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1.
This paper reported the results of the determination of Ag, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, P, Pb, Rb, Sr and Zn in Common Chanterelles (Cantharellus cibarius) Fr. and surface soil layer (0-10 cm) underneath the fruiting bodies. Mushrooms and soils were collected from a lowland site in the Hel Peninsula (Baltic Sea coast) and a high mountain site in the Tatra Mountains. The trace elements were determined using validated method and inductively coupled plasma - atomic emission spectroscopy (ICP-AES). Common Chanterelles that emerged at sites poor in mineral nutrients podzols of the Hel Peninsula forests efficiently bioconcentrated several essential trace elements (K, P, Co, Cu, Mn, Na, Zn), while the abundance of those elements in carpophores was around half less compared to specimens from Zakopane region and which emerged in soils much richer in minerals. Common Chanterelles collected at two spatially distant background areas in Poland were only weakly contaminated with metals such as Ag, Cd, Hg and Pb. The maximum tolerable Cd and Pb contents of certain cultivated mushrooms are regulated in the European Union by law and these hazardous metals in C. cibarius were far below tolerance limits set.  相似文献   

2.
Si, Ti, Al, Fe, Mn, Ca, Mg, K, Na, P and Sr, Ba, Rb, Ga, V, Zr, Cr, Ni, Co, Cu, Zn, Pb,Nb, Y, Th, La in the core S01 were analyzed and the pattems of their enrichment are discussed.Enrichment of Na, Fe, Mn, Ba, Cu elements in the core indicates volcanic material are an importantsoarce of the sediments in the area. The enrichment frequently varying with the deposition processshows bottom volcanism is frequent in the area and that the studied area is a margin basin with distinctoceanic characteristics. The abnormal enrichment of Mn at the layers(0-15 cm and 665-670 cm) of the core could beclosely related to and so, indicate, the wide deposition hiatus that have occurred in the West PacificOcean and adjacent margin seas since Late Pleistocene.  相似文献   

3.
In the current study, we determined concentrations and transfer rates of Ag, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, P, Rb, Sr and Zn to Brown Birch Scaber Stalks (Leccinum scabrum) mushrooms emerged in the area of Sudety Mountains (Sudetes) in Poland. Fruiting bodies and topsoil samples beneath L. scabrum were collected form the K odzka Dale. The trace elements were determined using validated method and inductively coupled plasma - atomic emission spectroscopy (ICP-AES) for final measurement. Mushrooms contained Ag, Cr, Hg, Co, Ni and Sr at < 1.0 μg/g dry weight; Ba and Pb at ~1.0 μg/g dw; Cd at < 5 μg/g dw; Cu and Mn at > 10 μg/g dw; Al and Ca at ~100 μg/g dw; Fe, Na, Rb and Zn at 100 to 500 μg/g dw, Mg at ~1,000 μg/g dw; P at ~5,000 μg/g dw and K at ~30,000 μg/g dw. Ca, Mn and Ni were nearly equally distributed between stipes and caps; stipes compared to caps were enriched in Ba, Na and Sr, while caps were enriched in Ag, Al, Cd, Co, Cr, Cu, Fe, K, P, Pb, Rb and Zn. The values of bioconcentration factor (BCF) varied highly depending on chemical element and were >1 for Ag, Cd, Cu, K, Mg, Na, P, Rb and Zn, while <1 for Al, Ba, Ca, Co, Cr, Fe, Mn, Ni, Pb and Sr. Topsoil showed elevated content of lead and mean concentration was 99 ± 32 μg/g dw, while cadmium was at 0.41 ± 0.15 and those two highly toxic to human elements occurred in edible caps of L. scabrum at 4.5 ± 2.2 and 2.9 ± 2.0 μg/g dw, respectively.  相似文献   

4.
This study applies a TuPu analysis to investigate ecological and environmental aspects of an Antarctic ice-free area, using Fildes Peninsula as an example. The TuPu unit was determined using a vector-grid mixed data model. Information from the eco-environment elements was effectively extracted, and was generalized into different classes by means of data mining technol- ogy. A series of single-factor thematic information TuPu models, such as topography, soil, animal and vegetation, and human activities for Fildes Peninsula were built in this study. The topography TuPu model contained information on elevation and slope. The soil TuPu model involved soil development stages and soil thickness information. The animal and vegetation TuPu model contained the distribution of animals, plant types, lichen cover and lichen height. The human activities TuPu model included popu- lation density and human disturbance index information. The landscape comprehensive information TuPu model of Fildes Penin- sula also was established, and contains twenty-nine landscape units and twelve types of combined environments. The study quan- titatively revealed the spatial morphology and correlation of the regional eco-environment based on the analysis of these TuPu models. From these models, we can draw the conclusion that there is a regular differentiation of eco-environment from the coastal bands to the central hills in Fildes Peninsula, and that the eco-environment condition of the eastern coasts is different from that of the western coasts. The eco-environmental spatial variation also differs greatly from north to south. Based on analysis of spatial correlation, the vegetation in Fildes Peninsula has the greatest correlation with human activity, and has a certain correlation with topography and soil. This research may provide a new technical approach and scientific basis for the in-depth study of Antarctic eco-environments.  相似文献   

5.
Ye  Liping  Zhang  Ruifeng  Sun  Qizhen  Jin  Jie  Zhang  Jing 《中国海洋湖沼学报》2018,36(6):2181-2193
King George Island, situated in the South Shetland Islands archipelago, is one of the most visited sites in Antarctica. Antarctica attracts much attention because it is one of the most sensitive areas under the influence of global warming. To understand its hydrochemistry characteristics, we collected various types of water samples, including samples from streams, meltwaters, ground waters, snow and ice from around the Great Wall Station, Fildes Peninsula, King George Island, from January to February, 2015. Major ions, alkalinities, silicate, pH, dissolved oxygen, temperature, and electric conductivities were measured. Several approaches were applied to identify processes that af fect the hydrochemistry on Fildes Peninsula, including ternary diagrams, principal components analysis and cluster analysis. Our data suggest that atmospheric seasalt deposition is the main factor controlling the hydrochemistry on Fildes Peninsula. After atmospheric influences were corrected for seasalt, we defined the weathering of local rocks to be another important factor on the Peninsula's hydrochemistry. Processes such as Ca dissolution from the Ca-bearing basalt, Si loss through secondary mineralization and biological uptake influence the chemical composition of runof fs on the peninsula. Cluster analysis identified 4 groups of streams based on their hydrochemical features, which reflect their original weathering characters under icecap and the combined effects with melt snow, biological activity and the anthropogenic input.  相似文献   

6.
Regular distribution patterns of elements Ca, Sr, K, Na, Mg, Fe, Mn, Ti, Cu, Co, Ni, Zn, Pb, Cr, Rb, Ba, Cd, and U in Late Quaternary strata have been studied in detail. The regional variation patterns of elements in these strata are similar to those in recent surface sediments, showing that the sedimentary environment has been relatively stable since Late Quaternary. Element distribution changes with the variations of lithological characters. Contents of Ca and Sr increase in coarse sediments, while those of other elements decrease. Na content increases in the pumice layer. Mn, content tends to increase sharply towards the surface layer. Ca content decreases sharply in strata where water depth is more than 2,000 m. The strata can be divided based on the distribution curves of element assemblages. The variations in contents of most elements in Holocene Series are smaller than those in Late Pleistocene Series, which might be related to the factors of glacial and interglacial changes, sea level fluctuations and material source differences. Contribution No. 1488 from Institute of Oceanology, Academia Sinica  相似文献   

7.
Lake core sampled from Xihu in Fildes Peninsula of King Gorge Island, Antarctica could reveal the environmental change of the district. The lake core( GA7) , 9.28 meters long , was sectioned at an interval of 2 cm. Through measuring the organic carbon, magnetic susceptibility, granularity and organic carbon isotope of GA7, by use of 14C age it was estimated that there were four periods of high temperature in Fildes Peninsula; 4800-4400 aB. P. , 3600-3350 aB. P. ,2100 - 1800 aB. P. and 900 aB. P. - present. Meanwhile, results showed that there was a strikingly positive correlation between the content of organic carbon and that of organic carbon isotope (δC01213 ) which could be the substitute indicators of environmental temperature.  相似文献   

8.
利用元素分析仪和原子吸收光谱仪分析了褶纹冠蚌(Cristaria plicata Leach)的四个不同培育阶段的珍珠的十三种元素的含量,以期从连续动态的角度探讨珍珠的形成机制。结果表明,随着育珠时间的延长,珍珠中Ca元素的含量是逐渐增加的,C和H元素的含量则是逐渐下降的。在微量元素中,Na、Cu、Zn、Mg和Sr的含量比较高,其中Na在晚期的珍珠中的含量显著高于早期的珍珠,而CuZn、Mg等其它微量元素则是在早期珍珠中的含量明显高于晚期珍珠,它们随着育珠时间的延长呈指数下降。  相似文献   

9.
The concentrations of major elements and some trace elements were determined at 8 core locations in Taihu Lake. The chemical composition of the cores was related to the sediment particle size-chronology and location of sampling site.Concentrations of Al, Mg, K, Ca and Na, the major mineral species in the sediments, were generally uniform, with only slight fluctuation influenced by water waves and current. Surface enrichment of Cu, Zn, and Ni at some locations was observed to be greater than that of the sediments accumulated 100 years ago. The enrichment of these elements is attributed to anthropogenic input in recent years. Concentration profiles for Mn and Fe are related to the migration of these elements in the pore water.  相似文献   

10.
于1999年元月在海南陵水黎安港采集卡帕藻,应用HPLC、原子吸收等分析手段,系统测定其营养成分(主要包括蛋白质、氨基酸、脂肪、粗纤维、粗灰分、矿物质及微量元素等),并与其它几种大型藻类比较,综合评价卡帕藻的营养价值。结果表明卡帕藻蛋白质含量为6.20%,而粗脂肪和粗灰分较高,分别为2.88%和39.04%;卡帕藻中富含K、Na、Ca、Mg、P、Fe、Zn、Mn、Se等矿物元素,尤其是Se的含量远高于其它几种大型藻类。  相似文献   

11.
Based on the data obtained from tens of the investigated soil profiles scattered over the Fildes Peninsula, King George Island, the maritime Antarctic, the soil-forming processes were discussed. It was concluded that on the weathering crusts resulted from various physical courses, the strong freeze-thaw action within regolith, significant organic matter accumulation, evident leaching and illuviation, as well as initial argillification dominated the formation and development of the soils on the Fildes Peninsula. Furthermore, this study indicated that the juvenility of genesis, poor profile-expression, variation in column thickness, etc. characterized the pedogenetic features of the soils of the Fildes Peninsula.  相似文献   

12.
A total of 21 elements, Si, Al, K, Na, Ca, Mg, Fe, Mn, Ti, P, Cu, Co, Ni, Zn, Pb, Cr, Rb, Sr Ba, Cd and Corg(organic carbon), was determined in the trough. Average contents of most elements were found to be higher in the trough bottom than in the western and eastern slopes. We call these elements the indicator elements because of their “transition” property. This is in keeping with the “intermediate” geographical position of the trough where the continental crust turns to oceanic crust. Though the authigenic fraction of some elements here increases, the detrital fraction of most elements is still dominant, indicating that the influences of terrigenous and volcanic detrital materials on the trough sediments are still dominant. The abundant biogenous component in the trough is characterized by the increase of Ca, Sr, and Corg contents. Ca existes mainly in the form of CaCo3 that is mostly found in various shells. Sr often easily replaces Ca within the shells. A belt-shaped distribution pattern of elements was found in the south and a “block” pattern in the north trough. Such distribution patterns are directly controlled by water depth, topography, current sediment type, and mineral, biological, and volcanic processes. This paper was published in Chinese in Oceanologia et Limnologia Sinica15(4): 371–379, 1984.  相似文献   

13.
辽宁金伯利岩地质—地球化学研究结果表明,辽宁金伯利岩主元素丰度较世界金伯利岩的平均成分,显示富Ca、Al和贫K、Na、Mg、Si,碱度偏低;与南非、苏联和我国山东含金刚石金伯利岩相比,Fe 质偏高。辽宁金伯利岩含矿程度由富到贫,有 Fe、Mg 组分增高,Ca 质降低,微量元素多趋富集的总体变化趋势。辽南金伯利岩较辽北金伯利岩具有碱性程度相对偏高,V、Li、Rb、Nb、La、Sn、Mo、Cu、Pb、Zn、Ag、Ba、Cd、B、S、F 等元素相对富集,Co、Ni、Cr、Th、Bi、Au、As、Sb、Hg、Sr 等元素相对贫化的特点。二者的元素组合和相关特征有明显差别。辽南金伯利岩 Na、Ca、Mn 3元素的相关组合特征是富、贫(中)金刚石金伯利岩的一个地球化学标志。  相似文献   

14.
作者利用全省不同地质时代和不同地质构造单元内的页岩41种元素的分析数据,计算出辽宁省全域内的页岩元素丰度休系。同时探讨了元素从中、晚元古代至中生代的演化规律,指出Ca、Cd、Sb、As、Na、Mn、P、Sr的元素丰度随时间序列的演化不断增长,B、F、K、Rb、W、Mg则显示出降低的趋势。某些元素比值从老至新表现出明显的规律性变化,如Sr/Ba、Ca/Mg值的演化具有阶段性,K/Na、Th/U值的演化具有方向性,Al/Ti值的演化则具有周期性。  相似文献   

15.
通过对山东省巨野县土壤元素背景值状况的计算和研究,发现土壤中Ca,Cd,Hg,Mg,F等元素显著高于全省和全国背景值;Mo,Pb,Cu,Co等元素则低于全省和全国背景值;其中土壤Mo含量远低于全省和全国平均水平。土壤质地是决定区内土壤N,K,Mg等元素含量的关键;由黄河冲积物发育的土壤P含量普遍较高,TOC空间分布与N密切相关。城镇及工业区土壤中Hg和Pb的积累趋势明显。元素分级结果显示,区内土壤K和有机质比较丰富;N,P和有机质缺乏区占比分别为23.82%,15.39%和6.47%。微量元素中Ca,Mg,S,Cl等元素较为丰富;而Mo,Si,Se,Co,Zn,Cu,Fe,Mn等元素的缺乏状况最突出。土地质量地球化学评价分等结果显示,全区大部分土地质量优良,区内东北部和中西部地区土壤肥力较好,但有害元素含量偏高,西北部地区肥力较差导致土地质量等级偏低。全区土壤有机质含量不足以满足农业生产需要,加之局部土壤盐分偏高,对粮食作物生长不利。区内土壤环境质量水平总体较好,多数重金属元素分布受地质背景控制,但Hg和Pb污染位置与城镇及工业区分布明显存在一定关系,高值区多呈点状分布于人类活动强烈的地带,说明工业或生活排放对区内土壤中Hg,Pb的积累贡献较大。  相似文献   

16.
A method was developed for content determination of Na, Mg, A1, Si, P,S, C1, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Nb, Zr, Y, Sr, Rb, Ba, La and Ce etc. covering 26 major, minor, and trace elements in marine sediment samples using fused glass disc by X-ray Fluorescence spectrometry. Calibration was made using marine sediment certified reference materials and the synthetic standard samples prepared by mixing several marine sediments with stream sediment and carbonate standard samples in different proportions. The matrix effect was corrected using theoretical alpha coefficients, experience coefficients and the scattered radiation as the internal standard (for the trace elements). The accuracy of the method was evaluated by analysis of certified reference materials GBW07314, GBW07334 and GSMS6. The results are in good agreement with the certified values of the standards with RSD less than 2.60%, except for Y, Cr, Ga, Ce, La, Nb, Rb, and V with RSD less than 9.0% (n=12).  相似文献   

17.
Huang  Yuhuan  Sun  Chengjun  Yang  Guipeng  Yue  Xin&#;an  Jiang  Fenghua  Cao  Wei  Yin  Xiaofei  Guo  Chaonan  Niu  Jiaohong  Ding  Haibing 《中国海洋湖沼学报》2020,38(3):650-664
Journal of Oceanology and Limnology - Two sediment cores were retrieved in the hadal zone of the Yap Trench, and their concentrations of six major elements Mg, Al, Ca, Ti, Mn and Fe and nine trace...  相似文献   

18.
Sediment samples obtained from the South Mid-Atlantic Ridge were analyzed for the major and trace elements by inductively coupled plasma atomic emission spectroscopy and inductively coupled plasma mass spectrometry. Results revealed that the contents of elements (e.g., Fe, Mn, Cu, Zn, V, Co) were high in samples 22V-TVG10 and 26V-TVG05 from the sites near the hydrothermal areas, and low in sample 22V-TVG14, which was collected far from the hydrothermal areas. The contents of Ca, Sr and Ba in the samples showed opposite trends. A positive correlation between the concentrations of metallic elements (Cu, Zn, Co, Ni, Pb, V) and Fe in the samples were observed. These results are consistent with chemical evolution of the dispersing hydrothermal plume.  相似文献   

19.
阿扎鲁岩体分布于哀牢山构造岩浆岩带中,通过野外地质调查与岩体剖面测量、岩石样品采集分析、薄片显微镜下鉴定等手段与方法,对其野外地质特征、岩石学特征及岩石地球化学特征进行了系统研究,并探讨了其形成的构造环境。研究结果表明,阿扎鲁岩体的岩性为花岗岩,岩体分布明显受断裂控制;岩石局部可见后期变质的片岩及糜棱岩,岩石具浅层侵入的特点;阿扎鲁花岗岩的A/NCK多大于1.0,为铝饱和型;具有富硅钾、低钙、贫铁、镁、钛的特点,岩石为高钾钙碱性系列。其主量元素、微量元素及稀土元素地球化学特征均表明,该岩体形成于造山期碰撞后期的弧陆碰撞阶段。   相似文献   

20.
本文首次报道海南省产的四种江蓠属中的藻类的十一种微量元素含量与测定方法。  相似文献   

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