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1.
The dissociative recombination coefficients α for capture of electrons by H3+ and H5+ ions have been determined as a function of electron temperature Te using a microwave afterglow-mass spectrometer apparatus. At ion and neutral temperatures Tu+ = Tn = 240 K, the coefficient α (H3+) is found to vary slowly with Te at first, decreasing from 1.6 × 10?7 cm3/s at Te = 240 K to 1.2 × 10?7 cm3/s at Te = 500 K, thereafter falling as Te?1 over the range 500 K ? Te, ? 3000 K. These results, which have a ± 20% uncertainty, agree satisfactorily over the common energy range (0.03–0.36 eV) with the recombination cross sections determined in merged beam measurements by Auerbach et al. At T+ = Tn = 128 K, the coefficient α(H5+) is found to be (1.8 ± 0.3) × 10?6 [Te(K)/300]?0.69 cm3/s over the range 128 K ? Te ? 3000 K, with a more rapid decrease, as Te?1, between 3000 K and 5500 K. The implications of these results for modelling planetary atmospheres and interstellar clouds are briefly touched on.  相似文献   

2.
Following our recently published measurements of the rate coefficients for mutual neutralization, α, of the ionospherically important reactions NO+ + NO2?(α1) and NO+ + NO3?(α2) carried out in ion-ion flowing afterglow plasmas at 300 K, we have determined the mutual neutralization rates for the water cluster ion H3O+ · (H2O)3 with a mixture of several negative ions which are known to exist in the D region. The α coefficients for these cluster ion reactions do not differ significantly from alpha;1 and α2, all of these reactions having α ?6 × 10?8 cm3/sec which is significantly smaller than values usually adopted in ionospheric calculations. Current information on the ionic composition of the D region and the implications of the present results to de-ionization rate calculations are discussed.  相似文献   

3.
A model of the predawn bulge ionosphere composition and structure is constructed and compared with the ion mass spectrometer measurements from the Pioneer Venus Orbiter during orbits 117 and 120. Particular emphasis is given to the identification of the mass-2 ion which we find unequivocally due to D+ (and not H2+). The atmospheric D/H ratio of 1.4% and 2.5% is obtained at the homopause (～ 130 km) for the two orbits. The H2+ contribution to the mass-2 ion density is less than 10%, and the H2 mixing ratio must be <0.1 ppm at 130 km altitude. The He+ data require a downward He+ flux of ～2 × 107 cm?2 sec?1 in the predawn region which suggest that the light ions also flow across the terminator from day to night along with the observed O+ ion flow.  相似文献   

4.
Loss processes which remove Si+ ions selectively relative to other meteor-derived atomic ions in the E- and D-regions of the ionosphere have been identified and measured in the laboratory. The major Si+ loss in the E-region is the reaction Si+ + H2O → HSiO+ + H (1) with a rate constant 2.3 ± 0.9 × 10?10 cm3s?1 at 300 K. The corresponding reactions with Fe+, Mg+ and other metallic meteor ions are endothermic. Presumably (1) is followed by a fast dissociative-recombination with electrons to produce neutral SiO or Si. At lower altitudes Si+ ions associate in a three-body reaction with O2 with a much larger rate constant than the corresponding associations of Fe+ and Mg+ with O2.  相似文献   

5.
S.K. Atreya  T.M. Donahue 《Icarus》1975,24(3):358-362
Model ionospheres are calculated for Saturn, Uranus, and Neptune. Protons are the major ions above 150 km altitude measured from a reference level where the hydrogen density is 1 × 1016 molecules cm?3, while below 150 km quick conversion of protons to H3+ ions by a three-body association mechanism leads to a rapid removal of ionization in dissociative recombination of H3+. Electron density maxima are found at about 260 km for Saturn and Uranus and 200 km for Neptune. Present knowledge of the physical and chemical processes in the atmospheres of these planets suggests that their ionospheres probably will not be Jupiter-like.  相似文献   

6.
Nitric oxide is formed in the atmosphere through the ionization and dissociation of molecular nitrogen by galactic cosmic rays. One NO molecule is formed for each ion pair produced by cosmic ray ionization.The height-integrated input (day and night) to the lower stratosphere is of the order of 6 × 107 NO molecules cm?2/sec in the auroral zone (geomagnetic latitude Φ ? 60°) during the minimum of the sunspot cycle and 4 × 107 NO molecules cm?2/sec in the subauroral belt and auroral region (Φ? 45°) at the maximum of solar activity. The tropical production is less than 10?7 NO molecules cm?2/sec above 17 km and at the equator the production is only 3 × 106NO molecules cm?2/sec.  相似文献   

7.
Resonant scattering theory is applied to the calculation of the rate of dissociative recombination in e-NO+ collisions. For ground state ions at 300 K, the recombination rate is 4.3 × 10?7 cm3 s?1, in good agreement with the afterglow data. At higher electron temperatures, the calculated rate lies between the values measured in afterglow and trapped-ion experiments. A possible explanation of this discrepancy is offered. For vibrationally excited ions, the recombination coefficient is significantly lower than that of the ground state.  相似文献   

8.
The formation of first molecules, negative Hydrogen ions, and molecular ions in a model of the Universe with cosmological constant and cold dark matter is studied. The cosmological recombination is described in the framework of modified model of the effective 3-level atom, while the kinetics of chemical reactions is described in the framework of the minimal model for Hydrogen, Deuterium, and Helium. It is found that the uncertainties of molecular abundances caused by the inaccuracies of computation of cosmological recombination are approximately 2–3%. The uncertainties of values of cosmological parameters affect the abundances of molecules, negative Hydrogen ions, and molecular ions at the level of up to 2%. In the absence of cosmological reionization at redshift z = 10, the ratios of abundances to the Hydrogen one are 3.08 × 10–13 for H–, 2.37 × 10–6 for H2, 1.26 × 10–13 for H2+, 1.12 × 10–9 for HD, and 8.54 × 10–14 for HeH+.  相似文献   

9.
Two extreme ultraviolet (EUV) spectrophotometers flown in December 1978 on Venera 11 and Venera 12 measured the hydrogen Lyman α emission resonantly scattered in the atmosphere of Venus. Measurements were obtained across the dayside of the disk, and in the exosphere up to 50,000 km. They were analyzed with spherically symmetric models for which the radiative transfer equation was solved. The H content of the Venus atmosphere varies from optically thin to moderately thick regions. A shape fit at the bright limb allows one to determine the exospheric temperature Tc and the number density nc independently of the calibration of the instrument or the exact value of the solar flux. The dayside exospheric temperature was measured for the first time in the polar regions, with Tc = 300 ± 25°K for Venera 11 (79°S) and Tc = 275 ± 25°K (59°S) for Venera 12. At the same place, the density is nc = 4?2+3 × 104 atom.cm?3, and the integrated number density Nt from 250 to 110 km (the level of CO2 absorption) is 2.1 × 1012 atom.cm?2, a factor of 3 to 6 lower than that predicted in aeronomical models. This probably indicates that the models should be revised in the content of H-bearing molecules and should include the effect of dynamics. Across the disk the value of Nt decreases smoothly with a total variation of two from the morning side to the afternoon side. Alternately it could be a latitude effect, with less hydrogen in the polar regions. The nonthermal component if clearly seen up to 40,000 km of altitude. It is twice as abundant as at the time of Mariner 10 (solar minimum). Its radial distribution above 4000 km can be simulated by an exospheric distribution with T = 1030K and n = 103 atom.cm?3 at the exobase level. However, there are less hot atoms between 2000 and 4000 km than predicted by an ionospheric source. A by-product of the analysis is a determination of a very high solar Lyman α flux of 7.6 × 1011 photons (cm2 sec Å)?1 at line center (1 AU) in December 1978.  相似文献   

10.
Vertical profiles of electron density obtained in the vicinity of the plasmapause using the Alouette-II topside sounder have been analyzed to assess the presence of H+ flow in the topside ionosphere. The observations in the midnight sector show clearly the presence of the plasmapause; i.e. there is a sharp boundary separating the poleward regions of polar wind H+ flow and the more gentle conditions of the plasmasphere where light ions are present in abundance. In contrast, in the sunlit morning sector upwards H+ flow is deduced to be present to invariant latitudes as low as 48° (L = 2·2) in the regions normally known to be well inside the plasmasphere. The upwards H+ flux is sufficiently large (3 × 108 ions cm?2 sec?1) that the plasmapause cannot be seen in the latitudinal electron density contours of the topside ionosphere. The cause for this flow remains unknown but it may be a result of a diurnal refilling process.  相似文献   

11.
Photoionization of the upper atmosphere of Titan by sunlight is expected to produce a substantial ionospheric layer. We have solved one-dimensional forms of the mass, momentum, and energy conservation equations for ions and electrons and have obtained electron number densities of about 103 cm?3, using various model atmospheres. The significant ions in a CH4H2 atmosphere are H+, H3+, CH5+, CH5+, CH3+, and C2H5+. Electron temperatures may be as high as 1000°K, depending on the abundance of hydrogen in the high atmosphere. Interaction of the solar wind with the ionosphere is also discussed.  相似文献   

12.
Models are presented for the height distribution of various photochemically active gases in Venus' upper atmosphere. Attention is directed to the chemistry and vertical transport of odd hydrogen (H, OH, HO2, H2O2), odd oxygen (O, O3), free chlorine (Cl, ClO, ClOO, Cl2), CO, O2, H2 and H2O. Supply of O2 may play a limiting role in the formation of a possible H2SO4 cloud on Venus. The supply rate is influenced by both chemical and dynamical processes in the stratosphere, and an analysis of recent spectroscopic data for O2 implies a lower limit to the appropriate eddy coefficient of about 3 × 105 cm2/sec. The abundances of thermospheric O and CO are determined largely by vertical mixing, and an analysis of Mariner 10 measurements of Venus' Lyman α airglow suggests that the eddy coefficient in the lower thermosphere may be as large as 5 × 107cm2sec. The corresponding values for the mixing ratios of O and CO at the ionospheric peak are approximately 1 per cent. The Lyman α data could be reconciled with larger values for thermospheric O, and smaller values for the vertical eddy coefficient, if non-thermal loss processes were to play a dominant role in hydrogen escape, and if the corresponding flux were to exceed 107 atoms/cm2/sec. A sink of this magnitude would imply major depletion of Venus' atmospheric water over geologic time, and would appear to require mixing ratios of H2O in the lower atmosphere in excess of 4 × 10?4. The extensive component to the Lyman α emission measured by Mariner 5 may be due to resonance scattering of sunlight by hot atoms formed by charge transfer with O+. The H scale height, therefore, may reflect the temperature of positive ions in Venus' topside ionosphere.  相似文献   

13.
New far-infrared observations of the NH3 rotation-inversion manifolds in the spectrum of Jupiter have been inverted with the use oftthe detailed ammonia line opacity. A temperature of 160°K at a 1-bar pressure level and a temperature of 105°K for the minimum temperature of the inversion level at 0.15 bars have been derived for gaseous absorption due to NH3, H2, and He. The overall fit to the brightness temperature as a function of frequency σ is within ±1°K for 100 ≤ σ ≤ 400 cm?1 except for the centers of the NH3 rotation-inversion manifolds where for J ≥ 7 the fit is about 5°K too high. In the continuum for 400 ≤ σ ≤ 630 cm?1 the fit is within 2.5°K. Consideration of an ammonia ice haze, photodissociation of NH3 by uv radiation, NH3 abundance variation, different He/H2 ratios, and uncertainties in the data effect the temperatures at 1 bar and the temperature at the inversion layer by <7°K. The presently derived temperature at 1 bar of 160°K is consistent with Jovian interior models which can match the gravitational moment, J2.  相似文献   

14.
A study has been undertaken of the vertical fluxes of ionization in the F2 region over Millstone Hill (L = 3.2) utilizing incoherent scatter measurements of electron density, electron and ion temperatures, ion composition and vertical velocity, made over 24-hr periods twice per month during 1969. The paper presents the results for all these parameters on five representative days, and discusses the distribution of the vertical flux observed during the daytime at other times during the year.Near noon the downward flux reached a peak near 300 km with an average value of ～3 × 109 el/cm2/sec in winter and ～1.6 × 109 el/cm2/sec in summer. The difference is thought to be real and be caused by the higher loss rates prevailing in summer. Above 550 km there is usually a transition to upward flux, which appears to be fully established by 700 km and has an average value of the order of 5 × 107 l/cm2/sec. From ion composition measurements, it appears that this flux is carried almost entirely by O+ ions to at least ～900 km, as the H+ ion concentration is small (<2% at ～775 km altitude) in this region by day. While the value of the escape flux appears in fair agreement with theoretical estimates of the limiting flux for this portion of the sunspot cycle, the extremely low H+ concentrations do not appear to be in accord with existing models.The diurnal variation of the upward flux through 650 km exhibits an abrupt onset close to the time of sunrise at the 200 km level (χ = 103°). A reversal to downward flux usually begins before sunset, often in the early afternoon.  相似文献   

15.
A model is presented for the photochemistry of PH3 in the upper troposphere and lower stratosphere of Saturn that includes the effects of coupling with NH3 and hydrocarbon photochemistry, specifically the C2H2 catalyzed photodissociation of CH4. PH3 is rapidly depleted with altitude (scale height ～35 km) in the upper troposphere when K～104cm2sec?1; an upper limit for K at the tropopause is estimated at ～105cm2sec?1. If there is no gas phase P2H4 because of sublimation, P2 and P4 formation is unlikely unless the rate of the spin-forbidden recombination reaction PH + H2 + M → PH3 + M is exceedingly slow. An upper limit P4 column density of ～2×1015cm?2 is estimated in the limit of no recombination. If sublimation does not remove all gas phase P2H4, P2 and P4 may be produced in potentially larger quantities, although they would be restricted almost entirely to the lowest levels of our model, where T?100°K. Potentially observable amounts of the organophosphorus compounds CH3P2H2 and HCP are predicted, with column densities of >1017 cm?2 and production rates of ～2×108cm?2sec?1. The possible importance of electronically excited states of PHx and additional PH3/hydrocarbon photochemical coupling paths are also considered.  相似文献   

16.
Altitude dependences of [CO2] and [CO2+] are deduced from Mariner 6 and 7 CO2+ airglow measurements. CO2 densities are also obtained from ne radio occultation measurements. Both [CO2] profiles are similar and correspond to the model atmosphere of Barth et al. (1972) at 120 km, but at higher altitudes they diverge and at 200–220 km the obtained [CO2] values are three times less the model. Both the airglow and radio occultation observations show that a correction factor of 2.5 should be included into the values for solar ionization flux given by Hinteregger (1970). The ratio of [CO2+]/ne is 0.15–0.2 and, hence, [O]/[CO2] is ～3% at 135 km. An atmospheric and ionospheric model is developed for 120–220 km. The calculated temperature profile is characterized by a value of T ≈ 370°K at h ? 220 km, a steep gradient (～2°/km) at 200-160 km, a bend in the profile at 160 km, a small gradient (～0.7°/km) below and a value of T ≈ 250°K at 120 km. The upper point agrees well with the results of the Lyman-α measurements; the steep gradient may be explained by molecular viscosity dissipation of gravity and acoustical waves (the corresponding energy flux is 4 × 10?2 erg cm?2sec?1 at 180 km). The bend at 160 km may be caused by a sharp decrease of the eddy diffusion coefficient and defines K ≈ 2 × 108cm2sec?1; and the low gradient gives an estimate of the efficiency of the atmosphere heating by the solar radiation as ? ≈ 0.1.  相似文献   

17.
The abundances of PH3, CH3D, and GeH4 are derived from the 2100- to 2250-cm?1 region of the Voyager 1 IRIS spectra. No evidence is seen for large-scale variations of the phosphine abundance over Jovian latitudes between ?30 and +30°. In the atmospheric regions corresponding to 170–200°K, the derived PH3/H2 value is (4.5 ± 1.5) × 10?7 or 0.75 ± 0.25 times the solar value. This result, compared with other PH3 determinations at 10 μm, suggests than the PH3/H2 ratio on Jupiter decreases with atmospheric pressure. In the 200–250°K region, we derive, within a factor of 2, CH3D/H2 and GeH4/H2 ratios of 2.0 × 10?7 and 1.0 × 10?9, respectively. Assuming a C/H value of 1.0 × 10?3, as derived from Voyager, our CH3D/H2 ratio implies a D/H ratio of 1.8 × 10?5, in reasonable agreement with the interstellar medium value.  相似文献   

18.
G.S. Orton  H.H. Aumann 《Icarus》1977,32(4):431-436
The Q and R branches of the C2H2 ν5 fundamental, observed in emission in an aircraft spectrum of Jupiter near 750 cm?1, have been analyzed with the help of an improved line listing for this band. The line parameters have been certified in the laboratory with the same interferometer used in the Jovian observations. The maximum mixing ratio of C2H2 is found to be between 5 × 10?8 and 6 × 10?9, depending on the form of its vertical distribution and the temperature structure assumed for the lower stratosphere. Most consistent with observations of both Q and R branches are: (1) distributions of C2H2 with a constant mixing ratio in the stratosphere and a cutoff at a total pressure of 100 mbar or less, and (2) the assumption of a temperature at 10?2 bar which is near 155°K.  相似文献   

19.
The yield of metastable nitrogen atoms in dissociative recombination of N2+ (v = 0, 1)ions has been tudied for different experimental conditions. In a first experiment, the branching ratio for N(2D) production was directly measured as being higher than 1.85; for N2+ (v = 0) this implies that 2D + 2D is the main reaction channel; for N2+ (v = 1) a minor channel could be 2P + 2D, 2P being then quenched toward 2D by electrons. In a second experiment, at higher electron densities, the influence of superelastic collisions was studied; a steady state analysis yields the quenching rate coefficient k4, of 2D towards 4S equal to 2.4 × 10?10 cm3 s?1for Te = 3900 K and shows that 2D + 2D is always the major channel of the reaction for N2+ (v = 1), 2D + 2P being a minor channel. All these results are in good agreement with thermospheric models but imply that N2+ dissociative recombination is a less important source for nitrogen escape of Mars.  相似文献   

20.
Steady-state calculations are performed for the daytime equatorial F2-region and topside ionosphere. Values are calculated of the electron and ion temperatures and the concentrations and field-aligned velocities of the ions O+, H+ and He+. Account is taken of upward E × B drift, a summer-winter horizontal neutral air wind and heating of the electron gas by thermalization of fast photoelectrons.The calculated plasma temperatures are in accord with experiment: at the equator there is an isothermal region from about 400–550 km altitude, with temperatures of about 2400 K around 800 km altitude. The transequatorial O+ breeze flux from summer to winter in the topside ionosphere is not greatly affected by the elevated plasma temperatures. The field-aligned velocities of H+ and He+ depend strongly on the O+ field-aligned velocity and on the presence of large temperature gradients. For the minor ions, ion-ion drag with O+ cannot be neglected for the topside ionosphere.  相似文献   

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