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1.
西昆仑普鲁新生代火山岩的矿物化学特征及其对岩浆演化过程的约束 总被引：2，自引：0，他引：2
对西昆仑普鲁新生代火山岩的矿物学进行了系统的研究。结果表明：该地区火山岩主要由橄榄石、单斜辉石和斜长石组成,并有少量的斜方辉石、黑云母、角闪石、碱性长石和铁钛氧化物。其矿物学特征指示了岩浆的性质有点类似于碱性岩浆,但与典型的碱性玄武岩又有明显的区别,属于橄榄安粗岩系列。利用橄榄石-熔体平衡原理估算了进入高位岩浆房中的熔体的MgO含量约为6．2％,Mg^#为0．57,说明其不是地幔熔融形成的原始岩浆,而是经历了深部岩浆房的分离结晶过程。由单斜辉石估算的高位岩浆房的深度约7～9km。岩浆在高位岩浆房中发生了较长时间的强烈分离结晶作用,分离结晶相主要为橄榄石、单斜辉石和斜长石以及少量的斜方辉石、黑云母、角闪石、碱性长石和铁钛氧化物。不同时期形成的铁钛氧化物指示了分离结晶过程由相对高温高氧逸度向相对低温低氧逸度演化。与此相对照的是岩浆在深部岩浆房中可能只发生了橄榄石和辉石等铁镁矿物的分离结晶作用,且分异作用时间较短。深部岩浆房可能存在于岩石圈地幔或壳幔过渡带中,岩浆由深部岩浆房上升到高位岩浆房中的过程是近绝热的,从浅部岩浆房到地表是快速上升的过程。 相似文献
2.
西昆仑山普鲁新生代火山岩中包体的发现及其地质意义 总被引：6，自引：1，他引：6
报道了在西昆仑用于田县南普鲁火山岩首次发现的包体的产出特下与矿物组成特征，提出其包体为岩浆在高位岩浆房中分离结晶作用形成的堆积相，并估算了其原始岩浆的成分特征。结果表明：其原始岩浆和处于同一火山带的康西瓦火山岩相似，暗示了它们来自于同一源区。但在高位岩浆房中，随着分离结晶作用的进行。岩浆的温度和氧逸度逐渐降低。 相似文献
3.
江西德兴银山火山岩-次火山岩带状岩浆房初步研究 总被引：4，自引：0，他引：4
银山地区火山岩－次火山岩由流纹岩、流纹英安斑岩、英安质熔岩、英安斑岩和粗面安山斑岩组成,喷发和侵入存在着反序特征。通过各种物理化学方法确定了岩浆房中存在的化学成分和温度、密度、粘度梯度。建立了以英安质岩浆为主,顶部有一层富ＳｉＯ２、富Ｋ的流纹质岩浆,底部为少量粗面安山质岩浆的带状岩浆房。岩浆演化及带状岩浆房折形成是分离结晶、同化混染、岩浆对流和边界层机制共同作用的结果。 相似文献
4.
银山地区火山岩－次火山岩由流纹岩、流纹英安斑岩、英安质熔岩、英安斑岩和粗面安山斑岩组成,喷发和侵入存在着反序特征．通过各种物理化学方法确定了岩浆房中存在的化学成分和温度、密度、粘度梯度．建立了以英安质岩浆为主,顶部有一层富ＳｉＯ２、富Ｋ的流纹质岩浆,底部为少量粗面安山质岩浆的带状岩浆房．岩浆演化及带状岩浆房的形成是分离结晶、同化混染、岩浆对流和边界层机制共同作用的结果． 相似文献
5.
峨眉山大火成岩省出露有少量酸性火山岩,它们与基性火山岩共生,表现出双峰式的特征,为研究峨眉山地幔柱晚期岩浆活动提供了重要的窗口。本文通过对双峰式火山岩主、微量元素和斑晶电子探针分析研究表明,基性火山岩属于碱性玄武岩,酸性火山岩主要由粗面岩组成;相对玄武岩,粗面岩中MgO、Fe2O3、P2O5、TiO2、CaO含量明显降低;粗面岩与玄武岩具有相互平行的REE配分模式,但粗面岩出现明显的Eu负异常,以及Sr、Ti等元素的强烈亏损;粗面岩与玄武岩具有同源的特征,通过稀土元素模拟计算表明粗面岩可以由玄武质岩浆经过80%分离结晶作用(辉石、斜长石和Fe-Ti氧化物)而形成。在峨眉山大火成岩省晚期出现双峰式火山岩,可能与地幔柱活动晚期岩浆供给少,在地壳岩浆房中停留时间长,岩浆发生强烈分离结晶作用有关。 相似文献
6.
准噶尔盆地老山沟火山岩晶体粒度分布及其结晶动力学意义 总被引：1，自引：0，他引：1
摘 要 阐述了火山岩晶体粒度分布的基本原理和研究方法分析了老山沟火山岩斜长石、
辉石、橄榄石、铁钛氧化物的晶体粒度分布。前3种矿物在中间粒度处发生了有意义的弯折
原因是岩浆上升时过冷度增大。估算了岩浆房中斜长石、橄榄石的成核速率、结晶时间及上
升过程中处于结晶带的时间。研究表明在岩浆的演化过程中晶体的分离和累积作用及岩
浆的混合和对围岩的同化作用可以忽略。 相似文献
7.
辽西义县盆地火山岩的基本特征及其成因探讨 总被引：17，自引：0，他引：17
通过对辽西义县盆地火山岩的岩石学、矿物学以及地球化学特征的研究，指出本区火山岩属于一套弱碱性、普通型的火山岩系列．通过热力学计算以及对岩石结构和动力学的分析，表明原始岩浆来自上地幔（约６７ｋｍ），并在约１７ｋｍ处（上下地壳附近）形成高位岩浆房．在高位岩浆房中，由于岩浆的双扩散对流作用，发生了伴随有分离结晶作用的液相分异作用，而同化混染作用则发生于岩浆演化的早期。喷出的岩浆成分受断裂切过高位岩浆房的相对位置的控制。 相似文献
8.
广东三水盆地火山岩:地球化学特征及成因——兼论火山岩性质的时空演化和南海形成的深部过程 总被引：12，自引：1，他引：12
位于中国东南部的三水盆地、珠江口盆地、雷琼半岛和北部湾地区广泛分布新生代火山岩。火山岩的形成时间具有从内陆向沿海变新的特点,早第三纪三水和珠江口盆地火山岩具有由玄武岩与粗面岩-流纹岩构成的双峰式特点。其中玄武岩和粗面岩的微量元素和稀土元素的配分形式相似,富集大离子亲石元素并且有相似的εNd(T)同位素组成(2.34～6.4),说明它们来自相同的地幔源区,为同源岩浆演化的产物。玄武岩和粗面岩经历了不同的结晶分异过程,其中玄武岩在较深部岩浆房中经历橄榄石和单斜辉石为主的分离结晶作用,而粗面岩则是在浅部岩浆房中由玄武岩浆分异形成的过渡性岩浆再经过强烈的钾长石和斜长石、以及磷灰石的结晶分异形成的。晚第三纪珠江口盆地和北部湾火山岩、雷琼半岛第四纪火山岩则由碱性和拉斑玄武岩构成。这些火山岩的形成时间和地球化学和同位素特征表明它们经历了连续的软流圈地幔上涌和部分熔融过程,受控于自晚中生代以来的地幔柱构造。南海的形成是地幔柱活动引起的地幔上涌和大陆裂解作用的结果。 相似文献
9.
论南京娘娘山碱性岩浆房的梯度及其成因机制 总被引：2，自引：0，他引：2
本文详细研究了娘娘山碱性火山杂岩体中矿物斑晶和化学成分的变化情况,发现它们定位前在岩浆房中就存在着物质成分的梯度和分带性。提出并论证矿物的分离结晶是该岩浆房中梯度形成的主要机制,但由对流所控制的热重力扩散作用对岩浆房中成分梯度的形成也具一定的影响。 相似文献
10.
论南京娘娘山碱性岩浆房的梯度及基成因机制 总被引：1，自引：0，他引：1
本文详细研究了娘娘山碱性火山杂岩体中矿物斑晶和化学成分的变化情况，发现它们
定位前在岩浆房中就存在着物质成分的梯度和分带性。提出并论证矿物的分离结晶是该岩浆房中
梯度形成的主要机制，但由对流所控制的热重力扩散作用对岩浆房中成分梯度的形成也具一定的
影响。 相似文献
11.
The Vandfaldsdalen macrodike, which lies in the Skaergaard region of East Greenland, is a remarkably zoned fossil magma chamber, with a granophyric cap overlying cumulate gabboros. The intrusion is distinctly bimodal, with a large compositional discontinuity at the contact between the gabbro and granophyre. Although the exposed part of the macrodike is in contact with Tertiary basalts and sediments, the granophyre originated by assimilation of xenoliths derived from the underlying Archean basement. Sr and Nd isotopic ratios throughout the cumulate sequence are remarkably similar, indicating insignificant contamination of the gabbro by the granophyre. Modelling of the compositional effects of cooling and crystallization indicate that the cumulate pile resulted from fractional crystallization, with the complicating effects of trapped liquid and post-cumulus fractionation. The uppermost rocks in the mafic part, of the chamber (SiO2=62%; FeO*=12.4%) resulted from about 85% fractional crystallization. A transgressive sill of strongly fractionated magma (SiO2=67%; FeO*=8.8%) formed from extracted intercumulus liquid that was the result of 90% fractional crystallization of the original magma. Mass-balance indicates that typical granophyre is made up of about 75% dissolved xenoliths, by weight, and 25% mantle-derived basaltic magma. The magmas were not measurably affected by material exchange across the interface between the gabbro and granophyre. This magma chamber evolved by both assimilation and fractional crystallization, but the residual liquids formed by fractional crystallization were unaffected by assimilation. Heat exchange between were unaffected by assimilation. Heat exchange between the two parts of the chamber was obviously important, but there was insignificant material exchange. The inability of fractional crystallization and assimilation to affect the same liquid is related to the dynamic behavior of this particular magma chamber, particularly the buoyancy of granophyre relative to evolving tholeiitic magma. 相似文献
12.
Koshi Nishimura 《Geochimica et cosmochimica acta》2009,73(7):2142-2149
Although many petrological studies of volcanic rocks have suggested that crystallization proceeds within magma bodies, highly compatible trace elements do not display the marked variations and extreme depletions predicted to result from perfect fractional crystallization. Imperfect crystal-liquid separation is a key process in explaining this paradox. The presence of suspended crystals greatly affects variations in highly compatible elements, and has been quantitatively modeled by assuming perfect equilibrium between the suspended crystals and the liquid (equilibrium crystallization and imperfect separation; ECIS); however, volcanic rocks generally contain zoned phenocrysts that reflect the absence of solid-state equilibration. The present study develops a mass-balance model for zoned crystallization and imperfect separation (ZCIS). The ZCIS process is more efficient than the conventional ECIS process in generating depleted compatible elements. These two end-member models are able to explain the compositional range of igneous rocks that experienced imperfect fractional crystallization under natural conditions. The predicted compositional regions in bivariate trace-element diagrams successfully account for the sizes and shapes of the regions defined by whole-rock and melt-inclusion data from the Bishop Tuff, CA, USA. 相似文献
13.
The Nimchak granite pluton (NGP) of Chotanagpur Granite Gneiss Complex (CGGC), Eastern India, provides ample evidence of magma interaction in a plutonic regime for the first time in this part of the Indian shield. A number of outcrop level magmatic structures reported from many mafic-felsic mixing and mingling zones worldwide, such as synplutonic dykes, mafic magmatic enclaves and hybrid rocks extensively occur in our study domain. From field observations it appears that the Nimchak pluton was a vertically zoned magma chamber that was intruded by a number of mafic dykes during the whole crystallization history of the magma chamber leading to magma mixing and mingling scenario. The lower part of the pluton is occupied by coarse-grained granodiorite (64.84–66.61?wt.% SiO2), while the upper part is occupied by fine-grained granite (69.80–70.57?wt.% SiO2). Field relationships along with textural and geochemical signatures of the pluton suggest that it is a well-exposed felsic magma chamber that was zoned due to fractional crystallization. The intruding mafic magma interacted differently with the upper and lower granitoids. The lower granodiorite is characterized by mafic feeder dykes and larger mafic magmatic enclaves, whereas the enclaves occurring in the upper granite are comparatively smaller and the feeder dykes could not be traced here, except two late-stage mafic dykes. The mafic enclaves occurring in the upper granite show higher degrees of hybridization with respect to those occurring in the lower granite. Furthermore, enclaves are widely distributed in the upper granite, whereas enclaves in the lower granite occur adjacent to the main feeder dykes.Geochemical signatures confirm that the intermediate rocks occurring in the Nimchak pluton are mixing products formed due to the mixing of mafic and felsic magmas. A number of important physical properties of magmas like temperature, viscosity, glass transition temperature and fragility have been used in magma mixing models to evaluate the process of magma mixing. A geodynamic model of pluton construction and evolution is presented that shows episodic replenishments of mafic magma into the crystallizing felsic magma chamber from below. Data are consistent with a model whereby mafic magma ponded at the crust-mantle boundary and melted the overlying crust to form felsic (granitic) magma. The mafic magma episodically rose, injected and interacted with an overlying felsic magma chamber that was undergoing fractional crystallization forming hybrid intermediate rocks. The intrusion of mafic magma continued after complete solidification of the magma chamber as indicated by the presence of two late-stage mafic dykes. 相似文献
14.
Archean volcanic rocks in the Confederation Lake area, northwestern Ontario, Canada, are in three mafic to felsic cycles collectively 8,500 to 11,240 m thick. Each cycle begins with pillowed basalt and andesite flows and is capped with andesitic to rhyolitic pyroclastic rocks and minor flows. Seventy five samples from this succession were analyzed for major and trace elements including the rare earth elements. In two cycles, tholeiitic basalts are overlain by calcalkaline andesite to rhyolite. In the third, cycle, the tholeiitic basalts are overlain by tholeiitic rhyolites. Fe enrichment in basalts is accompanied by depletion of Ca, Al, Cr, Ni, and Sr, and enrichment in Ti, P, the rare earth elements, Nb, Zr, and Y. This is interpreted as open system fractionation of olivine, plagioclase, and clinopyroxene. Si enrichment in dacites and rhyolites is attributed to fractional crystallization of plagioclase, K-feldspar, and biotite. Tholeiitic basalt liquids are believed to be mantle-derived. Intercalated andesites with fractionated rare earth patterns appear to be products of mixing of tholeiitic basalt and rhyolite liquids and, andesites with flat rare earth patterns are probably produced by melting of previously depleted mantle. Felsic magmas are partial melts of tholeiitic basalt or products of liquid immiscibility in a tholeiitic system perhaps involving extreme fractionation in a high level magma chamber, and assimilation of sialic crust. It is concluded that Archean cyclical volcanism in this area involves the interplay of several magmatic liquids in processes of fractional crystallization, magma mixing, liquid immiscibility, and the probable existence of compositionally zoned magma chambers in the late stages of each cycle. The compositionally zoned chambers existed over the time period represented by the upper felsic portion of each cycle. 相似文献
15.
The post-caldera Kameni islands of the Santorini volcanic complex, Aegean Sea, Greece are entirely volcanic and were formed by eleven eruptions between 197 B.C. and 1950. Petrographic, mineral chemical and whole-rock major and trace element data are presented for samples of lava collected from the products of seven eruptive cycles which span the entire period of activity. The main phenocryst phases are plagioclase, clinopyroxene, orthopyroxene and titaniferous magnetite, which are weakly zoned (e.g. plagioclase — An55 to An42). The lavas are typical calc-alkaline dacites and show a restricted range of composition (from 64.1 to 68.4 wt. % SiO2). The phenocrysts were in equilibrium with the melts at temperatures of 960–1012 °C, pressures of 800–1500 bars and oxygen fugacities of 10–9.6-10–9.9 bars. The pre-eruptive water content of the magmas was 3–4 wt. % but since the lavas contain only 0.1–0.4 wt. % H2O, a considerable amount (about 0.01–0.015 km3) of water was lost prior to or during eruption. This indicates that the magmas rose to the surface gradually allowing the (largely) non-explosive loss of volatiles. The lavas were probably extruded initially from more or less cylindrical conduits which developed into fissures as the eruptions proceeded. The post-caldera lavas evolved from more mafic parental magmas (basalt-andesite) via fractional crystallization. The small range of compositional variation shown by these lavas can be explained in terms of near-equilibrium crystallization. Analyses of samples of lavas belonging to single eruption cycles and to individual flows indicate that the underlying magma chamber is compositionally zoned. The average composition of erupted magma has remained approximately constant since 1570 A.D. but that fact that the 197 B.C. magma was sligthly richer in SiO2 provides additional evidence that the magma chamber is compositionally zoned. Crystal settling has not affected the composition of the magma over a 2,200 year period of time which indicates that the melts do not behave as Newtonian fluids. Zonation was thus probably established prior to the 197 B.C. eruption though it is possible that it is developed and maintained by crystal-liquid differentiation processes other than crystal settling (e.g. boundary layer crystallization). The data indicate that there has been no significant cooling during 2,200 years; the maximum amount of cooling is <50 °C and is probably less than 30 °C. Two hypotheses are considered to explain the thermal and chemical buffering of the post-caldera magma chamber: (i) The magma chamber is large and heat losses due to conduction are largely compensated by latent heat supplied by thick, partially crystalline cumulate sequences. (ii) Periodic influx of hot mafic magma, which does not mix with the dacitic magma, inhibits cooling. The second alternative is favored because the post-caldera lavas differ geochemically from the pre-caldera lavas which signifies that a new batch of magma was formed and/or emplaced after the catastrophic eruption of 1390 B.C., and hence that mafic magmas may still be reaching upper crustal levels. 相似文献
16.
花岗岩结晶分离作用问题——关于花岗岩研究的思考之二 总被引：11，自引：15，他引：11
岩浆结晶分离作用是一个古老的话题,很早就有学者指出,地球内部生成的岩浆大多是玄武质岩浆,大多数花岗岩是由玄武岩结晶分离形成的。本文在考察了岩浆结晶分离作用的制约因素、比较了不同性质岩浆结晶分离作用的特征之后指出:玄武质岩浆可以发生结晶分离作用,因为有与其相关的堆晶岩产出;安山质岩浆也可以发生结晶分离作用,因为也有与其相关的堆晶岩产出。但是,花岗质岩浆似乎不大可能发生结晶分离作用,因为,很少见到有与(富硅的)花岗质岩浆相伴的堆晶岩产出。花岗质岩浆之所以不大可能发生结晶分离作用的原因在于:(1)岩浆的黏性大,它不仅阻滞了矿物的结晶作用(使斜长石不能发育为自形晶),而且阻止了密度大的矿物(例如角闪石)下沉;(2)主要造岩矿物(例如斜长石)的密度与花岗质岩浆的密度相差无几,使结晶分离作用难以进行。本文详细考察了花岗质岩浆中斜长石的行为,指出在花岗质岩浆中斜长石结晶分离几乎是不可能的。那么,文献中大量充斥的花岗岩结晶分离作用的说法是依据什么呢?作者认为,文献中的许多说法可能主要是根据哈克图解得出的,而不是根据实际观察和理论研究得出的。作者认为,玄武岩和花岗岩不仅来源不同,成分不同,而且解释也不同。哈克图解中许多适合玄武岩的解释未必适合花岗岩。由于鲍文反应原理是结晶分离作用的理论基础,因此,文中也对鲍文反应原理进行了评述,并指出文献中存在的一些需要认真对待的问题,例如,从玄武岩-安山岩-英安岩-流纹岩的连续演化序列是不可能的;单元-超单元填图方法是不科学的;中国东部中生代大规模花岗岩不可能是玄武质岩浆结晶分离形成的等等。本文还以 Ajaji el ai.(1998)报道的摩洛哥 Tanncherfi 花岗岩为例,指出结晶分离作用的解释是不可能的。作者认为,花岗岩类的成分变化大,主要可能与源区组成、温度、压力、挥发分、部分熔融程度和过程、混合作用、岩浆分异及结晶分离作用有关。其中,源区组成可能是花岗岩多样性的最重要的原因,而结晶分离作用的影响可能是微乎其微的。本文认为,花岗岩结晶分离作用对于花岗岩成因的意义已经被大大地夸大了,我们应当重新思考结晶分离作用对于花岗质岩浆的意义。由于花岗岩的极端复杂性,许多问题还得不到比较合理的解释,本文的认识只是初步的。 相似文献
17.
Mixing of rhyolite,trachyte and basalt magma erupted from a vertically and laterally zoned reservoir,composite flow P1, Gran Canaria 总被引：1，自引：0，他引：1
The 14.1 Ma composite welded ignimbrite P1 (45 km3 DRE) on Gran Canaria is compositionally zoned from a felsic lower part to a basaltic top. It is composed of four component magmas mixed in vertically varying proportions: (1) Na-rhyolite (10 km3) zoned from crystal-poor to highly phyric; (2) a continuously zoned, evolved trachyte to sodic trachyandesite magma group (6 km3); (3) a minor fraction of Na-poor trachyandesite (<1 km3); and (4) nearly aphyric basalt (26 km3) zoned from 4.3 to 5.2 wt% MgO. We distinguish three sites and phases of mixing: (a) Mutual mineral inclusions show that mixing between trachytic and rhyolitic magmas occurred during early stages of their intratelluric crystallization, providing evidence for long-term residence in a common reservoir prior to eruption. This first phase of mixing was retarded by increasing viscosity of the rhyolite magma upon massive anorthoclase precipitation and accumulation. (b) All component magmas probably erupted through a ring-fissure from a common upper-crustal reservoir into which the basalt intruded during eruption. The second phase of mixing occurred during simultaneous withdrawal of magmas from the chamber and ascent through the conduit. The overall withdrawal and mixing pattern evolved in response to pre-eruptive chamber zonation and density and viscosity relationships among the magmas. Minor sectorial variations around the caldera reflect both varying configurations at the conduit entrance and unsteady discharge. (c) During each eruptive pulse, fragmentation and particulate transport in the vent and as pyroclastic flows caused additional mixing by reducing the length scale of heterogeneities. Based on considerations of magma density changes during crystallization, magma temperature constraints, and the pattern of withdrawal during eruption, we propose that eruption tapped the P1 magma chamber during a transient state of concentric zonation, which had resulted from destruction of a formerly layered zonation in order to maintain gravitational equilibrium. Our model of magma chamber zonation at the time of eruption envisages a basal high-density Na-poor trachyandesite layer that was overlain by a central mass of highly phyric rhyolite magma mantled by a sheath of vertically zoned trachyte-trachyandesite magma along the chamber walls. A conventional model of vertically stacked horizontal layers cannot account for the deduced density relationships nor for the withdrawal pattern. 相似文献
18.
The olivine phenocrysts of four basalts (12004, 12008, 12009 and 12022) are concentrically zoned and have core compositions about as magnesian as experimentally produced liquidas olivines, features which suggest fractional crystallization and absence of Fe-Mg reequilibration. In the magnesium- and olivine-rich granular basalt 12035, the olivines are either unzoned or are zoned toward adjacent grains and have compositions more iron-rich than either cumulus olivines or liquidus olivines (should the rock represent the composition of a melt), features which suggest extensive Fe-Mg re-equilibration. 相似文献
19.
Strong Compositional Zonation in a Silicic Magmatic System: Los Humeros, Mexican Neovolcanic Belt 总被引：2，自引：0，他引：2
The Los Humeros volcanic center, located 180 km east of MexicoCity, is one of several silicic centers in the ‘back-arc’portion of the Mexican Neovolcanic Belt. Eruptive products spanthe compositional range from high-silica rhyolite to basalt.During the last 0?46 Ma, three major explosive eruptions andan extended period of lava flow emplacement periodically sampledan integrated magma reservoir that was initially zoned fromrhyolitic uppermost levels to andesitic and perhaps basalticlower levels, with compositional gaps in the ranges 63–67and 72–75 per cent SiO2. The compositional zonation canlargely be explained by fractional crystallization, but mustbe accompanied by assimilation to explain the range of Sr andNd isotopic ratios. Higher than predicted concentrations ofNi, Cr, and strongly incompatible elements such as Rb and Bain andesites suggest continuous replenishment of a fractionatingchamber by mantle-derived basalts. The volumetric predominanceof rhyolite in the early history of the center points to a longperiod of accumulation of differentiates without eruptive withdrawal. Once volcanic activity started tapping the chamber, eruptiverates seem to have exceeded the rate of regeneration of differentiatedmagma. Although there is overlap in the compositional zonationof the products of successive eruptive events, the dominantvolume of each is always more mafic than that of the precedingeruption, indicating only limited regeneration of differentiatedmagmas during repose periods. This seems to have been a consequenceof the chamber remaining in approximate thermal balance duringthe last 0?46 Ma, as shown by similar Fe-Ti oxide temperaturesfor given magma compositions, regardless of age. Calculationssuggest that the chamber received thermal input through theinjection of basalt at an average rate of 0?1 km3 per thousandyears. Apparently this thermal input was too small to generatedifferentiated magma by partial melting of the wall rocks ofthe chamber, but large enough to offset conductive or hydrothermalcooling that would promote differentiation by extensive crystallization. 相似文献
20.
G. Wörrier J. -M. Beusen N. Duchateau R. Gijbels H. -U. Schmincke 《Contributions to Mineralogy and Petrology》1983,84(2-3):152-173
Twenty six whole rocks, seven matrix and fifty three mineral separates from the compositionally zoned late Quaternary Laacher See tephra sequence (East Eifel, W Germany) were analyzed by instrumental neutron activation. These data document the chemical variation within the Laacher See magma chamber prior to eruption with a highly fractionated phonolite at the top and a more mafic phonolite at its base as derived from other data. Incompatible elements such as Zn, Zr, Nb, Hf, U, light and heavy rare earths are extremely enriched towards the top whereas compatible elements (e.g. Sr, Sc, Co, Eu) are strongly depleted. Semicompatible elements (Ta and some middle REE) are depleted at intermediate levels. This chemical variation is shown by whole rock and matrix data indicating the phonolite liquid was compositionally zoned regardless of phenocryst content. Hybrid rocks (phonolite-basanite) show the largest concentrations for compatible elements. All elements (except Rb) display continuous compositional variations with regard to the stratigraphic position of pumice samples. From these data we are able to distinguish three main units: An early erupted highly fractionated magma, the main volume of evolved phonolite and a mafic phonolite as the final products. The extreme variation of trace element distribution coef ficients (K) for 9 mineral phases with respect to stratigraphic position (resp. matrix composition) cannot be explained by conventional mechanisms. We postulate a significant modification of the trace element content of the phonolite melt by liquid-liquid controlled differentiation processes subsequent to and/or contemporaneous with (fractional) crystallization which caused disequilibrium between phenocrysts and host matrix. Therefore, our “distribution coefficients” deviate from equilibrium partition coefficients equivalent to the amount of this post crystallization modification of the matrix composition. The relationship between varying K and matrix composition is demonstrated by a ΔK-ΔM-diagram (variation of K versus variation of matrix, M). Different parts of this diagram relate to different parameters (T, P, polymerization, complex-building, equilibrium crystallization in a zoned magma column and post crystallization disequilibrium effects) which are responsible for the variation of distribution coefficients in general. The ΔK-ΔM-diagram may allow to distinguish between different processes affecting the distribution coefficients measured in natural volcanic rocks from a differentiating magma system. 相似文献