共查询到19条相似文献，搜索用时 250 毫秒
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白云鄂博矿床白云石型矿石中独居石单颗粒U-Th-Pb-Sm-Nd定年 总被引：5，自引：3，他引：5
使用交换树脂TRU Spec同时分离REE、U、Th、Pb及其他的元素,然后用阴离子交换树脂纯化Pb并用萃淋树脂分离纯化Sm和Nd,Sm、Nd、U和Pb的定量测定借助同位素稀释法,Th的定量测定则用ICP-MS分析,Nd和Pb同位素组成分析用质谱法(TIMS),从而实现独居石U-Th-Pb-Sm-Nd联合定年。用这种方法可以在同一样品上,同时得到U-Th-Pb和Sm-Nd同位素年龄记录。白云鄂博矿床白云石型稀土矿石中12个单颗粒独居石的U-Th-Pb-Sm-Nd同位素联合定年给出Sm-Nd等时线年龄为1008±320 Ma,其中8个独居石的Th-Pb等时线年龄为1231±200 Ma,此二年龄在误差范围内相似。在同一组独居石样品上得到一致的Th-Pb与Sm-Nd的中元古年龄,表明白云鄂博在中元古代的稀土成矿作用是可能的。本文独居石的Th-Pb 和Sm-Nd年龄与以前报道的独居石加里东期Th-Pb年龄差别很大,此问题尚需进一步研究。 相似文献
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热液矿床中含钙矿物的Sm—Nd同位素定年 总被引：7，自引：0，他引：7
Sm、Nd的离子半径相似、化学性质很相近，母体衰变形成的子体易在矿物晶格中保存下来，故矿物或岩石中的Sm—Nd同位素体系易保持封闭，具有较强的抗风化、抗蚀变能力，是一种有效的定年工具。但长期以来，Sm—Nd同位素体系主要用于前寒武纪地质年代学研究，研究对象主要限于陨石、月球岩石、古老的基性、超基性岩和前寒武纪老地层等。近年的研究表明，热液矿床中一些含钙矿物，其REE含量较高，Sm／Nd分馏明显，是很有潜力的Sm—Nd同位素定年对象，能对矿床的成矿时间进行精确制约。本文对萤石、白钨矿、方解石、电气石等常见热液含钙矿物的Sm—Nd同位素研究现状进行归纳总结，并对该方法在中国热液矿床中进一步的应用前景进行了展望，以期促进Sm—Nd同位素成矿年代学在我国的推广和应用。 相似文献
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本文对《平潭—南澳变质岩带的Sm—Nd年代学研究及其大地构造意义》一文中涉及的某些问题,例如应用Nd模式年龄的前提条件,正变质岩Sm—Nd等时线年龄和Nd模式年龄的关系以及副变质岩Sm—Nd等时线年龄的解释提出了一些商榷意见。 相似文献
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本文研究了偶氮氯膦-mN在磷酸—草酸—焦磷酸钠体系中以锌-EDTA二乙酯作缓冲掩蔽剂在钇族稀土和常见元素存在下,不经分离,直接测定铈族稀土元素的可能性。 一、实验部分 偶氮氯膦-mN:0.05％水溶液(上海师大)。 Zn-EDTA二乙酯0.15％水溶液:称取EDTA二乙酯15克;乙酸锌15克溶于1000毫升水中,摇均。 混合铈组稀土标准:用光谱纯的稀土氧化物按La∶Ce∶Pr∶Nd:Sm等于50∶30∶20∶10∶10配成每毫升含10微克的酸性稀土溶液(0.1N盐酸)。 混合钇族稀土标准:按Y∶Ho∶Yb∶Lu等于66∶4∶18∶6配制成每毫升10微克的标准溶液(0.1N盐酸)。 相似文献
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本文主要介绍了分离Sm-Nd的3种化学方法,其中有适合分离高含量Sm,Nd的了酮-疏氰酸铵纸色层法;适合分离一般含量Sm,Nd的P_(204)柱色层法;适合低含量Sm,Nd的加压离子交换法。同时介绍应用Sm-Nd法得出的我国第一条Sm-Nd等时线,测出了冀东早太古代岩石Sm-Nd同位素地质年龄。 相似文献
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徐步台 《矿物岩石地球化学通报》1987,(1)
Sm和Nd均属稀土元素,放射性同位素~(147)Sm经α衰变的产物是稳定同位素~(143)Nd,其半衰期为1.06×10~(11)年。由于岩石中的稀土元素丰度一般都非常低,而~(147)Sm的半衰期又特别长,对稀土同位素的分离和超微量测定难度就相当大。因此,Sm-Nd法在地质年代学中长期得不到实际应用。直至近十年来,随着Sm-Nd同位素分离测试技术的迅速发展,并对它们的地球化学演化规律取得了新的认识之后,Sm-Nd法的应用才日趋广泛。它也同Rb-Sr法一样不仅可进行等时线年龄测定,而且还可以进行模式年龄测定。 相似文献
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政和“稻香组”地质时代的确定及其变质火山岩岩石成因探讨 总被引：5，自引：0，他引：5
地质时代置于晚震旦—寒武纪的“稻香组”主要出露于政和城关南面、稻香、铁山等地。根据这套变质岩系岩石共生组合、岩石化学、微古生物和稳定同位素及其 Sm—Nd 同位索模式年龄(T_(DM)~(ND)800±50Ma,作者认为:“稻香组”应属于早震旦世中基性火山—碎屑沉积建造的东岩组。根据稀土元素和 Sm—Nd 同位素地球化学资料分析,该套变质中基性火山岩岩源来自壳幔混合分离结晶作用的产物,是早震旦世华南海域火山喷发—钙硅碎屑沉积建造的重要组成部分。 相似文献
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贵阳地区碳酸盐岩风化红粘土剖面稀土、微量元素分布特征 总被引：7，自引：1，他引：6
碳酸盐岩风化形成的红粘土保存着喀斯特发展演化历史证据,同时也是喀斯特地区土壤研究重要对象。通过对西南喀斯特发育中心部位的贵阳市碳酸盐岩风化形成的红粘土剖面的结构、稀土、微量元素分布特征研究,提出红粘土层可划分为：下层为暗褐色—褐色粘土层,上层为黄色、黄褐色、紫红色粘土层。下层暗褐色—褐色粘土层具有较高的稀土、微量元素含量;上层黄色、黄褐色、紫红色粘土层稀土、微量元素含量较低。下部暗褐色—褐色粘土层中,特别是红粘土层最底部,Be、 Sr、 Nd、 Sm 等元素超常富集,表明上部元素大量向底部迁移富集,元素发生广泛的混合。因此,利用Be、 Sr、 Nd、 Sm、Pb等同位素研究红粘土年代学是非常困难的。同时,提出下部暗褐色—褐色粘土层超富集重金属、放射性元素U、 Th、Rn等,其对环境有一定的污染,在城市建设时应该加强处理。 相似文献
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本文用ＣＬ－Ｐ５０７萃淋树脂作为萃取色层的固定朴要研究了经Ｄ２３５阴离子树脂交换分离钴后和稀土镨钕钐的分离，对洗脱剂，洗脱条件进行了探讨，并选择出最佳分离条件。 相似文献
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A study of lateritic soils and samples of ground and river waters was carried out in the Nsimi-Zoetele, a tropical watershed in the southern Cameroon. The Nd isotopic compositions and concentrations of Nd and Sm were determined. It was found that the Nd isotopic composition of the river waters was much more radiogenic than the parent rocks, and that the Nd in the waters is not homogeneous but is carried by different dissolved and complexed components that are not isotopically homogenized. The soil profile shows a regular increase in εNd going from the parent rock (εNd = −36) to εNd = −18 near the top of the profile. The Nd transported in the river is thus not representative of the parent rock but reflects the results of differential weathering of constituent minerals and the redeposition of REE in phosphates and a significant contribution of radiogenic Nd from dust. The concentration of Nd in the river water is far above that found in temperate climate rivers and thus this type of tropical river may play a dominant role in the marine Nd and REE budget. It is suggested that the correlation of REE with DOC is related to DOC fixing some dissolved REE but that the REE in solution is governed by other mechanisms. No major shifts were found in Sm/Nd; however, a regular progression from the parent rock through the lateritic profile was found. The upper laterite profile shows large, almost uniform depletions in all REE below Tb and enrichment above. Complementary behavior was found in the lower part of the section. The concentration of Nd relative to the immobile elements Zr and Ti in the laterite is depleted by a factor of ∼10. Th, Nd and Sm are enriched in the lowest zone sampled and must reflect redeposition of REE from the upper part of the weathering section and is associated with phosphate formation. It is concluded that the soil evolution involves both differential dissolution of primary phases from the parent rock, significant to major input of REE from atmospheric dust from other regions, and the formation of diagenetic phases, particularly phosphates. 相似文献
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The development is described of a mixed-solvent ion-exchange technique for separating trace amounts of rare-earth elements from silicate rocks and minerals. A two-column method is used, bulk separation of rare earths from other elements being accomplished on the first, and separation into three groups for mass-spectrometric analysis on the second. This has been applied to the determination of nine REE (La, Ce, Nd, Sm, Eu, Gd, Dy, Er and Yb) in standard rock samples. Smooth variation of the chondrite-normalized abundance distributions and comparison with other published results indicate that the accuracy of the method, with the exception of La, is generally ± 2%. 相似文献
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There is a broad correlation between the εNd values for rivers (including both the water and the particulate material it carries) and the age of the source terrain. This paper presents Nd isotope distribution data for soil, soil water, groundwater, and stream water samples gathered in a small catchment in northern Sweden. The results show that the release of Nd and Sm from boreal forests into streams and, eventually, into the oceans is more complicated than previously realized. The weathering of till causes changes in both the Nd isotopic composition and Sm/Nd ratios. Both the Sm/Nd ratio and εNd were higher in strongly weathered soils horizons than in less weathered till, since minerals with high Sm/Nd ratios were, on average, more resistant to weathering than those with low Sm/Nd ratios. In contrast to the situation for the main minerals and the major elements, the weathering of rare earth elements (REE) was not restricted to the E-horizon: the measured REE concentrations continued to increase with depth in the C-horizon. In addition, REE released by weathering in the upper parts of the soil profile were partly secondarily retained at deeper levels. Therefore, the dissolved Nd released by weathering in the upper soil horizons was trapped and did not enter the groundwater directly. Rather, the Nd in the groundwater largely originated from weathering within the groundwater zone. However, this was not the only source of Nd in the stream water. The Nd isotope composition and Sm/Nd ratio were determined by the mixing between of Nd and Sm in the groundwater and REE-carrying organic material washed out of the soil profile. The groundwater close to the stream reaches the upper soil horizons during high discharge events such as snowmelts, and organic matter carrying Nd and Sm is washed out of the soils and thus released into the stream. Therefore, the Nd exported from catchment is derived from both the weathering within the groundwater zone, and the organic matter washed out from the soil. If longer timescales with more advanced weathering stages in the groundwater zone are considered, it cannot be ruled out that there will be a shift towards more radiogenic values in the exported Nd. Recorded shifts in the Nd isotopic composition in the ocean may thus not only reflect changed source regions, but also the weathering history of the same source region. 相似文献
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Clastic sedimentary rocks, deposited on eastern North America in response to the Taconian Orogeny, commonly have Sm/Nd isotope relationships indicating substantial isotope disturbance near or subsequent to the time of sedimentation that may be associated with severe depletion in light rare earth elements (LREE). Affected units [Normanskill Formation (Austin Glen and Pawlet Members), Frankfort Formation and Perry Mountain Formation] are widely separated both geographically (western New York to western Maine) and stratigraphically (Middle Ordovician to Silurian). A model is proposed for the most likely explanation of the observed REE and Sm/Nd isotope relationships involving a two‐stage process. In the first stage, REE are redistributed on a mineralogical scale (dissolution/precipitation on a sample scale) often with the involvement of REE‐enriched trace phases such as apatite and monazite. This stage typically takes place during diagenesis but may also take place later during metamorphism and/or recent weathering, and results in isotope re‐equilibration on a sample scale. The second stage occurs when one or more of these phases is redissolved and REE are transported on large advective scales. Where LREE‐enriched phases are involved, this gives rise to LREE depletion in whole rocks. The timing of this second stage cannot be constrained from Sm/Nd isotope data and may take place at any time subsequent to the isotope re‐equilibration. Such complex histories of REE redistribution may result in serious errors in estimating Nd model ages but not in estimating the Nd isotope composition at the age of sedimentation. Thus, Sm/Nd ratios even of unmetamorphosed sedimentary rocks have to be carefully evaluated before the calculation of depleted mantle model ages for the provenance. 相似文献
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牙形石作为划分地层的标准化石, 具有确切的地层层位和较高的REE含量, 并不容易受成岩作用的影响, 因此作为研究古海水演化的指示剂引起人们的广泛关注.利用同位素稀释法对扬子克拉通三峡地区寒武纪—三叠纪海相碳酸盐岩中代表古海水化学组成牙形石的Sm/Nd比值进行测定, Sm/Nd比值在0.108-0.348之间, 有较大的变化范围.建立Sm/Nd比值随时间的演化曲线, 并结合已有沉积地层学和沉积地球化学的成果进行研究, 结果表明, 古海水Sm/Nd比值变化与海平面升降、古陆块的隆起有明显对应关系, 同时, 区域性构造运动, 如海底地壳拉张产生的幔源组分和地幔柱活动也会影响古海水的Sm/Nd比值.因此, 古海水的Sm/Nd比值对海平面的升降、古大陆的风化作用和区域构造事件有指示意义. 相似文献
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The criteria for the evaluation of the REE composition of phosphorites and sedimentary rocks have been determined. These data are required to reconstruct depositional environments. Literature data on the geochemistry of some phosphorite deposits of Eurasia are considered. The REE patterns of Mesozoic phosphorites of the East European Platform are studied. On the basis of REE contents, the ratios of lanthanides and fields on the La–(Nd + Sm)–(Y + Dy), La–(Ce + Nd + Sm)–(Y + Dy), and LREE–MREE–(HREE×10) diagrams have been determined as indicators of climate and the depth and facies conditions of sedimentation. 相似文献
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MASUSDA Akimasa 《《地质学报》英文版》2004,78(5):1109-1121
Rare earth element (REE) contents, and Sr and Nd isotopic compositions were measured for three suites of mantle xenoliths from the Kuandian, Hannuoba and Huinan volcanoes in the north of the Sino-Korean Platform. From the correlations of Yb contents with Al/Si and Ca/Si ratios, the peridotites are considered to be the residues of partial melting of the primitive mantle. The chondrite-normalized REE compositions are diverse, varying from strongly LREE-depleted to LREE-enriched, with various types of REE patterns. Metasomatic alteration by small-volume silicate melts, of mantle peridotites previously variably depleted due to fractional melting in the spinel peridotite field, can account for the diversity of REE patterns. The Sr/ Ba versus La/Ba correlation indicates that the metasomatic agent was enriched in Ba over Sr and La, suggestive of its volatile-rich signature and an origin by fluid-triggered melting in an ancient subduction zone. The Sr and Nd isotopic compositions of these xenoliths, even from 相似文献
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武都黄土剖面稀土元素研究 总被引：9，自引：0，他引：9
武都剖面晚更新世以来黄土的稀土元素地球化学分析结果表明，轻重稀土元素具有比黄土高原其他地区较强烈的分异作用，而这种强烈的分异作用，与其较高的粘土矿物含量及其吸附作用相关；另一方面，武都稀土元素具有与其他地区黄土相似的稀土分布模式；反映沉积物来源的特征参数显示，武都黄土与黄土高原典型剖面十分一致，故具相同来源。 相似文献