共查询到16条相似文献，搜索用时 78 毫秒
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采用溶液共混法制备出硼酸镁晶须(MBOw)、硼酸钙晶须(Ca BOw)、硼酸铜铝晶须(Cu Al BOw)、碱式硫酸镁晶须(MOSw)、碳酸钙晶须(Ca CO3w)及硫酸钙晶须(Ca SO4w)增强的PVC复合材料,研究不同晶须对PVC力学性能的影响。采用扫描电镜分析PVC复合材料的拉伸断面及晶须分散情况。结果表明,除MOS外其它晶须对PVC的拉伸强度和弹性模量有不同程度的提高,MBOw对PVC复合材料的增强效果最显著,当MBOw含量为20%时,所得复合材料力学性能最佳,拉伸强度和弹性模量与纯PVC比较分别提高了38.08%和71.43%。 相似文献
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以硫酸镁和氢氧化钠为原料,通过水热法合成了碱式硫酸镁晶须5Mg(OH)2.MgSO4.2H2O(简称512MOS)。考察了前驱体制备方法、反应时间、反应温度以及形貌控制剂EDTA对碱式硫酸镁晶须形貌的影响,得出了较佳合成条件。研究结果表明,以固体氢氧化钠制备前驱体,在较低的温度下进行水热反应,可以获得形貌较好的晶须。添加EDTA可以改善晶须形貌,减少扇形晶须的出现。在较佳条件下制备的碱式硫酸镁晶须平均长度约40μm,平均直径约0.4μm,长径比达到100左右。XRD和化学分析显示产物组成为512MOS。SEM照片显示产物形貌为单根纤维状,表面光滑,有柔性弯曲现象。 相似文献
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本文报道了在四硼酸十八铝晶须材料制备实验中，原料明矾、脱水明矾和硼酸，以及制成品四硼酸十八铝晶须的熔样处理和分析方法，同时给出有关分析结果。 相似文献
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目前,超疏水涂层存在着制备成本高、工艺复杂和环境污染等问题,阻碍了其工程化应用进程。文章以 CaCO3晶须及其纳米粒子为填料,水性苯丙乳液为粘结剂,以及硬脂酸锌为疏水改性剂制备超疏水涂层。首先采用油酸对 CaCO3晶须及其纳米粒子进行表面改性,然后基于极端顶点设计将改性后的 CaCO3晶须、改性后的纳米 CaCO3、苯丙乳液和硬脂酸锌为混合分量进行混料实验,以涂层接触角为响应变量建立回归模型,分析混合分量对接触角的影响。结果表明:采用不同形貌的 CaCO3粉体复合苯丙乳液可制备出超疏水涂层,在纳米 CaCO3与硬脂酸锌混合分量较高, CaCO3晶须混合分量较低以及苯丙乳液适中的区域,接触角可达 153.5°。通过表面形貌分析,涂层的黏附性与其表面的孔洞有关,而较高的纳米 CaCO3混合分量可降低涂层表面粗糙度,促进其超疏水性能。 相似文献
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青海具有丰富的盐湖资源,其中提锂工艺副产了大量的粗品氢氧化镁,这些粗品氢氧化镁无法直接利用而被多数企业废弃,不仅引起了环境的污染,还造成了资源的浪费,因此需要对粗品氢氧化镁进行高值化利用。以盐湖提锂副产的氢氧化镁为原料,将其进行预处理后与七水硫酸镁水热合成了碱式硫酸镁MgSO_4·5Mg(OH)_2·3H_2O(153型)晶须。同时,考察了不同纯度氢氧化镁对晶须制备的影响,通过化学分析、XRD、SEM、TEM、TG-DTG等表征手段对所得材料的组成、结构和形貌进行了分析。研究结果表明,采用预处理的副产氢氧化镁(其纯度达到94.8%)原料时,得到的碱式硫酸镁晶须不仅纯度高,且表面光滑、长径比较高,可以实现废物回收利用、降低生产成本、盐湖资源高效综合利用的目标。 相似文献
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以活性氧化镁和氯化镁为原料在水热条件下合成了碱式氯化镁晶须。碱式氯化镁晶须热解后形貌保持得很好,得到氧化镁晶须。制得的晶须长度在200μm左右,直径约0.5μm。采用X射线衍射仪、扫描电镜、热重分析仪表征碱式氯化镁和氧化镁晶须,探讨了各个工艺条件对产物的影响。实验结果表明,碱式氯化镁晶须的最佳工艺条件为:反应时间8~12 h,搅拌速率初始在500 r.min-1左右,120 min时调为1 000 r.min-1,氧化镁与氯化镁的物质的量之比0.10~0.15,氯化镁溶液的浓度4.0 mol.L-1以上,反应温度150~200℃,反应釜的填充度50%~80%。在此条件下制得了形貌良好的碱式氯化镁晶须。 相似文献
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根据青藏高原16个气象观测台站有关气温和降水的多年数据,分析了近40年来青藏高原的气候变化特征。结果表明,近40年来青藏高原气候变化的总趋势是气温升高,降水量稍有增加。这种气候波动变化,对高原植被、冰雪水及土地沙化都有较大的影响。据预测到2100年青藏高原气温将上升2～3 6℃,降水量在高原中部和东部增加约0～300mm,而在西南部将减少0～500mm。气候的变化使植被群落发生明显的变化,分布界线向更高的海拔高度迁移。也使高原冰川退缩,但未来冰川不一定消失。 相似文献
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无机增强纤维Ⅰ.钛酸钾纤维 总被引：9，自引：0，他引：9
结晶质的钛酸钾纤维因其性质特殊而备受青睐，本文介绍了二钛酸钾、四钛酸钾、六钛酸钾和八钛酸钾纤维的结构、性质、用途，及国内外的研究现状． 相似文献
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Late Quaternary soils in southern New Mexico support previous work that suggested pedogenic gypsum accumulates in successive stages as a function of time, similar to pedogenic carbonate. However, gypsum also occurs as small (0·5–1 mm), powdery spheres that we term snowball morphology. The snowball morphology represents one of the initial stages of pedogenic gypsum development. Scanning electron microscope analyses indicate that soil microorganisms and organic material may play a crucial role in the development of this morphology. However, no trends were found in the crystal habits of gypsum suggesting the snowball morphology forms in a dynamic environment. 相似文献
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An episode of high lake levels prior to the last maximum glaciation has been identified at many localities in wastern Australia. Similar events have been recognized at playa lakes in central Australia, where gypsum dunes along playa margins formed during one or more episodes of high groundwater discharge, with a large influx of calcium sulphate.At Lake Lewis, exposures at two islands show similar sediment sequences: three pedogenic gypcrete layers interbedded with aeolian quartz and gypsum sand horizons form three units within gypsum dunes up to 7 m high. The lowest unit has cliffed edges buried by the upper units, indicating a significant time break. Four TL dates (coarse-grained quartz) show that this lowest unit was deposited at or before 70–80 ka. The middle unit of mixed gypsum and quartz sand capped by gypcrete represents the major phase of gypsum dune formation, and 6 TL dates range from 33 to 46 ka with overlapping error bars. These are slightly younger but statistically similar to TL dates (from 39 to 59 ka) of the shoreline gypsum dune at Lake Amadeus in the same region. The top unit of the two islands, up to 1 m thick, has not yet been well dated. One date is inconsistent with the well dated middle layer below, possibly because of incomplete bleaching, and has been rejected. The other date (17 ± 5 ka) is much younger which possibly indicates a minor and local reactivation of old gypsum sediments. At the lake margin, there are quartz dunes overlying the gypsum dunes, and a buried aeolian quartz sand layer occurs in a lake-margin terrace. These represent reactivation of the regional quartz dune field after the major gypsum dune formation. Two consistent TL dates (21 ± 4 ka and 23 ± 6 ka) indicate that regional dunes were active at about the time of the Last Glacial Maximum. 相似文献
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《Geomorphology》2003,49(1-2):25-43
Four small areas of Messinian (Upper Miocene) age gypsum, outcropping in western Sicily, are described. Messinian age evaporites are found in Sicily over a 1000-km2 area. Here, gypsum outcrops extensively as a consequence of soil erosion induced by human impact. Geomorphological maps show how the rocky surfaces are characterized by a wide range of forms. There are large, medium, small, and microsized forms, which can be identified as belonging to different morphotypes. The morphotypes can be classified into two main categories: those that originated by solution and those that originated through recrystallisation.Four areas, illustrated by geomorphological maps, were specifically chosen to describe a type of medium-sized form: dome-like hills. These medium-sized forms are covered by a mosaic of smaller forms, related to both the previous categories: different types of karren and of “expansion” forms. The types of karren can be explained as the results of the solution process under different hydro-dynamical behaviour; the dome-like hills and other related “expansion” forms are more difficult to understand. These “expansion” forms can be explained by the same process that leads to the development of gypsum tumuli. The outcrops of gypsum lacking soil cover and influenced by alternating seasonal water conditions of surplus and deficit are affected by both solution and recrystallisation processes. During the wet season, the water soaks into the rocky mass, filling all the fissures and pores of the outer rocky layer from a few centimetres to some metres below the surface. During the dry season, there is a capillary upward motion of the water solution. Near the surface, gypsum precipitates from the oversaturated solution, increasing the crystal size or forming new crystals. In this way, during the dry season, there is a pressure increase in the outer gypsum layers, which is responsible for the development of a “gypsum weathering crust” and characterised by many different forms such as gypsum tumuli, pressure ridges, pressure humps, and other related small forms. The crust may also lead to the development of mega-tumuli and dome-like hills. From the morphostructural point of view, the dome-like hills do not seem to be controlled by the strike, dip, or fissuring of the gypsum beds. Their evolution seems to be linked to the fact that on most of the dome surfaces, the weathering crust is evolving through a nearly isotropic field of stresses, resulting in volume increase in the outer gypsum layer. 相似文献