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1.
对长岛北四岛海洋牧场海域101个表层沉积物和102个表层海水样进行取样调查,开展表层沉积物类型、粒度、表层沉积物和海水重金属等指标分析测试,采用单因子污染指数法、富集系数法和潜在生态危害指数法评价该区表层沉积物潜在生态风险,采用海水水质分类和单因子污染指数法评价表层海水污染情况。表层沉积物结果表明:沉积物为泥质砂质砾、砾质泥质砂、砾质泥、含砾泥质砂、砂、粉砂质砂和砂质粉砂,平均粒径介于2.44~5.44Ф;Hg、Cu、Zn、Pb、Cd、As、Cr、硫化物和石油类都符合第一类标准,属于清洁沉积物;Cr、Cu、Pb、Zn、Cd、Hg和As富集系数均<1,处于低度污染水平;Cr、Cu、Pb、Zn、Cd、Hg和As单项潜在生态危害系数Eir介于0.56~30.71之间,RI均值为66.27,远低于低度生态危害的划分标准值。表层海水结果表明:21个站位受到Hg污染,略高于第一类标准,满足第二类标准,主要位于研究区西北部、西中部和东北部海域,其余指标均符合规定第一类标准;Hg、Cu和Zn含量处于较清洁环境范围内,As、COD、石油类、Pb、Cr和Cd含量处于自然本底环境。根据海底沉积物和海水分析结果得出,长岛北四岛海域海洋牧场规划区底质和水质环境适宜建设海洋牧场。  相似文献   

2.
通过系统生态地球化学调查与评价,在山东日照地区共采集了5 323个表层土壤样品,获取了表层土壤重金属元素地球化学分析数据。以表层土壤As、Cd、Cr、Cu、Hg、Ni、Pb、Zn等8种重金属元素为研究对象,按照《土壤环境质量标准》(GB 15618—1995),采用单因子指数和综合评价指数对土壤环境质量进行评价。土壤单因子环境质量评价结果表明:As、Cd、Cr、Cu、Hg、Ni、Pb、Zn等8种元素Ⅰ类土壤的面积比例分别为100.00%、98.21%、94.14%、98.10%、99.90%、89.18%、96.61%和98.37%,说明山东日照地区土壤环境质量良好;土壤单因子环境质量平均达到Ⅰ类土壤的占调查区土壤总面积的96.81%,Ⅱ类土壤占3.17%,Ⅲ类土壤仅占0.02%。表层土壤重金属元素污染综合评价结果表明:表层土壤环境质量属于Ⅰ类土壤(清洁—较清洁)的占调查区土壤总面积的86.39%,属于Ⅱ类土壤(轻度污染)的占13.55%,属于Ⅲ类土壤(中度污染)的占0.06%,说明山东日照地区表层土壤重金属综合污染很少,土壤环境质量总体状况良好。土壤重金属元素综合指标评价结果显示,未富集区面积累计占区域总面积的5.50%,弱富集区占38.63%,中度富集区占53.27%,重度富集区占2.60%,说明区域表层土壤中污染物已有积累趋势,虽未达到有害程度,亦应引起重视。  相似文献   

3.
根据2011年7月浙江舟山西蟹峙海洋倾倒区及邻近海域表层沉积物重金属的监测结果,采用单因子指数法和Hakanson生态危害指数法分析表层沉积物重金属的污染特征,并评价其潜在生态风险。结果表明:沉积物重金属元素Cu、Zn、Pb、Cd、Cr、Hg、As含量均符合国家海洋沉积物质量一类标准;重金属元素污染程度由高到低依次为Zn、Cr、Pb、Cu、As、Cd、Hg,其中Cu、Pb、Cd、Hg和As 5种重金属元素为低污染水平,Zn和Cr 2种重金属元素为中等污染程度水平;7种重金属元素单个和综合潜在生态危害程度均为低风险水平,由高到低依次为Cd、Hg、As、Pb、Cu、Cr、Zn。  相似文献   

4.
【目的】探究博贺湾海域表层沉积物重金属的污染特征和来源。【方法】基于2016年和2014年博贺湾海域表层沉积物Cu、Pb、Zn、Cd、Cr、Hg、As重金属调查结果,应用单因子污染指数法和Hakanson潜在生态风险指数法评估其生态风险,同时结合同步调查得到的总有机碳(TOC)参数,应用相关性分析和主成分分析方法,分析调查海域重金属的污染特征及来源。【结果】博贺湾海域表层沉积物重金属Zn、Cd、Pb、As、Hg含量均满足国家第一类海洋沉积物质量标准,95%站位的Cu、Cr满足国家第一类海洋沉积物质量标准,重金属污染程度由高到低依次为CrPbHgCuAsZnCd,重金属元素潜在生态危害影响程度依次为HgCdAsPbCuCrZn,TOC与重金属Hg含量成显著正相关,而与Cu、Zn、Cr无相关性。【结论】该海域Hg主要来源于有机质的降解,Cu、Zn、Cr具有相近来源,主要为人类工业生产与生活污染;Cd、Pb、As来源为人类工业生产与生活污染以及有机质的降解。调查海域综合潜在生态风险整体处于较低水平,重金属Hg为主要生态风险贡献因子。  相似文献   

5.
人类活动对水环境影响巨大,同时水环境影响着人类的生产生活。采用地质累积指数法及潜在生态危害指数法对武汉市东西湖区主要湖泊表层沉积物重金属情况展开评价发现东西湖主要湖泊表层沉积物平均污染程度处于相对较低水平。地累积指数法评价结果表明,东大湖和金湖中Cd元素处于中度污染水平累积,墨水湖和上金湖中Cd元素为偏中度污染累积水平,其他湖泊沉积物中重金属均处于轻度或无污染水平。潜在生态危害指数法评价结果表明金湖和东大湖沉积物中重金属的潜在风险处于重度生态风险水平,墨水湖、上金湖、下银湖处于中度风险水平,其余湖泊沉积物中重金属的潜在风险均处于低风险水平。主成分分析表明,Hg、Cr、Ni、Cu、Zn、Cd、Pb可能来自于工业和交通源的排放,而As可能与农药的使用有关。后期金湖、东大湖、墨水湖、上金湖和下银湖的内源污染治理过程中需考虑重金属的生态风险问题。   相似文献   

6.
烟台近岸海域表层沉积物重金属污染特征   总被引:1,自引:0,他引:1       下载免费PDF全文
采取烟台近岸海域150个海底表层沉积物样品进行Hg,Cu,Pb,Zn,Cd,Cr,As,Ni元素分析。结果显示,烟台市近岸海域重金属主要富集在芝罘湾(Cd,Cu)、龙口(As,Cr,Cu)及海阳东部(Ni,Pb)一带,而莱州、招远及牟平近岸海域重金属含量较低。单因子、内梅罗和潜在生态危害指数评价结果显示,研究区88%海域的沉积物达到一类标准,轻污染区主要分布在芝罘岛北部及龙口市西部,龙口、招远及烟台市近岸沉积物潜在风险中等。  相似文献   

7.
于2015年11月和2016年3月调查了较场尾海域海洋环境状况,以海水水质标准、综合污染指数和潜在生态风险指数、目标危险系数来评价较场尾海域海水、沉积物及生物体重金属的污染现状和摄入健康风险。结果表明:两个航次海水均有个别重金属含量超标,其中2015年11月份航次重金属Pb、Hg超标,站位超标率分别为40%和20%,2016年3月份航次重金属Cu、Pb、Hg超标,站位超标率分别为5%、20%和5%,较场尾海域表层海水重金属浓度基本呈现由北向南逐渐递减的趋势;较场尾海域表层沉积物主要受到Cu、Pb、Cr、Hg的污染,其中5站的Cr和15站的Hg均超过海洋沉积物质量二类标准,Cu和Cr的站位超标率为16.7%,Pb和Hg的站位超标率为8.3%,站位综合污染指数以5站6.02为最大,潜在生态风险指数以15站65.14为最大;较场尾附近海域的重金属污染主要来自附近的工业厂区和燃煤电厂;较场尾海域所捕获到的鱼、虾、头足类目标危险系数之和由大到小为:鱼(0.132)头足(0.062)虾(0.012),均不存在人体摄入健康风险。  相似文献   

8.
以山东省济南市章丘区北部表层土壤中As等8种重金属元素为研究对象,利用多元统计进行重金属来源分析,采用污染负荷指数法及潜在生态危害指数法进行污染评价,结果表明:研究区表层土壤重金属元素含量低于济南市土壤背景值,Cd和Hg元素含量为强度变异,在表层土壤产生一定的富集;不同土地利用类型下重金属元素含量具有差异性。土壤中Cr,Cu,Ni和Zn来源于土壤母质,Cd和Pb元素来源于人类活动,As元素来源复杂。土壤综合污染以轻度污染为主,重金属元素污染程度大小为AsNiPbZnCrCuCdHg。综合潜在生态风险以轻微和中度为主,潜在生态风险强弱程度为HgCdAsCuPbNiCrZn,建议防范Hg和Cd元素污染及生态风险。  相似文献   

9.
山东省东部地区农业生态地球化学调查与评价   总被引:1,自引:0,他引:1  
介绍了山东省东部地区农业生态地球化学调查与评价工作取得的一些基本成果以及该区存在的生态地球化学问题。调查与评价结果显示,Zn,Pb,Cu,Se,Cd,S,P,Hg,N,OrgC等元素或指标在表生作用或人类活动等因素影响下,使表层土壤含量明显大于深层;总体上该区地球化学环境质量优良,Ⅲ类和劣Ⅲ类土壤仅占全区总面积的0.13%,主要分布在矿集区和城镇周边,主要污染元素为Cd,Cr,Ni,Hg。浅层地下水大部分元素或指标处于自然低背景含量状态,部分水样总硬度超标,溶解性总固体、NO2-和F-等超标,已不适合饮用。该区存在的生态地球化学问题有:①山地丘陵区土壤pH值低,且表层土壤具有向强酸、强碱两极化发展的趋势,易引起重金属元素活化,危害人类健康;②沿海地带土地贫瘠,N,P和有机质等营养水平多属缺乏级;③莱州-烟台和牟平-乳山矿集区以及人口密集的城镇地带表层土壤Hg,Cd,Pb,Zn,Se,S等元素污染严重。地质高背景、酸性的表生环境和工业污染的共同作用,是造成环境中重金属元素含量较高的主要原因。  相似文献   

10.
通过对青岛城区土壤进行调查取样,运用单因子评价和内梅罗指数法对青岛表层土壤8种重金属元素(As,Cd,Cr,Cu,Ni,Hg,Pb和Zn)的测试结果进行评价,查明了土壤环境质量现状及其污染程度:青岛市土壤环境质量总体较高,绝大部分地区土壤环境保持在清洁水平;污染区域以孤岛状零星分布于青岛市内,区内胶州湾入海口污染指数偏高,很可能是由于河流上游污水排放导致的。通过对未来20年城区土壤在大气降尘影响下重金属Cd,Zn的累积情况进行了预测,结果表明:随着时间的推移,土壤有害元素含量会有所增高。其中,大气降尘中Zn元素对青岛市区土壤影响明显。该研究对于正确认识青岛区域地球化学特征和地质环境具有一定的指导意义。  相似文献   

11.
The southern sea area of the Huludao City, Liaoning Province might be polluted by heavy metals because it is close to the Jinzhou Bay, one of the heaviest sea area polluted by heavy metals in China. The undisturbed modern sediment core can be used to analyze the accumulation and source of the pollutants using 137 Cs and 210 Pb ex . Thirty-five samples of surface sediment and two core sediments were collected from the southern sea area of Huludao City. The concentrations of copper (Cu), lead (Pb), chrome (Cr), zinc (Zn), arsenic (As) and mercury (Hg) in the surface sediments as well as Cu, Pb, Zn, Cr, 137 Cs and 210 Pb ex in the core sediments were determined to research the spatial distribution and accumulation characteristics, and to analyze the sources and the potential risks of heavy metals. The results show that the pollution levels of Zn and Hg are serious, and 26 stations are at moderate or heavy ecological risks. The concentrations of the heavy metals increase from east to west, as well as from open sea to offshore marine area. The concentrations of heavy metals are not high in the sediments adjacent to the Jinzhou Bay, and the influence caused by the seawater exchange with the Jinzhou Bay is little. The concentrations of the heavy metals in the core sediments show low-high-low characteristic, and it coincides with the pollution history of Huludao City. The atmospheric deposition of heavy metals from the Huludao Zinc Plant is likely to be the main source of pollution without direct discharge of wastewater. The high concentrations of heavy metals appear on the upper sediment of 20 cm. The shallow sediment with high heavy metal contents might be exposed to surface when it was disturbed by the ocean engineering and big storm surge, then cause risk to the safety of aquaculture and human healthy.  相似文献   

12.
A total of 30 surface sediments samples from the estuary wetland of the Tangxi River, Chaohu Lake Basin were obtained and tested. Enrichment factor (EF) and geoaccumulation index (I_(geo)) as well as multivariate statistical analysis methods including Factor Analysis (FA) and Hierarchical Cluster Analysis (HCA) were applied for the assessment of heavy metal pollution in surface sediments. The results of EF values show that the pollution of copper (Cu) and cadmium (Cd) occurs in the estuarine sediments, and that zinc (Zn), lead (Pb) and chrome (Cr) may originate from crustal materials or natural weathering process. The mean EF values of the five heavy metals are in the decreasing order: Cu>Cd>Zn>Pb>Cr. Based on the I_(geo) of target heavy metals, the surface sediments collected from the study area can be approximately categorized as unpolluted with Zn, Pb and Cr, and moderately polluted with Cu and Cd. The degree of heavy metal pollution decreases in the order of Cu>Cd>Zn>Pb>Cr. Three groups of pollution factors are presented from FA: Zn-TOC, Cu-Cd and Cr-Pb, which respectively accounte for 27.22%, 25.20% and 21.05% of variance. By means of HCA, a total number of seven groups are distinguished from 30 sampling sites. Results indicate that Cu and Cd are the prior controlled pollutants in the estuarine sediments of the Tangxi River.  相似文献   

13.
研究石漠化峰丛洼地土壤重金属空间分异特征及其影响因素, 对推动区域土壤重金属污染防治、石漠化综合治理具有重要的指导意义和实践价值。以广西平果市典型石漠化峰丛洼地土壤为研究对象, 通过调查采样分析以及综合运用地统计学、地质累积指数、潜在生态危害指数和地理探测器等方法, 分析探讨土壤重金属的空间分异特征及其影响因素。结果表明, 研究区8种重金属元素的空间分布总体呈东北向西南降低的变化格局, 研究区东北部和东南部为重金属高值叠加区的集中分布区, Cr,Cd元素呈现中等的空间相关性, 其他6个重金属元素表现为强空间相关性;研究区受Cd,As,Cr,Cu,Zn等元素不同污染程度的影响, 且以Cd的影响尤为突出, 其地质累积指数和潜在生态危害指数分别高达1.34和107.73;pH、地层、Fe2O3、土地利用、P、CaO、Mn、到断层距离、石漠化程度是影响研究区土壤重金属空间分异的主要因子, 而且不同因子组对土壤重金属空间分异的交互作用以双因子增强型和非线性增强为主。因此认为不同因子对石漠化峰丛洼地土壤不同重金属元素空间分异特征的影响程度存在差异, Cd是石漠化峰丛洼地土壤污染程度和潜在生态危害程度最严重的重金属元素, 地层、Mn、CaO、岩性、到断层距离、P是影响Cd空间分异的关键因子。   相似文献   

14.
We analyzed heavy metal concentrations in a number of surface sediments and cores from the Qiongzhou Strait and surrounding marine areas.The areas of high concentrations are primarily outside the eastern mouth of the Qiongzhou Strait and on the west side of the Leizhou Peninsula,whereas the areas of low concentrations are located primarily in the eastern Qiongzhou Strait.The maximum Cd,Pb and Zn concentrations in the samples collected in our study do not exceed the official standards for marine sediments,whereas the concentrations of Cr and Cu slightly exceed the standards.Correlations exist between the concentrations of Cu,Pb,Zn,Cr and Cd,and the concentrations of these metals are positively correlated with the mean particle size(φ value),indicating that the finer sediments have adsorbed greater amounts of heavy metal elements than the coarser sediments.An evaluation of the potential environmental risks demonstrates that certain indices of heavy metal pollution and environmental risks are relatively low and may be assigned low risk levels,thereby indicating that,in terms of heavy metals,the marine sedimentary environment in this region is only mildly impacted.Our analysis of the contaminant origins shows that the heavy metals in this region primarily originate in the Pearl River Estuary and that a small amount of them is derived from local runoff.The elevated heavy metal concentrations from the upper sections of the cores started 130 years ago,which indicats that heavy metals in the surface sediments are primarily due to human activities associated with industrialization.  相似文献   

15.
Twenty-nine samples of surface sediments from tidal flats in the Northern Shandong Province were collected for grain size, heavy metal(Hg, Cu, Pb, Zn, Cd, and Cr), and oil pollution analyses. The geoaccumulation index(Igeo) and factor analysis were introduced to evaluate sediment quality and source of contaminants. The mean concentrations of Hg, Cu, Pb, Zn, Cd, Cr, and oil in the surface sediments in the study area are 0.033, 17.756, 19.121, 55.700, 0.291, 59.563, and 14.213 μg g-1, respectively. The heavy metal contamination in the old delta lobe is slightly higher than that in the abandoned delta lobe; however, the opposite was observed for oil pollution. The Igeo results revealed that the overall quality of the surface sediments in the study area is in good condition. The heavy metal pollution levels show a descending order: Cd Hg Cr Cu Zn Pb, Cd being the main pollutant. The contamination level for in the study area is relatively lower than those for China's other tidal flats. Heavy metals are mainly derived from natural sources of rock weathering and erosion, partly influenced by industrial and agricultural discharge. However, oil pollution is mainly from runoff input, motorized fishing boat sewage, and oil exploitation.  相似文献   

16.
Surface sediments were collected from Lake Manzala, the Mediterranean coastal wetland located to the east of the Nile Delta, Egypt, to assess the effect of drain effluent on the spatial variations of sedimentary characteristics and heavy metal pollution. Grain-size compositions, textures, and heavy metal distribution patterns in sediments are presented using GIS technique. Results of the analysis of the sediment showed a clear effect of drain effluent, with an increase in fine fractions and homogeneous suspensions in transportation mode. Lake sediments were dominated by sandy mud textures, and mode of transportation was homogeneous suspension and rolling. Spatial distribution of heavy metals(Fe, Mn, Zn, Cu, Ni, Cr, and Pb) was studied in the lake's surficial sediments, along with their relationship to drain effluent and their contamination status in the ecological system. Heavy metal pollution status was assessed by means of accepted sediment quality guidelines and contamination assessment methods(contamination factor, contamination degree, modified contamination degree, geo-accumulation, and enrichment factor). Among the determined heavy metals, Pb had the most ecological risk. Generally, the heavy metals in the surface sediments indicated pollution risk ranging from moderate to considerable, particularly, in those sites facing drains and inlets that had the highest toxic effluent. The results were interpreted by statistical means. A cluster analysis defined areas facing drain discharge and inlets as separated groups. ANOVA indicated that most of the sedimentation and studied metals directed this clustering.  相似文献   

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