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1.
Cores of recent sediments were sampled along a depth gradient in a 23 m deep kettle lake with stagnant deep waters containing exceptionally high concentrations of dissolved iron and manganese. Sediment cores were taken on two occasions, in 1978 and 1997, before and after an incidence of full circulation. The aims of this study are to see how oxic and anoxic conditions in the water column influence stratigraphy and sediment focusing and, to compare cores from 1979 and 1998 to see how measured element fluxes and external events are reflected in the chemical stratigraphy. Element analyses show characteristic stratigraphic patterns that depend on the ability to undergo redox transformations, sorptive properties and chemical equilibria in the anoxic deep waters and porewaters. In sediments from the oxic part of the lake Al, Cr, Co, Ni, Zn Cu, Cd, and Pb were well correlated. Positive correlations are seen between elements associated with primary production and sulphur. In the anoxic part of the lake most metals were positively correlated with carbonate. Phosphorus correlated positively with iron in sediments from oxic waters and negatively with manganese and iron deep-water sediments. Porewater analyses indicate that recycling from the deep-water sediments was negligible. The stratigraphy of lead agrees with the historic variation in atmospheric input and is used as a chronological marker. Assessed deposition rates agree with measurements in sediment traps. Most elements more than double their rates of deposition towards the deepest point of the lake, while sulphur, manganese and carbonate had maxima around the depth of the redoxcline in the water. Variations in the external loading and variable redox conditions in the deep waters explain variations in the chemical composition of recent sediments.  相似文献   

2.
Major components of lacustrine sediments, such as carbonates, organic matter, and biogenic silica, provide significant paleoenvironmental information about lake systems. Fourier transform infrared spectroscopy (FTIR) and scanning X-ray fluorescence (XRF) techniques are fast, cost effective, efficient methods to determine the relative abundances of these components. We investigate the potential of these techniques using sediments from two large lakes, Lake Malawi in Africa and Lake Qinghai in China. Our results show statistically significant correlations of conventionally measured concentrations of carbonate (%CaCO3), total organic carbon (%TOC), and biogenic silica (%BSi), with absorbance in the corresponding FTIR spectral regions and with XRF elemental ratios including calcium:titanium (Ca/Ti), incoherent:coherent X-ray scatter intensities (Inc/Coh), and silicon:titanium (Si/Ti), respectively. The correlation coefficients (R) range from 0.66 to 0.96 for comparisons of FTIR results and conventional measurements, and from 0.70 to 0.90 for XRF results and conventional measurements. Both FTIR and XRF techniques exhibit great potential for rapid assessment of inorganic and organic contents of lacustrine sediments. However, the relationship between XRF-ratios or FTIR-absorbances and abundances of corresponding sedimentary components can vary with sediment source and lithology.  相似文献   

3.
Stable carbon and oxygen isotope data from mollusc aragonite extracted from sediment cores provide new information on the origin and history of sedimentation in the southwestern area of the central basin of Lake Erie. Sediments infilling the Sandusky subbasin consist of three lithologic units overlying glacial deposits. The lowest of these is a soft gray mud overlain by a shell hash layer containing Sphaerium striatinum fragments. A fluid mud unit caps the shell hash layer and extends upwards to the sediment-water interface. New stable isotope data suggest that the soft gray mud unit is of postglacial, rather than proglacial, origin. These data also suggest that the shell hash layer was derived from erosional winnowing of the underlying soft gray mud layer. This winnowing event may have occurred as a result of the Nipissing flood.The Pelee-Lorain moraine, which forms the eastern boundary of the Sandusky subbasin, is an elevated area of till capped by a sand deposit that originated as a beach. The presence of both the shell hash layer and relict beach deposit strengthens the interpretation that the Nipissing flood was a critical event in the development of the southwestern area of the central basin of Lake Erie. This event, which returned drainage from the upper lakes to the Lake Erie basin, was a dominant influence on regional stratigraphy, bathymetry, and depositional setting.  相似文献   

4.
镁、镁资源与镁质材料概述   总被引：4，自引：0，他引：4       下载免费PDF全文
中国盐湖卤水镁资源的开发形势十分严峻。首先是量大,仅青海盐湖集团提钾副产的镁卤量就超过中国海盐副产镁卤总量的3倍;其二是缺少适合开发的大宗镁产品,受中国镁碳酸盐矿物开发的冲击,世界范围内,以海湖卤镁为原料的炼镁企业和氧化镁厂商都逐渐退出行业竞争。镁碳酸盐矿物方面,菱镁矿主要生产镁质耐火材料,中国镁质耐火材料产量和产能居世界首位,且已开始变强并良性发展;白云石主要生产金属镁材料,中国金属镁产量和产能占世界的比例更大,也正努力做强;与另两大类镁质材料形成鲜明对比,镁质化工材料领域的现状是又小又弱,相关发展取决于能否率先将产品做成系列和规模。中国盐湖卤水镁资源过多甚至成为"镁害",但该资源价廉、含杂质少,是镁质化工材料的优质原料,应该在相关领域加大投入。  相似文献   

5.
In recent years, large areas of farmland in the North China Plain have been converted into short-rotation poplar plantations. To analyze the impacts of poplar plantations on soil, 22 soil samples were collected and assayed from the soil profiles of a corn field and a poplar plantation. The results showed that the average soil moisture content of the soil profile in the poplar field was 2.6 percent lower than that of the arable land. The maximum difference in soil moisture content was found in the upper 0-10 cm of topsoil. Soil organic matter and nitrogen, phosphorus and potassium in the cornfield were significantly higher than in the poplar field. Higher nutrient content in the corn field may result from higher fertilizer inputs and the practice of returning straw to the cropped field. The analysis also showed no significant increase in soil organic matter content in deeper soil layers of the poplar field, which means that the conditions are not favorable for the formation of soil organic matter, or that soil organic matter needs a longer time to develop. Elements such as magnesium, iron, manganese and copper in both the corn field and the poplar field had a tendency to accumulate with increasing soil depth. Magnesium, iron, manganese and copper in the 0-80 cm soil layer of the poplar field were higher than those of the cornfield, but the situation was reversed at depths greater than 80 cm. It is concluded that poplar trees consume a large amount of soil moisture and soil nutrients. Local governments should prevent the development of new plantations of fast-growing trees in farmland and help farmers to recover their farmland from forestry plantations.  相似文献   

6.
A short-core paleolimnological investigation was carried out to acquire knowledge of the recent history of Lake Pihlajavesi, Saimaa Lake complex, and define its natural state before cultural disturbances. In the natural state, with negligible human interference, the basin was oligotrophic and oxygen-rich. The bioproductivity in the littoral zone was low and the profundal benthic quality was good according to Wiederholm's Benthic Quality Index.Based on diatom analyses, no significant changes have taken place in the phytoplankton communities during the past decades. Sedimentary chironomid communities reveal, however, slight changes on profundal life in the Pihlajavedenselkä basin, near the main pollution sources, whereas there were no significant changes in the outer basin. Three stages could be distinguished in the pollution history of Pihlajavedenselkä: (1) 'The natural state' up until the 1960s, (2) 'the period of increasing loading' during the 1960s and 1970s, and (3) 'the recovery of the basin' during the past two decades.Untreated municipal waste water from the town of Savonlinna was partly responsible for the commencement of eutrophication in the Pihlajavedenselkä basin in the 1960s. The paper and pulp industry in Varkaus, some 40 kilometres upstream from Lake Pihlajanvesi, has also increased eutrophication, especially during the worst period of water quality in the 1960s and 1970s. More effective waste water purification has markedly reduced effluent loading and led to a general recovery of the area. Neverthless the effects of slight nutrient loading can still be seen, especially in littoral bioproductivity.Our paleolimnological data indicate that the present ecosystem will offer living conditions for the endemic Saimaa ringed seal population that are similar to those that existed prior to human disturbances.  相似文献   

7.
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8.
Many freshwater resources receive materials from human development causing a decrease in ecological services when compared to pre-disturbance periods. As a result, the understanding of eutrophication and limnological change has increased, but less attention has been given to systems under intense human impact that have not eutrophied so that drivers precluding eutrophication can be documented. The primary objective of this research was to reconstruct allochthonous inputs and in-lake processes for Long Pond, Georgia, USA from the mid Holocene to present and link them to primary producer community changes. Long Pond is a mesotrophic lake located in a highly altered watershed from agricultural and municipal land use and housing developments. A 5 m sediment core was collected from Long Pond, and organic matter, nutrients (C, N, P), metals (Al, Fe, Cu), and photosynthetic pigments were measured. Long Pond existed in three limnological states spanning the past ~6000 years. Prior to modern lacustrine conditions, Long Pond was a wetland/peat system that experienced the highest primary producer abundance recorded in the core. The modern lacustrine state began in the late Holocene and was characterized by increased connectivity with the surrounding watershed and low productivity. Human impacts began around 1900 AD and included high levels of phosphorus and metal deposition but moderate levels of primary producer abundance. As a result, in-lake dynamics are believed to be regulating the trophic status of Long Pond. Low concentrations of available phosphorus in the water column combined with high concentrations of sedimentary phosphorus may imply the binding of phosphorus to the sediments by certain materials such as aluminum and iron. Long Pond serves as an example of the complex in-lake processes that can occur from allochthonous inputs and autochthonous responses in lake systems thus complicating management decisions.  相似文献   

9.
Abstract

Waquoit Bay, a shallow bay on Cape Cod, Massachusetts, is exhibiting symptoms of eutrophication, largely attributed to septic nitrogen inputs. This study assessed septic nitrogen inputs by linking a three-dimensional ground-water model, a geographic information system (GIS), and a customized spatio-temporal nitrogen loading program. Owing to the slow speed of ground-water movement, the bulk of septic nitrogen entering the bay lags behind development by nearly a decade. Even if residential development is held at 1989 levels, nitrogen input from septic systems wilt increase by 36% over the current levels. At full residential build-out (i.e., development), septic nitrogen loading will eventually increase to more than twice the current levels.  相似文献   

10.
Musky Bay in Lac Courte Oreilles, Wisconsin, USA, is currently eutrophic. This large, shallow bay of an oligotrophic lake possesses the densest aquatic plant growth and a floating algal mat. Paleoecological reconstructions encompassing the last 130 years, were based on multiproxy analyses of sediment cores from three coring sites, two within the bay and one in the lake itself. These data were compared to historical records of the construction and expansion of two commercial cranberry bogs and shoreline residential homes to identify temporal and causal relations of eutrophication. The proxies investigated included: minor and trace elements; biogenic silica; and the diatom community. Post-depositional diagenesis of organic carbon, nitrogen, and phosphorus in the upper 30 cm of the core obscured records of historical ambient nutrient concentrations in the bay obviating their usefulness for this purpose. In contrast, calcium, magnesium, and potassium concentration profiles appeared to reflect runoff of soil amendments applied to the cranberry bogs and aerial fertilizer spraying over the eastern bog adjacent to Musky Bay. The increase in aluminum content since about 1930 coincided with the historical trend in shoreland development and construction of the original commercial cranberry farm. The biogenic silica profile recorded a steady increase of nutrients to Musky Bay over the last several decades. Stratigraphic changes in the diatom community indicated that nutrient input began to increase in the 1940s and accelerated in the mid-1990s with the onset of a noxious floating algal mat. The diatom community indicates the bay has possessed a significant macrophyte community for at least the last 200 years, but increased nutrient input was manifested by a change in the composition, and an increase in the density of the epiphytic diatom community. Cranberry farming appeared to be the major source of nutrients because the diatom community changes occurred prior to the significant increase in residential housing.  相似文献   

11.
Reservoir sediments are rarely used as environmental archives because of the potential for sediment disturbance by fluctuating water levels. However, rapid rates of sedimentation, proximity to urban centres and often the existence of management records, may make them potentially important resources for reconstructing recent, anthropogenically-derived environmental change. This project assesses the potential of reservoir sedimentary records for reconstructing past atmospheric and drainage basin fluxes of heavy metals (manganese, iron, nickel, copper, zinc and lead) in the southern Pennines, UK. Five reservoirs were selected on the basis of management history and drainage basin characteristics. Multi-parameter analysis showed sediments to be replicable across the ȁ8accumulating zone’ with reasonably consistent rates of sedimentation. Water level fluctuations were not found to detrimentally affect sediment records in the deepwater area of the reservoirs. In fact, spheroidal carbonaceous particle (SCP) profiles show trends in inputs that closely reflect major changes in industrialisation, indicating the reservoir sediments to be excellent records of particulate inputs. Only lead (Pb) and zinc (Zn) were significantly enriched in the reservoir sediment in comparison to background levels. Manganese (Mn), iron (Fe) and to a limited degree, copper (Cu), appeared to be affected by post-deposition mobility. Preliminary calculations of Pb fluxes indicate that over 80% of the current Pb input to the reservoirs is from Pb deposited onto drainage basin soils in the past, rather than from direct atmospheric deposition or natural background inputs. In Howden reservoir, for example, the total Pb flux to deepwater sediment cores in 2000 was 119 mg m−2 a−1. Of this, an estimated 99 mg m−2 a−1 was from anthropogenically-derived Pb, initially deposited onto drainage basin soils and subsequently entering the reservoir via erosion and leaching processes. There is, therefore, no indication that the flux of Pb to the aquatic system is declining in response to reductions in Pb deposition. The ecotoxicological effects of the high and continuing Pb flux to these reservoirs, despite recent decreases in atmospheric deposition, is an area requiring further investigation.  相似文献   

12.
In lake sediment investigations of heavy metal pollution history, it has become a common approach to calculate enrichment factors (EFs) by normalizing elemental distributions to a reference lithogenic element. However, this approach requires that the reference element remains stable once it has been deposited to the sediment (it is not affected by diagenetic processes). This is rarely studied in well-controlled field experiments. Here, we test the commonly used reference elements titanium (Ti), zirconium (Zr), aluminum (Al), and rubidium (Rb). We use a unique series of freeze cores collected in different years since 1979 in Lake Nylandssjön in northern Sweden. This lake has sediment with distinct varves (annually laminated deposit). Element concentrations in individual varves were analyzed using X-ray fluorescence (XRF) spectroscopy. By tracking the newly formed surface varve from different cores across this core series, i.e., following the element concentration in a specific varve as it becomes progressively aged, it was possible to assess the potential impact of diagenetic processes on geochemical signatures. Results confirm the conservative character of the studied elements; there was neither an increasing nor a decreasing concentration trend with time during sediment ageing for any of these elements. Secondly, we addressed the question ‘which of them is the most appropriate for EFs estimates with the aim of distinguishing anthropogenic from geogenic inputs, for example in pollution studies’. To assess the reliability of the EFs we used lead (Pb) as an example, because anthropogenic Pb in the sediment could be independently calculated using stable Pb isotopes. When anthropogenic Pb concentrations calculated with Pb-EFs were compared to the anthropogenic Pb concentrations derived from stable Pb isotopes, the differences found were 20% for Ti, 10% for Zr, 11% for Al, and 27% for Rb when upper continental crust concentrations were used for the background ratio. Based on the results from Nylandssjön our suggestions are that (1) when using EFs on a single core, which is the normal case in paleolimnology, multiple reference elements should be used together and (2) the results from those should be critically evaluated.  相似文献   

13.
A ~106-cm sediment core from the eastern basin of Lake Erie was examined to investigate biogeochemical processes in this large lake during its cultural eutrophication over the last century. We measured stable carbon isotopes of total organic carbon and calcium carbonate (δ13CTOC and d13 \textC\textCaCO 3 \delta^{13} {\text{C}}_{{{\text{CaCO}}_{ 3} }} ) as well as the concentrations of total organic carbon (TOC) and calcium carbonate (CaCO3). δ13CTOC and TOC show a strong positive correlation throughout the core and record changes in phytoplankton productivity and nutrient loading. CaCO3 and TOC concentrations display a negative correlation throughout the core, suggesting that CaCO3 concentrations are controlled primarily by decomposition of TOC in the hypolimnion and the sediments, although temperature and invasive mussels are also potential controlling factors. d13 \textC\textCaCO 3 \delta^{13} {\text{C}}_{{{\text{CaCO}}_{ 3} }} values show a positive correlation with δ13CTOC between 1909 and 1969, indicating phytoplankton productivity was the primary control for d13 \textC\textCaCO 3 \delta^{13} {\text{C}}_{{{\text{CaCO}}_{ 3} }} values during eutrophication. However, a negative correlation between d13 \textC\textCaCO 3 \delta^{13} {\text{C}}_{{{\text{CaCO}}_{ 3} }} and δ13CTOC from 1970 to 2002 suggests that these two proxies tracked different aspects of the carbon cycle in the lake in more recent times. The cause for the negative correlation is not yet known, but it is perhaps associated with temperature variations and seasonal differences in productivity.  相似文献   

14.
Sediment geochemistry and testate amoebae (thecamoebians) were used to track the spatial extent and temporal evolution of mine loading and its impact on aquatic biota in Lake Pyh?j?rvi, central Finland. Pyh?salmi is an operating Zn-Cu–S mine, located by Lake Pyh?j?rvi. Mine loading to the lake comes mainly from wastewater. Highest metal loading occurred in the 1970s and 1980s. Present loading consists mainly of Ca and S that nearly saturate dense wastewaters with gypsum. This affects oxygen concentration in the lake’s northern basin, where effluent is presently discharged. Of 25 short sediment cores retrieved from Lake Pyh?j?rvi, 10 came from sites ‘downstream’ and 15 from ‘upstream’ of the mine. Three sample levels from each core were selected for further investigation after exploratory XRF metal analysis. Samples were chosen to represent lake conditions before the mine impact, during the peak impact phase, and at present. Results from pre-disturbance deposits show that the two lake basins are naturally different. The ‘downstream’ basin (Junttiselk?) has lower oxygen and a higher sedimentation rate, which was revealed by concentrations of redox-sensitive and clastic-related elements, as well as faunal distributions. The peak mine impact is reflected in the high concentration of S and metals Cu, Zn, Cd, Pb, which spread widely in the lake and increased > 100% at sites near the tailings area. These concentrations have since decreased, but not to pre-disturbance levels. The faunal response to peak metal concentrations was weak, spatially limited and masked by larger responses to other environmental factors, including eutrophication, oxygen concentration, and increased clastic input generated by land-use changes. These environmental factors and changes in mine water composition probably account for the reason that faunal assemblages did not return to the pre-mine situation. Instead, the modern fauna reflects a third assemblage type that developed after the peak-loading phase. Geochemical and thecamoebian analyses show that the mine has affected the two basins of the lake differently during the lake history. Results suggest that mining impacts could be mitigated with good planning and management.  相似文献   

15.
The Ayn Formation of the Neoproterozoic Mirbat Group comprises <400 m of little‐deformed, glacially influenced basin margin deposits. These deposits are preserved in several palaeovalleys eroded in crystalline basement and overlain by a discontinuous cap carbonate. The Ayn Formation and the cap carbonate, which are superbly exposed along a 20 km SW–NE‐striking escarpment in south Oman, provide important insights into the processes operating on a basin margin during a Neoproterozoic glaciation and its demise. The Ayn Formation comprises units of glacimarine rain‐out diamictite and sediment gravity flow deposits, alternated with units of fluvial and deltaic sandstones and conglomerates, which may have formed by proglacial outwash. The stratigraphic evolution of the Ayn Formation indicates a highly active hydrological cycle during a phase of overall (glacio‐eustatic?) low stand when glaciers advanced into and receded upon bedrock valleys. The transgressive cap carbonate was deposited primarily in shallow marine or shallow lacustrine environments over palaeohighs during the deglaciation, and was partly reworked into deeper parts of the basin through sediment gravity flow processes. Locally, the cap carbonate transgresses over crystalline basement containing a network of fissures filled with carbonate originating from the cap. The δ13C isotopic composition of the cap carbonate varies systematically between ?3.5 and +5.8‰ Pee Dee Belemnite standard, in common with other older Cryogenian examples.  相似文献   

16.
The evolution from Late Cretaceous to early Eocene of the well dated Amiran foreland basin in the NW Iranian Zagros Mountains is studied based on the reconstruction of successive thickness, palaeobathymetry and subsidence maps. These maps show the progressive forelandwards migration of the mixed carbonate‐siliciclastic system associated with a decrease in creation of accommodation. Carbonate facies variations across the basin suggest a structural control on the carbonate distribution in the Amiran foreland basin, which has been used as initial constraint to study the control exerted by syndepositional folding in basin architecture and evolution by means of stratigraphic numerical modelling. Modelled results show that shallow bathymetries on top of growing folds enhance carbonate production and basin compartmentalization. As a consequence, coarse clastics become restricted to the internal parts of the basin and only the fine sediments can by‐pass the bathymetric highs generated by folding. Additionally, the development of extensive carbonate platforms on top of the anticlines favours the basinwards migration of the depositional system, which progrades farther with higher fold uplift rates. In this scenario, build‐ups on top of anticlines record its growth and can be used as a dating method. Extrapolation of presented modelling results into the Amiran foreland basin is in agreement with an early folding stage in the SE Lurestan area, between the Khorramabad and Kabir Kuh anticlines. This folding stage would enhance the development of carbonate platforms on top of the anticlines, the south‐westward migration of the system and eventually, the complete filling of the basin north of the Chenareh anticline at the end of the Cuisian. Incremental thickness maps are consistent with a thin (0.4–2 km) ophiolite complex in the source area of the Amiran basin.  相似文献   

17.
福建山地龙眼园土壤镁素状况与龙眼缺镁调控措施   总被引：13，自引：0，他引：13  
李延  刘星辉  庄卫民 《山地学报》2001,19(5):460-464
福建山地龙眼园土壤镁素状况因成土母质不同而异，玄武岩发育的土壤供镁充足，第四纪红壤尤其是花岗岩、凝灰岩发育的土壤供镁水平低或极低，这类土壤是福建山地龙眼园的主要土壤类型，应重视旋用镁肥。土壤活性铝含量高，部分龙眼园土壤K／Mg比值过高，抑制了龙眼镁素吸收，也是造成山地龙眼缺镁的重要原因。龙眼缺镁的调控措施是：施用镁肥（硝酸镁喷施结合土施钙镁磷肥）；合理配施钾肥和镁肥；消除铝毒。  相似文献   

18.
The late Messinian mixed carbonate‐siliciclastic platforms of the Sorbas Basin, known as the Terminal Carbonate Complex, record significant changes in carbonate production and geometry. Their facies and stratigraphic architecture result from complex interactions between base‐level fluctuations, evaporite deformation/dissolution and detrital inputs. A 3D quantitative approach (with DIONISOS software) is used to explore the basin‐scale platform architecture and to quantify the carbonate production of the Terminal Carbonate Complex. The modelling strategy consists in integrating detailed 2D field‐based transects and modern carbonate system parameters (e.g. carbonate production rates, bathymetric and hydrodynamic ranges of production). This approach limits user impact and so provides more objective output results. Tests are carried out on carbonate production rates, subsidence and evaporite deformation/dissolution. Numerical modelling provides accurate predictions of geometries, facies distributions and depositional sequence thicknesses, validated by field data. Comparative statistical testing of the field transects and of the various model outputs are used to discern the relative contribution of the parameters tested to the evolution of basin filling. The 3D visualization and quantification of the main carbonate producers (ooids and microbialites) are discussed in terms of changes in base‐level and detrital supply. This study demonstrates that base‐level fluctuations have the greatest impact on the carbonate budget. Evaporite deformation/dissolution affects the type and amount of carbonate production, inducing a transition from an ooid‐ to microbialite‐dominated system and also has a major effect on stratigraphic architecture by inducing the migration of depocentres. The numerical modelling results obtained using modern carbonate system parameters could also be applied to subsurface ooid‐microbialite reservoirs, and the Terminal Carbonate Complex is a good analogue for such systems.  相似文献   

19.
以镁、铝、锌为主要合金元素的镁铝合金材料是轻合金的基础,评述了镁合金和铝合金的优缺点及应用概况,介绍了Zn、RE、Mn、Cu等主要元素对合金微观组织、铸造性能、力学性能和抗腐蚀性能的影响。随着轻合金综合性能不断提高和改进,其应用前景更加广阔。  相似文献   

20.
This study interprets the recent history of Lake Kivu, a tropical lake in the East African Rift Valley. The current gross sedimentation was characterized from a moored sediment trap array deployed over 2 years. The past net sedimentation was investigated with three short cores from two different basins. Diatom assemblages from cores were interpreted as reflecting changes in mixing depth, surface salinity and nutrient availability. The contemporary sediment trap data indicate seasonal variability, governed by diatom blooms during the annual mixing in the dry season, similar to Lakes Malawi and Tanganyika. The ratio of settling fluxes to net sediment accumulation rates implies mineralization rates of 80–90% at the sediment-water interface. The sediment cores revealed an abrupt change ~40 years ago, when carbonate precipitation started. Since the 1960s, deep-water methane concentrations, nutrient fluxes and soil mineral inputs have increased considerably and diatom assemblages have altered. These modifications probably resulted from a combination of three factors, commonly altering lake systems: the introduction of a non-native fish species, eutrophication, and hydrological changes inducing greater upwelling. Both the fish introduction and increased rainfall occurred at the time when the onset of carbonate precipitation was observed, whereas catchment population growth accompanied by intensified land use increased the flux of soil minerals already since the early twentieth century due to more intense erosion.  相似文献   

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