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1.
西藏努日矽卡岩型铜钨钼矿辉钼矿 Re-Os定年及其地质意义   总被引:5,自引:2,他引:3  
西藏努日层状矽卡岩型铜钨钼矿床是冈底斯东段南缘斑岩-矽卡岩铜多金属成矿带上规模最大的矿床。笔者对采自该矿床的9件不同产状、不同形态含钼矿石中的辉钼矿进行了Re-Os同位素组成分析,获得其模式年龄为23.46~24.77 Ma,等时线年龄为(23.36±0.49) Ma(MSWD=0.60),模式年龄与等时线年龄结果基本一致。由于辉钼矿与黄铜矿、白钨矿呈共生关系,并考虑到该矿区内黄铜矿的年龄〔(23.75±0.18) Ma〕(作者未发表数据),表明努日矽卡岩型铜钨钼矿床的成矿时代为23~24 Ma。结合前人研究资料可见,冈底斯南缘克鲁-冲木达斑岩-矽卡岩铜多金属成矿带从32 Ma至23 Ma发生了强烈的成矿作用。该成矿带的成矿时代明显有别于后碰撞期地壳伸展环境下形成的冈底斯斑岩铜矿带,显示出其为一套独立的成矿事件。该成矿事件可能主要受冈底斯南缘的晚碰撞走滑环境的控制。努日矿床成矿时代的确定及晚碰撞成矿事件的厘定,为今后研究和勘查该成矿带内同类型矿床提供了重要依据。  相似文献   

2.
利用锆石LA-ICPMS U-Pb法测定了西藏冈底斯带冲木达黑云角闪二长花岗岩的年龄.获得冲木达与夕卡岩矿化有关岩体锆石U-Pb年龄为(27.7±1.1)Ma(MSWD=2.6).冲木达岩体锆石U-Pb年龄表明,冲木达夕卡岩型铜-金(钼)矿床主要是晚碰撞期形成的.冲木达岩体形成时代明显早于冈底斯成矿带后碰撞期伸展环境的含铜斑岩体的形成时代(12~18 Ma),说明在冈底斯矿带除发育后碰撞期斑岩型铜矿成矿作用外.还发育晚碰撞期夕卡岩型铜矿成矿作用.这一年龄的厘定为深入探讨克鲁-冲木达成矿带成岩成矿机理乃至分析整个冈底斯成矿带成矿演化有着重要的意义.  相似文献   

3.
文章首次对冈底斯成矿带的甲马和知不拉铜_铅_锌矿床的辉钼矿进行了Re_Os同位素定年。甲马矿区辉钼矿的模式年龄介于15.4~15.5Ma之间,7件样品得到187Re_187Os等时线年龄为(15.18±0.98)Ma。知不拉矿区辉钼矿样品的模式年龄介于16.88~17.06Ma之间,5件样品得到187Re_187Os等时线年龄为(16.90±0.64)Ma。获得的Re_Os年龄与冈底斯成矿带驱龙、拉抗俄和冲江、厅宫等斑岩铜矿床的成矿年龄一致,明显晚于侏罗纪拉萨弧间盆地的发育时限。据此作者认为甲马和知不拉等铜_铅_锌矿床不属于喷流型矿床,而是冈底斯成矿带斑岩_矽卡岩成矿系统的组成部分,是岩浆_热液流体系统在不同的深度条件下与富钙围岩交代成矿的产物。  相似文献   

4.
通过对西藏冈底斯成矿带东段的帮浦矿床中的辉钼矿进行Re_Os精确测年 ,首次获得北矿带的铜多金属矿化时间。其Re_Os模式年龄为 (14 .30± 0 .2 5 )Ma~ (14 .75± 0 .2 8)Ma ,5件样品得到的187Re_187Os等时线年龄为 (15 .32± 0 .79)Ma。年龄数据与冈底斯成矿带东段南侧斑岩铜矿化带的矿化时间 (14Ma左右 )具有一致性 ,表明北矿带的成矿作用与斑岩有关。斑岩成矿是冈底斯成矿带内的一次主导成矿事件 ,冈底斯南矿带以斑岩型铜钼矿床为主 ,其北矿带以斑岩型铜铅锌多金属矿床为主。冈底斯南、北矿带的成矿作用具有统一的成矿动力学背景 ,发生在碰撞造山带侧向伸展时期 ,均为陆_陆碰撞造山带演化过程中同构造岩浆活动期的产物  相似文献   

5.
<正>冈底斯南缘努日矽卡岩铜-钼-钨矿位于克鲁-冲木达成矿亚带中部,是冈底斯成矿带上首个达到大型规模以上的矽卡岩型铜-钼-钨矿,辉钼矿Re-Os年龄结果指示其成矿年龄为23 Ma,但到目前为止,仍然没有发现与矿化有关的成矿斑岩体。本文首次报道了努日矿区新发现的与矿化关系密切的花岗闪长斑岩,LA-ICP-MS锆石U-Pb年龄为24.9 Ma,与成矿时代一致。努日矿区成矿斑岩体的发现首次证  相似文献   

6.
西藏甲玛铜多金属矿辉钼矿Re-Os定年及其成矿意义   总被引:18,自引:0,他引:18  
西藏墨竹工卡县甲玛铜多金属矿中,辉钼矿普遍发育,产于各类矿石中,尤其在矽卡岩型和角岩型矿石中最常见,其次是斑岩型矿石,极少量产于大理岩和结晶灰岩型矿石中。本文采集了甲玛铜多金属矿矽卡岩、角岩和斑岩中不同产状、不同形态的辉钼矿,进行Re-Os同位素定年,获得了27件样品的模式年龄为14.2~17.5Ma,等时线年龄为15.22±0.59Ma。其中,斑岩型辉钼矿等时线年龄为14.78±0.33Ma,角岩型辉钼矿等时线年龄为14.67±0.19Ma,结果一致。辉钼矿中187Re含量变化于38.75~387.4μg/g,其中,角岩中辉钼矿187Re含量为121.5~387.4μg/g,矽卡岩中为123.7~304.7μg/g,含量较高,而斑岩中辉钼矿的187Re含量相对较低,38.75~130.5μg/g,平均69.0μg/g;辉钼矿187Os含量变化情况基本与187Re相同。甲玛辉钼矿187Re值与冈底斯其他矿体的值对比,显示冈底斯成矿带斑岩-矽卡岩型矿床成矿原岩具有相对较高187Re值的特点。本文研究成果表明,甲玛大型铜多金属矿床形成于中新世Langhian期,辉钼矿为主成矿期的产物之一。鉴于辉钼矿的产出状态,以及其与黄铜矿等的共生组合关系,辉钼矿的成矿时代可代表矿区内主要矿石矿物的成矿时代,且与冈底斯成矿带上一大批大中型斑岩型铜矿的成矿时代一致,成矿集中在20~10Ma之间,形成于印度大陆与亚洲大陆碰撞之后,从而否定了前人海底喷流沉积的成因观点,为矿区内及其外围进一步的找矿指明了方向。  相似文献   

7.
沙让钼矿是念青唐古拉地区扎雪—亚贵拉成矿带的重要矿床,是西藏第一个达详查程度的独立钼矿,初步的勘查成果表明,钼资源量已经达到大型规模。为了查明念青唐古拉成矿带是否存在主碰撞期的大规模成矿作用,对沙让亚贵拉洞中拉矿集区沙让斑岩钼矿的7件辉钼矿样品进行了ReOs同位素分析,辉钼矿187Re的含量22.75~46.66(μg/g),187Os的含量为19.98~40.32(ng/g),辉钼矿的模式年龄分布在51.57~52.69Ma的范围内,模式年龄较为一致,所获ReOs等时线年龄为51±1.0Ma(MSWD=0.55)。该成矿年龄对应于冈底斯带主碰撞期岩浆岩底侵作用事件(介于47.0~52.5Ma之间(大约50Ma的始新世)),也与形成林子宗群帕那组43.93~53.52 Ma的火山事件一致,由此表明,冈底斯构造岩浆带存在主碰撞期的大规模成矿,沙让花岗斑岩型钼矿形成于始新世早期,而分布于沙让花岗斑岩外4km范围内的矽卡岩型热液脉型铅锌铜银(Mo)多金属矿可能也属该时期成矿的产物。  相似文献   

8.
<正>克鲁-冲木达矽卡岩成矿亚带位于冈底斯—念青唐古拉板片次级构造单元冈底斯火山—岩浆弧的东段南缘,属冈底斯铜多金属成矿带的重要组成部分,双布结热矿区位于冈底斯成矿带东段泽当矿田,地处西藏自治区山南地区乃东县境内,雅鲁藏布江北侧,是典型的矽卡岩型矿床。本文通过野外地质调研、岩相分带以及LA-ICP-MS锆石U-Pb年代学研究,探讨其产出的构造背景,不仅可以深入研究南亚带的成矿机制,同时为研究冈底斯成矿带各亚带的时空关系、冈底斯成矿带与板块俯冲-碰撞构造  相似文献   

9.
笔者通过对冈底斯成矿带驱龙、厅宫斑岩铜矿区和甲马、知不拉等矽卡岩型铜多金属矿区的辉钼矿样品进行的Re-0s法同位素定年研究,获得驱龙、厅宫、甲马和知不拉等矿区的精确成矿年龄。4件驱龙斑岩铜矿区辉钼矿样品的Re-Os模式年龄介于(15.75±0.42)Ma~(16.23±0.90)Ma之间,等时线年龄为(15.99±0.32)Ma;7件厅宫斑岩铜矿矿区辉钼矿样品的Re-Os模式年龄介于(15.5±0.3)Ma~(16.3±0.3)Ma之间,等时线年龄为(15.49±0.36)Ma;在矽卡岩型铜多金属矿区中,7件甲马矿区辉钼矿样品的Re-Os模式年龄介于(15.4±0.2)Ma~(15.5±0.2)Ma之间,等时线年龄为(15.18±0.98)Ma;5件知不拉矿区辉钼矿样品的Re-Os模式年龄介于(16.88±0.28)Ma~(17.06±0.27)Ma之间,等时线年龄为(16.90±0.64)Ma。斑岩铜矿区和矽卡岩型铜多金属矿区所获得的年龄数据基本一致,其年龄明显晚于中生代弧间盆地和碰撞型花岗岩的发育时间,同时矽卡岩型铜多金属矿床在空间上亦分布于斑岩铜矿床的外围。因此笔者认为甲马和知不拉等铜铅锌矿床与冈底斯成矿带新生代晚期大规模成矿形成的斑岩铜钼矿床属于统一的斑岩-矽卡岩成矿系统,是由深源花岗质岩浆的岩浆-热液系统在不同的围岩介质条件成矿的产物。  相似文献   

10.
西藏冈底斯成矿带驱龙铜矿Re—Os年龄及成矿学意义   总被引:46,自引:0,他引:46  
驱龙铜矿位于冈底斯成矿带东部冈底斯花岗岩基内,为典型的斑岩型铜矿床。选择辉钼矿Re-Os同位素法对该矿床进行成矿年龄精确测定,6个辉钼矿Re-Os模式年龄范围为15.99~16.74 Ma,变化较小,不超过1 Ma。6个样品拟和的~(187)Re-~(187)Os等时线年龄为16.41±0.48 Ma(2σ误差,MSWD=1.5),与模式年龄一致。驱龙铜矿的成矿年龄与冈底斯带区域上已有的斑岩铜矿成矿年龄(14 Ma±)相吻合。目前的年龄数据结果显示冈底斯带斑岩铜矿的成矿时间主要集中在16~14 Ma之间,成矿时限不到2 Ma,具有爆发成矿特征。斑岩成矿发生在区域上钾质熔岩喷发和东西向伸展活动时期。含矿斑岩特点及其与钾质熔岩和南北向张性构造系统的时空依附关系,说明冈底斯带斑岩成矿受西藏碰撞造山带演化过程中深部构造岩浆活动的制约。冈底斯斑岩型矿床的爆发成矿具有深层次的动力学背景。  相似文献   

11.
Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N2 in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.  相似文献   

12.
在野外地质调查的基础上,选取滹沱群豆村亚群底部四集庄组玄武岩、顶部青石村组玄武岩和东冶亚群中下部河边村组玄武岩,进行岩石学和地球化学研究。分析结果表明:玄武岩主量元素高TiO2、TFeO,低MgO,具有演化的基性岩浆的特征。稀土元素含量相对较高,具有弱—中等程度的轻稀土元素富集,中等程度的轻重稀土元素分异,轻微的Eu异常;玄武岩中Cr、Ni含量变化较大,但与Mg#具有很好的正相关性。微量元素配分图解中具有明显的Sr负异常,部分样品具有Nb、Ta和Ti负异常,无Zr、Hf负异常,与岛弧火山岩不同;同时Nb、Ta无分异,Zr/Hf值较高,具有板内玄武岩浆的特征。综合分析认为,滹沱群玄武岩可能形成于板内裂谷环境。在岩浆上升过程中发生橄榄石与尖晶石的分离结晶作用,同时不同程度地受到地壳的混染。  相似文献   

13.
马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。  相似文献   

14.
岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...  相似文献   

15.
填海工程使滨海地区的地下水物理化学条件改变,导致该区域地下水中重金属浓度升高。本文以深港西部通道填海区为例,采用实验室模拟填海条件的办法,初步探讨了影响填海区地下水重金属迁移的关键因素。模拟实验结果表明,填海区地下水中钨元素含量升高与地下水淡化、淤泥氧化过程以及填料风化有关;铜元素含量升高则与淤泥氧化过程以及填料风化有关;钒元素含量升高与地下水淡化和淤泥氧化过程有关,而其他元素含量升高则主要与填料风化释放有关。  相似文献   

16.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

17.
The geology and mineralogy of host metamorphic rocks, the mineralogy of sulfide ores, and the distribution of PGE mineralization were studied in detail for the Kvinum-1 and Kvinum-2 copper-nickel occurrences of the Kvinum ore field, which are the most promising targets for the copper-nickel-PGE mineralization of the Sredinny Range of Kamchatka. It was established that stringer-disseminated and massive copper-nickel ores are localized in amphibole peridotites, cortlandites, and form ore bodies varying from tens of centimeters to 5–20 m thick among the layered cortlandite-gabbroid massifs. The massive sulfide ores were found only at the bottom of cortlandite bodies and upsection grade into stringer-disseminated and disseminated ores. Pyrrhotite, chalcopyrite, and pentlandite are the major ore minerals with a sharply subordinate amount of pyrite, sphalerite, galena, arsenopyrite, and löllingite. Besides pentlandite, the Ni-bearing minerals include sulforasenides (gersdorffite), arsenides (nickeline), and tellurides (melonite) of nickel. It was found that PGE mineralization represented by antimonides (sudburyite) and tellurobismuthides (michenerite) of Pd with sharply subordinate platinum arsenide (sperrylite) is confined to the apical parts of massive sulfide zones and the transition zone to the stringer-disseminated ores. Ore intervals enriched in arsenides and tellurides of Ni, Pd, and Bi contain high-purity gold. In the central parts of the orebodies, the contents of PGE and native gold are insignificant. It is suggested that the contents of major sulfide minerals and the productivity of PGE mineralization in the cortlandites are defined by combined differentiation and sulfurization of ultramafic derivatives under the effect of fluids, which are accumulated at the crystallization front and cause layering of parental magmas with different sulfur contents. The fluid-assisted layering of mafic-ultramafic massifs resulted in the contrasting distribution of PGM in response to uneven distribution of sulfur (as well as As, Te, and Bi) during liquid immiscibility. The productivity of PGE mineralization significantly increases with increasing contents of S, As, Te, and Bi (elements to which Pt and, especially, Pd have high affinity) in fluids.  相似文献   

18.
 A geophysical survey was conducted to determine the depth of the base of the water-table aquifer in the southern part of Jackson Hole, Wyoming, USA. Audio-magnetotellurics (AMT) measurements at 77 sites in the study area yielded electrical-resistivity logs of the subsurface, and these were used to infer lithologic changes with depth. A 100–600 ohm-m geoelectric layer, designated the Jackson aquifer, was used to represent surficial saturated, unconsolidated deposits of Quaternary age. The median depth of the base of the Jackson aquifer is estimated to be 200 ft (61 m), based on 62 sites that had sufficient resistivity data. AMT-measured values were kriged to predict the depth to the base of the aquifer throughout the southern part of Jackson Hole. Contour maps of the kriging predictions indicate that the depth of the base of the Jackson aquifer is shallow in the central part of the study area near the East and West Gros Ventre Buttes, deeper in the west near the Teton fault system, and shallow at the southern edge of Jackson Hole. Predicted, contoured depths range from 100 ft (30 m) in the south, near the confluences of Spring Creek and Flat Creek with the Snake River, to 700 ft (210 m) in the west, near the town of Wilson, Wyoming. Received, May 1997 · Revised, February 1998 · Accepted, April 1998  相似文献   

19.
李涛  王宗秀 《地质通报》2008,27(4):469-476
对巴颜喀拉山年宝玉则花岗岩岩体样品的锆石、磷灰石进行了裂变径迹(FT)分析。结果显示该区的隆升可以分为三大阶段:①从低绿片岩相到锆石时钟启动:从200MaBP到105.57MaBP,去顶量约为2km,样品埋深上升到距地表约6km深度。去顶速率约为0.02mm/a;②从锆石时钟启动到磷灰石时钟启动:由于磷灰石在此时已抬升到距地表约6km的深度。由此到达时钟启动需距地表约3km时,去顶量应为3km,此阶段的持续时间为101.53MaBP,去顶速率约为0.03mm/a:③从磷灰石时钟启动至达到地表(至今):由于磷灰石在前一阶段也已抬升到距地表约3km的深度。即去顶量为3km。此阶段的持续时间为4.04MaBP,去顶速率约为0.74mm/a。  相似文献   

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