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1.
缅甸硬玉岩区的硬玉化绿辉石岩 总被引：1，自引：3，他引：1
绿辉石岩是缅甸硬玉岩区一种新的岩石类型,普遍遭受多期次硬玉化.未发生硬玉化的绿辉石含较高TFeO和CaO,但较低的MgO,按化学成分分类部分已属霓石-普通辉石系列的中间相.这种绿辉石很可能是硬玉质的流体/熔体交代地幔辉石岩类的产物,与主期大规模硬玉岩的结晶、钠质-钠钙质角闪石边和钠铬辉石的形成同期或稍后,是该区第Ⅰ期的硬玉化.沿绿辉石的解理或裂隙交代并伴有充填的硬玉是在相对拉张的构造背景下形成的,是该区第Ⅱ期的硬玉化.切割早期绿辉石和硬玉的充填硬玉细脉可能是最晚一期的硬玉化.硬玉化绿辉石岩的结构与显微构造特征指示了在缅甸硬玉岩区,至少存在不少于3期的硬玉化的交代充填作用.文中讨论了硬玉化物质的可能来源,认为其可能与俯冲板片上的沉积物有密切关系. 相似文献
2.
硬玉岩是一种较为少见的高压低温变质岩,不仅具有重要的科研价值,也是一种名贵的玉石材料。本文对产于哈萨克斯坦卡拉干达州伊特穆伦矿区的硬玉岩进行了岩相学观察和矿物化学成分分析,并与缅甸、俄罗斯和危地马拉的硬玉岩进行对比。结果表明,哈萨克斯坦硬玉岩主要组成矿物为硬玉、绿辉石以及少量方沸石和钠沸石,具有粒柱状变晶结构,硬玉矿物的平均化学成分为w(SiO2)=58.38%,w(Al2O3)=21.88%,w(Na2O)=12.69%,w(CaO)=3.40%,w(MgO)=2.58%,w(FeO)=0.29%。不同产地样品中绿辉石和硬玉的SiO2含量相差不大。哈萨克斯坦样品中绿辉石Na2O和FeO的含量略低于缅甸、俄罗斯和危地马拉,MgO和CaO稍高于其它3个产地,硬玉MgO和CaO略高于其它3个产地。 相似文献
3.
俄罗斯极地乌拉尔Сыум-Кеу超基性岩体中的硬玉岩呈脉状在以叶蛇纹石为主的蛇纹岩中产出,硬玉岩由硬玉和绿辉石组成,根据硬玉岩的颜色、结构和构造可划分出三个世代,可能对应存在三期硬玉化过程。第一世代硬玉为主体,灰白色,粗粒结构,致密块状,硬玉分子(Jd)含量54%～88%;第二世代硬玉发育在灰白色硬玉中,呈浅绿色,细粒-隐晶结构,细脉状-囊状,硬玉分子(Jd)含量74%～86%;第三世代硬玉呈绿色-深绿色,半透明-透明,中-细粒结构,瘤状。第二、三世代硬玉达到珠宝首饰级,具有较高的商业价值。根据硬玉岩的产状和晶体具有韵律生长环带及流体包裹体发育等特征,认为硬玉岩是在高压低温环境中由富含Na、Al、Si的流体直接结晶形成的。 相似文献
4.
俄罗斯极地乌拉尔Сыум-Key超基性岩体中的硬玉岩呈脉状在以叶蛇纹石为主的蛇纹岩中产出,硬玉岩由硬玉和绿辉石组成,根据硬玉岩的颜色、结构和构造可划分出三个世代,可能对应存在三期硬玉化过程.第一世代硬玉为主体,灰白色,粗粒结构,致密块状,硬玉分子(Jd)含量54%～88%;第二世代硬玉发育在灰白色硬玉中,呈浅绿色,细粒-隐晶结构,细脉状.囊状,硬玉分子(Jd)含量74%～86%;第三世代硬玉呈绿色-深绿色,半透明-透明,中-细粒结构,瘤状.第二、三世代硬玉达到珠宝首饰级,具有较高的商业价值.根据硬玉岩的产状和晶体具有韵律生长环带及流体包裹体发育等特征,认为硬玉岩是在高压低温环境中由富含Na、Al、Si的流体直接结晶形成的. 相似文献
5.
缅甸硬玉岩地区的热液型钠长石岩 总被引：2，自引：0，他引：2
产于俯冲带内的低温高压带的由单矿物构成的硬玉岩通常伴有钠长石岩,目前对于硬玉岩研究的关注度较高,而对于钠长石岩则相对较低,很少有相关论文报导.产于缅甸翡翠矿区的钠长石岩,经常与硬玉岩相伴而生,是良好的研究样品.钠长石岩的主要矿物成分是低温钠长石,其次含有硬玉、绿辉石、透辉石等辉石类矿物和钠透闪石、蓝透闪石、镁钠闪石等闪石类矿物,此外还有钠沸石等.钠长石沿着解理和裂隙交代硬玉,说明钠长石形成晚于硬玉岩.钠长岩中的主要组成矿物钠长石的形成温度小于300℃,且其形成压力小于0.5kb,推测是在硬玉岩抬升程中通过交代与沉淀作用形成.其内的透辉石有两种类型,一类可能是被交代的硬玉中的透辉石组分会渐进增加,最终形成透辉石.另一类是被绿辉石包裹的透辉石残留,其很有可能是早期来自地幔楔或者俯冲带岩石中的矿物残留,即异剥钙榴岩或辉石岩类,可以视作硬玉化绿辉石岩和硬玉化异剥钙榴岩的矿物学证据.热液型钠长石岩的存在进一步说明缅甸翡翠矿区钠化热液存在现象的普遍性与穿越性. 相似文献
6.
《吉林大学学报(地球科学版)》2015,(Z1)
<正>缅甸硬玉岩是世界上最大和最重要的玉石矿床之一,位于印度板块和欧亚板块之间的新特提斯洋缝合带中。缅甸硬玉岩的研究对于了解新特提斯洋俯冲带流体作用过程具有重要意义,有利于了解洋壳俯冲过程中流体、元素迁移/循环。一般认为硬玉岩的成因和俯冲的大洋岩石圈析出流体相关,但是目前关于其成因还存在争议。根据硬玉的韵律环带特征以及流体包裹体,前人认为它可能来自矿物从流体中的结晶[1];然而硬玉岩中存在有较多的锆石,又说明其可能由流体交代中酸性岩石而形成[2-3]。 相似文献
7.
本文介绍了名义上无水的辉石族矿物中结构水的研究现状,特别是硬玉矿物的结构水红外表征和含量。且笔者以缅甸硬玉岩为研究对象,使用显微红外光谱、电子探针等测试手段,从微观角度研究其中硬玉矿物的结构水表征。研究结果表明:缅甸硬玉岩中硬玉矿物的结构水在红外光谱中主要表征为3 610~3 620 cm-1和3 540~3 550cm-1两个区域的吸收峰,且结构疏松的硬玉岩中硬玉矿物的结构水含量呈现外侧多中间少,结构致密的硬玉矿物的结构水含量各部位较为均一。结构水的含量差异和变化趋势可能是硬玉岩形成时板块俯冲和折返过程中的流体参与作用的结果,进一步为缅甸硬玉岩成因提供了的佐证。 相似文献
8.
缅甸硬玉岩是世界上最大和最重要的玉石矿床之一,位于印度板块和欧亚板块之间的新特提斯洋缝合带中。研究表明,缅甸硬玉岩是新特提斯洋壳俯冲过程中橄榄岩经高压变质、交代作用形成的。对不同变质程度缅甸硬玉岩样品中的流体包裹体的研究表明,缅甸硬玉岩中含有4种类型的流体包裹体:1不含或含少量甲烷的低盐度水溶液包裹体(Ⅰ型),呈孤立状或小群(簇状)产于硬玉晶体核部,或沿着硬玉晶体的生长环带分布,具有原生生长结构;2含石盐子晶的H2O+Na Cl±CH4三相包裹体(Ⅱ型);3纯甲烷(CH4)包裹体(Ⅲ型),可以细分为高密度(Ⅲa)和低密度(Ⅲb)两种;4气相或空包裹体(Ⅳ型)。研究表明,缅甸硬玉岩及其相关岩石在形成和演化过程中发生了多期次流体交代事件。硬玉形成过程中,交代橄榄岩的流体相可能来自海水。首次在缅甸硬玉岩中识别出高盐度的含水包裹体和高密度的含CH4包裹体。高盐度的含水包裹体可能与硬玉岩重结晶过程相关,而高密度的CH4流体可能为俯冲板片的上地幔楔中超基性岩蛇纹石化过程的副产物。计算的流体包裹体等容线表明,硬玉岩演化过程中这些流体包裹体发生了不同程度的再平衡。 相似文献
9.
根据缅甸硬玉岩的化学成分,利用相平衡热力学模拟硬玉岩的成因理论,采用对称溶体的模型表达式:RTlnγi=-∑∑(X0K-Xk)(X0j-Xj)Wkj,根据Holland等的热力学数据库,计算得出硬玉岩中4种端元矿物硬玉(Jd)、普通辉石(Acm)、透辉石(Di)与钙铁辉石(Hed)的Wkj值. 相似文献
10.
蛇纹岩体中的硬玉岩与异剥钙榴岩 总被引：1，自引：4，他引：1
硬玉岩是一种稀少的岩类，常以构造岩包体和脉体的型式产出在蛇纹岩中。本文着重介绍与蛇纹岩化过程密切相关的硬玉岩。这类硬玉岩总是出现在洋壳俯冲碰撞带中，常常与蓝片岩、偶尔也与榴辉岩伴生。通过研究硬玉岩的矿物组合、化学成分和结构构造，综合世界各地硬玉岩产状，可将硬玉岩从广义的变质成因上分为三类，即：在蛇纹岩体中、或其它岩类包体中由交代作用形成的硬玉岩脉体；蛇纹岩中的构造岩成因岩石包体经固相变质作用后形成的块状硬玉岩：以及介于上述两者之间，由变质和交代的共同作用形成的硬玉岩。此外，还对交代成因的硬玉岩在蛇纹岩化过程中与异剥钙榴岩化作用的关系从流体及其化学成分演化的角度进行了分析和研究。提出了在海底和俯冲带上板片的构造背景下硬玉岩形成的模式。 相似文献
11.
俯冲带是壳-幔物质循环的重要场所,硬玉岩可以记录这一循环过程。文中总结了俄罗斯极地乌拉尔硬玉岩的研究进展。硬玉岩呈脉状或透镜状产在蛇纹石化的方辉橄榄岩中,主要由硬玉和绿辉石组成。根据结构和颜色,硬玉可识别出两个世代。硬玉韵律环带发育,含有H2O和CH4流体包裹体,显示从流体中结晶的特征。硬玉岩中的锆石为热液锆石,锆石稀土元素中LaN/YbN=0.001~0.01,LuN/GdN=10~83,Ce/Ce*=2.8~72,显示正异常,δEu=0.53~1.02,类似于岩浆锆石。锆石的176Hf/177Hf=0.282 708~0.283 017,εHf(t)=+6~+17,类似于N-MORB的Hf同位素组成,锆石δ18O组成为5.03‰~6.04‰,平均δ18O为(5.45±0.11)‰,类似于岩浆热液和地幔的氧同位素组成。这可能反映了锆石是被俯冲带流体从途经火成岩中捕获的或者形成锆石的流体与寄主岩(方辉橄榄岩)达到了平衡。硬玉岩稀土元素配分模式近平坦或轻稀土元素略显富集,LaN/YbN比值为0.82~2.42,δEu为1.2~1.6,显示正异常,这与寄主岩稀土元素配分模式相似。富集Sr、Ba、Zr、Hf,Nb为负异常,与岛弧岩浆特征类似。(87Sr/86Sr)t为0.703 400~0.703 519(t=368 Ma),变化较小,与古海水差别明显;εNd(t)值为+0.77~+5.61,变化较大,与寄主岩(方辉橄榄岩)的Nd同位素组成类似,但不同于海水及沉积物的Nd同位素组成,表明硬玉岩的物质来源与寄主岩有明显继承关系,海水与沉积物的贡献不是主要的。矿物学和岩石学证据支持极地乌拉尔的硬玉岩主要是俯冲带流体与橄榄岩相互作用后并在其中结晶的产物。 相似文献
12.
13.
以危地马拉蓝水料与缅甸油青种翡翠为研究对象,通过显微镜观察、岩石薄片观察、X射线粉末衍射分析、激光拉曼光谱分析、扫描电镜分析、电子探针分析等测试手段对两者进行了常规宝石学特征、结构特征、杂质矿物、化学成分等方面的对比研究。结果表明,危地马拉蓝水料发育等粒变晶结构,主要成分为硬玉,含有绿辉石,硬玉环带以2～3层为主,绿辉石分别以自形颗粒、交代残余、沿微裂隙充填3种形式存在,其中白色点状物为钠长石,绿色点状物为霓辉石和绿辉石的混杂物;缅甸油青种翡翠以硬玉为主颗粒相对粗大,呈柱粒状镶嵌结构,硬玉发育3～5层环带结构,绿辉石以脉状充填硬玉颗粒间隙或被硬玉颗粒交代呈孤岛状。危地马拉蓝水料硬玉颗粒与脉状绿辉石的CaO含量均高于缅甸油青种翡翠,另外由于霓辉石的存在,推测两产地翡翠结晶环境中的Ca、Fe含量可能存在差异。 相似文献
14.
为详细探讨含钠长石翡翠的成因机制,笔者选取了若干来自缅甸的含钠长石翡翠,对其进行了详细的岩相学、矿物化学等方面的研究。含钠长石翡翠样品属于豆青种,主要由硬玉、钠长石、方沸石和少量的多硅白云母、钡铝硅酸盐等矿物组成。其中的硬玉发育清晰的环带结构,成分从核部至边缘发生规律性的成分变化。翡翠同时受到两期后期流体活动的改造,第一期以钠长石为代表,第二期以方沸石为代表,流体的改造作用使硬玉呈现碎裂状、碎斑状结构和交代穿孔等结构。结果表明,含钠长石翡翠样品表现出从成岩流体中直接结晶的特点,该流体富集Na、Al、Si、K、Ba以及少量的Ca、Fe、Mg等元素,微量元素则相对富集LREE、HFSE和sr等元素。结合前人的研究结果以及该玉石中的矿物反应关系,笔者推测缅甸翡翠形成的压力和温度范围分别在6-14kbar和300℃-450℃。 相似文献
15.
A new jadeitite jade locality (Sierra del Convento, Cuba): first report and some petrological and archeological implications 总被引：1，自引：1，他引：0
Antonio García-Casco A. Rodríguez Vega J. Cárdenas Párraga M. A. Iturralde-Vinent C. Lázaro I. Blanco Quintero Y. Rojas Agramonte A. Kröner K. Núñez Cambra G. Millán R. L. Torres-Roldán S. Carrasquilla 《Contributions to Mineralogy and Petrology》2009,158(1):1-16
A new jadeitite jade locality has been discovered in the serpentinite-matrix subduction mélange of the Sierra del Convento
(eastern Cuba) in a context associated with tectonic blocks of garnet-epidote amphibolite, tonalitic–trondhjemitic epidote
gneiss, and blueschist. The mineral assemblages of jadeitite jade and jadeite rocks are varied and include combinations of
jadeite, omphacite, albite, paragonite, analcime, clinozoisite-epidote, apatite, phlogopite, phengite, chlorite, glaucophane,
titanite, rutile, zircon, and quartz formed during various stages in their P–T evolution. Field relationships are obscure,
but some samples made almost exclusively of jadeite show evidence of crystallization from fluid in veins. In one of these
samples studied in detail jadeite shows complex textural and chemical characteristics (including oscillatory zoning) that
denote growth in a changing chemical medium. It is proposed that interaction of an Al–Na rich fluid with ultramafic rocks
produced Al–Na–Mg–Ca fluids of varying composition. Episodic infiltration of these fluids, as a result of episodic opening
of the veins, developed oscillatory zoning by direct precipitation from fluid and after reaction of fluid with pre-existing
jadeite. The latest infiltrating fluids were richer in Mg–Ca, favouring the formation of omphacite and Mg–Ca rich jadeite
in open voids and the replacement of earlier jadeite by fine-grained omphacite + jadeite at 550–560°C. This new occurrence
of jadeite in Cuba opens important perspectives for archeological studies of pre-Columbian jade artifacts in the Caribbean
region. 相似文献
16.
《International Geology Review》2012,54(9):899-940
Jadeitite is a rare constituent of serpentinite-matrix mélange bodies from certain subduction complexes. Most jadeitite crystallizes from Na-, Al-, and Si-bearing fluids that are apparently derived from multiple subduction-zone sources. Even though jadeitite is near-end-member NaAlSi2O6 in major element composition and is volumetrically minor in subduction complexes, its trace elements and stable isotopes appear to record fluid compositions not directly seen in other subduction zone metasomatic systems. Prior to our work, how jadeitite-forming fluids interact with serpentinite host rocks and serpentinizing fluids were largely unknown, because serpentinite-to-jadeitite contacts are generally not exposed. In the Sierra de las Minas, Guatemala, we have studied a 3 m-wide pit transecting the contact between a mined-out jadeitite body and its host serpentinite. An apparent transition zone between the former jadeitite and nearby serpentinite exposed in the mine pit contains four texturally distinct rock types of differing outcrop colours, composed of albitites and meta-ultramafic rocks. (The jadeitite body is now represented only by a large spoil pile.) Seven samples from the contact zone, jadeitite from the spoil pile, a serpentinite outcrop approximately 1 m outside the pit, and a jadeitite nodule within the contact zone albitite were analysed for major, minor, and trace elements. Abundances of Al2O3, Na2O, MgO, FeO, Cr, Ni, and Sc track the contact between sheared albitite and foliated meta-ultramafic rocks. These elements change from values typical of Guatemalan jadeitites in the jadeitite block and albitites in the contact zone to values for Guatemalan meta-ultramafic rocks and serpentinites across the contact zone. In addition, the abundances of SiO2, CaO, Fe2O3, K2O, Rb, Cs, and Y show important features. Of greatest interest, perhaps, approximately 15 cm from the contact with meta-ultramafic rock, Zr, U, Hf, Pb, Ba, Sr, Y, and Cs in albitite are greatly enriched compared to elsewhere in the contact zone. Element enrichments spatially coincide with the appearance, increase in modal abundance, and/or increase in grain sizes of zircon, rare earth element (REE) rich epidote, titantite, and celsian within albitite. All of these ‘trace-element-rich’ accessory minerals show poikiloblastic inclusions of albite, which suggests that they grew concomitantly in the metasomatic zone. Graphical and computational methods of evaluating mass changes of metasomatites relative to likely protoliths show that, near the contact, fewer minor and trace elements in albitite show 1:1 coordination with presumed protoliths. Most metasomatitites are enriched in large-ion lithophile elements (LILE) and heat-producing elements (HPE) relative to likely protoliths. Albitite near the contact with meta-ultramafic rocks also shows ultramafic components. Except for a Ca-rich actinolite schist zone, the meta-ultramafic rocks are depleted in LILE and HPE relative to serpentinite; host serpentinite is itself under-abundant in these elements relative to average upper mantle or chondrite. In summary, the metasomatic zone shows more evidence for the introduction of components to albitite and actinolitic meta-ultramafic rock than it does for exchange of protolith components between jadeitite and serpentinite. The fluid that presumably formed the metasomatites was sufficiently rich in LILE and high-field-strength elements (HFSE) to both saturate and grow minerals in which Zr, Ba, and Ti are essential structural constituents and/or HFSE, LILE, and HPE minor to moderate substituents. These geochemically diverse element groups were fixed in albitite via the crystallization and growth of new accessory minerals within these rocks during albititization. The amount of LILE and HPE-depleted meta-ultramafic rock appears to be too small to call upon a local source for the LILE and HPE-enrichment seen in albitites. Therefore, LILE and HPE must be of exotic origin, carried and deposited by fluids within the albitites at the jadeitite-serpentinite contact. This contact clearly testifies to an alteration style that involved crystallization of ‘trace-element’-rich minerals during fluid flow; this process appears to be essential to mass transfer within subduction zones. 相似文献
17.
基于多期次流体活动在硬玉岩及后成合晶冠状体的交互作用过程中发挥了至关重要的作用,采用电子探针、显微红外光谱等测试方法,从微尺度角度重点对缅甸角闪石质硬玉岩中角闪石+铬硬玉+硬玉后成合晶冠状体的成分和结构羟基赋存状态进行了研究。结果显示,参与后成合晶冠状体形成的流体组分较为复杂且形成过程是多阶段的;后成合晶冠状体的共生矿物组合不同,角闪石质硬玉岩中普遍发育角闪石+铬硬玉+硬玉化学成分环带;后成合晶冠状体中核部角闪石结构羟基含量较为均一,铬硬玉边缘至硬玉、硬玉晶粒中的结构羟基含量呈较为规律的递增趋势。核部角闪石中结构羟基均一且外层硬玉中结构羟基含量的变化规律表明缅甸硬玉岩中后成合晶冠状体的形成环境相对稳定,主要以多期次流体交代为主,未出现较大规模的动力变质作用。缅甸硬玉岩中后成合晶冠状体成分及水含量的变化规律有助于解析该地区俯冲带流体参与硬玉岩交互作用的轨迹,从而为缅甸硬玉岩的成岩机制提供一定的佐证。 相似文献
18.
G. E. HARLOW 《Journal of Metamorphic Geology》1994,12(1):49-68
Jadeitites from Guatemala are found as weathered blocks in tectonized serpentinite in a 15-km zone north of the Motagua Fault Zone. Rock types found with jadeitite include albitites, albite-mica rocks, omphacite/taramitic amphibole-bearing metabasites, chlorite-actinolite schists, talc-carbonate rocks and antigorite schists. In addition to the predominant jadeitic (Jd93_100) pyroxene, common phases in jadeitite include micas (paragonite and/or phengite ± rarer phlogopite), omphacite, albite, titanite /Pm zircon, apatite and graphite. Conditions of jadeitite formation are 100-400d? C, 5-11 kbar with 0.0 > log10asio2≥= 0.7. Fluid inclusions, coarse textures, vein structures, and rhythmic zoning of pyroxene indicate an aqueuos fluid was involved. Jadeitites are either (1) metasomatic modifications of former felsic-to-pelitic inclusions that have undergone silica depletion plus efficient soda exchange and enrichment, or (2) solution precipitations derived from such a source. The close spatial relationship of faults and shear zones, serpentinites, and jadeitites suggests jadeitites form in a relatively high-P/T setting with substantial flow of sodic fluid in a tectonized zone. Most Guatemalan jadeitites are extensively altered to analcime, albite, taramitic amphibole, (clino)zoisite ± nepheline and preiswerkite. This alteration reflects depressurization /Pm heating to below the jadeite + fluid = analcime reaction at high aNa. With progressive alteration, analcime and nepheline are replaced by albite; the increase in silica content may result from fluid flowing up a tectonized zone reaching saturation with an albite assemblage. Albitite phases, albite, actinolite, zoisite, /Pm chlorite, phengite, K-feldspar and quartz, record conditions of c. 3-8 kbar at T < 400d? C, indicating a clockwise P-T trajectory of the blocks. Barium aluminosilicates—banalsite, celsian, cymrite and hyalophane—are common minor late-stage phases in jadeitites and albite-rich rocks. Barian phengite is common in albite-mica rocks. 相似文献
19.
基于相对密度和X射线粉晶衍射技术测定硬玉岩中硬玉的含量 总被引：2，自引：2，他引：0
硬玉岩能否命名为宝石级"翡翠",其硬玉的含量是关键参数,目前测量岩石中矿物质量分数的方法多为有损分析,难以应用于珠宝玉石检测中。本文基于硬玉岩矿物组成及其质量分数的变化,建立了一种通过测量硬玉岩相对密度获得硬玉质量分数的无损分析方法。对186件相对密度在3.30~2.88之间的硬玉岩样品采用静水称重法测试,根据相对密度范围进行分组,利用X射线粉晶衍射、人工重砂分析、电子探针、红外光谱、拉曼光谱等技术确定硬玉岩的主要矿物及其质量分数,进而统计分析硬玉质量分数与硬玉岩相对密度的线性关系。研究表明:硬玉岩的主要矿物为硬玉和杂质矿物钠长石、方沸石。随着硬玉的质量分数(wA)下降,钠长石、方沸石质量分数增加,硬玉岩实测相对密度(SG)发生相应变化,两者的线性方程为wA=1.3454×SG-3.4531(相关系数为0.9814),线性关系良好。由于本方法的硬玉岩实测相对密度近似等于理论相对密度,即可通过测量相对密度获得硬玉的质量分数,这种无损测试方法适用于相对密度在3.3~3.0,硬玉含量在95%~60%,硬玉与钠长石的质量分数之和在90%~97%之间的硬玉岩样品。 相似文献