共查询到20条相似文献，搜索用时 406 毫秒
1.
报道由硫酸钠水溶液实验径向分布函数通过理论模型计算,解析溶液结构参数的方法。其中包括建立理论结构模型的基本依据,专用KURLVR程序使用和结构参数最小二乘精修,以及高斯多峰拟合等实用方法,最终给出能够阐述溶液本质的微观结构参数。结果表明,硫酸钠溶液中水合Na+有2个水合层,第一水合层Na+-OH2(I)距离为0.243 nm,配位数6.0;第二水合层距离为0.448 nm,配位数为13.3;SO2-4存在第一水合层,SO2-4-H2O距离为0.374 nm,配位数为9.1;水合硫酸根原子团中氧原子与水分子的作用距离和配位数按OS-W(1)、OS-W(2)、OS-W(3)、OS-W(4),距离依次为0.283、0.322、0.375和0.486 nm,配位数除OS-W(2)为12.9,其余都在8左右;除此之外溶液中还存在NaOSO-3接触离子对,Na-S距离为0.348 nm,配位数0.20,与晶体结构比较证实SO2-4以单齿形式配位到Na+;水共享离子对Na+-W-SO2-4中Na-S距离精修为0.491 nm,配位数0.62。精修的R因子为0.16,表明获得了很好的精修结果。 相似文献
2.
由密度泛函理论(DFT)和扩展X-射线吸收精细结构(EXAFS)光谱研究硫酸镍溶液的微观水合结构。对硫酸镍水合团簇[NiSO4(H2O)n]0 (n=1-12) 的结构优化和能量计算采用DFT计算中的B3LYP方法进行。对于每一个团簇尺寸尽可能考虑所有初始构型，并以此确定能量最低结构。 DFT计算结果表明，在[NiSO4(H2O)n]0团簇中六配位结构的Ni2+为稳定构型. 水合能计算结果表明，当水合团簇尺寸较小时(n≤5),六配位直接接触离子对(CIP)为稳定构型；而当6≤n≤10时, 溶剂共享离子对 (SSIP)为稳定结构。随着团簇尺寸的增加，当n≥11时，x个水分子分割离子对 (xSIP, x是Ni2+和SO42-之间的水分子数目，且x≥2)为稳定构型。对 NiSO4溶液和NiSO4?6H2O进行EXAFS实验，结果证实Ni2+第一水合层是由六个水分子形成的稳定八面体结构，且当 NiSO4溶液浓度从0.70 mol/L到2.22 mol/L(近似饱和溶液)并未发现CIP构型。Ni-O距离和配位数(CN)分别是 2.040±0.020 ? 和6.0±1.0，这些结论与[NiSO4(H2O)n]0水合团簇的DFT计算结果一致。 相似文献
3.
运用密度泛函理论(DFT)在ωB97XD/gen (O、H元素Aug-cc-PVDZ; Rb元素Lanl2DZ)基组水平上研究了[Rb(H_2O)_n]~+(n=1～12)水合团簇的结构和光谱学性质。研究结果表明,通过分析气相和液相中的稳定能以及水合团簇可知,稳定构型出现在8配位的团簇中。第一配位层水分子数为8时形成Rb~+第一近似饱和水合层。此外,拉曼光谱显示[Rb(H_2O)_n]~+(n=1～12)水合团簇中O-H伸缩振动峰随着水分子数增加发生移动和加宽,Rb~+发生水合时,O-H对称和非对称伸缩振动发生红移,随着水合数的增多,频率蓝移。此外,文中对拉曼光谱中O-H振动的频率位置结合团簇结构进行了说明。 相似文献
4.
在 L i Br与水的物质量比分别为 1∶ 64、1∶ 32、1∶ 16、1∶ 8、1∶ 4和 1∶ 3的情况下 ,对 L i Br溶液从低温到高温的分子动力学模拟进行了研究。随浓度增加 ,锂离子的水合数量呈减少趋势但同时又从 L i+- Br-接触离子对的数量增加中得到补偿 ,而 L i离子的第一配位壳层的配位数量保持不变。在高浓度 Li Br溶液中 ,Br- O之间的距离有所增加 ,Br-- O的径向分布的形状更趋于非对称 ,从而很好地确定了 Br离子水合壳层 L i+- Br-接触离子对可以在更稀的溶液中产生 ,但随浓度增加而增加。L i+- Br-距离明显短于溶液中 Li离子与 Br离子的离子半径之和 ,也短于 L i Br晶体中两者离子半径之和。高浓度溶液中水分子的结构几乎被破坏 ,水分子间的氢键明显增加 ,但没有消失。对 L i+、Br-和水的扩数系数计算值与实验值进行了比较 相似文献
5.
Cs+水合结构的密度泛函理论计算研究 总被引：1，自引：1，他引：0
基于密度泛函理论在ωB97XD/gen def2-tzvp基组水平上对[Cs(H_2O)n]~+(n=1～15)水合团簇结构的振动光谱进行了研究。研究表明,随着水分子数的增加,在气相和液相中,八配位的Cs~+水合团簇是最稳定的;随着水分子数的增加,Cs-O键长增大,Cs~+上的电荷密度减小。当水分子数大于11时,Cs-O键长和Cs~+上的电荷密度变化很小。O(H_2O)-O(H_2O)距离、∠O(H_2O)-Cs-O(H_2O)°统计结果表明,15个水分子足以形成Cs~+的近似饱和水合层。此外,红外光谱显示[Cs(H_2O)n]~+水合团簇中O-H伸缩振动随着水分子数的增加而发生变化,由此可以作为鉴别水合层位置的一种参考方法。 相似文献
6.
本文用密度泛函理论在WB97XD/gen def2-tzvp基组水平上对[Cs(H2O) n] +(n=1-15)水合团簇结构的振动光谱进行了研究。研究表明,随着水分子数的增加,在气相和液相中,8配位的Cs+ 水合团簇是最稳定的;随着水分子数的增加,Cs-O键长增大,Cs+上的电荷密度减小。当水分子数大于11时,Cs-O键长和Cs+上的电荷密度变化很小。O(H2O)-O(H2O)距离、∠O(H2O)-Cs-O(H2O)°统计结果表明,15个水分子足以形成Cs+的近似饱和水合层。此外,红外光谱显示[Cs(H2O)n]+水合团簇中O-H伸缩振动随着水分子数的增加而发生变化,由此可以作为鉴别水合层位置的一种参考方法。 相似文献
7.
通过测试不同Cl~-(NaCl)掺量磷酸镁水泥(MPC)浸取液中离子浓度及MPC硬化体的孔结构和吸水率,研究了Cl~-掺量和浸取时间对MPC硬化体平均孔径、孔隙率、孔径分布、孔体积分布、吸水率、MPC浸取液中Cl~-、Na~+、OH~-、Mg~(2+)、PO■和K~+浓度的影响,结果表明外掺Cl~-对MPC孔结构、离子溶出及吸水率有显著影响,当Cl~-掺量为1%时,MPC硬化体结构密实、孔隙率低、平均孔径小、吸水率小、MPC水化产物在水中的溶蚀量小。 相似文献
8.
X射线散射法是溶液结构研究的重要手段,是研究物质微观结构起源较早的一种方法。从X射线散射图解析出的径向分布函数可以得到具体的结构参数,因此这种方法在溶液结构的研究中得以广泛应用。国内外学者应用X射线散射法对溶液结构进行了大量的研究,确定了不同离子的水合数和水合离子半径,研究了温度、浓度、压力等因素对离子水化结构的影响,发现部分离子存在第二水合层。本文将按照碱金属离子、碱土金属离子、重金属离子、稀土元素离子、卤素离子、含氧酸根离子进行分类,对X射线散射法在溶液结构研究中取得的成果进行总结。在此基础上,分析了应用X射线散射法对水溶液结构研究的现状及其面临的挑战,讨论了该领域的发展前景。 相似文献
9.
结合密度泛函理论,运用B3LYP/aug-cc-pVDZ方法对[Li(H2O)n]+(n=1~10)水合团簇的结构进行了研究。研究结果表明,在气相和液相中,四配位结构的[Li(H2O)n]+水合团簇比其五配位的异构体稳定,即在水溶液中Li+易形成四配位的四面体结构。随着同时水分子数的增加,Li-O键长增大,Li+上的电荷密度减小。但是当水分子数大于4时,Li-O键长和Li+上的电荷密度变化很小。[Li(H2O)n]+水合团簇中每个水分子的结合能计算结果表明,7个水分子已足以形成Li+的近似饱和水合层。另外红外光谱显示[Li(H2O)n]+水合团簇中O-H伸缩振动随着水分子数的增加发生蓝移,而~3 600 cm-1和~3 500 cm-1处的吸收峰是第二水合层与第一水合层、第三水合层和第二水合层的水分子形成氢键引起的。 相似文献
10.
该文为硕士学位论文,于1999年5月在中国科学院青海盐湖研究所完成。该论文进行了过饱和ＭｇＳＯ4水溶液结构的Ｘ射线衍射研究,其溶液的水与盐之比及过饱和度分别是样Ａ为1∶16,11.3%;样Ｂ为1∶17,3.496%。获得了过饱和ＭｇＳＯ4溶液中关于Ｍｇ2 阳离子水合、ＳＯ42-阴离子水合和接触离子对Ｍｇ2 ＳＯ42-形成的进一步的信息;给出了数据组合前后的实验强度图形,极化校正后的实验强度图形,实验与理论的ＳｉＳ曲线,实验与理论径向分布函数曲线。研究结果表明,溶液中的Ｍｇ2 离子周围存在两个水合层,其中第二水合层中的水分子通过氢键与第一水合… 相似文献
11.
12.
13.
《The Professional geographer》1988,40(4):471-499
Books reviewed in this article: USA, Eine Geographische Landeskunde , Vol. I, Der Grossraum in Strukturellem, Wandel, 3rd Ed. Helmut Blume . Introduction to Remote Sensing . James B. Campbell . The Sounds of People and Places: Readings in the Geography of American Folk and Popular Music . George O. Carney , ED. Development and Underdevelopment . John Cole . Mobility and Employment in Urban Southeast Asia: Example from Indonesia and the Philippines . Michael A. Costello , Thomas R. Leinbach , AND Richard Ulack . Soviet Asia: Economic Development and National Policy Choices . Leslie Dienes . The Third World City . David Drakakis -Smith . Scholars' Guide to Washington, DC for Cartography and Remote Sensing Imagery (maps, charts, aerial photographs, satellite images, cartographic literature and geographic information systems). Ralph E. Ehrenberg . Population and Development in the Third World . Allan AND Anne Findlay . The Early Mapping of Hawaii . Gary L. Fitzpatrick . Energetics of Physical Environment: Energetic Approaches to Physical Geography . K. J. Gregory , ED. Wildland Recreation: Ecology and Management . William E. Hammitt and David N. Cole . Agricultural Commercialization and Government Policy in Africa . J. Hinderink AND J. J. Sterkenburg . The Dynamics of American Housing . James W. Hughes AND George Sternlieb . Thailand: Buddhist Kingdom as Modern Nation State . Charles F. Keyes . Resolving Locational Conflict . Robert W. Lake , ED. Lands at Risk in the Third World: Local-level Perspectives . Peter D. Little and Michael M. Horowitz , EDS. Nathaniel Southgate Shaler and the Culture of American Science . David N. Livingstone . Regions: The Economics and Politics of Territory . Ann R. Markusen . Wetlands . William J. Mitsch and James G. Gosselink . Historical Geography: Progress and Prospect . Michael Pacione , ED. Loess and Periglacial Phenomena . Marton P$eacsi and Hugh M. French , EDS. Regional Management of Metropolitan Floodplains, Experience in the United States and Abroad . Rutherford H. Platt , ED. Human Cartography: Mapping the World of Man . Janos Szegö . Atlas of Great Lakes Indian History . Helen H. Tanner , ED. The Botany of Mangroves . P. B. Tomlinson . Urban Spatial Traffic Patterns . Rodney Vaughan . The Night After … Climatic and Biological Consequences of a Nuclear War . Yevgeni Velikhov , ED. Industrial Geography . H. D. Watts . Dictionary of Quotations in Geography . James O. Wheeler and Francis M. Sibley . Vermont Townscape . Norman Wiliams , Jr. , Edmund K. Kellogg and Peter M. Lavigne . 相似文献
14.
《The Professional geographer》2013,65(4):488-489
Book Reviewed in this article: Main Street: Northeastern Oregon: The Founding and Development of Small Towns. Barbara Ruth Bailey. Food Politics: The Regional Conflict. David N. Balaam and Michael J. Carey, eds. The International Economy and Industrial Development: Trade and Investment in the Third World. R. Ballance, J. Ansari and H. Singer. Neighborhoods in Urban America. Ronald H. Bayor, ed. The English Heartland. By Robert Beckinsale and Monica Beckinsale. Regional Dimensions of Industrial Policy. Michael E. Bell and Paul S. Lande, eds. Tension Areas of the World. D. Gordon Bennett, ed. Latin America: an Introductory Survey. B. W. Blouet and O. M. Blouet, eds. Integration and Division: Geographical Perspectives on the Northern Ireland Problem. Frederick W. Boal and J. Neville H. Douglas, eds. Energy and Land Use. Robert W. Burchell and David Listokin, eds. Slopes and Weathering. Michael Clarke and John Small. Alaska's Rural Development. Peter G. Cornwall and Gerald McBeath, eds. The Politics of Park Design: A History of Urban Parks in America. Galen Cranz. World Congress on Land Policy, 1980, Proceedings. Matthew Cullen and Sharon Woolery, eds. Oregon Divided: A Regional Geography. Samuel N. Dicken and Emily F. Dicken. Urban Food Marketing and Third World Rural Development. T. Scarlett Epstein. South Africa: Spatial Frameworks for Development. T. J. D. Fair. Institutions and Geographical Patterns. Robin Flowerdew, ed. Industrialization of U.S. Agriculture, An Interpretive Atlas. Howard F. Gregor. Planning Theory: Prospects for the 1980s. Patsy Healy, Glen McDougall and Michael J. Thomas, eds. Neighborhood Mobilization: Redevelopment and Response. Jeffrey R. Henig. The American Urban System: A Geographical Perspective. R. J. Johnston. Climate, History and the Modern World. Hubert H. Lamb. Climate and History: Studies in Past Climates and Their Impact on Man. T. M. L. Wigley, M. J. Ingram and G. Farmer. China: Railways and Agricultural Development, 1875–1935. Ernest P. Liang. A Desirable Energy Future—A National Perspective. Robert S. Livingston, T. D. Anderson, T. M. Besmann, M. Olszewski, A. M. Perry, and C. D. West. Topothesia: Essays Presented to T. S. Ó Máille. B. S. Mac Aodha, ed. Transportation for the Poor: Research in Rural Mobility. Hal S. Maggied. Land Uses in American Cities. Harold M. Mayer and Charles R. Haves. Industrial Organisation and Location. Philip McDermott and Michael Taylor. Human Adaptability: an Introduction to Ecological Anthropology. Emilio F. Moran. Regional Analysis and the New International Division of Labor. Frank Moulaert and Patricia W. Salinas, eds. The Nuclear War Atlas. Victoriaville, Quebec, Canada: Urbanization and Environmental Quality. Isao Orishimo. The Garden of Eden: The Botanic Garden and the Re-Creation of Paradise. John Prest. Earthfire, The Eruption of Mount St. Helens. Charles Rosenfeld and Robert Cooke. Contest for the South China Sea. Marwyn S. Samuels. The Future of the Wetlands: Assessing Visual-Cultural Values. Richard C. Smardon, ed. Tucson: the Life and Times of An American City. C. L. Sonnichsen. The Geography of Multinationals. Michael Taylor and Nigel Thrift, eds. Impact of Marine Pollution on Society. Virginia Tippie and Dana Kester. Reviving the Industrial City: the Politics of Urban Renewal in Lyon and Birmingham. Jerry A. Webman. Andean Reflections: Letters from Carl O. Sauer While on a South American Trip under a Grant from the Rockefeller Foundation, 1942. Robert C. West, ed. Cartographic Drawing with Computers. P. Yoeli. 相似文献
15.
《The Professional geographer》1983,35(4):488-524
Book Reviewed in this article: Main Street: Northeastern Oregon: The Founding and Development of Small Towns . Barbara Ruth Bailey . Food Politics: The Regional Conflict . David N. Balaam and Michael J. Carey , eds. The International Economy and Industrial Development: Trade and Investment in the Third World . R. Ballance , J. Ansari and H. Singer . Neighborhoods in Urban America . Ronald H. Bayor , ed. The English Heartland . By Robert Beckinsale and Monica Beckinsale . Regional Dimensions of Industrial Policy . Michael E. Bell and Paul S. Lande , eds. Tension Areas of the World . D. Gordon Bennett , ed. Latin America: an Introductory Survey . B. W. Blouet and O. M. Blouet , eds. Integration and Division: Geographical Perspectives on the Northern Ireland Problem . Frederick W. Boal and J. Neville H. Douglas , eds. Energy and Land Use . Robert W. Burchell and David Listokin , eds. Slopes and Weathering . Michael Clarke and John Small . Alaska's Rural Development . Peter G. Cornwall and Gerald Mc Beath , eds. The Politics of Park Design: A History of Urban Parks in America . Galen Cranz . World Congress on Land Policy, 1980, Proceedings . Matthew Cullen and Sharon Woolery , eds. Oregon Divided: A Regional Geography . Samuel N. Dicken and Emily F. Dicken . Urban Food Marketing and Third World Rural Development . T. Scarlett Epstein . South Africa: Spatial Frameworks for Development . T. J. D. Fair . Institutions and Geographical Patterns . Robin Flowerdew , ed. Industrialization of U.S. Agriculture, An Interpretive Atlas . Howard F. Gregor . Planning Theory: Prospects for the 1980s . Patsy Healy , Glen Mc Dougall and Michael J. Thomas , eds. Neighborhood Mobilization: Redevelopment and Response . Jeffrey R. Henig . The American Urban System: A Geographical Perspective . R. J. Johnston . Climate, History and the Modern World . Hubert H. Lamb . Climate and History: Studies in Past Climates and Their Impact on Man . T. M. L. Wigley , M. J. Ingram and G. Farmer . China: Railways and Agricultural Development, 1875–1935 . Ernest P. Liang . A Desirable Energy Future—A National Perspective . Robert S. Livingston , T. D. Anderson , T. M. Besmann , M. Olszewski , A. M. Perry , and C. D. West . Topothesia: Essays Presented to T. S. Ó Máille . B. S. Mac Aodha , ed. Transportation for the Poor: Research in Rural Mobility . Hal S. Maggied . Land Uses in American Cities . Harold M. Mayer and Charles R. Haves . Industrial Organisation and Location . Philip Mc Dermott and Michael Taylor . Human Adaptability: an Introduction to Ecological Anthropology . Emilio F. Moran . Regional Analysis and the New International Division of Labor . Frank Moulaert and Patricia W. Salinas , eds. The Nuclear War Atlas. Victoriaville, Quebec, Canada : Urbanization and Environmental Quality . Isao Orishimo . The Garden of Eden: The Botanic Garden and the Re-Creation of Paradise . John Prest . Earthfire, The Eruption of Mount St. Helens . Charles Rosenfeld and Robert Cooke . Contest for the South China Sea . Marwyn S. Samuels . The Future of the Wetlands: Assessing Visual-Cultural Values . Richard C. Smardon , ed. Tucson: the Life and Times of An American City. C. L. Sonnichsen . The Geography of Multinationals . Michael Taylor and Nigel Thrift , eds. Impact of Marine Pollution on Society . Virginia Tippie and Dana Kester . Reviving the Industrial City: the Politics of Urban Renewal in Lyon and Birmingham . Jerry A. Webman . Andean Reflections: Letters from Carl O. Sauer While on a South American Trip under a Grant from the Rockefeller Foundation, 1942 . Robert C. West , ed. Cartographic Drawing with Computers . P. Yoeli . 相似文献
16.
《寒旱区科学》2014,(4):I0001-I0001
Permafrost engineering has been developing rapidly in recent years. Many projects have been undertaken with the latest technologies and show their importance in supporting regional social and economical development. For example, the Qinghai-Tibet Railway has been a milestone project in permafrost engineering. However, when designing and building infrastructures in cold regions, 相似文献
17.
HAYASHI Hiroaki 《资源与生态学报(英文版)》2014,(4):395-397
<正>1 Characteristics of Kunisaki GIAS and aims of this research Kunisaki GIAHS in the Kunisaki peninsula and Usa area,Oita,Japan,is a system where forestry,agricultural production,and fisheries are sustained by the strong connection between Sawtooth Oak forest,multiple interlinked irriga tion ponds,and Seto Inland Sea(Vafadari 2013a;2013b;Hayashi 2013).This area receive around 1,500 mm of annual precipitation with a 相似文献
18.
《The Professional geographer》1984,36(3):376-412
Book Reviewed in this article: Introduction to Climatology for the Tropics . J. O. Ayoade. Conservation and Management of Natural Resources in the United States . Charles F. Bennett. The Keeping of Animals: Adaptation and Social Relations in Livestock Producing Communities . Riva Berleant-Schiller and Eugenia Shanklin, ed. The Evolution of Geographic Thought in America: A Kentucky Root Wilford A. Bladen and Pradyumna P. Karan, eds. Latin America: Geographical Perspectives , 2nd ed. Harold Blakemore and Clifford T. Smith, ed. The Rural Real Estate Market. Department of Geography Publication Series, No. 18 . Chris Bryant. Urban Geomorphology in Drylands . R. U. Cooke, D. Brunsden, J. C. Doornkamp, and D. K. C. Jones with contributions by J. Griffiths, P. Knott, R. Potter, and R. Russell. Italian Geography, 1960–1980. Meeting of the Status of the Geographic Research in Italy, 1960–1980. Treated under the auspices of Consiglio Nazionale delle Ricerche and organized by Istituto di Geografia Umana della Facoltà di Lettere e Filosofia dell'Università degli Studi di Milano , Giacomo Corna Pellecrini and Carlo Brusa, eds. The Changing Fenland . H. C. Darby. The Future for the City Centre . R. L. Davies and A. G. Champion, eds. Saudi Arabia, Energy, Developmental Planning, and Industrialization . Ragaei El Mallakh, Dorothea H. El Mallakh, eds. For We Are Sold, I and My People: Women and Industry in Mexico's Frontier . Maria Patricia Fernández-Kelly. The Great Lakes Forest: An Environmental and Social History . Susan L. Flader, ed. Regional Transformation and Industrial Revolution: A Geography of the Yorkshire Woolen Industry . Derek Gregory Crime in City Politics . Anne Heinz, Herbert Jacob and Robert L. Lineberry, eds. Revitalizing Cities . H. Briavel Holcomb and Robert A. Beauregard. Cartographic Relief Presentation . Eduard Imhof. H. J. Steward, Trans. Soviet Union: A Geographical Survey . S. V. Kalesnik and V. F. Pavlenko, ed. Cognition and Environment . Stephen Kaplan and Rachel Kaplan. Environmental Protection: The International Dimension . David A. Kay and Harold K. Jacobsen, eds. Mathematical Programming Methods for Geographers and Planners , James Killen. Gentrification Amid Urban Decline: Strategies for America's Older Cities . Michael H. Lang. The North Atlantic Sulphur System . Risto Laulajainen. The Jerusalem Cathedra: Studies in the History, Archaeology, Geography and Ethnography of the Land of Israel, Vol. 2 . Lee I. Levine ed. Jerusalem and Detroit: Recreation Planning and Management . Stanely R. Lieber and Daniel R. Fesenmaier, eds. Heartland and Hinterland: A Geography of Canada . L. D. McCann, ed. Scarborough Where We Live: The Residential Districts of Minneapolis and St. Paul . Judith A. Martin and David A. Lanegran. California: The Geography of Diversity . Crane S. Miller and Richard S. Hyslop. Palo Alto The Dilemma of Amazonian Development . Emilio F. Moran, ed. Boulder Nuclear Waste: Socioeconomic Dimensions of Long-Term Storage . Steve H. Murdock, F. Larry Leistritz, and Rita R. Hamm, eds. Boulder Communism and the Politics of Inequalities . Daniel N. Nelson, ed. The Los Angeles Metropolis . Howard J. Nelson. Dubuque An Historical Geography of Urban System Development: Tidewater Virginia in the 18th Century . James O'Mara. Procedures and Standards for a Multipurpose Cadastre . East Asia: Geographical and Historical Approaches to Foreign Area Studies . Clifton W. Pannell, ed. Dubuque Mackinder: Geography as an Aid to Statecraft . W. H. Parker. Beyond the Urban Fringe: Land Use Issues of Nonmetropolitan America . Rutherford H. Platt and George Macinko, eds. Recreation Geography of the USSR . V. S. Preobrazhensky and V. M. Krivosheyev, eds. Missouri: A Geography . Milton D. Rafferty The Invisible Farmers: Women in Agricultural Production . Carolyn E. Sachs. Cayman Islands Seashore Vegetation: A Study in Comparative Biogeography . Jonathan D. Sauer. Hillslope Materials and Processes . Michael J. Selby. Housing in Britain: The Post-War Experience . John R. Short The Study of Population: Elements, Patterns and Processes . George A. Schnell and Mark Stephen Monmonier. Columbus The Soviet Union: A Systematic Geography . Leslie Symons, ed. The Ottoman Slave Trade and Its Suppression . Ehud R. Toledano. The Impact of Recession on Industry, Employment and the Regions, 1976–1981 . Alan R. Townsend. Landslides and Their Control , 2nd ed. Quido Záruba and Vojtech Mencl. Translated from the Czech by H. Zárubová and V. Mencl. 相似文献
19.
《The Professional geographer》1986,38(1):105-130
Book Reviewed in this article: Unfairly Structured Cities . Blair Badcock Religion and Rural Revolt . Janos M. Bak and Gerhard Benecke The Industrial Geography of Canada . Anthony Blackbourn and Robert G. Putnam The Cuban-American Experience, Culture, Images, and Perspectives. Thomas D. Boswell and James R. Curtis Quaternary Paleoclimatology . R. S. Bradley Development and Crisis in Brazil, 1930–1983 . Luiz Bresser Pereiras Centres of Origin in Biogeography . John C. Briggs Analytical Urban Geography . Martin Cadwallader Geomorphology . Richard J. Chorley , Stanley A. Schumm, and David E. Sugden South Africa: The Impact of Past Geographies . A. J. Christopher The Geography of Underdevelopment. A Critical Survey . D. K. Forbes Health Care in Developing Countries . Wilbert M. Gesler Place to Grow Old: The Meaning of Environment in Old Age . Stephen M. Golant The Emerging Marine Economy of the Pacific . Chennat Gopalakrishnan An Introduction to Agricultural Geography . David B. Grigg The Soviet Union: A Geographical Study . G. Melvyn Howe Geographical Aspects of Health: Essays in Honour of Andrew Learmonth . N. D. Mc Glashan and J. R. Blunden Physical Geography: A Landscape Appreciation . Tom L. Mc Knight Mountain Experience. The Psychology and Sociology of Adventure. Richard G. Mitchell Jr . Systematic and Regional Biogeography. Stanley A. Morain The Economic Transformation of American Cities. T. J. Noyelle and T. M. Stanback , Jr . Normal Accidents: Living With High-Risk Technologies. Charles Perrow Vanishing Farmland: A Legal Solution for the States. Sarah E. Redfield Applied Methods of Regional Analysis: The Spatial Dimensions of Development Policy. Dennis A. Rondinelli Urbanization in Romania. A Geography of Social and Economic Change Since Independence. Per Ronnas Statistical Techniques in Geographical Analysis. Gareth Shaw and Dennis Wheeler The Granite Garden: Urban Nature and Human Design. Anne Whiston Spirn Political Geography: Recent Advances and Future Directions. Peter Taylor and John House Geographia y Medio Ambiente. Manuel Valenzuela -Rubío Nãgara and Commandery: Origins of the Southeast Asian Urban Traditions. Paul Wheatley The Common Fisheries Policy of the European Community. Mark Wise Geography and Gender. Women and Geography Study Group of the IBG Technological Hazards. D. J. Zeigler , J. H. Johnson , S. D. Brunn 相似文献
20.
P. Guilizzoni A. Marchetto A. Lami N. G. Cameron P. G. Appleby N. L. Rose Ø. A. Schnell C. A. Belis A. Giorgis L. Guzzi 《Journal of Paleolimnology》1996,15(3):245-264
A palaeoecological study of an oligotrophic alpine lake, Paione Superiore (Italy), provided a record of historical changes in water quality. Historical trends in lake acidification were reconstructed by means of calibration and regression equations from diatoms, chrysophycean scales and pigment ratios. The historical pH was inferred by using two different diatom calibration data sets, one specific to the alpine region. These pH trends, together with the record of sedimentary carbonaceous particles and chironomid remains, indicate a recent acidification of this low alkalinity lake.Concentration of total organic matter, organic carbon, nitrogen, biogenic silica (BSiO2), chlorophyll derivatives (CD), fucoxanthin, diatom cell concentration and number of chironomid head capsules increased during the last 2–3 decades. When expressed as accumulation rates, most of these parameters tended to decrease from the past century to c. 1950, then all except P increased to the present day. A marked increase in sedimentary nitrogen may be related to atmospheric pollution and to the general increases in output of N in Europe. High C/N ratios indicate a prevailing allochthonous source of organic matter.Finally, the increase in measured air temperature from the mid-1800's appeared to be related to lake water pH before industrialization: cold periods generally led to lower pH and vice-versa. The more recent phenomenon of anthropogenic acidification has apparently decoupled this climatic-water chemistry relationship. 相似文献