of the upper continental crust except for the presence of a significant positive Eu anomaly (Eu/Eu1 = 1.15). Felsic provenance for all samples is suggested by the clustering on the Th/Sc–Zr/Sc and GdN/YbN–Eu/Eu1 diagrams. Averages of unmodified Groups 1 and 3 REE patterns compare well with cratonic sediments from the Roraima Formation in the Guyana Shield, suggesting derivation from a continental source of similar composition. In comparison with modern sediments, the geochemical parameters (K2O/Na2O, LaN/YbN, LaN/SmN, Eu/Eu1, La/Sc, La/Y, Ce/Sc) suggest the Paja Formation was deposited at a passive margin. The Paja shales thus represent highly mature sediments recycled from deeply weathered, older, sedimentary/metasedimentary rocks, possibly in the Guyana Shield, though Na-rich volcanic/granitic rocks may have contributed to some extent. 相似文献
14.
《Chemical Geology》2007,236(1-2):112-133
The Cida A-type granitic stock (∼ 4 km2) and Ailanghe I-type granite batholith (∼ 100 km2) in the Pan-Xi (Panzhihua-Xichang) area, SW China, are two important examples of granites formed during an episode of magmatism associated with the Permian Emeishan mantle plume activity. This is a classic setting of plume-related, anorogenic magmatism exhibiting the typical association of mantle-derived mafic and alkaline rocks along with silicic units. SHRIMP zircon U–Pb data reveal that the Cida granitic pluton (261 ± 4 Ma) was emplaced shortly before the Ailanghe granites (251 ± 6 Ma). The Cida granitoids display mineralogical and geochemical characteristics of A-type granites including high FeO⁎/MgO ratios, elevated high-field-strength elements (HFSE) contents and high Ga/Al ratios, which are much higher than those of the Ailanghe granites. All the granitic rocks show significant negative Eu anomalies and demonstrate the characteristic negative anomalies in Ba, Sr, and Ti in the spidergrams. It can be concluded that the Cida granitic rocks are highly fractionated A-type granitoids whereas the Ailanghe granitic rocks belong to highly evolved I-type granites.The Cida granitoids and enclaves have Nd and Sr isotopic initial ratios (εNd(t) = − 0.25 to + 1.35 and (87Sr/86Sr)i = 0.7023 to 0.7053) close to those of the associated mafic intrusions and Emeishan basalts, indicating the involvement of a major mantle plume component. The Ailanghe granites exhibit prominent negative Nb and Ta anomalies and weakly positive Pb anomalies in the spidergram and have nonradiogenic εNd(t) ratios (− 6.34 to − 6.26) and high (87Sr/86Sr)i values (0.7102 to 0.7111), which indicate a significant contribution from crustal material. These observations combined with geochemical modeling suggest that the Cida A-type granitoids were produced by extensive fractional crystallization from basaltic parental magmas. In contrast, the Ailanghe I-type granites most probably originated by partial melting of the mid-upper crustal, metasedimentary–metavolcanic rocks from the Paleo-Mesoproterozoic Huili group and newly underplated basaltic rocks.In the present study, it is proposed that petrogenetic distinctions between A-type and I-type granites may not be as clear-cut as previously supposed, and that many compositional and genetically different granites of the A- and I-types can be produced in the plume-related setting. Their ultimate nature depends more importantly on the type and proportion of mantle and crustal material involved and melting conditions. Significant melt production and possible underplating and/or intrusion into the lower crust, may play an important role in generating the juvenile mafic lower crust (average 20 km) in the central part of the Emeishan mantle plume. 相似文献
15.
《Chemie der Erde / Geochemistry》2016,76(4):579-595
Appinites are commonly derived from a mantle source and are potentially significant in constraining the tectonic nature and evolution of ancient orogens, yet they have received little attention because of their limited outcrop. Here we investigate the newly identified appinitic rocks from the Laoniushan complex in the eastern Qinling Orogen. The appinites are composed of coarse-grained hornblendite, medium- and fine-grained hornblende-gabbro, and diorite porphyrite in the field occurrence. Winthin the appinitic rocks, the hornblendite displays features of cumulates. This study presents LA-ICP-MS zircon U-Pb data, mineral chemistry and whole rock geochemistry of the appinites. Zircons in the mafic to ultramafic rocks yield a U-Pb age of 152 ± 1Ma. The geochemistry of the rocks displays: lower SiO2, higher Fe2O3T and MgO contents, relatively flat chondrite normalized REE patterns with slight enrichment in light REE and a minor negative Eu anomaly; enrichment in large-ion lithophile elements(LILE, e.g. Rb, Ba, Sr and P), and depletion in high field strength elements(HFSE, e.g. Nb, Zr, Hf and Ti). Such geochemical features, together with crust-like bulk Sr-Nd isotopic compositions(initial 87Sr/86Sr ratios of 0.7057–0.7072, εNd(t) = −17.2 to −9), suggest that the Laoniushan appinites likely originated from an ancient metasomatised mantle, followed by fractional crystallization in the petrogenetic process. The studied appinites were most likely generated in an intracontinental extensional environment in the Late Mesozoic. 相似文献
16.
The Storø greenstone belt, southern West Greenland, consists of thrust-imbricated slices of Mesoarchean (>3060 Ma) and Neoarchean (ca. 2800 Ma) mafic to ultramafic volcanic rocks, volcaniclastic sediments, and gabbro–anorthosite associations. The belt underwent polyphase metamorphism at upper amphibolite facies conditions between 2650 and 2600 Ma. The contacts between the Mesoarchean and Neoarchean volcanic rocks, and surrounding Eoarchean to Neoarchean tonalite–trondhjemite–granodiorite (TTG) gneisses are tectonic and typically bounded by high-grade mylonites. Regardless of age, the volcanic rocks are dominated by mafic amphibolites with a tholeiitic basalt composition, near-flat to slightly enriched light rare earth element (LREE) patterns (La/Smcn = 0.91–1.48), relatively flat to slightly depleted heavy-REE (HREE) (Gd/Ybcn = 1.0–1.28), and pronounced negative Nb–Ta anomalies (Nb/Nb* = 0.34–0.73) on chondrite- and primitive mantle-normalized diagrams. These geochemical characteristics are consistent with subduction zone geochemical signatures and partial melting of a shallow (<80 km) mantle source free of residual garnet. There is no geochemical evidence for contamination by older continental crust. The overall field and geochemical characteristics suggest that the thrust-imbricated basaltic rocks were erupted in intra-oceanic subduction zone settings. Sedimentary rocks are represented by garnet–biotite and quartzitic gneisses. They are characterized by relatively high contents of transition metal (Ni = 10–154 ppm; Cr = 7–166 ppm) and enriched LREE patterns (La/Smcn = 1.38–3.79). These geochemical characteristics suggest that the sedimentary rocks were derived from erosion of felsic to mafic igneous source rocks. Collectively, the structural and lithogeochemical characteristics of the Storø greenstone belt are consistent with collision (accretion) of unrelated Archean volcanic rocks formed in supra-subduction zone geodynamic settings. Accordingly, the Mesoarchean and Neoarchean rock record of the Storø greenstone belt may well be explained in terms of modern-style plate tectonic processes. 相似文献
17.
The Wajilitag igneous complex is part of the early Permian Tarim large igneous province in NW China, and is composed of a layered mafic–ultramafic intrusion and associated syenitic plutons. In order to better constrain its origin, and the conditions of associated Fe–Ti oxide mineralization, we carried out an integrated study of mineralogical, geochemical and Sr–Nd–Hf isotopic analyses on selected samples. The Wajilitag igneous rocks have an OIB-like compositional affinity, similar to the coeval mafic dykes in the Bachu region. The layered intrusion consists of olivine clinopyroxenite, coarse-grained clinopyroxenite, fine-grained clinopyroxenite and gabbro from the base upwards. Fe–Ti oxide ores are mainly hosted in fine-grained clinopyroxenite. Forsterite contents in olivines from the olivine clinopyroxenite range from 71 to 76 mol%, indicating crystallization from an evolved magma. Reconstructed composition of the parental magma of the layered intrusion is Fe–Ti-rich, similar to that of the Bachu mafic dykes. Syenite and quartz syenite plutons have εNd(t) values ranging from +1.4 to +2.9, identical to that for the layered intrusion. They may have formed by differentiation of underplated magmas at depth and subsequent fractional crystallization. Magnetites enclosed in olivines and clinopyroxenes have Cr2O3 contents higher than those interstitial to silicates in the layered intrusion. This suggests that the Cr-rich magnetite is an early crystallized phase, whereas interstitial magnetite may have accumulated from evolved Fe–Ti-rich melts that percolated through a crystal mush. Low V content in Cr-poor magnetite (<6600 ppm) is consistent with an estimate of oxygen fugacity of FMQ + 1.1 to FMQ + 3.5. We propose that accumulation of Fe–Ti oxides during the late stage of magmatic differentiation may have followed crystallization of Fe–Ti-melt under high fO2 and a volatile-rich condition. 相似文献
18.
《Chemie der Erde / Geochemistry》2016,76(4):605-620
We discuss here the mineralogical and geochemical characteristics of mafic intrusive rocks from the Nagaland-Manipur Ophiolites (NMO) of Indo-Myanmar Orogenic Belt, northeast India to define their mantle source and tectonic environment. Mafic intrusive sequence in the NMO is characterized by hornblende-free (type-I) and hornblende-bearing (type-II) rocks. The type-I is further categorized as mafic dykes (type-Ia) of tholeiitic N-MORB composition, having TiO2 (0.72–1.93 wt.%) and flat REE patterns (LaN/YbN = 0.76–1.51) and as massive gabbros (type-Ib) that show alkaline E-MORB affinity, having moderate to high Ti content (TiO2 = 1.18 to 1.45 wt.%) with strong LREE-HREE fractionations (LaN/YbN = 4.54–7.47). Such geochemical enrichment from N-MORB to E-MORB composition indicates mixing of melts derived from a depleted mantle and a fertile mantle/plume source at the spreading center. On the other hand, type-II mafic intrusives are hornblende bearing gabbros of SSZ-type tholeiitic composition with low Ti content (TiO2 = 0.54 wt.%–0.86 wt.%) and depleted LREE pattern with respect to HREE (LaN/YbN = 0.37–0.49). They also have high Ba/Zr (1.13–2.82), Ba/Nb (45.56–151.66) and Ba/Th (84.58–744.19) and U/Th ratios (0.37–0.67) relative to the primitive mantle, which strongly represents the melt composition generated by partial melting of depleted lithospheric mantle wedge contaminated by hydrous fluids derived from subducting oceanic lithosphere in a forearc setting. Their subduction related origin is also supported by presence of calcium-rich plagioclase (An16.6–32.3). Geothermometry calculation shows that the hornblende bearing (type-II) mafic rocks crystallized at temperature in range of 565°–625 °C ± 50 (at 10 kbar). Based on these available mineralogical and geochemical evidences, we conclude that mid ocean ridge (MOR) type mafic intrusive rocks from the NMO represent the section of older oceanic crust which was generated during the divergent process of the Indian plate from the Australian plate during Cretaceous period. Conversely, the hornblende-bearing gabbros (type-II) represent the younger oceanic crust which was formed at the forearc region by partial melting of the depleted mantle wedge slightly modified by the hydrous fluids released from the subducting oceanic slab during the initial stage of subduction of Indian plate beneath the Myanmar plate. 相似文献
19.
J.E. Otamendi E. Cristofolini A.M. Tibaldi F.I. Quevedo I. Baliani 《Journal of South American Earth Sciences》2010,29(3):685-704
This work presents the field setting, petrography, mineralogy and geochemistry of a gabbroic and peridotitic layered body that is lens-shaped and surrounded by gabbronorites, diorites, and metasedimentary migmatites. This body exposed at Jaboncillo Valley is one among several examples of mafic and ultramafic layered sequences in the Sierras Valle Fértil and La Huerta, which formed as part of the lower crust of the Ordovician Famatinian magmatic arc in central-western Argentina. The layered sequence grew at deep crustal levels (20–25 km) within a mafic lower crust. The base of the layered body was detached during the tectonic uplift of the Famatinian lower crust, whereas the roof of the layered body is exposed in the eastern zone. In the inferred roof, olivine-bearing rocks vanish, cumulate textures are less frequent, and the igneous sequence becomes dominated by massive or thinly banded gabbronorites. Mainly based on the petrographic relationships, the inferred order of crystallization in the gabbroic and peridotitic layered sequence is: (1) Cr–Al-spinel + olivine, (2) Cr–Al-spinel + olivine + clinopyroxene + magnetite, (3) Cr–Al-spinel + olivine + plagioclase + magnetite ± orthopyroxene, and (4) Al-spinel + orthopyroxene + amphibole. A strong linear negative correlation between olivine and plagioclase modal proportions combined with field, petrographic and geochemical observations are used to demonstrate that the physical separation of olivine and plagioclase results in rock diversity at scales of a few centimeters to tens of meters. However, the composition of olivine (Fo ～ 0.81) and plagioclase (An > 94%) remains similar throughout the layered sequence. Spinels are restricted to olivine-bearing assemblages, and display chemical trends characteristic of spinels found in arc-related cumulates. Gabbroic and peridotitic layered rocks have trace element concentrations reflecting cumulates of early crystallizing minerals. The trace element patterns still retain the typical features of subduction-related arc magmatism, showing that the process of cumulate formation did not obscure the trace element signature of the parental magma. Using the composition of cumulus minerals and whole-rock chemical trends, we show that the parental magma was mafic (SiO2 ～ 48 wt.%) with Mg-number around 0.6, and hydrous. The oxygen fugacity (fO2) of the parental magma estimated between +0.8 and ?0.6 log fO2 units around the fayalite–magnetite–quartz (FMQ) buffer is also characteristic of primitive hydrous arc magmas. The initially high water content of the parental magma allowed amphibole to crystallize as an interstitial phase all over the crystallization evolution of the layered sequence. Amphibole crystallization in the inter-cumulus assemblage gives rise to the retention of many trace elements which would otherwise be incompatible with the mineral assemblage of mafic–ultramafic cumulates. This study shows that there exist strongly mafic and primitive magmas that are both generated and emplaced within the lower crustal levels of subduction-related magmatic arc. Our findings together with previous studies suggest that the Early Ordovician magmatic paleo-arc from central-northwestern Argentina cannot be regarded as a typical Andean-type tectono-magmatic setting. 相似文献
20.
《Journal of South American Earth Sciences》2007,23(2-3):147-175
The crystalline basement of the Sierra de San Luis, which belongs to the Eastern Sierras Pampeanas in central Argentina, consists of three main units: (1) Conlara, (2) Pringles, and (3) Nogolí metamorphic complexes. In the Pringles Metamorphic Complex, mafic–ultramafic bodies occur as discontinuous lenses along a narrow central belt concordant with the general NNE–SSW structural trend. A metamorphic gradient from granulite to greenschist facies is apparent on both sides of the mafic–ultramafic bodies. This work focuses on the characteristics of the mylonitization overprinted on the mafic–ultramafic intrusives in the Pringles Metamorphic Complex and their gneissic–migmatitic surroundings, both previously metamorphosed within the granulite facies. Petrogenetic grid and geothermobarometry applied to the paragenesis equilibrated during the mylonitic event, together with mineral deformation mechanisms, indicate that mafic and adjacent basement mylonites developed under upper amphibolite transitional to granulite facies metamorphic conditions at intermediate pressures (668–764 °C, 6.3–6.9 kbar, 0.3 < XCO2 < 0.7). However, the following mylonitic assemblages can be distinguished from the external limits of the Pringles Metamorphic Complex to its center: lower amphibolite facies ⇒ middle amphibolite facies ⇒ upper amphibolite transitional to granulite facies. Geothermobarometry applied to mylonitic assemblages indicate a temperature gradient from 555 °C to 764 °C and pressures of 6–7 kbar for the mylonitic event. This event is considered to have developed on a preexisting temperature gradient attributed to the intrusion of mafic–ultramafic bodies. The concentration of sulfides in mylonitic bands and textural relationships provide evidence of remobilization of primary magmatic sulfides of the mafic–ultramafic rocks (+PGM) during the mylonitic event. A lower-temperature final overprint produced brittle fracturing and localized retrogression on mafic–ultramafic minerals and ores by means of a water-rich fluid phase, which gave rise to a serpentine + magnetite ± actinolite association. Concordantly in the adjacent country rocks, fluids channeled along preexisting mylonitic foliation planes produced local obliteration of the mylonitic texture by a randomly oriented replacement of the mylonite mineralogy by a chlorite + sericite/muscovite + magnetite assemblage. Observed mineral reactions combined with structural data and geothermobarometry suggest a succession of tectonometamorphic events for the evolution of the Pringles Metamorphic Complex of Sierra de San Luis, developed in association with a counterclockwise P–T–d path. The most likely geological setting for this type of evolution is a backarc basin, associated with east-directed Famatinian subduction initiated in Mid-Cambrian times and closed during the collision of the allochthonous Precordillera terrane in Mid-Ordovician times. 相似文献