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1.
郭聪  赵正  刘战庆  吴小辉  刘洋 《矿床地质》2024,43(1):102-127
瑶岗仙钨矿是南岭地区唯一一个石英脉型黑钨矿和矽卡岩型白钨矿均达大型规模的超大型矿床。两类钨矿体均产出于瑶岗仙复式花岗岩体的内外接触带,复式花岗岩体主要由中粒黑云母花岗岩和细粒二云母花岗岩组成,但多阶段岩浆演化与两类钨矿化关系问题一直存在较大争议。文章以瑶岗仙矿区中粒黑云母二长花岗岩与细粒二云母二长花岗岩中的黑云母和石榴子石为切入点,对比研究两阶段花岗质岩浆氧逸度、挥发分、结晶分异程度,探讨了岩浆演化对钨矿化成因的制约。结果显示,细粒二云母二长花岗岩相较于中粒黑云母二长花岗岩中黑云母拥有更低的XMg值、更靠近Fe2+端员、更低的Ⅳ（F）和更高的log（fHF/fHCl）fluid值,指示其形成于还原性岩浆环境,且F含量更高,而后者更偏向氧化性,F含量偏低。两类花岗岩中的石榴子石均为岩浆成因的锰铝榴石,从中粒黑云母花岗岩至细粒二云母花岗岩,随着石榴子石中MnO含量的递增,CaO、FeO、MgO含量逐渐降低,Mn/（Mn+Fe）比值、Sc、Zn、Y、HREE含量随MgO降低而逐渐升高,表明细粒二云母二长花岗岩较中粒黑云母二长花岗岩演化程度更高,更有利于W的富集。石英脉型黑钨矿和矽卡岩型白钨矿成矿岩浆均具有低氧逸度和高F含量的特征,与细粒二云母二长花岗岩成岩环境一致。基于上述研究,结合矿区地球物理、地球化学、钻探信息,笔者建立了瑶岗仙矿床深部勘查模型,圈定了大根垄深部石英脉型黑钨矿找矿靶区、杨梅岭深部云英岩型找矿靶区、和尚滩南东侧矽卡岩型白钨矿找矿靶区。  相似文献   

2.
藏南特提斯喜马拉雅东部的错那洞淡色花岗岩产出有白云母、石榴子石、电气石等特征性矿物,显示具有高度分异岩浆岩的特征。从二云母花岗岩到电气石花岗岩到石榴子石花岗岩,碱性长石均为正长石,斜长石从更长石演变为钠长石,白云母Al2O3、Na2O含量逐渐升高,反映花岗岩逐渐向富Al富Na演化的趋势。二云母花岗岩中黑云母XFe值、AlⅥ逐渐升高,表明二云母花岗岩之间存在结晶分异演化。电气石Xvac值、Al、Mg和Fe含量之间的变化,反映电气石花岗岩到花岗伟晶岩岩浆结晶环境中Na含量的增加,表明花岗伟晶岩结晶分异演化程度高于电气石花岗岩。石榴子石高XFe、XMn值的特征,也是高分异花岗岩的标志。上述矿物学研究结果表明,错那洞二云母花岗岩是由岩浆早期结晶矿物与残余的母岩浆组成的糊状物经过长期结晶形成的,而电气石花岗岩和石榴子石花岗岩由从晶粥体中分离出来的衍生熔体形成。  相似文献   

3.
严翔  陈斌  王志强  段晓侠 《岩石学报》2019,35(2):558-588
西伯利亚板块和华北克拉通之间的古亚洲洋最终消减闭合的时间问题一直存在很大的争议,对区域内A型花岗岩的研究可以为该问题的解决提供有效约束。本文详细研究了华北克拉通北缘牛圈银矿区及其外围出露的海西期A型花岗岩和相关的暗色镁铁质微粒包体及辉绿岩脉的地质年代学和地球化学特征,以期解释其岩石成因并讨论构造指示意义。牛圈银矿区的花岗岩主要包括中粗粒黑云母二长花岗岩和细粒钾长花岗岩,锆石U-Pb定年结果表明中粗粒黑云母二长花岗岩和细粒钾长花岗岩分别形成于268.7±3.2Ma和254.2±2.8Ma,基性辉绿岩脉则形成于267.6±3.9Ma,与矿区早期中粗粒黑云母花岗岩几乎同时代或略晚。矿区两期花岗岩都具有弱过铝质特征,属于高钾钙碱性-钾玄岩系列岩石,均以高SiO2、富碱、高FeOT/（FeOT+MgO）和Ga/Al比值;贫CaO、MgO、TiO2、P2O5;富集Rb、Th、U、Y、F而亏损Ba、Sr、P、Ti、Eu等为特征,结合矿物学特征（半自形石英、他形铁质黑云母、出现条纹长石、缺乏碱性暗色矿物等）表明它们均为铝质A2型花岗岩。这也得到了较高的全岩锆石饱和温度（TZr）的支持,中粗粒黑云母二长花岗岩和细粒钾长花岗岩的岩浆结晶温度分别为784~822℃（平均值805℃）和843~871℃（平均值856℃）。中粗粒黑云母二长花岗岩中广泛发育镁铁质暗色包体。本文认为牛圈中粗粒黑云母二长花岗岩为古元古界红旗营子群基底杂岩中的花岗质片麻岩为主的中下地壳物质部分熔融,并与幔源基性岩浆发生岩浆混合作用形成的。年代学、主微量元素及Sr-Nd同位素数据表明,牛圈细粒钾长花岗岩与中粗粒黑云母二长花岗岩不是同一岩浆房演化的产物,而是代表两期岩浆活动,且晚期细粒钾长花岗岩形成过程中地幔物质添加相对更多。通过对牛圈银矿区两期A型花岗岩的研究,结合前人关于华北克拉通北缘中二叠世碱性岩浆岩带的研究,本文认为华北北缘在中二叠世伊始（~270Ma）就已经发生构造体制转换并进入后造山伸展环境,古亚洲洋的最终闭合可能早于270Ma。从牛圈早期中粗粒黑云母二长花岗岩到晚期细粒钾长花岗岩的相继侵位,伴随着更多的地幔物质的加入,其A型花岗岩特征愈发明显,指示华北北缘被破坏大陆边缘越来越强烈的伸展作用。  相似文献   

4.
湖南千里山花岗岩体的Nd-Sr同位素及岩石成因研究   总被引：24，自引：5，他引：24  
本文利用Rb-Sr等时线方法测得第一阶段似斑状黑云母花岗岩、第二阶段等粒黑云母花岗岩和第三阶段花岗斑岩的成岩年龄分别为（152士9）×l06 a、（137士7）×l06 a ~（136士6）×106 a和（131士1）×l06 a。Sr-Nd同位素资料表明各阶段花岗质岩石均基本上源于地壳物质的重熔。与钨多金属矿化有关的似斑状黑云母花岗岩和等粒黑云母花岗岩属同一岩浆体系分异演化的产物，其钕模式年龄(tDM= 2307×l06 a)反映出成岩物质来自早元古宙地层的重熔。与铅，锌一银矿化有关的花岗斑岩的钕模式年龄(tDM= 1284×l06 ~ 1578×l06 a)示意出其成岩物质来自中元古宙地层的重熔。  相似文献   

5.
黄兰椿  蒋少涌 《岩石学报》2012,28(12):3887-3900
江西省大湖塘钨(钼、铜、锡)矿集区位于江南造山带中段,九岭山脉中段北部之武宁、修水、靖安三县交界区域,是目前世界最大的钨矿之一。本文对该矿床中与成矿关系密切的似斑状白云母花岗岩进行了详细的锆石U-Pb年代学、云母矿物化学、主量元素、微量元素以及Sr-Nd同位素研究。结果表明,LA-ICP-MS锆石U-Pb定年测得大湖塘似斑状白云母花岗岩成岩年龄为144.2±1.3Ma。岩体中白云母显示原生白云母的特征;黑云母属于富铁黑云母,其物质来源是地壳物质,Fe3+/Fe2+组成表明岩浆氧逸度很低。岩石地球化学特征表明似斑状白云母花岗岩为强过铝质的S型花岗岩,表现为高的SiO2(72.88%~73.33%),轻重稀土分馏明显,Eu负异常明显,亏损Nb、Ta,Rb/Sr比值高。似斑状白云母花岗岩的εNd(t)值变化于-7.47~-7.78之间,两阶段模式年龄tDMC为1543~1568Ma, 推测其源区很可能来源于双桥山群的富泥质岩石,双桥山群可能是大湖塘钨矿的初始矿源层。九岭燕山期的岩浆活动发生在侏罗纪和白垩纪之交的早白垩世早期,花岗岩形成于拉张的构造环境。  相似文献   

6.
乌图布拉克岩体位于准噶尔北东缘,额尔齐斯-玛因鄂博构造带南侧。岩体主要由花岗闪长岩和二长花岗岩组成,有少量石英闪长岩和钾长花岗岩。岩体的锆石SHRIMP U-Pb年龄为360.1±3.6Ma。岩石的K2O+Na2O=7.05%~9.48%,A/NKC=0.91~1.04,属准铝-过铝质“I”型花岗岩。岩石稀土总量低,∑REE为72×10-6~184×10-6,轻稀土富集,(La/Yb)N=5~13。石英闪长岩、花岗闪长岩、二长花岗岩具弱的铕负异常或无明显异常（δEu=0.72~0.98）;钾长花岗岩铕负异常明显（δEu=0.15~0.21）。在微量元素配分模式中,具有Sr、Ba、P、Ti的亏损,而Nb、Ta亏损不明显。岩石有低的Sr初始值（0.70165~0.70462）和高的εNd(t)u（+4.7~+6.9）。2个样品的Nd模式年龄分别为758Ma和551Ma。上述特征表明,岩浆可能具有较复杂的来源,推测该岩体岩浆可能来源于年轻的玄武质地壳,并有幔源物质的加入。综合本文资料及区域地质特征分析,阿尔泰造山带后碰撞时限可能为360~290Ma,即泥盆纪末-石炭纪末。  相似文献   

7.
松林口岩体位于松潘—甘孜造山带中东部,为确定岩体的侵位时代和地球化学特征,通过镜下薄片观察、主微量元素分析以及锆石U-Pb测年,对松林口岩体进行了研究。结果表明,松林口岩体由二长花岗岩体和花岗闪长岩体组成,花岗闪长岩锆石206Pb/238U年龄加权平均值为（212.4±0.9） Ma （MSWD=0.66）,二长花岗岩锆石206Pb/238U年龄加权平均值为（222.4±1.1） Ma （MSWD=0.39）,形成于晚三叠世,由两期次岩浆作用形成;岩石的SiO2含量56.56%~61.97%;铝饱和指数A/CNK=0.93~1.05,全碱含量3.78~5.38,K2O/Na2O=1.02~1.68,里特曼指数σ=1.194~1.612,样品属于准铝质中—高钾钙碱性岩系列。岩石轻重稀土比值LREE/HREE=5.22~7.13,LaN/YbN比值为6.93~8.96,轻、重稀土分异较明显,具较强的负Eu异常。岩石Mg#值较高（50.97~61.27）,w（Rb）/w（Sr）为0.12~0.25,Rb-（Y+Nb）图解显示为后碰撞环境。因此,松林口二长花岗岩—花岗闪长岩属后碰撞准铝质中—高钾钙碱性I型花岗岩类。  相似文献   

8.
宣城矿集区是长江中下游成矿带内新提出的矿集区,近年来取得了重大的找矿突破,尤其是大型斑岩型铜金矿的发现使宣城矿集区逐渐成为研究热点。宣城矿集区一系列的斑岩-矽卡岩矿床均与早白垩世侵入体密切相关。荞麦山铜钨矿床是区内典型的矽卡岩矿床,矿床形成与花岗闪长斑岩密切相关,且花岗闪长斑岩发育较多的暗色包体。确定暗色包体的成因有助于深入理解含矿岩体的岩浆演化过程及成矿意义。本次工作以荞麦山矿床花岗闪长斑岩和暗色包体作为研究对象进行U-Pb同位素年代学、岩石及矿物地球化学、全岩Sr-Nd、锆石Hf-O同位素地球化学分析,探讨暗色包体及成矿岩体的源区、岩浆演化过程及其对成矿的意义。暗色包体的形成时代为141Ma（MSWD=0.8）,（87Sr/86Sr）i值为0.7059~0.7069,εNd（t）值为-6.0~-9.2,εHf（t）值为-12.7~-5.8,δ18O值为5.8‰~7.7‰;寄主岩石形成时代为140Ma（MSWD=0.3）,（87Sr/86Sr）i值为0.7061~0.7064,εNd（t）值为-8.7~-7.7,εHf（t）值为-12.1~-8.1,δ18O值为5.6‰~7.4‰。此外,暗色包体与寄主岩石主要氧化物含量与SiO2含量呈线性负相关趋势、微量元素特征相似和寄主岩石斜长石斑晶的不平衡结构及捕掳晶的发现指示荞麦山暗色包体为岩浆混合成因,花岗闪长斑岩为起源于富集地幔的岩浆与壳源岩浆混合成的母岩浆侵位而来,同时幔源岩浆和壳源岩浆的混合也分别提供了成矿金属元素铜和钨,最终形成了铜钨共生的荞麦山矿床。  相似文献   

9.
东天山造山带的图拉尔根镁铁-超镁铁杂岩体为一个早古生代长期活动的幔源岩浆通道，大型铜镍钴硫化物矿体赋存于Ⅰ号超镁铁质岩体的顶部，不同类型岩石中辉石矿物的流体挥发份化学组成以H2O为主（平均91%，5400.4mm3/g），其次为H2（2.0%）、H2S（2.3%）和CO2（2.1%）；赋矿角闪橄榄岩中CO2和H2S含量最高，辉长岩中流体挥发份含量低于辉石橄榄岩和橄榄辉石岩等岩浆早期结晶的岩石。CO2和CH4的δ13C值位于地壳与甲烷氧化的范围内，甲烷同系物的碳同位素组成具有正序分布模式，部分样品（TLG512）释出的CH4和C2H6具有较重的δ13C值和反序分布特征。表明I号岩体不同类型岩石可能是不同期次岩浆活动的产物，成矿岩浆具有富H2O和H2S的特征，可能起源于被流体交代的亏损地幔源区，混染壳源组分可能为俯冲板片来源蚀变沉积有机质组分。  相似文献   

10.
东北黑龙江小古里河-科洛-五大连池-二克山火山岩带是我国近代保存最好的火山群之一,此带火山岩的岩石化学特点全都强碱富钾,K2O/Na2O>1.2,属于一套高钾过碱性火山岩。通过对东北钾质火山岩及金云母橄榄岩地幔捕虏体中钾质矿物金云母、白榴石的成分、结晶环境与岩浆成分及来源关系的研究,认为在岩石圈伸展构造背景下,地幔金云母橄榄岩的低度部分熔融形成钾质岩浆,钾质岩浆上升到地壳浅部经历了白榴石的结晶作用。岩浆演化晚期,因钾质矿物大量晶出导致岩浆相对富钠而出现他形霞石和方钠石等填隙矿物。火山岩及地幔捕虏体中富挥发分矿物金云母、白榴石、磷灰石、霞石和方钠石还提供了钾质岩浆富含H2O、F、Cl、P等挥发分的证据。  相似文献   

11.
阳储岭斑岩型W-Mo矿床位于江南造山带中部,是华南地区最早发现的斑岩型钨钼矿床。已探明WO3资源储量6.13万吨(平均品位0.2%),Mo资源储量1.69万吨(平均品位0.03%～0.06%),其成矿作用与中生代花岗质岩浆活动密切相关。区内发育早期花岗闪长岩和晚期二长花岗斑岩,钨矿体以细脉状和浸染状产于二长花岗斑岩体内,而花岗闪长岩内未见矿化。两期岩浆活动与钨成矿的关系尚不明确,制约其含矿差异性的因素尚不清楚。本文以花岗闪长岩和二长花岗斑岩中的黑云母为研究对象,对比研究两类岩浆结晶分异程度、氧逸度、岩浆流体卤素浓度,探讨其对钨成矿的制约。黑云母主量元素分析结果显示,阳储岭两类岩浆岩均为壳源,但显著不同于S型花岗岩的Mg/(Fe+Mg)和AlVI值,指示其具有I型花岗岩的特征。黑云母的微量元素信息显示,相对于花岗闪长岩中的黑云母(类型一),二长花岗斑岩中的黑云母(类型二)显示低的K/Rb、Nb/Ta比值,高的Rb、Cs、Nb和Ta含量,表明其分异程度较花岗闪长岩更高,更有利于钨的富集。两类黑云母所指示的岩浆氧逸度均在NNO缓冲线附近,表明其母岩...  相似文献   

12.
The Sisson Brook W–Mo–Cu deposit was formed by hydrothermal fluids likely related to the Nashwaak Granites (muscovite–biotite granite, Group I; and biotite granite, Group II) and related dykes (biotite granitic dykes, Group III; and a feldspar–biotite–quartz porphyry dyke, Group IV). Chemical data obtained using EPMA and LA-ICP-MS data of primary magmatic biotites were used to investigate magmatic processes and associated hydrothermal fluids.Trace element features of biotite in the Group I two-mica granite suggest other magmatic processes along with a simple fractional crystallization. The K/Rb ratios and compatible elements (Cr, Ti, Co, V, and Ba) in biotite from Groups II, III, and IV decrease, whereas incompatible elements including Ta, Tl, Ga, Cs, Li, and Sn increase with magma fractionation. No correlation of Cu, W and Mo with K/Rb ratios is evident, suggesting that partitioning of Cu, W, and Mo into biotite may not be entirely controlled by magma fractionation.Halogen fugacity of the parental magma of the Nashwaak Granites and related dykes, calculated from zircon saturation temperature shows that Group I has high fHF/fCl ratios (broadly higher than 0), similar to the plutons at the Henderson porphyry Mo deposit. The fHF/fCl ratios of the other groups are generally lower than 0, comparable to the Santa Rita porphyry Cu deposit. The fH2O/fHCl and fH2O/fHF ratios inferred from biotite in the Nashwaak Granites and related dykes range from 3 to 5 and from 4 to 5, respectively. The inferred oxygen fugacity shows that the dyke phases (Groups III and IV) have the oxygen fugacity around the nickel–nickel oxide buffer. The plutonic phases (Groups I and II) have the oxygen fugacity around the quartz–fayalite–magnetite (QFM) buffer at high temperatures and oxidized to nickel–nickel oxide buffer at lower temperatures. This oxidation process in the plutonic phases (Groups I and II) could be caused by H2 release at or near H2O vapor saturation at high H2O/Fe2 +. The magma associated with the biotite dykes (Group III) is more likely the source of the hydrothermal fluids at the Sisson Brook deposit since it has the highest differentiation degree and seems to have formed in an oxidized setting, necessary for Mo to concentrate in the late stage fluids.  相似文献   

13.
The evolution characteristics of Gejiu granites, Yunnan Province are described in terms of their petrology, especially their trace elements and REE geochemistry. The three major types of Gejiu granites: porphyritic biotite monzonitic granite (stage I), medium-coarse-grained biotite-K-feldspar granite (stage II) and two-mica alkali-feldspar granite (stage III) are thought to have been formed successively from the same granite magma source through fractional crystallization (Rayliegh fractionation), because linear correlations are found between log(Rb/Sr)-log Sn, log(Rb/Ba)-log Sn, log(Rb/Ba)-log(Rb/Sr), log La-log Sr, log Ce-log Sr, log Eu-log Sr, etc. In addition, the characteristics of REE distribution patterns in these three major types of granites also reflect the magmatic differentiation features of Gejiu granites. Of the three major types, the two-mica alkali-feldspar granite of stage III underwent the strongest differentiation, and thus has the closest genetic relationship with the Gejiu tin-polymetallic ore deposit. Such tin-polymetal mineralized granites are characterized by high Rb/Sr and Rb/Ba ratios, low K/Rb and ΣCe/ΣY ratios and remarkable Eu depletion.  相似文献   

14.
Whole rock major and trace element and Sr-, Nd- and Hf-isotope data, together with zircon U-Pb, Hf- and O-isotope data, are reported for the Nb-Ta ore bearing granites from the Lingshan pluton in the Southeastern China, in order to trace their petrogenesis and related Nb-Ta mineralization. The Lingshan pluton contains hornblende-bearing biotite granite in the core and biotite granite, albite granite and pegmatite at the rim. In addition, numerous mafic microgranular enclaves occur in the Lingshan granites. Zircon SIMS U-Pb dating gives consistent crystallization ages of ca. 132 Ma for the Lingshan granitoids and enclaves, consistent with the Nb-Ta mineralization age of ∼132 Ma, indicating that mafic and felsic magmatism and Nb-Ta mineralization are coeval. The biotite granites contain hornblende, and are metaluminous to weakly peraluminous, with high initial 87Sr/86Sr ratios of 0.7071–0.7219, negative εNd(t) value of −5.9 to −0.3, εHf(t) values of −3.63 to −0.32 for whole rocks, high δ18O values and negative εHf(t) values for zircons, and ancient Hf and Nd model ages of 1.41–0.95 Ga and 1.23–1.04 Ga, indicating that they are I-type granites and were derived from partial melting of ancient lower crustal materials. They have variable mineral components and geochemical features, corresponding extensive fractionation of hornblende, biotite and feldspar, with minor fractionation of apatite. Existence of mafic microgranular enclaves in the biotite granites suggests a magma mixing/mingling process for the origin of the Lingshan granitoids, and mantle-derived mafic magmas provided the heat for felsic magma generation. In contrast, the Nb-Ta mineralized albite granites and pegmatites have distinct mineral components and geochemical features, which show that they are highly-fractionated granites with extensive melt and F-rich fluid interaction in the generation of these rocks. The fluoride-rich fluids induce the enrichment in Nb and Ta in the highly evolved melts. Therefore, we conclude that the Nb-Ta mineralization is the result of hydrothermal process rather than crystal fractionation in the Lingshan pluton, which provides a case to identify magmatic and hydrothermal processes and evaluate their relative importance as ore-forming processes.  相似文献   

15.
The Jurassic granitoids (200–164 Ma) are distributed in the Korean Peninsula due to the Paleo-Pacific plate subduction. Early Jurassic (200–182 Ma) granitoids are mainly distributed in the southern Korean Peninsula. By contrast, Early to Middle Jurassic (182–164 Ma) granitoids are distributed in the central Korean Peninsula. In this study, we report detailed petrology, zircon U–Pb ages, and whole-rock geochemistry from the Seoul–Uijeongbu and Pocheon–Gimhwa pluton units in the central Korean Peninsula. The Seoul–Uijeongbu unit is dominated by biotite granite, with minor porphyritic biotite and garnet-biotite granite while the Pocheon–Gimhwa unit consists of biotite granite and porphyritic biotite granite, garnet-biotite granite, and two-mica granite. Zircon U–Pb age from those granites gives 180–167 Ma. The granitoids in the Pocheon-Gimhwa unit formed through fractional crystallization from biotite granite and porphyritic biotite granite to garnet-biotite granite, and two-mica granite based on gradually decreasing their Nb/Ta, Zr/Hf, and Eu/Eu* ratios. The strongly fractionated granitoids are garnet-biotite granite and two-mica granite. The LILE enrichment, Ta–Nb, Sr–P, and Eu–Ti troughs, and Ba depletion in most granitoids are similar to those of granitoids due to the subduction in the arc environment. Thus, these Jurassic granitoids (180–167 Ma) are mainly peraluminous granites with moderate crystal fractionation corresponding to I-type granite. Alkali feldspar granite associated with ore mineralization occurs in the Gwanaksan pluton from the southwestern Seoul–Uijeongbu unit. The alkali feldspar granite displays distinct negative Eu anomaly with high contents of Rb, Hf, Cs, and Nb compared with other granites. These characteristics imply that alkali feldspar granite experienced strong hydrothermal activity leading to feldspar ore mineralization compared to the other granites. The formation of a wide range of moderately evolved peraluminous granitoids is presumed to be related to rapid flat-subduction during 182–164 Ma, and the mineralization-related alkali feldspar granite indicates the termination of Jurassic granitoid magmatism in the central Korean Peninsula.  相似文献   

16.
巴斯铁列克钨多金属矿床位于新疆阿尔泰造山带南缘,是近年来在区内发现的首例中型钨多金属矿床。矿体主要产于二叠纪花岗岩与上志留统-下泥盆统康布铁堡组火山-沉积岩接触带的矽卡岩中。钨矿化与矿区花岗质岩石有明显的空间关系。然而,与钨矿化有关的花岗质岩石成因尚不清楚。本文对矿区出露的与矿化关系密切的黑云母花岗岩、二长花岗岩和二云母花岗岩进行了锆石U-Pb年代学和岩石地球化学研究。3个样品的LA-ICP-MS锆石U-Pb加权平均年龄分别为282.3±3.2Ma、284.3±2.2Ma和284.8±2.3Ma,属早二叠世岩浆活动的产物,与成矿年龄一致。所有岩石具有高硅(Si O_2=73.6%~78.3%)、富碱(K_2O+Na_2O=5.15%~9.62%)富钾(K_2O/Na_2O> 1.1)、贫钙(Ca O=0.19%~0.75%)和钛(Ti O_2=0.04%~0.24%)、弱过铝-强过铝质(A/CNK=1.01~1.39)特征。这些岩石稀土元素总量(∑REE)变化较大(变化于20.3×10-6~328×10-6),但二云母花岗岩显示轻重稀土元素分异不明显((La/Yb)N=0.96~2.06)、Eu强烈负异常(δEu=0.07~0.41)的深"V"型稀土元素分布特征,黑云母花岗岩和二长花岗岩显示轻稀土略富集((La/Yb)N分别为2.8~5.5和4.8~7.4)且Eu负异常(δEu=0.33~0.39和0.34~0.63)明显的右倾型稀土元素分布特征。所有样品均显示相对富集Rb、Th、U、Pb元素和相对亏损Nb、Ti、P、Sr、Ba元素,但二云母花岗岩中W含量(4.6×10-6~9.4×10-6)相对低于黑云母花岗岩和二长花岗岩中W含量(分别为15.1×10-6~168×10-6和8.4×10-6~16.0×10-6)。所有样品的锆石具有正的高εHf(t)值(+3.8~+11)和相对年轻的亏损地幔模式年龄(Hf的tDM2为0.60~1.0Ga)。以上特征说明,这些岩石属高钾钙碱性分异I-A过渡型花岗岩。结合区域地质背景,认为这些岩体是二叠纪时期后碰撞伸展环境下两个独立岩浆事件的产物,母岩浆均来源于新生地壳熔体与幔源岩浆,经过高度分异演化后结晶形成矿区岩石。花岗质岩浆活动为巴斯铁列克钨矿床提供了成矿物质,岩浆演化过程(结晶分异与熔体-流体作用)对成矿元素有富集作用。  相似文献   

17.
桃岭-段莘带是位于江南造山带东段的一条东西向展布的燕山期花岗岩带,由7个岩体构成。通过锆石LA-ICPMS定年方法得到该带6个岩石样品的年龄分别为131.2Ma±1.9Ma,131.3Ma±1.9Ma,132.0Ma±1.8Ma,129.7Ma±1.6Ma,149.1Ma±1.8Ma和152.4Ma±2.6Ma。定年结果表明,该带花岗岩存在早、晚两期岩浆活动。早期花岗岩形成时代为晚侏罗世(152.4Ma^149.1Ma),岩性以黑云母二长花岗岩和二云母二长花岗岩为主;晚期花岗岩形成时代为早白垩世(132.0Ma^129.7Ma),岩性以二云母花岗岩和二云母二长花岗岩为主。江南造山带东段燕山期岩浆活动可划分为早、晚两个期次(155Ma^137Ma和137Ma^121Ma),早期岩浆作用和W,Mo多金属成矿密切相关,而晚期岩浆作用成矿作用不显著。桃岭-段莘带燕山早、晚期花岗岩年代学上分别与江南造山带东段燕山早、晚期岩浆岩相对应,这些花岗岩可能是在伸展构造背景下形成。  相似文献   

18.
The Jálama pluton (JP) is a Variscan peraluminous granitoid that intruded into low-grade metasediments from the Central Iberian Zone (CIZ). It comprises a sillimanite-bearing two-mica monzogranite in the inner zone, followed by a tourmaline-bearing two-mica monzogranite, and a marginal tourmaline-muscovite leucogranite in the northern half of the pluton. Microgranitoid enclaves and metasedimentary xenoliths occur locally in monzogranites. The change in rock type from the central monzogranite to the marginal leucogranite corresponds to decreasing TiO2, MgO, FeO, CaO, Sr, Ba, Zr, and ΣREE, and increasing SiO2, Na2O, P2O5, Rb, Li, Cs, Ta, Sn, and W. Fe/(Fe+Mg) ratios in biotite, muscovite and tourmaline increase with increasing Fe/(Fe+Mg) in bulk rock, suggesting an important control of the bulk-rock composition on mineral chemistry. The high peraluminosity, the low CaO and high P contents, as well as the similarity of ε(Nd)300 values in both the granites and metasediments of the southern CIZ constitute strong evidences for a crustal origin of the granite suite, probably by melting of these metasedimentary rocks. Field and petrographic observations, together with mineralogical and geochemical data, suggest that assimilation and mingling/mixing acted in concert with fractional crystallization during the formation of the JP. These processes may also have been important in the evolution of other granitoids from this region.  相似文献   

19.
赣西北大湖塘钨矿田位于江南造山带东段，是世界级超大型W-Cu-Mo多金属矿田，矿化类型以细脉浸染型矿化为主，成矿作用与燕山期高分异花岗岩密切相关。本文通过对平苗矿区与成矿关系密切的燕山期花岗岩中黑云母和斜长石等矿物进行系统的原位主量元素和微量元素分析，探究岩浆的氧逸度、岩浆系统的深部动力学特征和详细结晶过程，并对成矿作用的指示意义进行探讨。研究表明，似斑状二云母花岗岩从岩浆结晶早期到晚期，一直保持较低的氧逸度（NNO-QFM），可能与岩浆源区中更多的富泥质沉积岩有关，这种富钨的泥质岩源区和还原性岩浆环境更有利于钨矿的形成。燕山期花岗岩中斜长石的钙长石（An）和CaO含量均远低于晋宁期黑云母花岗闪长岩，很难为白钨矿化提供足够的钙，而黑云母花岗闪长岩由于体积巨大、钙含量高，很可能为区内大规模的白钨矿化贡献了大量的钙元素。斜长石原位分析显示，An和Al2O3含量之间存在显著的正相关性，而与FeO含量之间无明显的正相关性，FeO随着An含量的增加基本保持稳定，斜长石中Sr和Ba含量之间也无显著的负相关性，表明该区岩浆房为化学成分相对封闭的岩浆系统，岩浆演化过程中只有热量混合和/或减压作用，没有发生明显的镁铁质岩浆注入与混合。因此，钨、铜、硫等成矿元素应主要来自岩浆源区双桥山群的富泥质变质沉积岩和变质玄武岩的贡献，而非由外来基性岩浆的补给提供。该区岩浆岩形成于华南板块由挤压向伸展的转换期，挤压环境有利于在地壳浅部形成长期稳定的、规模较大的高分异岩浆房，促进成矿元素高度富集和大规模岩浆热液的形成，导致该区发生大规模的钨铜矿化。  相似文献   

20.
叶茂  赵赫  赵沔  舒珣  张若曦  杨水源 《岩石学报》2017,33(3):896-906
灵山花岗岩体在平面上为一环状分布的侵入体,中心为角闪石黑云母花岗岩,外围为黑云母花岗岩。在角闪石黑云母花岗岩中分布有大量的暗色镁铁质微粒包体。黑云母是大多数中酸性火成岩中比较重要的一种镁铁质矿物,它能很好地反映寄主岩浆的属性和成岩时的物理、化学条件,因此,本文对这两种花岗岩及镁铁质微粒包体中的黑云母开展了系统的岩相学观察和电子探针化学组成研究,探讨灵山岩体的物质来源、成岩条件和岩浆的混合作用过程。研究结果表明两种花岗岩体的黑云母具有不同化学成分,而暗色镁铁质微粒包体中黑云母的化学成分则变化较大。三种黑云母均在低氧逸度条件下晶出。两种花岗岩中的黑云母均富Fe贫Mg,属于铁质黑云母,含铁系数[(Fe~(3+)+Fe~(2+))/(Fe~(3+)+Fe~(2+)+Mg~(2+))]分别为0.65~0.70,0.72~0.78,FeOT/MgO均接近7.04。MF值[2×Mg/(Fe~(2+)+Mg+Mn)]分别为0.64~0.76和0.48~0.60,指示两种花岗岩的物质来源都是以壳源为主。镁铁质微粒包体中黑云母的MF值变化范围比较大,为0.63~1.06,为铁质黑云母到镁质黑云母,暗示包体岩浆经历过不同程度的岩浆混合作用。镁铁质微粒包体中部分黑云母与角闪石黑云母花岗岩中黑云母的结晶条件相似,而部分则有明显差异,推测是由于基性的镁铁质包体岩浆注入到酸性的花岗岩浆是一个连续多阶段的过程。  相似文献   

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