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1.
Hydrothermal barite is a typical low-temperature mineral formed during the mixing of hydrothermal fluid and seawater. Because of its extremely low solubility, barite behaves as a close system after crystallization and preserves the geochemical fingerprint of hydrothermal fluid. In this study, the elemental contents and Sr isotope compositions of hydrothermal barites from the Yonaguni IV were determined using electron microprobe and LA-MC-ICP-MS respectively. On these bases, the fluid/sediment interaction during the hydrothermal circulation and physicochemical condition of barite crystallization were discussed. Results show that the 87 Sr/86 Sr values of hydrothermal barites from the Yonaguni IV are apparently higher than those of the seawater and associated volcanic rocks, indicating the sufficient interaction between the hydrothermal fluid and overlying sediment. Monomineral Sr abundance shows large variations, reflecting the changes in barite growth rate during the fluid mixing. The mineralization condition in the Yonaguni IV was unstable. During the crystallization of barite, hydrothermal fluid and seawater mixed in varying degrees, with the pro-portions of hydrothermal fluid varied from 36% to 72%. The calculated crystallization temperatures range from 109 to 220℃. Sediment plays a critical role during the mineralization process in the Yonaguni IV and incorporation of sediment component into hydrothermal system was prior to barite crystallization and sulfide mineralization.  相似文献   

2.
Hydrothermal barite is a typical low-temperature mineral formed during the mixing of hydrothermal fluid and seawater.Because of its extremely low solubility,barite behaves as a close system after crystallization and preserves the geochemical fingerprint of hydrothermal fluid.In this study,the elemental contents and Sr isotope compositions of hydrothermal barites from the Yonaguni IV were determined using electron microprobe and LA-MC-ICP-MS respectively.On these bases,the fluid/sediment interaction during the hydrothermal circulation and physicochemical condition of barite crystallization were discussed.Results show that the 87 Sr/86 Sr values of hydrothermal barites from the Yonaguni IV are apparently higher than those of the seawater and associated volcanic rocks,indicating the sufficient interaction between the hydrothermal fluid and overlying sediment.Monomineral Sr abundance shows large variations,reflecting the changes in barite growth rate during the fluid mixing.The mineralization condition in the Yonaguni IV was unstable.During the crystallization of barite,hydrothermal fluid and seawater mixed in varying degrees,with the pro-portions of hydrothermal fluid varied from 36%to 72%.The calculated crystallization temperatures range from 109 to 220℃.Sediment plays a critical role during the mineralization process in the Yonaguni IV and incorporation of sediment component into hydrothermal system was prior to barite crystallization and sulfide mineralization.  相似文献   

3.
the Sishanlinchang gold-silver deposit is mainly composed of gold-quartz vein type ores.It has many kinds of sulfides and gold in high grade.The Au has a close correlation with As,Pb,Ag and Cu.Geochemically,the deposit is characterized by relatively enrichment in LREE with moderate or lower Eu negative anomaly.Sulfur isotopes appear as single and deep source,and lead isotopes indicate the Pb is from the earth’s mantle and crust,which mainly are orogenic belt Pb,the ore-forming fluid has a temperature of 215℃-350℃ and a low salinity with a mixture of characteristics of magmaitc hydrothermal and meteoric water.The ore-forming age is 111.1-111.4 Ma.The deposit is formed in mineralization and precipitation of metallogenic materials caused by the mixture of the magmatic hydrothermal fluid and meteoric water.  相似文献   

4.
This article presents the evidence in support of the direct magma degassing as the principal mechanism of volatiles releasing into the hydrothermal fluids in the Okinawa Trough, as contrastcd to the argument for the hydrothermal stripping of volatiles from the volcanic rocks. Laser Raman microprobe and stepped-heating techniques arc employed to determine the compositions and contents of the volatiles in pumices in the middle Okinawa Trough. The results show that the volatiles are similar to the gases in the hydrothermal fluid,s and hydrothermal minerals in composition, the mean percent content of each component and variation trend. This indicates the direct influence of magma degassing on the hydrothermal fluids. In addition, the contents of volatiles in pumices are rather low and do not support the hydrothermal stripping as the main mechanism to enrich the fluids with gases. The results are consistent with the idea that the direct magma degassing is more important than hydrothermal stripping in supplying gases to the hydrothermal fluids in the Okinawa Trough.  相似文献   

5.
Distribution of suspended matter in seawater in the Southern Yellow Sea is investigated in five regions: 1) the Northern Jiangsu bank, the highest TSM (total suspended matter) content region; 2) the high TSM content region off the Changjiang River mouth; 3) the high TSM content region off the Chengshan Cape; 4) the low TSM region off Haizhou Bay; 5) the central part of the Southern Yellow Sea, a low TSM content region. The vertical distribution of TSM is mainly characterized by a spring layer of suspended matter, written as "suspended-cline" whose genesis is related to storms in winter. In this paper, non-combustible components and grain sizes in suspended matter, relationship between suspended matter and bottom sediments, and salinity in seawater are described. Investigation result shows that, in this area, suspended matter comes mainly from resuspended bottom sediment and secondarily from present discharged loads from rivers and biogenic materials. Discharged sediments from the Huanghe River move arou  相似文献   

6.
Deep ice drilling in Polar Regions plays a key role in paleo-climate, microbiological and glaciological researches. For deep ice and subglacial coring the special purpose-built electromechanical cable-suspended drills with bottom-hole circulation are designed and explored. Used at present drilling fluid circulation systems are specified by very high fluid wastes during processing. Measurements in deep drilling projects in Antarctic and Greenland ice sheets showed that 25%-40% of the drilling fluid, pumped into the hole, is retrieved to the surface with cable and drill, and up to 45% of retrieved fluid goes to waste. This leads not only to increasing of the fluid consumption and cost of the project in general but also to severe contamination of air, surface and near-surface snow-firn layers at the drilling site. In order to reduce wastes and environmental impact, it is proposed to modify drilling fluid processing system by avoiding of evaporation and leakages of fluid as far as practicable. Drilling fluid is prepared and pumped into the hole according to predetermined program on semiautomatic mode, and volume and density of blended and pumped into the hole drilling fluid are measured continuously. Components of the drilling fluid are stored and mixed in the special closed containers equipped by pressure relief valves. Separation of drilling fluid from ice cuttings is carried out by two steps: firstly, fluid is separated with hydro extractor and then with thermal separator. To reduce the amount of removed drilling fluid with cable special squeezing collar is installed on the borehole mouth. All these arrangements are able to decrease drilling fluid wastes in many times.  相似文献   

7.
Qingchengzi ore concentration area in Liao-Ji rift is an important lead-zinc ore area of China,and the deep prospecting in this area has great prospects.Based on the spatial occurrence of ore bodies the Pb-Zn deposit can be divided into three types:layered,vein-shaped and pinnate.The deep geological conditions in this area are deduced by analyzing the tectonic evolution process and rock mass gravity inversion.The tectonic evolution of Liao-Ji rift can be divided into three stages:Paleoproterozoic extension period,Mesoproterozoic compression period and Mesozoic reactivation period.The magmatic activities in the Indosinian epoch led to the distribution pattern of the present deposits.According to the gravity inversion,Shuangdinggou-and Xinling rock masses on the north and south sides of the mining area are connected in the deep.The connected rock body might be distributed in the entire mining area.Xinling rock mass may be a branch extending from Shuangdinggou rock mass along the northeast trending fault,the connected rocks provide magmatic hydrothermal fluid for the final,folds and faults result in different types of ore body shapes.  相似文献   

8.
The Diakha gold deposit is located in the southeastern margin of the highly prospective/productive Paleoproterozoic( Birimian) Kédougou-Kéniéba Inlier. Gold mineralization is closely associated with a narrow,sub-vertical,NE-trending shear corridor. The corridor is to the east of a sinistrally reactivated D1 west-dipping fault,which emanated from SMSZ( D2 reverse-sinistral regional structure). The mineralization is hosted by fine-grained sandstone and breccias units associated with a moderate to strong hydrothermal alteration,which is dominated by albitization,carbonization,silicification,hematization,and chloritization. Diakha field data and laboratory analysis suggest the existence of two main stages of hydrothermal mineralization,namely stage I and stage II. Stage I is of a breccias type of mineralization and represents the major gold bearing stage. It isassociated with hematite + calcite + ankerite/dolomite and quartz pervasive alteration,controlled by the predominantly brittle-ductile NNE to NE-shearing structures of the main deformation event D2. Stage II is represented by the second minor hydrothermal episode,showing local quartz-tourmaline and tremolite alteration which is structurally controlled by the dipping S3 cleavage formed during D3 deformation. Petrographic and microthermometric studies of fluid inclusions from quartz veins reveal the presence of early dominant carbonic CO2-pure and aqueous-carbonic CO2-rich( LCO2+ VCO2± H2 O) in stage I. The exclusively aqueous H2 O + Na Cl ± CO2 fluid inclusions( L-type) are observed in stage II. Interpretation shows that the ore-forming fluids originated from a homogeneous H2 O-CO2 fluid during phase separation,with trapping temperatures of 250℃ to 280℃ and low salinity( 6 wt % Na Cl equiv),indicating an estimated trapping pressure for the deposit between 610 to 800 bars.  相似文献   

9.
Gaotaigou borate deposit in Ji'an area, southeastern Jilin, is located in the easten end of Liaoning-Jilin (Liaoji) Proterozoic paleo-rift, which is a medium-sized deposit and makes up 67% of the total borate reserves in Jilin Province. The original borate ore bodies were formed by sedimentary exhalative process in Paleoproterozoic, but were activated and enriched by later metamorphism. In late stage of metamorphism, hydrothermal fluid of metamorphic origin made wallrocks be altered and the borate ore bodies be reformed. Ore bodies are strictly controlled by strata and their lithologies. In addition, the shape and spatial distribution of ore bodies are also defined by the Gaotaigou syncline. Combined with the ore-controlling factors and mineralizing features, it has been proposed that Gaotaigou borate deposit is a metamorphosed and hydrothermally altered sedimentary exhalative deposit.  相似文献   

10.
Gaotaigou borate deposit in Ji'an area, southeastern Jilin, is located in the easten end of Liaoning-Jilin (Liaoji) Proterozoic paleo-rift, which is a medium-sized deposit and makes up 67% of the total borate reserves in Jilin Province. The original borate ore bodies were formed by sedimentary exhalative process in Paleoproterozoic, but were activated and enriched by later metamorphism. In late stage of metamorphistn, hydrothermal fluid of metamorphic origin made wallrocks be altered and the borate ore bodies be reformed. Ore bodies are strictly controlled by strata and their lithologies. In addition, the shape and spatial distribution of ore bodies are also defined by the Gaotaigou syncline. Combined with the ore-controlling factors and mineralizing features, it has been proposed that Gaotaigou borate deposit is a metamorphosed and hydrothermally altered sedimentary exhalative deposit.  相似文献   

11.
INTRODUCTIONResearchesonsea floorhydrothermalactivitiesandhydrothermalsulfidesyieldedthenewestknowledgeaboutmodernmarinegeologicalevolutionandmineralizationpatterns.Sincethe 1 980s,scientistshavebeenapplyingtheoxygenisotopemethodtorecoverthenotdirectlyde…  相似文献   

12.
依据矿床地质特征沿及铅、硫、氢、氧同位素以及包裹体和微量元素等测试资料分析表明,该矿床为中泥盆世沿海底同生断层喷溢的含矿热卤水与生物还原海水硫酸盐中的硫相互作用,形成同生含矿硅质岩,再经后期改造而成层控多金属矿床。所以矿床既有同生沉积标志,又有后生改造迹象。属海底喷气沉积—受改造的层控矿床。  相似文献   

13.
In this study, geochemical compositions of elements in sulfide samples collected from the Deyin-1 hydrothermal field near the 15°S southern Mid-Atlantic Ridge (SMAR) were analyzed by the X-ray fluorescence spectrometry (XRF) and inductively coupled plasma mass spectrometry (ICP-MS) to examine the enrichment regulations of ore-forming elements and hydrothermal mineralization. These sulfide precipitates can be classified macroscopically into three types: Fe-rich sulfide, Fe-Cu-rich sulfide and Fe-Zn-rich sulfide, and are characterized by the enrichment of base metal elements along with a sequence of Fe>Zn>Cu. Compared with sulfides from other hydrothermal fields on MAR, Zn concentrations of sulfides in the research area are significantly high, while Cu concentrations are relatively low. For all major, trace or rare-earth elements (REE), their concentrations and related characteristic parameters exhibit significant variations (up to one or two orders of magnitude), which indicates the sulfides from different hydrothermal vents or even a same station were formed at different stages of hydrothermal mineralization, and suggests the variations of chemical compositions of the hydrothermal fluid with respect to time. The hydrothermal temperatures of sulfides precipitation decreased gradually from station TVG10 (st.TVG10) to st.TVG12, and to st.TVG11, indicating that the precipitation of hydrothermal sulfides is subjected to conditions changed from high temperature to low temperature, and that the hydrothermal activity of study area was at the late stage of a general trend of evolution from strong to weak. The abnormally low concentrations of REE in sulfides and their similar chondrite-normalized REE patterns show that REEs in all sulfides were derived from a same source, but underwent different processes of migration or enrichment, or sulfides were formed at different stages of hydrothermal mineralization. The sulfides collected from the active hydrothermal vent were mainly attributed to precipitating directly from the hydrothermal fluid, while those collected from the extinct hydrothermal chimney might have already been altered by the seawater. Generally, ore-forming elements in the sulfides can be divided into three groups: Fe-based element group, Cu-based element group and Zn-based element group. The first group includes Fe, Mn, Cr, Mo, Sn, Rb and bio-enriching elements, such as P and Si, reflecting the similar characteristics to Fe in the study area. And the second group contains Cu, W, Co, Se, Te and Bi, suggesting the similar behavior with Cu. Moreover, the third group includes Zn, Hf, Hg, Cd, Ta, Ga, Pb, As, Ag, Ni and Sb, which indicates the geochemical characteristics of most dispersed trace elements controlled by Zn-bearing minerals to some extent.  相似文献   

14.
Distribution of suspended matter in seawater in the Southern Yellow Sea is investigated in five regions: 1) the Northern Jiangsu bank, the highest TSM (total suspended matter) content region; 2) the high TSM content region off the Changjiang River mouth; 3) the high TSM content region off the Chengshan Cape; 4) the low TSM region off Haizhou Bay; 5) the central part of the Southern Yellow Sea, a low TSM content region. The vertical distribution of TSM is mainly characterized by a spring layer of suspended matter, written as “suspended-cline” whose genesis is related to storms in winter. In this paper, non-combustible components and grain sizes in suspended matter, relationship between suspended matter and bottom sediments, and salinity in seawater are described. Investigation result shows that, in this area, suspended matter comes mainly from resuspended bottom sediment and secondarily from present discharge loads from rivers and biogenic materials. Discharged sediments from the Huanghe River move around the Chengshan Cape and affect the northwestern region of this area. Sediments from the Changjiang River affect only the southern part and have little or no direct influence on the central deep region. Wave is the main factor affecting distribution of suspended matter. Water depth controls the critical depth acted on by waves. The cold water mass in the central region limits horizontal and vertical dispersions of terrigenous materials. Suspended matter here has the transitional properties of the epicontinental sea. Its concentration and composition are different from those of a semi-closed sea (such as the Bohai Sea) and those of the East China Sea outer continental shelf or those near oceanic areas.  相似文献   

15.
谭家沟金矿产于中泥盆统热水沉积岩中。矿体位于铁白云石硅质岩构造角砾带 ,是以浸染状矿化为主 ,由热水沉积铁白云石硅质岩提供矿质并基本在层内富集成矿的热水沉积改造型金矿床。铅同位素特征表明成矿金属来源于地壳 ;硫同位素组成特征表明硫主要来自海水硫酸盐的还原硫 ;氢氧同位素测试数据表明 ,成矿流体主要为原生建造水。成矿流体为SO4 2 F/Na Ca2 型 ,成矿物理化学条件为弱中等还原环境 ,成矿温度 15 0~ 170℃ ,盐度w(NaCl)为 6 .86 %。  相似文献   

16.
An unusual feature of the saline stratified lakes that were formed due to ongoing postglacial uplift on the White Sea coast is the presence of several differently colored thin layers in the zone with sharp gradients. Colored layers in five lakes at various stages of separation from the sea were investigated using optical microscopy, spectrophotometry, spectrofluorimetry, and photobiology. The upper greenish colored layer located in the aerobic strata of all lakes near the compensation depth of 1% light penetration contains green algae. In the chemocline, another layer, brightly green, red or pink, is dominated by mixotrophic flagellates. Despite the very low light intensities and the presence of H 2 S, active photosynthesis by these algae appears to be occurring, as indicated by high values of the maximum quantum yield of primary photochemistry, electron transport activity, photosynthetic activity of photosystem II, the fraction of active centers, and low values of heat dissipation. In the reduced zone of the chemocline, a dense green or brown suspension of anoxygenic phototrophs(green sulfur bacteria) is located.  相似文献   

17.
玲珑西山幔源脉岩主微量元素的变化暗示了源岩很可能经历过类似俯冲带流体的交代作用,矿化流体中含有较高含量的金属矿物,具有Eu的正异常,指示了源区是深源的。脉岩中的CO2来源可能是花岗岩岩浆热液的混入,石英来源于陆壳碎屑物质部分熔融形成的S型花岗岩,硫的来源与幔源脉岩岩浆同源,或来自地幔,或来自地壳深部。  相似文献   

18.
成岩相识别与划分有助于碳酸盐岩储层分类评价及预测。为了明确塔里木盆地中央隆起带寒武系-奥陶系的白云岩成岩相类型及特征, 通过岩心描述、常规及铸体薄片观察、X衍射分析以及粒度分析等方法, 首先对其岩相学特征进行了详细研究并对成岩相类型进行了划分, 在此基础上, 结合O、C稳定同位素测试方法以及Fe、Mn、Sr、Li、U等常、微量元素测试技术探讨了各类白云岩成岩相的地球化学特征并建立了各类成岩相的模式。研究结果表明, 塔里木盆地中央隆起带寒武系-奥陶系白云岩成岩相可划分为准同生云化亚相(PD-F)、浅埋藏隐伏回流渗透云化亚相(SLRD-F)、浅埋藏活跃回流渗透云化亚相(SARD-F)、表生风化壳岩溶亚相(WK-F)和构造破碎亚相(TF-F)共5类。其中, PD-F模式的白云岩云化流体主要来自咸化海水并受部分淡水影响, 表现出O同位素负偏, Fe、Mn、Sr和Li质量分数明显偏高的特征; SARD-F模式的白云岩基本形成于正常海水, 个别样品受到埋藏溶蚀或重结晶作用以及淡水影响, 整体表现为O同位素值与奥陶纪海水一致, Fe、Mn、Sr质量分数相对较低的特点; SLRD-F模式的白云岩形成环境相对封闭, 受淡水影响较小, 表现为O同位素值与海水一致, Fe、Mn质量分数相对较低, Sr质量分数相对较高的特征; WK-F模式的白云岩样品由于经历表生淡水溶蚀作用和埋藏期的白云化作用, 具有O同位素负偏, Fe、U质量分数较高, Sr质量分数较低的特征; TF-F模式的白云岩样品受到构造热液的影响, 具有O同位素负偏, Fe、Mn、U、Li质量分数低的特征。   相似文献   

19.
喇嘛萨依铜矿位于天山西段库松木切克山北坡,产于中元古界蓟县系库松木切克群。矿体的赋存和形态严格受地层层位、岩相和构造的控制。容矿岩石主要为钾长岩、硅质岩等热液沉积岩。矿体有与围岩整合的层状和切穿围岩层理的脉状两种产状形态。成矿物质来源于深部地层的循环热液,属海底喷气沉积-再造型层控矿床。  相似文献   

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