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1.
选用3种有机溶剂甲醇、乙醇和丙酮作为沉析剂,以淡水浸取的东台吉乃尔盐田钾盐矿所得的富钾卤水为试验原料,进行了有机溶剂沉析结晶分离富钾卤水中钾盐的研究。研究表明3种溶剂均能分离出富钾卤水中的钾盐,其中甲醇的分离效果优于乙醇和丙酮,当甲醇与富钾卤水体积比为1.5∶1时,甲醇分离提取富钾卤水中钾离子的析出率最大为87.38%,同时结晶分离所得钾盐中钾离子的收率高达81.79%。  相似文献   

2.
众所周知,卤水蒸发过程将使某些盐类结晶析出。由于这一蒸发而形成的残存卤水,对原来含于原始卤水中,其含量未达到饱和的那些易溶盐类来说,就会进一步浓缩。同时这样的浓卤水本身就是各种有价值的矿物原料。在制盐业或钾盐工业中,当海水或其他一些卤水蒸发浓缩时得到的卤水,通常称做“苦卤”。这些卤水的特点是含有饱和的盐类,特别是氯化镁,它是最易溶的主  相似文献   

3.
利用潜江凹陷大量井筒及试水资料,研究古盐湖深层卤水赋存方式及成矿规律,开展卤水资源评价,为深层卤水开发利用提供建议。研究表明潜江凹陷潜江组卤水赋存于砂岩孔隙中,纵向上划分为5个卤水组,平面上受砂岩物源影响由北向南矿体厚度逐渐变薄直至尖灭;卤水总矿化度垂向分带平面分异明显,垂向上随着深度增加而增加,平面上凹陷中心矿化度高,向四周逐渐降低;卤水中的钾、锂、硼、溴、碘、铷、铯等元素含量与总矿化度呈正比,平面上与总矿化度规律一致,均呈环带状分布。通过对该区资源量进行测算和评价,得出潜江凹陷潜江组砂岩卤水为中孔、中渗、中产能、中深层、氯化钠型,含锂、溴、硼、钾大型工业卤水矿床;由此提出利用油田钻井和油田伴生卤水采卤并进行综合利用,提取食盐、碘、溴、氨水、氯化钾、硼砂、碳酸锂、氯化铷、氯化铯等产品,具有良好的开发前景。  相似文献   

4.
在生产碳酸锂的工艺中,尤其除硫过程中,锂会伴随其它盐类析出,造成锂的大量夹带损失。因此盐湖高锂卤水中硫酸根的脱除对锂的高效富集,提高锂的收率有重大意义。研究以盐湖高锂卤水为原料,通过加入氯化钡,采用化学沉淀法除去卤水中的SO_4~(2-)。详细考察了原料配比(SO_4~(2-)与Ba~(2+)的摩尔比)、加料方式、加料时间、反应时间、搅拌速度和反应温度等操作条件对除硫率的影响;同时,重点研究了不同操作条件下锂的夹带损失率。结果表明:除硫的适宜条件为,原料配比1.3,并流加料,反应温度25℃,加料时间18 min,搅拌速度250 r/min,反应时间40 min;最终SO_4~(2-)的脱除率可达99.98%,锂的夹带损失率为17.77%。  相似文献   

5.
综述了海水和盐湖卤水低温物理化学性质研究的历史与现状,介绍了相关的矿物鉴定方法,并对冷冻实验在油田卤水开发和利用中的应用前景进行了展望。  相似文献   

6.
柴达木盆地西台吉乃尔盐湖矿区卤水水化学特征   总被引:1,自引:4,他引:1       下载免费PDF全文
西台吉乃尔盐湖位于柴达木盆地中部,矿区卤水中富含锂、钾、硼、镁等多种元素,极具开发价值。自2003年开始,矿区已开始进行大规模采卤,利用前人1959年和2001年两次勘查资料,从水化学角度分析和探讨了西台吉乃尔盐湖矿区未大规模采卤前卤水中各元素的分布规律和变化特征。研究表明,矿区西北部主要为氯化物型卤水,其余大部分地区基本为硫酸镁亚型卤水,我们推测地下卤水水化学类型的差异很可能与不同区域原始卤水的组成及补给水等因素有关。有益组分中,高含量的Li+、K+主要分布在矿区的西北部;B2O3的高含量区主要在矿区的中东部广大地区。赋存于孔隙卤水中K+、Ca2+、Mg2+、Li+、Cl-等元素的平均含量要高于晶间卤水;B2O3、Na+、SO42-等则低于晶间卤水;卤水矿化度、pH值和密度则相差不多。孔隙卤水在Na+、K+、Mg2+/Cl--H2O四元体系介稳相图中的投影点接近光卤石相区;湖表卤水和晶间卤水在Na+、K+、Mg2+/Cl-,SO42--H2O五元体系介稳相图中位于泻利盐、软钾镁矾和钾石盐的共结点附近,且分布比较集中;湖表卤水在演化阶段上存在较大差别;晶间潜卤水已普遍进入钾石盐析出阶段。研究还表明,西台吉乃尔湖湖水的水化学变化明显受季节变化的影响,而湖表卤水与地下卤水存在着一定程度的水力联系,这种联系的强弱和变化特征尚待进一步研究。  相似文献   

7.
选择U含量高的尕斯库勒盐湖卤水样为初始条件,利用PHREEQC软件模拟CO2侵入卤水后对卤水中U的影响。结果表明,CO2侵入卤水后,卤水中U的形态发生明显变化,新增了碳酸盐型的络合物,占总U(6)的12%;U的价态在CO2侵入卤水前后无明显变化,以U(+6价)为主,占总U含量的99%以上;卤水的p H值减小,导致卤水中U可能发生沉淀作用而浓度减小,CO2侵入前后分别为7.24E-07 mol·L-1和5.03E-07mol·L-1。研究对深入评估盐水层CO2地质封存的环境风险提供理论依据。  相似文献   

8.
卤水中钙离子的存在会对盐湖化工生产及其产品质量造成较大影响,研究钙离子在卤水蒸发过程中的分布规律具有重要意义。通过室外自然蒸发及盐田实地采样,研究了察尔汗盐湖盐田生产过程中钙离子分布变化规律。结果表明,在自然蒸发实验中卤水钙离子浓度随蒸发量的增加逐渐减少,在盐田生产现场采样结果显示钙离子浓度随卤水蒸发而增加,结合生产实际,推断外界钙离子补给是造成这种现象的主要原因。因此,避免车间含钙尾水混入,阻止盐田卤水和周边土壤可溶性钙盐间离子交换是有效降低卤水钙离子浓度的主要方法。  相似文献   

9.
<正> 中国科学院化学研究所盐湖组针对大柴旦盐湖卤水提出利用盐田日晒分离一般盐类的基础上,获得富含硼和锂的氯化镁饱和卤水的日晒工艺。大柴旦湖区冬季最低气温可到-30℃,卤水最低温度可达-20℃,夏季日晒过程中得到的氯化镁浓缩卤水在储存越冬期间,需要弄清在冷冻过程中析出盐类固相和相应液  相似文献   

10.
油泉子矿床是一个以卤水钾镁盐矿为主的小型综合性盐类矿床,盐湖卤水水化学类型主要为氯化物型,从KCl等组分含量来看,属高钾高钠低镁的卤水。在柴达木盆地与油泉子条件相类似的盐类矿床中,氯化物型卤水钾的选矿工艺已十分成熟,但对于不同矿区不同组分含量的卤水,其结晶路线各不相同,为此,对油泉子矿床氯化物型卤水进行自然蒸发试验,确定盐类结晶析出顺序和钾矿物的最佳分离点,取得钾矿物的产率和钾石盐中KCl含量等基础数据,并对该类型卤水工业利用性能作出评价。  相似文献   

11.
河北沿海海侵灾害初探   总被引:5,自引:1,他引:4  
文中以包含海进、海岸侵蚀和海水入侵的广义“海侵”概念,论述河北沿海地区海侵现状及其危害,探讨海侵产生的自然原因和人为活动的影响,在此基础上,评估海侵发展趋势。  相似文献   

12.
The land accretion processes of the Yellow River delta, with its quantities of sediment transport, are dominated by drainage basin factors. Since the tidal and the sea wave processes are weak, the delta provides an ideal site to study the response of land accretion to the changing climate and human activities. Firstly, by using sea charts and remote sensing images, the annual land accretion area has been identified and is related to annual precipitation and human activities in the drainage basin. It is found that the rate of land accretion of the delta is positively correlated with precipitation, but negatively correlated with the areas of erosion control measures and with the quantity of water diversion. Secondly, a multiple regression equation has been established between the rate of land accretion of the delta and the influencing factors: the area of terrace land building and tree‐ and grass‐planting, the area of the land created by the sediment trapped by check dams, the annual precipitation and the annual quantity of water diversion. The regression indicates that the changing precipitation contributes most to the land accretion rate of the delta, the contribution made by erosion control measures ranks the second, and the contribution made by water division the third.  相似文献   

13.
Classic sequence stratigraphy suggests depositional sequences can form due to changes in accommodation and due to changes in sediment supply. Accommodation‐dominated sequences are problematic to define rigorously, but are commonly interpreted from outcrop and subsurface data. In contrast, supply‐dominated sequences are much less commonly identified. We employ numerical stratigraphic forward modelling to compare stratal geometries forced by cyclic changes in relative sea level with stratal geometries forced by sediment discharge and water discharge changes. Our quantitative results suggest that both relative sea‐level oscillations and variations in sediment/water discharge ratio are able to form sequence‐bounding unconformities independently, confirming previous qualitative sequences definitions. In some of the experiments, the two types of sequence share several characteristics, such as an absence of coastal‐plain topset deposits and stratal offlap, something typically interpreted as the result of falling relative sea level. However, the stratal geometries differ when variations in amplitude and frequency of relative sea‐level change, sediment/water discharge ratio, transport diffusion coefficient and initial bathymetry are applied. We propose that the supply‐dominated sequences could be recognised in outcrop or in the subsurface if the observations of stratal offlap and the absence of coastal‐plain topset can be made without any strong evidence of relative sea‐level fall (e.g. descending shoreline trajectory). These quantitative results suggest that both supply‐dominated and accommodation‐dominated sequences are likely to occur in the ancient record, as a consequence of multiple, possibly complex, controls.  相似文献   

14.
1998年 1 2月 1 1日至 1 999年 1月 1 3日在中山站近岸海域进行了一次较为全面的生态环境监测 ,监测内容包括∶ p H、T、盐度 (电导率 )、浊度、DO、COD、营养盐 (NO3 - N、NO2 - N、NH4 -N和 PO4 - P)和叶绿素 ,部分监测站位海水样品分层采集 ;其间还进行两次中山站区排污口生活污水连续 2 4小时监测。结果表明 ,冰缝间以及海冰底层下 1 m内的海水为各种环境理化因子的急剧变化层 ,大于冰底 1 m深的海水中的各要素变化梯度趋于平稳 ,营养盐垂直分布具有一定规律。p H和 DO为一类海水水质 ,无机氮属一、二类水质 ,无机磷属超三类水质 ,表层海水中叶绿素 a的平均值为 0 .6 71 mg/m3。中山站排放的生活污水中 COD、p H和悬浮物均符合我国的废污水排放标准 ,仅无机磷超一级排放标准。文中还探讨了在中山站近岸海域开展生态环境监测的监测方法  相似文献   

15.
《Polar Science》2014,8(3):306-313
Atmospheric dimethylsulfide (DMS) was measured to investigate the variation in its concentration over sea ice free oceans and sea ice regions of the Southern Ocean, using a proton transfer reaction-mass spectrometer (PTR-MS) on board the icebreaker Shirase from 1 December 2009 to 16 March 2010. In general, DMS concentrations over sea ice regions were very low compared with those over the sea ice free ocean. However, abrupt increases in DMS concentrations occurred over sea ice regions while the ship was moving and crushing the sea ice. Undoubtedly, the elevated DMS concentrations were caused by large DMS emissions from gaps in the ice made by the ship. During the period when Shirase had anchored off Syowa Station (69°00.4′S, 39°35.3′E), Antarctica, DMS concentrations were not detected. At this time, the surrounding sea of East Ongul island, on which Syowa Station is located, was completely covered with multi-year fast ice. Sea ice probably inhibits DMS emission from the ocean to the atmosphere. In addition, there was no evidence that chlorophyll a concentration in the sea water or wind speed above the sea surface affect atmospheric DMS concentrations over the sea ice free ocean regions.  相似文献   

16.
夏季西北冰洋表层淡水分布的总碱度示踪研究   总被引:1,自引:0,他引:1       下载免费PDF全文
高众勇  孙恒  陈立奇  张凡 《极地研究》2012,24(2):120-128
利用中国第三次北极科学考察在西北冰洋所进行的海水总碱度的测量,通过海水、海冰融化水以及河源淡水三个端元总碱度特征的显著差异计算西北冰洋夏季表层海水中淡水所占的比例。研究表明,西北冰洋海冰融化水所占比例最大区域在加拿大海盆区75°N附近,这是冰缘带位置,往北向高纬度的冰密集中逐渐增加。而河源淡水的组份则与北冰洋的环流密切相关,并且在西北冰洋水体中逐渐累积。  相似文献   

17.
A numerical model of flow over sand waves in water of finite depth   总被引:1,自引:0,他引:1  
Summary. A model of turbulent flow above sand waves in water of finite depth is described. Closure assumptions are based on an eddy viscosity proportional to the square root of the local value of turbulent kinetic energy and mixing length dependent upon distance from the lower boundary. Results are presented for some idealized cases to investigate the effects of wave slope, water depth, Froude number and wave shape. The implications of the model for the transport of sediment are discussed and the development of the wave investigated. It is found that the crest of the wave will become sharper for lower flow rates, as has been observed in the sea. Comparisons are made with recent measurements made over sand waves in the Columbia River.  相似文献   

18.
In this paper, the spreading way in the southern hemisphere that anomalous warm water piled in tropical eastern Pacific is analysed and then impact of El Nino on the variability of the Antarctic sea ice extent is investigated by using a dataset from 1970 to 2002. The analysis result show that in El Nino event the anomalous warm water piled in tropical eastern Pacific is poleward propagation yet the westward propagation along southern equator current hasn't been discovered . The poleward propagation time of the anomalous warm water is about 1 year or so. El Nino event has a close relationship with the sea ice extent in the Amundsen sea , Bellingshausen sea and Antarctic peninsula .After El Nino appears , there is a lag of two years that the sea ice in the Amundsen sea , Bellingshausea sea, especially in the Antarctic peninsula decreases obviously. The processes that El Nino has influence with Antarctic sea ice extent is the warm water piled in tropical eastern Pacific poleward propagation along off the coast of southern America and cause the anomalous temperature raise in near pole and then lead the sea ice in Amundsen sea , Bellingshausen sea and Antarctic peninsula to decrease where the obvious decrease of the sea ice since 80' decade has close relation to the frequently appearance of El Nino .  相似文献   

19.
It is shown that the melting of ice floating on the ocean will introduce a volume of water about 2.6 per cent greater than that of the originally displaced sea water. The melting of floating ice in a global warming will cause the ocean to rise. If all the extant sea ice and floating shelf ice melted, the global sea level would rise about 4 cm. The sliding of grounded ice into the sea, however, produces a mean water level rise in two parts ; some of the rise is delayed. The first part, while the ice floats, is equal to the volume of displaced sea water. The second part, equal to 2.6 per cent of the first, is contributed as it melts. These effects result from the difference in volume of equal weights of fresh and salt water. This component of sea rise is apparently unrecognized in the literature to date, although it can be interpreted as a form of halosteric sea level change by regarding the displaced salt water and the meltwater (even before melting) as a unit. Although salinity changes are known to affect sea level, all existing analyses omit our calculated volume change. We present a protocol that can be used to calculate global sea level rise on the basis of the addition of meltwater from grounded and floating ice; of course thermosteric volume change must be added.  相似文献   

20.
贝壳堤的形成与风暴沉积——以广东台山长湾贝壳堤为例   总被引:3,自引:0,他引:3  
王为  谭惠忠 《热带地理》2003,23(3):209-213
台山市西南部沿海有一条由典型风暴潮沉积堆积形成,出露高度远高于现代风暴潮增水面的贝壳堤.根据贝壳堤出露的横向与纵向剖面以及横剖面上的3个钻孔的形成年代、沉积特征的分析表明风暴潮在贝壳堤发育过程中的不同阶段具有不同的侵蚀与堆积作用;贝壳堤风暴沉积也具有丘状层理、切割充填结构等典型的风暴沉积特征,但贝壳堤风暴沉积与浅海陆架上的风暴沉积在沉积过程、堆积层位、保存条件等方面具有明显的差异.长湾贝壳堤是由多次风暴加积而成,形成贝壳堤的风暴增水高度接近或高于历史最高记录.形成贝壳堤的风暴沉积堆积于平均海面之上,所以增  相似文献   

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