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1.
The Visible and Infrared Spectrometer (VIR) instrument on the Dawn mission observed Ceres’s surface at different spatial resolutions, revealing a nearly uniform global distribution of surface mineralogy. Clearly, Ceres experienced extensive water‐related processes and chemical differentiation. The surface is mainly composed of a dark component (carbon, magnetite?), Mg‐phyllosilicates, ammoniated clays, carbonates, and salts. The observed species suggest endogenous, global‐scale aqueous alteration. While mostly uniform at regional scale, Ceres’s surface shows small localized areas with different species and/or variations in abundances. Few local exposures of water ice are seen, especially at higher latitudes. Sodium carbonates have been identified in several areas on the surface, notably in Occator bright faculae. Organic matter has also been discovered in several places, most conspicuously in a large area close to the Ernutet crater. The observed mineralogies, with the presence of ammoniated species and sodium salts, have a strong resemblance to materials found on other bodies of the outer solar system, such as Enceladus. This poses some questions about the original material from which Ceres accreted, suggesting a colder environment for such material with respect to Ceres’s present position.  相似文献   

2.
The formation of hydrated salts is an expected consequence of aqueous alteration of Main Belt objects, particularly for large, volatile‐rich protoplanets like Ceres. Sulfates, present on water‐bearing planetary bodies (e.g., Earth, Mars, and carbonaceous chondrite parent bodies) across the inner solar system, may contribute to Ceres’ UV and IR spectral signature along with phyllosilicates and carbonates. We investigate the presence and stability of hydrated sulfates under Ceres’ cryogenic, low‐pressure environment and the consequent spectral effects, using UV–Vis–IR reflectance spectroscopy. H2O loss begins instantaneously with vacuum exposure, measured by the attenuation of spectral water absorption bands, and a phase transition from crystalline to amorphous is observed for MgSO4·6H2O by X‐ray powder diffraction. Long‐term (>40 h), continuous exposure of MgSO4·nH2O (n = 0, 6, 7) to low pressure (10?3–10?6 Torr) causes material decomposition and strong UV absorption below 0.5 μm. Our measurements suggest that MgSO4·6H2O grains (45–83 μm) dehydrate to 2% of the original 1.9 μm water band area over ~0.3 Ma at 200 K on Ceres and after ~42 Ma for 147 K. These rates, inferred from an Avrami dehydration model, preclude MgSO4·6H2O as a component of Ceres’ surface, although anhydrous and minimally hydrated sulfates may be present. A comparison between Ceres emissivity spectra and laboratory reflectance measurements over the infrared range (5–17 μm) suggests sulfates cannot be excluded from Ceres’ mineralogy.  相似文献   

3.
The geologic context of red organic‐rich materials (ROR) found across an elongated 200 km region on Ceres is evaluated with spectral information from the multispectral framing camera (FC) and the visible and near‐infrared mapping spectrometer (VIR) of Dawn. Discrete areas of ROR materials are found to be associated with small fresh craters less than a few hundred meters in diameter. Regions with the highest concentration of discrete ROR areas exhibit a weaker diffuse background of ROR materials. The observed pattern could be consistent with a field of secondary impacts, but no appropriate primary crater has been found. Both endogenic and exogenic sources are being considered for these distinctive organic materials.  相似文献   

4.
Impact crater Dantu not only exhibits a very complex geological history but also shows an exceptional heterogeneity of its surface composition. Because of its location within a low‐lying region named Vendimia Planitia, which has been proposed to represent an ancient impact basin, Dantu possibly offers a window into the composition of Ceres’s deeper crust, which apparently is enriched in ammonia. Local concentration of carbonates within Dantu or its ejecta blanket may be either exposed or their emplacement induced by the Dantu impact event. Because carbonates can be seen along Dantu's crater walls, exposed due to recent slumping, but also as fresh spots or clusters of spots scattered across the surface, the deposition/formation of carbonates took place over a long time period. The association of several bright spots enriched in carbonates with sets of fractures on Dantu's floor might be accidental. Nevertheless, its morphological and compositional similarity to the faculae in Ceres’s prominent impact crater Occator including its hydrated state does not exclude a cryo‐volcanic origin, i.e., upwelling of carbonate‐enriched brines influenced by H2O ice in the subsurface. Indeed, an isolated H2O ice spot can be identified near Dantu, which shows that ice still exists in Ceres’s subsurface at midlatitudes and that it can exist on the surface for a longer period of time.  相似文献   

5.
Mg‐phyllosilicate‐bearing, dark surface materials on the dwarf planet Ceres have NH4‐bearing materials, indicated by a distinctive 3.06 μm absorption feature. To constrain the identity of the Ceres NH4‐carrier phase(s), we ammoniated ground particulates of candidate materials to compare their spectral properties to infrared data acquired by Dawn's Visible and Infrared (VIR) imaging spectrometer. We treated Mg‐, Fe‐, and Al‐smectite clay minerals; Mg‐serpentines; Mg‐chlorite; and a suite of carbonaceous meteorites with NH4‐acetate to exchange ammonium. Serpentines and chlorites showed no evidence for ammoniation, as expected due to their lack of exchangeable interlayer sites. Most smectites showed evidence for ammoniation by incorporation of NH4+ into their interlayers, resulting in the appearance of absorptions from 3.02 to 3.08 μm. Meteorite samples tested had weak absorptions between 3.0 and 3.1 μm but showed little clear evidence for enhancement upon ammoniation, likely due to the high proportion of serpentine and other minerals relative to expandable smectite phases or to NH4+ complexing with organics or other constituents. The wavelength position of the smectite NH4 absorption showed no variation between IR spectra acquired under dry‐air purge at 25 °C and under vacuum at 25 °C to ?180 °C. Collectively, data from the smectite samples show that the precise center wavelength of the characteristic ~3.05 μm v3 absorption in NH4 is variable and is likely related to the degree of hydrogen bonding of NH4‐H2O complexes. Comparison with Dawn VIR spectra indicates that the hypothesis of Mg‐saponite as the ammonium carrier phase is the simplest explanation for observed data, and that Ceres dark materials may be like Cold Bokkeveld or Tagish Lake but with proportionally more Mg‐smectite.  相似文献   

6.
As the Dawn mission approaches a successful conclusion at Ceres, it seems time to assess how its findings have sharpened the picture of Ceres’s evolution. Before Dawn, we inferred from Ceres's bulk density of about 2100 kg m?3 that Ceres contained about 25% water by mass. Thermodynamic modeling of the interior evolution suggested that the original accreted ice had to melt even if only long‐lived radionuclides were present, leading to the aqueous alteration of the original chondritic silicates and differentiation of the altered silicates from any remaining water, consistent with telescopic detection of aqueously altered silicates (serpentine and clay minerals) on Ceres’s surface. Earth‐based observations of Ceres’s shape were not accurate enough to constrain the extent of differentiation of its interior. Dawn's results confirm these early findings and extend them dramatically to reveal an evolved and active small planet, probably even today, due to water/ice‐driven processes. A nearly uniform global distribution of surface mineralogy, which includes Mg‐serpentines, ammoniated clays, and salts including carbonates, suggests extensive, endogenous, planet‐wide aqueous alteration. Local exceptions show salt‐rich deposits of varied composition, which suggests subsurface heterogeneities. Concentration of Fe below carbonaceous chondrite levels suggests chemical fractionation, leading to Ceres being chemically differentiated. The high spatial uniformity of element abundance measurements of equatorial regolith also indicates that some ice‐rock fractionation occurred on a global scale. Even some local exposures of ice are seen, especially in higher latitudes and in low‐illumination regions that must be very young, as surface water ice is unstable on time scales of 1–1000 years under Ceres’s surface temperatures. Subsurface ice is also likely in abundance at higher latitudes in at least the upper few meters of the surface, as suggested by near‐surface H‐rich polar deposits. Observations of bright ice deposits in permanently shadowed regions suggest cold‐trapping of migrating H2O across the surface. Gravity field measurements indicate a concentration of mass toward the center and near isostatic equilibrium, consistent with at least some mass differentiation driven by water‐related processes. Abundant small and midsize craters but relaxed or missing large craters suggest a stiff upper crust with water abundance lower than 30 vol%. A sharp decrease in viscosity at ~40 km depth suggests the occurrence of a small fraction of liquid, consistent with earlier thermophysical models. Surface cryogenic features, such as flows, extrusions, and domes, some geologically very recent, are evidence of active water/ice‐driven subsurface processes. Ceres experienced extensive water‐related processes and at least some mass and chemical fractionation and is probably active today, consistent with previous moderate heating thermodynamic models. Clearly, Ceres is a “wet,” evolved planet at the edge of the inner solar system, as described in this special issue. We conclude with a list of questions suggested by the Dawn findings; they especially regard the state and fate of water and its role in driving past and possibly current chemical and physical activity in this dwarf planet.  相似文献   

7.
Ceres’ surface has commonly been linked with carbonaceous chondrites (CCs) by ground‐based telescopic observations, because of its low albedo, flat to red‐sloped spectra in the visible and near‐infrared (VIS/NIR) wavelength region, and the absence of distinct absorption bands, though no currently known meteorites provide complete spectral matches to Ceres. Spatially resolved data of the Dawn Framing Camera (FC) reveal a generally dark surface covered with bright spots exhibiting reflectance values several times higher than Ceres’ background. In this work, we investigated FC data from High Altitude Mapping Orbit (HAMO) and Ceres eXtended Juling (CXJ) orbit (~140 m/pixel) for global spectral variations. We found that the cerean surface mainly differs by spectral slope over the whole FC wavelength region (0.4–1.0 μm). Areas exhibiting slopes ?1 constitute only ~3% of the cerean surface and mainly occur in the bright material in and around young craters, whereas slopes ≥?10% μm?1 occur on more than 90% of the cerean surface; the latter being denoted as Ceres’ background material in this work. FC and Visible and Infrared Spectrometer (VIR) spectra of this background material were compared to the suite of CCs spectrally investigated so far regarding their VIS/NIR region and 2.7 μm absorption, as well as their reflectance at 0.653 μm. This resulted in a good match to heated CI Ivuna (heated to 200–300 °C) and a better match for CM1 meteorites, especially Moapa Valley. This possibly indicates that the alteration of CM2 to CM1 took place on Ceres.  相似文献   

8.
The mineralogy of a planetary surface is a diagnostic product of its formation and geologic evolution. Global assessment of lunar mineralogy at high spatial resolution has been a long standing goal of lunar exploration. Currently, the only global data available for such study is multispectral imagery from the Clementine mission. We use the detailed compositional, petrographic, and spectroscopic data of lunar soils produced by the Lunar Soil Characterization Consortium to explore the use of multispectral imaging as a diagnostic tool. We compare several statistically optimized formulations of links between spectral and mineral parameters and apply them to Clementine UV-VIS data. The most reliable results are for estimations of pyroxene abundance and maturity parameters (agglutinate abundance, Is/FeO). Estimations of different pyroxene composition (low-Ca versus high-Ca) appear good in a relative sense, but absolute values are limited by residual wavelength dependent Clementine photometric calibrations. Since the signal-to-noise of Clementine multispectral data is good at the 1-km scale, almost any combination of parameters that capture inherent spectral variance can provide spatially coherent maps, although the parameters may not actually be directly related to composition. Clementine estimates are useful for identifying scientific or exploration targets for imaging spectrometer sensors of the next generation that are specifically designed to characterize mineralogy.  相似文献   

9.
Abstract– We present a case modeling study of impact crater formation in H2O‐bearing targets. The main goal of this work was to investigate the postimpact thermal state of the rock layers modified in the formation of hypervelocity impact craters. We present model results for a target consisting of a mixture of H2O‐ice and rock, assuming an ice/water content variable with depth. Our model results, combined with results from previous work using dry targets, indicate that for craters larger than about 30 km in diameter, the onset of postimpact hydrothermal circulation is characterized by two stages: first, the formation of a mostly dry, hot central uplift followed by water beginning to flow in and circulate through the initially dry and hot uplifted crustal rocks. The postimpact thermal field in the periphery of the crater is dependent on crater size: in midsize craters, 30–50 km in diameter, crater walls are not strongly heated in the impact event, and even though ice present in the rock may initially be heated enough to melt, overall temperatures in the rock remain below melting, undermining the development of a crater‐wide hydrothermal circulation. In large craters (with diameters more than 100 km or so), the region underneath the crater floor and walls is heated well above the melting point of ice, thus facilitating the onset of an extended hydrothermal circulation. These results provide preliminary constraints in characterizing the many water‐related features, both morphologic and spectroscopic, that high‐resolution images of Mars are now detecting within many Martian craters.  相似文献   

10.
The mineralogy and geochemistry of Ceres, as constrained by Dawn's instruments, are broadly consistent with a carbonaceous chondrite (CM/CI) bulk composition. Differences explainable by Ceres’s more advanced alteration include the formation of Mg‐rich serpentine and ammoniated clay; a greater proportion of carbonate and lesser organic matter; amounts of magnetite, sulfide, and carbon that could act as spectral darkening agents; and partial fractionation of water ice and silicates in the interior and regolith. Ceres is not spectrally unique, but is similar to a few other C‐class asteroids, which may also have suffered extensive alteration. All these bodies are among the largest carbonaceous chondrite asteroids, and they orbit in the same part of the Main Belt. Thus, the degree of alteration is apparently related to the size of the body. Although the ammonia now incorporated into clay likely condensed in the outer nebula, we cannot presently determine whether Ceres itself formed in the outer solar system and migrated inward or was assembled within the Main Belt, along with other carbonaceous chondrite bodies.  相似文献   

11.
The extent of impact‐generated hydrothermal activity in the 24 km sized Ries impact structure has been controversially discussed. To date, mineralogical and isotopic investigations point to a restriction of hydrothermal activity to the impact‐melt bearing breccias, specifically the crater‐fill suevite. Here, we present new petrographic, geochemical, and isotopic data of postimpact carbonate deposits, which indicate a hydrothermal activity more extended than previously assumed. Specifically, carbonates of the Erbisberg, a spring mound located upon the inner crystalline ring of the crater, show travertine facies types not seen in any of the previously investigated sublacustrine soda lake spring mounds of the Ries basin. In particular, the streamer carbonates, which result from the encrustation of microbial filaments in subaerial spring effluents between 60 and 70 °C, are characteristic of a hydrothermal origin. While much of the primary geochemical and isotopic signatures in the mound carbonates have been obliterated by diagenesis, a postimpact calcite vein from brecciated gneiss of the subsurface crater floor revealed a flat rare earth element pattern with a clear positive Eu anomaly, indicating a hydrothermal fluid convection in the crater basement. Finally, the strontium isotope stratigraphic correlation of the travertine mound with the crater basin succession suggests a hydrothermal activity for about 250,000 yr after the impact, which would be much longer than previously assumed.  相似文献   

12.
M. Parente  J.L. Bishop 《Icarus》2009,203(2):421-436
The objective of this work is to propose an automated unmixing technique for the analysis of 11-channel Mars Exploration Rover Panoramic Camera (MER/Pancam) spectra. Our approach is to provide a screening tool for identifying unique/distinct reflectance spectra. We demonstrate the utility of this unmixing technique in a study of the mineralogy of the bright salty soils exposed by the rover wheels in images of Gusev crater regions known as Paso Robles (Sols 400,426), Arad (Sol 721), and Tyrone (Sol 790). The unmixing algorithm is based on a novel derivation of the Nonnegative Matrix Factorization technique and includes added features that preclude the adverse effects of low abundance materials that would otherwise skew the unmixing. In order to create a full 11-channel spectrum out of the left and right eye stereo pairs, we also developed a new registration procedure that includes rectification and disparity calculation of the images. We identified two classes of endmember spectra for the bright soils imaged on Sols 426 and 790. One of these endmember classes is also observed for soils imaged on Sols 400 and 721 and has a unique spectral shape that is distinct from most iron oxide, sulfate and silicate spectra and differs from typical martian surface spectra. Instead, its unique spectral character resembles the spectral shape of the ferric sulfate minerals fibroferrite (Fe3+(SO4)(OH) · 5H2O) and ferricopiapite and the phosphate mineral ferristrunzite . The other endmember class is less consistent with specific minerals and is likely a mixture of altered volcanic material and some bright salts. Further analyses of data from Sols 400 and 790 using an anomaly detection algorithm as a tool for detecting low abundance materials additionally suggests the identification of the sulfate mineral paracoquimbite (Fe2(SO4)3 · 9H2O). This spectral study of Pancam images of the bright S- and P-enriched soils of Gusev crater identifies specific ferric sulfate and ferric phosphate minerals that are consistent with the unique spectral properties observed here in the 0.4-1 μm range.  相似文献   

13.
Abstract– The 3.8 km Steinheim Basin in SW Germany is a complex impact crater with central uplift hosted by a sequence of Triassic to Jurassic sedimentary rocks. It exhibits a well‐preserved crater morphology, intensely brecciated limestone blocks that form the crater rim, as well as distinct shatter cones in limestones. In addition, an impact breccia mainly composed of Middle to Upper Jurassic limestones, marls, mudstones, and sandstones is known from drilling into the impact crater. No impact melt lithologies, however, have so far been reported from the Steinheim Basin. In samples of the breccia that were taken from the B‐26 drill core, we discovered small particles (up to millimeters in size) that are rich in SiO2 (～50 wt%) and Al2O3 (～28 wt%), and contain particles of Fe‐Ni‐Co sulfides, as well as target rock clasts (shocked and unshocked quartz, feldspar, limestone) and droplet‐shaped particles of calcite. The particles exhibit distinct flow structures and relicts of schlieren and vesicles. From the geochemical composition and the textural properties, we interpret these particles as mixed silicate melt fragments widely recrystallized, altered, and/or transformed into hydrous phyllosilicates. Furthermore, we detected schlieren of lechatelierite and recrystallized carbonate melt. On the basis of impactite nomenclature, the melt‐bearing impact breccia in the Steinheim Basin can be denominated as Steinheim suevite. The geochemical character of the mixed melt particles points to Middle Jurassic sandstones (“Eisensandstein” Formation) that crop out at the center of the central uplift as the source for the melt fragments.  相似文献   

14.
A principal goal of the Lunar Soil Characterization Consortium (LSCC) is to evaluate tools that might be successfully used in remote compositional analysis of the lunar surface. Mathematical methods are extremely valuable to assess whether variations exist in a statistically significant manner, independent of their interpretation. The bounds of widely used correlation of visible to near-infrared spectral parameters with composition are first defined and evaluated. We then evaluate direct (or indirect) links between the combined spectral properties of lunar mare soils and their compositional properties (elemental abundance and mineralogy) through a statistical analysis of the variance across each measurement using principal component analysis (PCA). We first separately analyze LSCC elemental abundance, mineralogy, and spectroscopy data (0.35 to 2.5 μm) using PCA to capture the variance of each system with a relatively small number of independent variables. With this compact set of independent variables for each type of data, we derive functions to link composition and spectroscopy. For these mare soils, one of the best empirical predictive capability is that for FeO. This is not surprising since the effect of ferrous iron on optical properties is well documented. Although Al2O3 has no direct effect on optical properties, its strong anticorrelation with FeO also produces a relatively high predictive capability from spectra. Similarly, a high accuracy in predicting the abundance of pyroxene is observed and should be expected since iron-bearing pyroxene is one of the most optically active components of lunar soil. The accuracy for predicting either TiO2 or ilmenite, on the other hand, is disappointing. High- and low-Ti soils are readily distinguished, but these statistics suggest that making subclass distinctions based on spectral predictions of TiO2 would be risky.  相似文献   

15.
Abstract— The 40 km diameter Mjølnir Crater is located on the central Barents Sea shelf, north of Norway. It was formed about 142 ± 2.6 Myr ago by the impact of a 1–2 km asteroid into the shallow shelf clays of the Hekkingen Formation and the underlying Triassic to Jurassic sedimentary strata. A core recovered from the central high within the crater contains slump and avalanche deposits from the collapse of the transient crater and central high. These beds are overlain by gravity flow conglomerates, with laminated shales and marls on top. Here, impact and post‐impact deposits in this core are studied with focus on clay mineralogy obtained from XRD decomposition and simulation analysis methods. The clay‐sized fractions are dominated by kaolinite, illite, mixed‐layered clay minerals and quartz. Detailed analyses showed rather similar composition throughout the core, but some noticeable differences were detected, including varying crystal size of kaolinite and different types of illites and illite/smectite. These minerals may have been formed by diagenetic changes in the more porous/fractured beds in the crater compared to time‐equivalent beds outside the crater rim. Long‐term post‐impact changes in clay mineralogy are assumed to have been minor, due to the shallow burial depth and minor thermal influence from impact‐heated target rocks. Instead, the clay mineral assemblages, especially the abundance of chlorite, reflect the impact and post‐impact reworking of older material. Previously, an ejecta layer (the Sindre Bed) was recognized in a nearby well outside the crater, represented by an increase in smectite‐rich clay minerals, genetically equivalent to the smectite occurring in proximal ejecta deposits of the Chicxulub crater. Such alteration products from impact glasses were not detected in this study, indicating that little, if any, impact glass was deposited within the upper part of the crater fill. Crater‐fill deposits inherited their mineral composition from Triassic and Jurassic sediments underlying the impact site.  相似文献   

16.
The highly hydrated, petrologic type 1 CM and CI carbonaceous chondrites likely derived from primitive, water‐rich asteroids, two of which are the targets for JAXA's Hayabusa2 and NASA's OSIRIS‐REx missions. We have collected visible and near‐infrared (VNIR) and mid infrared (MIR) reflectance spectra from well‐characterized CM1/2, CM1, and CI1 chondrites and identified trends related to their mineralogy and degree of secondary processing. The spectral slope between 0.65 and 1.05 μm decreases with increasing total phyllosilicate abundance and increasing magnetite abundance, both of which are associated with more extensive aqueous alteration. Furthermore, features at ~3 μm shift from centers near 2.80 μm in the intermediately altered CM1/2 chondrites to near 2.73 μm in the highly altered CM1 chondrites. The Christiansen features (CF) and the transparency features shift to shorter wavelengths as the phyllosilicate composition of the meteorites becomes more Mg‐rich, which occurs as aqueous alteration proceeds. Spectra also show a feature near 6 μm, which is related to the presence of phyllosilicates, but is not a reliable parameter for estimating the degree of aqueous alteration. The observed trends can be used to estimate the surface mineralogy and the degree of aqueous alteration in remote observations of asteroids. For example, (1) Ceres has a sharp feature near 2.72 μm, which is similar in both position and shape to the same feature in the spectra of the highly altered CM1 MIL 05137, suggesting abundant Mg‐rich phyllosilicates on the surface. Notably, both OSIRIS‐REx and Hayabusa2 have onboard instruments which cover the VNIR and MIR wavelength ranges, so the results presented here will help in corroborating initial results from Bennu and Ryugu.  相似文献   

17.
The origin and nature of the early atmosphere of Mars is still debated. The discovery of sulfate deposits on the surface, coupled with the evidence that there are not large abundances of carbonates detectable on Mars in the optically accessible part of the regolith, leaves open different paleoclimatic evolutionary pathways. Even if carbonates are responsible for the feature observed by TES and Mini-TES at 6.76 μm, alternative hypotheses suggest that it could be due to the presence of Hydrated Iron Sulfates (HIS). Carbonates can be discerned from HIS by investigating the spectral region in which a strong overtone carbonate band is present. The Planetary Fourier Spectrometer on board the Mars Express spacecraft has acquired several thousand martian spectra in the range 1.2-45 μm since January 2004, most of which show a weak absorption feature between 3.8 and 4 μm. A similar feature was observed previously from the Earth, but its origin could not be straightforwardly ascribed to surface materials, and specifically to carbonates. Here we show the surficial nature of this band that can be ascribed to carbonate mixed with the martian soil materials. The materials that best reproduce the detected feature are Mg-rich carbonates (huntite [CaMg3(CO3)4] and/or magnesite [MgCO3]). The presence of carbonates is demonstrated in both bright and dark martian regions. An evaluation of the likeliest abundance gives an upper limit of ∼10 wt%. The widespread distribution of carbonates supports scenarios that suggest carbonate formation occurred not by precipitation in a water-rich environment but by weathering processes.  相似文献   

18.
In this work we investigate p‐mode power variation with solar atmosphere. To this aim, we use THÉMIS observations of the Na D1 (λ 5896 Å) and K (λ 7699 Å) spectral lines. While the formation heights of the K spectral line are essentially located in the photospheric layer, the formation heights of the Na D1 line span a much wider region: from photosphere up to chromosphere. Hence, we had the opportunity to infer p‐mode power variation up to the chromospheric layer. By analyzing power spectra obtained by temporal series at different points of the Na D1 and K spectral lines, we confirm and quantify the increase in p‐mode power towards higher atmospheric layers. Furthermore, the large span in formation heights of the Na D1 line induces a larger enhancement of p‐mode power with solar atmosphere compared to the K spectral line. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   

19.
An assemblage with FeNi metal, troilite, Fe‐Mn‐Na phosphate, and Al‐free chromite was identified in the metal‐troilite eutectic nodules in the shock‐produced chondritic melt of the Yanzhuang H6 meteorite. Electron microprobe and Raman spectroscopic analyses show that a few phosphate globules have the composition of Na‐bearing graftonite (Fe,Mn,Na)3(PO4)2, whereas most others correspond to Mn‐bearing galileiite Na(Fe,Mn)4(PO4)3 and a possible new phosphate phase of Na2(Fe,Mn)17(PO4)12 composition. The Yanzhuang meteorite was shocked to a peak pressure of 50 GPa and a peak temperature of approximately 2000 °C. All minerals were melted after pressure release to form a chondritic melt due to very high postshock heat that brought the chondrite material above its liquidus. The volatile elements P and Na released from whitlockite and plagioclase along with elements Cr and Mn released from chromite are concentrated into the shock‐produced Fe‐Ni‐S‐O melt at high temperatures. During cooling, microcrystalline olivine and pyroxene first crystallized from the chondritic melt, metal‐troilite eutectic intergrowths, and silicate melt glass finally solidified at about 950–1000 °C. On the other hand, P, Mn, and Na in the Fe‐Ni‐S‐O melt combined with Fe and crystallized as Fe‐Mn‐Na phosphates within troilite, while Cr combined with Fe and crystallized as Al‐free chromite also within troilite.  相似文献   

20.
CV (Vigarano type) carbonaceous chondrites, comprising Allende‐like (CVoxA) and Bali‐like (CVoxB) oxidized and reduced (CVred) subgroups, experienced differing degrees of fluid‐assisted thermal and shock metamorphism. The abundance and speciation of secondary minerals produced during asteroidal alteration differ among the subgroups: (1) ferroan olivine and diopside–hedenbergite solid solution pyroxenes are common in all CVs; (2) nepheline and sodalite are abundant in CVoxA, rare in CVred, and absent in CVoxB; (3) phyllosilicates and nearly pure fayalite are common in CVoxB, rare in CVred, and virtually absent in CVoxA; (4) andradite, magnetite, and Fe‐Ni‐sulfides are common in oxidized CVs, but rare in reduced CVs; the latter contain kirschsteinite instead. Thus, a previously unrecognized correlation exists between meteorite bulk permeabilities and porosities with the speciation of the Ca‐, Fe‐rich silicates (pyroxenes, andradite, kirschsteinite) among the CVox and CVred meteorites. The extent of secondary mineralization was controlled by the distribution of water ices, permeability, and porosity, which in turn were controlled by impacts on the asteroidal parent body. More intense shock metamorphism in the region where the reduced CVs originated decreased their porosity and permeability while simultaneously expelling intergranular ices and fluids. The mineralogy, petrography, and bulk chemical compositions of both the reduced and oxidized CV chondrites indicate that mobile elements were redistributed between Ca,Al‐rich inclusions, dark inclusions, chondrules, and matrices only locally; there is no evidence for large‐scale (>several cm) fluid transport. Published 53Mn‐53Cr ages of secondary fayalite in CV, CO, and unequilibrated ordinary chondrites, and carbonates in CI, CM, and CR chondrites are consistent with aqueous alteration initiated by heating of water ice‐bearing asteroids by decay of 26Al, not shock metamorphism.  相似文献   

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