首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
Marine dissolved organic matter(DOM) is one of the largest dynamic pools of organic carbon in the global carbon cycle, yet DOM is still chemically poorly characterized. To better understand the origin, composition, and cycling of DOM in the China marginal sea, dissolved humic substances(DHS) were isolated from seawaters in two locations in the Southern Yellow Sea. The DHS were subdivided into fulvic acids(FAs), humic acids(HAs) and the XAD-4 fractions. Complementary analytical approaches were used to characterize the isolated DHS samples including stable carbon isotopic composition, Fourier transform infrared spectroscopy(FTIR), ~(13) C cross polarization magic angle spinning(CP/MAS) nuclear magnetic resonance(NMR), and pyrolysis gas chromatography-mass spectrometry(Py-GC/MS). The results demonstrated that both DHS samples encountered the influences from marine source, indicating that algal and microbial-derived materials are the predominant precursors for the studied samples. The three fractions of DHS showed diff erent properties. FAs presented more aromatic features, whereas HAs contained more aliphatic lipids and proteinaceous materials. The XAD-4 fractions were enriched in ~(13) C and contained more carbohydrates but less aromatic compounds. The lower molecular weight and higher heteroatom content and number of carboxyl groups for the XAD-4 fractions may give them considerable geochemical significance for aspects of trace metal species, bioavailability of pollutants, mineral weathering and water acidification in marine environments.  相似文献   

2.
Biologically utilizable dissolved organic compounds, including dissolved organic carbon (DOC), dissolved carbohydrates (DCHO) and dissolved free amino acids (DFAA) were analyzed in filtered surface seawater samples collected at 19 stations in Jiaozhou Bay, China, on June 3, 2007. In these samples, concentrations of DOC, dissolved free carbohydrates (DFCHO), dissolved combined carbohydrates (DCCHO), total dissolved carbohydrates (TDCHO) and total dissolved free amino acids (TDFAA) ranged from 141.7 to 191.1 μmol C/L, 1.98 to 18.18 μmol C/L, 5.04 to 24.90 μmol C/L, 14.52 to 30.36 μmol C/L, and 1.83 to 11.89 μmol C/L, respectively. As a major component of the dissolved carbohydrates, the concentrations of DCCHO were about three times higher than those of DFCHO. Three major constituents of the DFAA were threonine (23.0±5.7 mol%), glutamic acid (16.6±3.2 mol%) and arginine (9.1±3.3 mol%). Based on the composition of DFAA, a molar C:N ratio of 3.60±0.75 in DFAA was derived, indicating longer carbon chains in the amino acids. DCCHO (8.1%) was the most abundant fraction of DOM in most samples, followed by DFCHO (4.8%) and TDFAA (2.7%). These DOM concentrations displayed a decreasing trend from the coast to the central region. Significant correlations were found between the DCCHO and DFCHO concentrations (r=-0.724, n=19, P<0.001) and the DCCHO and TDCHO concentrations (r=0.506, n=19, P=0.027).  相似文献   

3.
The investigation shows that the concentrations of nutrients are high in estuarine and coastal waters and low in offshore waters. The concentration of nitrate in estuaries is controlled through a physical mixing process and is also affected by biotic activity. The annual transport of total inorganic nitrogen and dissolved phosphate-phosphorus from the Huanghe River water to the sea is about 8.45 ×104 and 1.45×103 tons respectively. The distributions of inorganic nitrogen and silicate in interstitial water of surface sediments are similar to those in surface and bottom seawater. Their contents in interstitial water are 227–552 μmol/l (average375) for ammonia, 0.31–9.0 μmol/l (average 1.6) for nitrite, 0–41 μmol/l (average6.0) for nitrate, and 41–139 μmol/l (average 77) for silicate. The average concentrations of phosphate in the surveyed area are 0.64 μmol/l for seawater and 1.2 μmol/l for interstitial water. A cycle of phosphate in the estuary is also suggested in this paper. Contribution No. 1434 from Institute of Oceanology, Academia Sinica.  相似文献   

4.
Jellyfish blooms have increased worldwide,and the outbreaks of jellyfish population not only affect the food web structures via voracious predation but also play an important role in the dynamics of nutrients and oxygen in planktonic food webs.However,it remains unclear whether specific carbon compounds released through j ellyfish metabolic processes have the potential to shape bacterial community composition.Therefore,in this study,we aimed to investigate the compositional succession of the bacterioplankton community in response to the dissolved organic matter(DOM)released by the live Scyphomedusae Cyanea lamarcki'i and Chrysaora hysoscella collected from Helgoland Roads of the North Sea.The bacterial community was significantly stimulated by the DOM released form live jellyfish and different dominant phylotypes were observed for these two Scyphomedusae species.Furthermore,the bacterial community structures in the different DOM sources,jellyfish-incubated media,Kabeltonne seawater,and artificial seawater(DOM-free)were significantly different,as revealed by automated ribosomal intergenic spacer analy sis fingerprints.Catalyzed reporter depo sition fluorescence in situ hybridization(CARD-FISH)revealed a rapid species-specific shift in bacterial community composition.Gammaproteobacteria dominated the community instead of the Bacteroidetes community for C.lamarckii,whereas Gammaproteobacteria and Bacteroidetes dominated the community for C.hysoscella.The significant differences in the bacterial community composition and succession indicate that the components of the DOM released by jellyfish might differ with jellyfish species.  相似文献   

5.
The finfish and shellfish resources were assessed quantitatively and qualitatively in regard to their abundance in creek waters at three sites within a period of two years, from January 1999 to December 2000, in the western mangrove areas of Kachchh. The catch rate varied from 0.69 to 6.99 kg h−1. It was low during monsoon (July to October), which could be due to the freshwater-flow-induced salinity reduction in all the sites. Among 38 species recorded, 5 were shellfish and 33 were finfish. The spawning period of fishes was found to be during summer and early monsoon period (May to August). Surface water temperatures varied from 17 °C to 37 °C. Salinity values varied from 34 to 44 and the pH ranged between 7 and 8.9. Variation in dissolved oxygen content was from 3.42 to 5.85 mL L−1. The high fishery densities in these semi arid mangrove creek areas were recorded during monsoon and early winter season.  相似文献   

6.
Filtration and cross-flow ultrafiltration techniques were used to separate culture media of Prorocentrum donghaiense at the exponential growth,stationary and decline stages into <0.45 μm filtrate,100 kDa-0.45 μm,10-100 kDa and 1-10 kDa retentate and <1 kDa ultrafiltrate fractions.The fluorescence properties of different molecular weights of dissolved organic matter(DOM) were measured by excitation-emission matrix spectra.Protein-like and humic-like fluorophores were observed in the DOM produced by P.donghai...  相似文献   

7.
采用五态连续提取法(SEP)对雷州半岛高桥红树林群落内外不同深度的沉积物砷含量进行测定.结果表明,高桥红树林湿地0~60cm深处沉积物中除Al-结合态砷和Ca-结合态砷含量低,难以检出外,交换态砷、残渣态砷、Fe-结合态砷皆可检出,沉积物砷积累以残渣态砷和 Fe-结合态砷为主,总砷测定含量为7.34±0.39~10.32±0.48 mg/kg,其中以20~40cm深处沉积物总砷测含量最多;不同深度沉积物砷含量中林内与林区外裸滩呈现不同的分布规律,林外裸滩-林缘-林内的表土总砷含量的分布呈波浪式分布,以林缘为最高,总砷达9.97±1.29 mg/kg,林内显著大于林外裸滩(p值<0.05),林内沉积物对砷的吸附强度较林外裸滩高  相似文献   

8.
INTRODUCTIONMarinehedsresultinginenomouslossestousuallyPOpulousandeconondcallyde-veloPedlowandcoastalandestUdrineregi0nsareforngseriousattenti0n.msarticlediscussesP0ssiblepreventivemeasaresagainstInariflehazaIdsbasedonacasestUdyoftheestUedesoftheChanaiiangffiverandQiantanffiver-ThesetwoareasoftheChanaiiangDeltaareboicalofc0astalregionsfreqUenilysufferingfromdrinehazanls,andarethemostsociallyandeconondcallydeveloPedregionsinChina.Theirinhabitantshaveahist0-ryofmorethanathouSandyeare0…  相似文献   

9.
China's eastern coastal area marine hazards (storm surge, erosion and deposition by tidal currents and seawater intrusion) and the history, present situation, experiences and problems of inhabitants in their fight against marine hazards are discussed in this paper, which also suggests counter-measures against, and scientific and rational management of, coastal area marine hazards in order to protect the coastal and estuarine ecosystems.  相似文献   

10.
Niu  Jiaohong  Sun  Chengjun  Yang  Bo  Xie  Lei  Jiang  Fenghua  Cao  Wei  Chen  Yan  Ding  Haibing  Huang  Yuhuan  Gao  Xianchi 《中国海洋湖沼学报》2023,41(1):118-137

The composition and concentration of dissolved free amino acid (DFAA) of seawater samples collected in May 2016 from the surface to the hadal zone of the northern region of the Yap Trench were analyzed by pre-column derivatization of o-phthalaldehyde. Results show that the average concentration of DFAA in the study area was 0.47±0.36 µmol/L. In different sampling stations, the concentrations of DFAA with water depth showed complex variation patterns. At the sediment-seawater interface, the concentrations of DFAA in the western side of the trench were obviously higher than that in its eastern side. In the study area, there were no significant correlations between the concentrations of DFAA and the environmental parameters such as concentrations of chlorophyll a (Chl a), dissolved oxygen (DO), pH, and dissolved inorganic nitrogen (DIN), indicating that the concentrations of DFAA in seawater of the trench are affected by many factors, such as photosynthesis, respiration, temperature, pressure, illumination, and circulation. The dominant DFAA are similar in different water layers of sampling stations, including aspartic acid (Asp), glutamic acid (Glu), glycine (Gly), and serine (Ser). The composition of different amino acids, and the relative abundance of acidic, basic, and neutral amino acids might be related to the sources and consumption of various amino acids. Nine pairs of amino acids in the DFAA showed significantly positive relationship by correlation matrix analysis, suggesting that they might share similar biogeochemical processes. The degradation index (DI) of the DFAA in seawater of the Yap Trench could reflect the degradation, source, and freshness of DFAA in the trench to some extents. This is a preliminary study of amino acids from sea surface to hadal zone in the ocean, more works shall be done in different trenches to reveal their biogeochemical characteristics in extreme marine environments.

  相似文献   

11.
This paper reports the approprite ranges of Mg^2 ,Ca^2 and their ratio Mg^2 /Ca^2 in mixed seawater for rearing of Penaeus japonicus larvae,The ranges for the above three indices are 1150-1450mg/L,360-440mg/L and 2.8-3.4,respectively,the proper salinity range of mixed seawater is 22.1-33.9 obtained by mixing estuarine water and concentrated seawater.  相似文献   

12.
Guo  Chaonan  Sun  Chengjun  Yang  Guipeng  Zhang  Honghai  Chen  Yan  Yin  Xiaofei  Jiang  Fenghua  Huang  Yuhuan  Niu  Jiaohong  Ding  Haibing 《中国海洋湖沼学报》2020,38(3):606-618
Journal of Oceanology and Limnology - The concentrations of dissolved monosaccharides (MCHO), polysaccharides (PCHO), and total carbohydrates (TCHO) in the seawater samples collected from the north...  相似文献   

13.
Alpine grassland soils on Qinghai-Tibet Plateau store approximately 33.5 Pg of organic carbon(C) at 0–0.75 m depth and play an important role in the global carbon cycle.We investigated soil organic C(SOC),water-soluble organic C(WSOC),easily oxidizable organic C(EOC),humic C fractions,aggregate-associated C,aggregate stability,and humic acid(HA) composition along an east-west transect across Qinghai-Tibet Plateau,and explored their spatial patterns and controlling factors.The contents of SOC,WSOC,EOC,humic C fractions and aggregate-associated C,the proportions of macroaggregates(2-0.25) and micro-aggregates(0.25-0.053 mm),and the aggregate stability indices all increased in the order alpine desert alpine steppe alpine meadow.The alkyl C,O-alkyl C,and aliphatic C/aromatic C ratio of HA increased as alpine desert alpine meadow alpine steppe,and the trends were reverse for the aromatic C and HB/HI ratio.Mean annual precipitation and aboveground biomass weresignificantly correlated with the contents of SOC and its fractions,the proportions of macro- and microaggregates,and the aggregate stability indices along this transect.Among all these C fractions,SOC content and aggregate stability were more closely associated with humic C and silt and clay sized C in comparison with WSOC,EOC,and macro- and microaggregate C.The results suggested that alpine meadow soils containing higher SOC exhibited high soil aggregation and aggregate stability.Mean annual precipitation should be the main climate factor controlling the spatial patterns of SOC,soil aggregation,and aggregate stability in this region.The resistant and stable C fractions rather than labile C fractions are the major determinant of SOC stocks and aggregate stability.  相似文献   

14.
Mangroves accumulate sedimentary sequences, where cores can provide historical records of mangrove evolution with past climate change and human activity. The study traced the history of mangrove evolution during the past one hundred years in a mangrove swamp of Maowei Sea, SW China. The sedimentation rates(0.38-0.95 cm yr~(-1)) were calculated on the basis of ln(~(210)Pb_(xs)/Al) and mass depth in the core sediments. Chemical tracers, such as δ~(13)C_(org) and C:N values, were utilized to trace the contribution of mangrove-derived organic matter using a ternary mixing model. Because of potential diagenetic alteration and / or overlap in the isotopic signatures of different components, simultaneous use of mangrove pollen diagrams can help to supplement some of these limitations. Combined with mangrove pollen, mangrove evolution was reconstructed and could be divided into three stages: flourishment(1886-1905 AD), slight degradation(1905-1949 AD) and rapid degradation period(1949-2007 AD), which was consistent with previous reports. The reclamation of mangrove swamps to shrimp ponds was the major reason for rapid degradation of mangrove ecosystems in recent years, rather than climate change in the region.  相似文献   

15.
Photochemical oxidation of benzothiophene in seawater   总被引：3，自引：0，他引：3  
ＩＮＴＲＯＤＵＣＴＩＯＮｐｈｏｔｏｃｈｅｍｉｃａｌｏｘｉｄａｔｉｏｎｏｆｂｅｎｚｏｔｈｉｏｐｈｅｎｅｉｎｓｅａｗａｔｅｒｉｎｏｒｄｅｒｔｏｌｅａｒｎｍｏｒｅａｂｏｕｔｔｈｅｒｅｍｏｖａｌｐａｔｔｅｒｎｏｆｔｈｉｓｐｏｌｌｕｔａｎｔｉｎｍａｒｉｎｅｅｎｖｉｒｏｎｍｅｎｔｓ.Ｂｅｎｚｏｔｈｉｏｐｈｅｎｅｗａｓｃｈｏｓｅｎｆｏｒｔｈｉｓｓｔｕｄｙｓｉｎｃｅｉｔｉｓｔｈｅｓｉｍｐｌｅｓｔ　　Ｔｈｅｈｉｇｈ -ｐｒｅｓｓｕｒｅｍｅｒｃｕｒｙｌａｍｐｕｓｅｄｉｎｔｈｉｓｓｔｕｄｙｃｏｕｌｄｐｒｏｄｕｃｅｌｉｇ…  相似文献   

16.
Coastal lagoons with small catchment basins are highly sensitive to natural processes and anthropogenic activities. To figure out the environmental changes of a coastal lagoon and its contribution to carbon burial, two sediment cores were collected in Xincun Lagoon, southeastern Hainan Island and (210) ~Pb activities, grain size parameters, total organic carbon(TOC), total nitrogen(TN), total inorganic carbon(TIC) and stable carbon isotopes(δ~(13)C) were measured. The results show that in 1770–1815, the decreasing water exchange capacity with outer open water, probably caused by the shifting and narrowing of the tidal inlet, not only diminished the currents and fined the sediments in the lagoon, but also reduced the organic matter of marine sources. From 1815 to 1950, the sedimentary environment of Xincun Lagoon was frequently influenced by storm events. These extreme events resulted in the high fluctuation of sediment grain size and sorting, as well as the great variation in contributions of terrestrial(higher plants, soils) and marine sources(phytoplankton, algae, seagrass). The extremely high content of TIC, compared to TOC before 1950 could be attributed to the large-scale coverage of coral reefs. However, with the boost of seawater aquaculture activities after 1970, the health growth of coral species was severely threatened, and corresponding production and inorganic carbon burial flux reduced. The apparent enhanced inorganic carbon burial rate after 1990 might result from the concomitant carbonate debris produced by seawater aquaculture. This result is important for local government long-term coastal management and environmental planning.  相似文献   

17.
This study on the sectional and vertical distribution of dissolved oxygen (DO) and the O2 fluxes across the sea-air interface in East China Sea (ESC) waters shows that the waters were in steady state and that the difference of DO was great in upper and bottom waters in Apr. 1994; but that seawater mixing was strong and the difference of DO was small in upper and bottom waters in Oct. 1994. The above conclusions were specially obvious in continental shelf waters under 100 m. The DO maximum in subsurface layer waters appeared only at several stations and in general the DO in the waters decreased with depth. The horizontal distributions of O2 fluxes across the sea-air interface appeared in stripes in Leg 9404 when most regions covered were supersaturated with O2 seawater to air flux was large, and that on section No. 1 was 1.594 L/m2·d. The horizontal distribution of O2 fluxes across the sea-air interface appeared lumpy in Leg 9410, when most regions covered were unsaturated with O2·O2 was dissolved from air to seawater, and the fluxes were 0.819 L/m2·d on section No. 1 in Leg 9310, 0.219 L/m2·d in Leg 9410. The main reasons for DO change in surface layer seawater were the mixture of upper and bottom layer water, and the exchange of O2 across the sea-air interface. The variation of DO by biological activity was only 20% of total change of DO. Contribution No. 2716 from Institute of Oceanology, Chinese Academy of Sciences.  相似文献   

18.
Based on plant specimen data, sediment samples, photos, and sketches from 45 coastal crosssections, and materials from two recent countrywide comprehensive investigations on Chinese coasts and islands, this paper deals with China’s vegetative tidal-flats: salt marshes and mangrove swamps. There are now 141700 acres of salt marshes and 51000 acres of mangrove swamps which together cover about 30% of the mud-coast area of the country and distribute between 18°N (Southern Hainan Island) and 41 °N (Liaodong Bay). Over the past 45 years, about 1750000 acres of salt marshes and 49400 acres of mangrove swamps have been reclaimed. The 2.0×109 tons of fine sediments input by rivers into the Chinese seas form extensive tidal flats, the soil basis of coastal helophytes. Different climates result in the diversity of vegetation. The 3∼8 m tidal range favors intertidal zone development. Of over 20 plant species in the salt marshes, nativeSuaeda salsa, Phragmites australis, Aeluropus littoralis, Zoysia maerostachys, Imperata cylindrica and introducedSpartina anglica are the most extensive in distribution. Of the 41 mangrove swamps species,Kandelia candel, Bruguiera gymnorrhiza, Excoecaria agallocha andAvicennia marina are much wider in latitudinal distribution than the others. Developing stages of marshes originally relevant to the evolution of tidal flats are given out. The roles of pioneer plants in decreasing flood water energy and increasing accretion rate in the Changjiang River delta are discussed. The project was supported by the NSFC (No. 49476281).  相似文献   

19.
To realize potential cost savings in coastal monitoring programs and provide timely advice for marine management, there is an urgent need for efficient evaluation tools based on easily measured variables for the rapid and timely assessment of estuarine and offshore eutrophication. In this study, using parallel factor analysis(PARAFAC), principal component analysis(PCA), and discriminant function analysis(DFA) with the trophic index(TRIX) for reference, we developed an approach for rapidly assessing the eutrophication status of coastal waters using easy-to-measure parameters, including chromophoric dissolved organic matter(CDOM), fluorescence excitation–emission matrices, CDOM UV-Vis absorbance, and other water-quality parameters(turbidity, chlorophyll a, and dissolved oxygen). First, we decomposed CDOM excitation-emission matrices(EEMs) by PARAFAC to identify three components. Then, we applied PCA to simplify the complexity of the relationships between the water-quality parameters. Finally, we used the PCA score values as independent variables in DFA to develop a eutrophication assessment model. The developed model yielded classification accuracy rates of 97.1%, 80.5%, 90.3%, and 89.1% for good, moderate, and poor water qualities, and for the overall data sets, respectively. Our results suggest that these easy-to-measure parameters could be used to develop a simple approach for rapid in-situ assessment and monitoring of the eutrophication of estuarine and offshore areas.  相似文献   

20.
In this study, seawater was pumped up from 150, 200, 300, 500 and 1000 m in the South China Sea and analyzed to make certain what depth should deep-sea water (DSW) be pumped up for medicinal usage. The pumping depth of DSW was determined on the basis of chemical ingredients. The analyses of inorganic elements and dissolved organic matter (DOM) were performed by inductively coupled plasma mass spectrometry (ICP-MS) and ultra performance liquid chromatography-mass spectrometry (UPLC-MS) respectively. The raw data were used for hierarchical cluster analysis (HCA) and principal component analysis (PCA). The results showed that seawater pumped up from 500 m and 1000 m was similar in their chemical ingredients, and was different from the seawater pumped up from other depths. These results indicated that seawater from more than 500 m depth had relatively stable chemical ingredients and could be used as DSW in the South China Sea.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号