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1.
Evaluation of analyses of leachate for inorganic constituents, from selected landfills in Illinois indicates that leachate quality is variable and is strongly affected by waste type and cover material. Twenty parameters were detectable in all samples, but selenium was not detected in any of the samples analyzed. More than 98% of the mean leachate composition was comprised, in descending order, of total alkalinity (bicarbonate plus carbonate), sulfate, sodium plus potassium, calcium plus magnesium, chloride, and iron plus managese. Excluding iron, trace metals contributed less than one percent to the total; of these, copper, zinc and boron were most significant. Based on milliequivalents per liter of major constituents, approximately 73 percent of the cations and 92% of the anions fall within the concentration range of potable waters. Heavy metals, organics, suspended matter, microorganisms, odor and color are among the objectionable qualities of leachate which should not be present in potable waters. In assessing the impact of leachate on ground-water quality, use of indicator parameters in place of comprehensive analyses for routine water samples is frequently desirable in the interest of both time and economics. Availability, mobility, persistence, analyticity and contrast of concentrations in leachate and ground water are important factors to consider in selection of an indicator. Boron, iron, ammonia and total dissolved solids appear to be reliable parameters for indicating ground-water pollution by leachate. Chloride and hardness may also be useful under certain conditions. Sulfate was the least reliable parameter considered. Although many of the trace elements in leachate exceed Illinois Environmental Protection Agency Public Water Supply Standards in more than 50% of the samples, these elements are most useful as indicators when a waste rich in trace elements is deposited in a landfill of unfavorable hydrogeology.  相似文献   

2.
Anthropogenic sources of carbon from landfill or waste leachate can promote reductive dissolution of in situ arsenic (As) and enhance the mobility of As in groundwater. Groundwater from residential-supply wells in a fractured crystalline-rock aquifer adjacent to a Superfund site in Raymond, New Hampshire, USA, showed evidence of locally enhanced As mobilization in relatively reducing (mixed oxic-anoxic to anoxic) conditions as determined by redox classification and other lines of evidence. Redox classification was determined from geochemical indicators based on threshold concentrations of dissolved oxygen (DO), nitrate (NO 3 – ), iron (Fe2+), manganese (Mn2+), and sulfate (SO 4 2– ). Redox conditions were evaluated also based on methane (CH4), excess nitrogen gas (N2) from denitrification, the oxidation state of dissolved As speciation (As(III) and As(V)), and several stable isotope ratios. Samples from the residential-supply wells primarily exhibit mixed redox conditions, as most have long open boreholes (typically 50–100?m) that receive water from multiple discrete fractures with contrasting groundwater chemistry and redox conditions. The methods employed in this study can be used at other sites to gauge redox conditions and the potential for As mobilization in complex fractured crystalline-rock aquifers where multiple lines of evidence are likely needed to understand As occurrence, mobility, and transport.  相似文献   

3.
Simultaneous in situ immobilisation of uranium (U) and radium (226Ra) by injectible amounts of grey cast iron (gcFe), nano-scale iron (naFe) and a gcFe/MnO2 mixture (1:1) was studied in batch and column tests. Both 0.5 g/L naFe and gcFe are effective in 226Ra and U removal from mine water, whereas MnO2 addition clearly increased the efficiency of gcFe for 226Ra and U immobilisation. In a column test with 0.6 wt% gcFe/MnO2 mixture (1:1), neither 226Ra nor U was detected in the effluent after replacement of 45 pore volumes. A sequential extraction under flow condition revealed 226Ra to be mostly occluded in manganese oxides. Uranium was mostly sorbed onto poorly crystalline iron hydroxides, but a significant part was found to be occluded in manganese oxides also. The results of this study suggest that MnO2 promotes iron hydroxide formation under slightly reducing environmental conditions resulting in an increased pollutant retention capacity.  相似文献   

4.
Mercury (Hg) concentrations in air, effluent water, landfill gas, leachate, groundwater, and soil at a hazardous solid waste landfill site in Korea were measured along with air–soil surface Hg exchange fluxes at the site. The concentrations and fluxes were considerably higher than have been found elsewhere in Korea. Gaseous Hg concentrations in the air peaked during the day, coinciding with Hg being released from the landfill surface. This suggests that air–soil exchange increased the Hg concentrations in the atmosphere. The air–soil exchange flux increased abruptly when solar radiation reached the soil surface. The Hg flux peaked about 3 h before the solar radiation peaked, possibly because reducible Hg was abundant at the soil surface. The Hg emission flux activation energy (E a) was low, indicating that the Hg species present and Hg–soil binding were probably not as important (because of the high Hg content of the soil) as in previous studies. The methylmercury to total Hg ratios in the discharged effluent, groundwater, and leachate was clearly higher than typically found in coastal water and freshwater, suggesting bacteria caused active methylation to occur under the reducing conditions in the anaerobic landfill. The results suggested that considerable amounts of Hg are probably transported from the landfill to nearby environmental media and that this will continue if waste with a high Hg content continues to be added to the landfill without being pretreated.  相似文献   

5.
The potential of the autoclaved Tunisian landfill leachate treatment using microalgae (Chlorella sp.) cultivation was investigated in this study. Landfill leachate was collected from Borj Chakir landfill, Tunisia. A full factorial experimental design 22 was proposed to study the effects of the incubation time and leachate ratio factors on the organic matter removal expressed in chemical oxygen demand (COD) and ammoniacal nitrogen (NH4─N) and on the biological response of Chlorella sp. expressed by the cell density and chlorophyll content. All experiments were batch runs at ambient temperature (25 ± 2 °C). The Chlorella sp. biomass and chlorophyll a concentrations of 1.2 and 5.32 mg L?1, respectively, were obtained with 10% leachate spike ratio. The obtained results showed that up to 90% of the ammoniacal nitrogen in landfill leachate was removed in 10% leachate ratio spiked medium with a residual concentration of 40 mg L?1. The maximum COD removal rate reached 60% within 13 days of incubation time indicating that microalgae consortium was quite effective for treating landfill leachate organic contaminants. Furthermore, with the 10% leachate ratio spiked medium, the maximum lipid productivity was 4.74 mg L?1 d?1. The present study provides valuable information for potential adaptation of microalgae culture and its contribution for the treatment of Tunisian landfill leachate.  相似文献   

6.
The grid-net electrical conductivity measurement system for detecting exact locations of landfill leachate intrusion in the subsurface was developed in this study. Laboratory and pilot-scale field model tests were performed to evaluate the direct application of a grid-net electrical conductivity measurement system for the detection of landfill leachate. A significant increase in electrical conductivity of soil was observed by adding landfill leachate. This can be explained as an increase in electrical conductivity of pore fluid due to an increase in leachate constituents as charge carriers. In pilot-scale field model tests, leachate intrusion locations were accurately identified at the initial stage of landfill leachate release by the grid-net electrical conductivity measurement system. The electrical conductivity of the subsurface before leachate injection lay within a small range of 24.8–43.0 S/cm. The electrical conductivity values in detected points were approximately ten times more than the conductivity values of the subsurface without landfill leachate intrusion. The results in this study indicate that the grid-net electrical conductivity measurement method has a possible application for detecting locations of landfill leachate intrusion into the subsurface at the initial stage, and thus has great potential in monitoring leachate leakage at waste landfills.  相似文献   

7.
This paper studies a landfill where there are three faults running through. As serious pollution has occurred to the geological environment, the landfill is to be closed up and renovated. The paper aims to explore the role of fracture structure in leachate pollution at the landfill. The research was carried out in several stages. First, mathematical models of the pre-renovation landfill with three faults running through and the landfill after renovation were established. And then, the boundary conditions and parameters of the two mathematical models were determined. The groundwater level of the landfills was simulated in order to modify the two mathematical models. As a result, a feasible mathematical model was achieved. Based on this model, a comparison was made of the COD concentration variations in the inside leachate and outside leachate between the two landfills. Accordingly, the impacts of the fracture structure on the pollution of leachate at the landfills could be identified. The study results show that while faults contribute to the migration of ieachate, they also serve as a confluence of leachate, thus further deteriorating the environment. The COD concentrations of the inside leachate and the outside leachate of the pre-renovation landfill are respectively 800 mg/L and 220 mg/L higher than those of the post-renovation landfill. Therefore, measures must be taken to handle the ieachate seepage in areas where there are faults as well as the neighboring areas so as to get the environmental pollution under control.  相似文献   

8.
This paper describes a case study concerning the use of integrated geophysical methods applied to environmental assessment. The study is focused on an old municipal solid waste sealed landfill site, located in Gaeiras, Central Portugal. The problem is related with leachate overproduction in this domestic and industrial waste landfill that became an environmental problem with urgent assessment, so that a solution could be planned. Due to the lack of accurate information regarding the shape, history and development of the landfill, the use of a set of classical geophysical methods was the option, since they are non-invasive and non-destructive. The available area was small, almost restricted to the landfill area. To conduct this assessment, electromagnetic RF-EM and Geonics EM34, spontaneous potential (SP), vertical electrical soundings (VES) and magnetic prospecting surveys were planned to understand the various problems that could be related with the leachate overproduction. The joint use of these classical geophysical methods was targeted to investigate bedrock depth and structure (RF-EM, EM34 and VES), waste and leachate characteristics (EM34 and magnetics) and groundwater flow (SP) in the landfill. Geophysical results were correlated with hydrogeological information, integrated and interpreted, using geographic information system tools. The results obtained were important to understand the geological mechanisms that are responsible for leachate overproduction and to suggest remedial measures.  相似文献   

9.
Because domestic landfill leachate concentrates complex organic pollutants, effective treatment of landfill leachate has gained increasing attention in recent years. In this paper, three-stage physicochemical and biochemical technology for treatment of domestic landfill leachate is presented. Based on an eight-month pilot operation, over 96% of the main pollutants, for example CODCr, BOD5, SS, NH4 +–N, coliform, and chrominance, can be removed, among which the removal efficiency of CODCr was 89.5, 8.6, and 1.7% in stages 1, 2, and 3, respectively, and the removal efficiency of BOD5 was 90.3, 8.3, and 1.4%. In the treatment, the biochemical process played a principal role on the removal of pollutants from the leachate. The treatment efficiency depends on how the syntheses of physicochemical, anaerobic, and hydrolytic procedures pave the way for biochemical treatment. Application of a combined efflux and mixed-flow aerator enhanced the removal efficiency during each procedure.  相似文献   

10.
The influence of local hydrogeology on natural attenuation of contaminants from landfill leachates in shallow aquifer underlying the active Olusosun landfill base in Lagos was investigated. In addition, the level of groundwater contamination in the vicinity of the landfill and of leachate migration pattern in groundwater down gradient of the landfill base was equally assessed. Landfill leachate and groundwater samples were collected and analyzed and characterized. Physico-chemical analyses of sampled water followed standard analytical methods. Analytical results showed a measurable impact of leachate outflows on groundwater quality. Elevated levels of anions: nitrate, chloride and sulphate in the groundwater body and heavy metals: Cr3. Cd and Cu, were detected at measurable levels in groundwater down gradient of the landfill location without any particular attenuation pattern. The migration pattern and dispersion of leachates down gradient, 750 m away from the landfill location are irregular and difficult to predict as depicted by levels of contaminants present in groundwater. The study highlighted the importance of soil stratigraphy beneath the landfill base as an important factor in the natural attenuation of leachate constituents in the groundwater body.  相似文献   

11.
The major, trace and rare earth element (REE) composition of Late Archean manganese, ferromanganese and iron ores from the Iron Ore Group (IOG) in Orissa, east India, was examined. Manganese deposits, occurring above the iron formations of the IOG, display massive, rhythmically laminated or botryoidal textures. The ores are composed primarily of iron and manganese, and are low in other major and trace elements such as SiO2, Al2O3, P2O5 and Zr. The total REE concentration is as high as 975 ppm in manganese ores, whereas concentrations as high as 345 ppm and 211 ppm are found in ferromanganese and iron ores, respectively. Heavy REE (HREE) enrichments, negative Ce anomalies and positive Eu anomalies were observed in post‐Archean average shale (PAAS)‐normalized REE patterns of the IOG manganese and ferromanganese ores. The stratiform or stratabound shapes of ore bodies within the shale horizon, and REE geochemistry, suggest that the manganese and ferromanganese ores of the IOG were formed by iron and/or manganese precipitation from a submarine, hydrothermal solution under oxic conditions that occurred as a result of mixing with oxic seawater. While HREE concentrations in the Late Archean manganese and ferromanganese ores in the IOG are slightly less than those of the Phanerozoic ferromanganese ores in Japan, HREE resources in the IOG manganese deposits appear to be two orders of magnitude higher because of the large size of the deposits. Although a reliable, economic concentration technique for HREE from manganese and ferromanganese ores has not yet been developed, those ores could be an important future source of HREE.  相似文献   

12.
土壤与地下水污染的地球物理地球化学勘查   总被引：5，自引：0，他引：5  
列举了土壤、地下水中常见的有机和无机污染组分.进入地下水中的绝大部分污染物与介质发生物理化学反应后,各种金属、非金属离子、固体溶解物、盐类在地下潜水面附近逐渐浓集,导电性增强,电阻率明显降低,对电磁波的反射能力增强.经实际检测发现,某垃圾填埋场被垃圾渗漏液污染的土壤视电阻率在10 Ω·m左右,垃圾渗出液的实测电阻率在0.40 Ω·m左右.比较高密度电阻率法、瞬变电磁法、探地雷达法的效果后发现,高密度电阻率法的效果显著.荧光光谱和吸附乙烷、游离甲烷对指示储油气设施泄漏有显著效果,实际应用中,检测游离甲烷可快速圈定污染范围.  相似文献   

13.
刘静静  曾南石  徐文炘 《矿产与地质》2012,26(2):165-167,176
文章以垃圾渗滤液为研究对象,分别用铁粉、改性膨润土、活性炭及其混合物为反应介质,设计4种不同介质配比的PRB反应器进行实验研究。结果表明,PRB对垃圾渗滤液有较好的处理效果,其中,以还原铁粉、改性膨润土为介质的反应器,对氨氮的去除效率最大为97.58%,以还原铁粉、活性炭为介质的反应器对COD的去除效率为84.87%,对总磷的去除效率最大为80%。  相似文献   

14.
Attenuation characteristics of landfill leachate were examined for two uncontrolled landfills in Korea. The two landfills containing municipal wastes without appropriate bottom liner and leachate treatment system have different landfill age, waste volume, and most importantly different hydrogeologic settings. One landfill (Cheonan landfill) is situated in an open flat area while the other (Wonju landfill) is located in a valley. Variations of various parameters including dissolved organic carbon (DOC), dissolved oxygen (DO), alkalinity, pH, electrical conductivity (EC), redox potential (ORP), ammonia (NH3), nitrate (NO3−), sulfate (SO42−), and chloride (Cl−) were examined along groundwater flow path. All these parameters were analyzed every month for a year. In the interior of the landfills, typical anaerobic conditions revealed by low DO and NO3 concentrations, negative ORP values, high NH3, alkalinity, and Cl− concentrations were observed. Generally, higher levels of contaminants (DOC, NH3, and Cl−) were detected in the dry season while they were greatly lowered in the wet season. Significantly, large decrease of Cl- concentration in the wet season indicates that the dilution or mixing is one of dominant attenuation mechanisms of leachate. But detailed variation behaviors in the two landfills are different and they were largely dependent on permeability of surface and subsurface layers. The intermediately permeable surface of the landfills receives part of direct rainfall infiltration but most rainwater is lost to fast runoff. The practically impermeable surface of clayey silt (paddy field) at immediately adjacent to the Cheonan landfill boundary prevented direct rainwater infiltration and hence redox condition of the ground waters were largely affected by that of the upper landfill and the less permeable materials beneath the paddy fields prohibited dispersion of the landfill leachate into down gradient area. In the Wonju landfill, there are three different permeability divisions, the landfill region, the sandy open field and the paddy field. Roles of the landfill and paddy regions are very similar to those at the Cheonan. The very permeable sandy field receiving a large amount of rainwater infiltration plays a key role in controlling redox condition of the down gradient area and contaminant migration. This paper reports details of the attenuation and redox conditions of the landfill leachates at the two uncontrolled landfills.  相似文献   

15.
There is an urgent need for characterization of leachate arising from waste disposal to ensure a corresponding effective leachate management policy. Field and laboratory studies have been carried out to investigate the impact of municipal landfill leachate on the underlying groundwater at a site in West Malaysia. The solid waste was disposed of directly onto an unprotected natural soil formation. This situation was made worse by the shallow water table. The hydrochemical composition of groundwater in the vicinity of the site (background) is a dilute mixed cation, bicarbonate water. The high ionic balance error of ~13.5% reveals that the groundwater body underneath the site was a highly contaminated leachate rather than contaminated groundwater. Elevated concentration of chloride (355.48 mg/L), nitrate (10.40 mg/L as NO3), nitrite (14.59 mg/L), ammoniacal-N (11.61 mg/L), sodium (227.56 mg/L), iron (0.97 mg/L), and lead (0.32 mg/L) measured downgradient indicate that the contamination plume has migrated further away from the site. In most cases, the concentration of these contamination indicators, together with the ranges of sodium percentage (66.3–89.9%) and sodium adsorption ratio (10.1–19.7%), were found to be considerably higher than the limit values of safe water for both domestic and irrigation purposes, respectively.  相似文献   

16.
Geoelectrical surveys of the Nanjido waste landfill in Seoul,Korea   总被引：3，自引：0，他引：3  
Electrical surveys have routinely been taken to map and monitor groundwater contamination. In 1994-1996, various electrical surveys were applied to investigate contaminant distributions in the ground at the Nanjido landfill. The geophysical survey data were compared with other available information, particularly boring data. Interpretations of electrical survey data show low resistivity zones below 10 ohm-m which appear to be zones fully saturated with leachate. Annual variations of resistivity anomalies clearly indicate that resistivities and thicknesses of layers contaminated by leachate become lower and thicker in and around the Nanjido landfill during one year. In particular, mean thickness of saturated layers with leachate increased by about 3-6 m/year and the resistivity of bedrock decreased. It seems obvious that ground contamination by leachate is in progress. In the area northeast of the landfill, no evidence of bedrock contamination is indicated. Soundings made at one year intervals in this area do not show any evidence of further ground contamination by leachate. From these results, it appears that contamination of the weathered zone and bedrock is in progress mainly southwest of the Nanjido landfill.  相似文献   

17.
This paper studies a landfill where there are three faults running through.As serious pollution has occurred to the geological environment,the landfill is to be closed up and renovated.The paper aims to explore the role of fracture structure in leachate pollution at the landfill.The research was carried out in several stages.First,mathematical models of the pre-renovation landfill with three faults running through and the landfill after renovation were established.And then,the boundary conditions and parameters of the two mathematical models were determined.The groundwater level of the landfills was simulated in order to modify the two mathematical models.As a result,a feasible mathematical model was achieved.Based on this model,a comparison was made of the COD concentration variations in the inside leachate and outside leachate between the two landfills. Accordingly,the impacts of the fracture structure on the pollution of leachate at the landfills could be identified.The study results show that while faults contribute to the migration of leachate,they also serve as a confluence of leachate,thus further deteriorating the environment.The COD concentrations of the inside leachate and the outside leacbate of the pre-renovation landfill are respectively 800 mg/L and 220 mg/L higher than those of the post.renovation landfill.Therefore,measures must be taken to handle the leachate seepage in areas where there are faults as well as the neighboring areas so as to get the environmental pollution under control.  相似文献   

18.
Redox Processes in Groundwater Impacted by Landfill Leachate   总被引：6，自引：0，他引：6  
Groundwater downgradient from Trandum municipallandfill was investigated in summer 1996, with a viewto assessing the distribution of redox-sensitivespecies. The water table at Trandum is 10–26 metersbelow the surface. Monitoring well filters have beeninstalled at depths of up to 15 m below water table,covering an area of 400 m by 200 m. Groundwaterinfluenced by the landfill seems to be confined tothis area. Pristine groundwater has a chemicalsignature indicative of calcite and pyrite weathering.Groundwater influenced by leachate from the landfillexhibits an excess of alkalinity relative to calcium,which is likely to be derived from degradation oforganic matter in the landfill. Groundwaterimmediately below and downstream of the landfillcontains elevated concentrations of Fe and Mn, largelymobilized under reducing conditions from the aquifermatrix and reflected in depleted HNO3-extractable Feand Mn in sediment samples from the same area.Groundwater samples allow the tentative identificationof redox zones based on oxidized and reduced forms ofFe, Mn, N and S. A methanogenic zone is notobserved.  相似文献   

19.
Current risk-based methods for assessing the effects of landfill leachate migration on groundwater resources are conservative and generalised. Cost-effective and practical strategies are required which can robustly determine the potential for contaminant attenuation on a site-specific basis. In this paper laboratory column experiments and reactive transport modelling are evaluated as a combined approach for assessing the chem’ical impact of leachate migration in the Triassic Sandstone aquifer. The results are compared with field data for a landfill in the East Midlands. Columns of aquifer sandstone were flushed sequentially with groundwater, followed by acetogenic or methanogenic leachate to simulate chemical interactions occurring during leachate loading episodes. The key contaminants in leachate (NH4, heavy metals, organic fractions) were attenuated by ion exchange, redox reactions, sorption and degradation. These processes produce a consistent hydrochemical signature which may help identify the extent of leachate migration in the aquifer. The laboratory results largely replicate those found in the field system, and the behaviour of inorganic contaminants during leachate flushing of the aquifer columns can be described by the reactive transport model. The experimental and modelling approach presented represents a powerful tool for risk assessment and prediction of leachate contaminant fate at unlined and lined landfills.  相似文献   

20.
 An engineering geological investigation has been undertaken of a proposed landfill site in coastal southwestern Ghana which is characterized by torrential rains, high relative humidity, shallow groundwater conditions and almost surrounded by a ridge. The study shows that the site has some desirable characteristics such as availability of suitable soils for the construction of the capping and bottom liners of the landfill, a large tract of land for landfilling operation and its location close to a major highway. However, the groundwater table was shallow and there was a high potential for leachate intrusion into and consequent contamination of nearby groundwater abstraction wells and surface potable water sources thereby constituting serious threat to life. Construction costs could be prohibitive as extensive dewatering and backfilling of vast portions of the project site would be required to enable the provision of a separation between the shallow water table and the bottom of the landfill. Received: 20 January 1998 · Accepted: 26 May 1998  相似文献   

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