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1.
Thomas M Donahue 《Icarus》2004,167(1):225-227
A recently published model for accretion of water by Mars from asteroids and comets beyond 2.5 AU calls for Mars to have accreted 6-27% of Earth's ocean (equivalent to 600-2700 meters depth on Mars' surface) with a D/H ratio 1.2-1.6 times Standard Mean Ocean Water. This model is shown to provide enough outgassed water to account for the subsequent evolution of D/H because of loss of hydrogen and the D/H ratio in water of hydration found in martian meteoric minerals, but enhanced rate loss of hydrogen from early Mars is necessary to permit adequate fractionation to occur during the lifetime of the planet.  相似文献   

2.
Encouraged by recent results of the Mars Odyssey spacecraft mission and the OMEGA team (Mars Express) concerning water in equatorial latitudes between ±45° on Mars and the possible existence of hydrated minerals, we have investigated the water sorption properties of natural zeolites and clay minerals close to martian atmospheric surface conditions as well as the properties of Mg-sulfates and gypsum. To quantify the stability of hydrous minerals on the martian surface and their interaction with the martian atmosphere, the water adsorption and desorption properties of nontronite, montmorillonite, chabazite and clinoptilolite have been investigated using adsorption isotherms at low equilibrium water vapor pressures and temperatures, modeling of the adsorption equilibrium data, thermogravimetry (TG), differential scanning calorimetry (DSC), and proton magic angle spinning nuclear magnetic resonance measurements (1H MAS NMR). Mg-sulfate hydrates were also analyzed using TG/DSC methods to compare with clay mineral and zeolites. Our data show that these microporous minerals can remain hydrated under present martian atmospheric conditions and hold up to 2.5-25 wt% of water in their void volumes at a partial water vapor pressure of 0.001 mbar in a temperature range of 333-193 K. Results of the 1H MAS NMR measurements suggest that parts of the adsorbed water are liquid-like water and that the mobility of the adsorbed water might be of importance for adsorption-water-triggered chemistry and hypothetical exobiological activity on Mars.  相似文献   

3.
The Analyzer of Space Plasma and Energetic Atoms (ASPERA) on-board the Mars Express spacecraft (MEX) measured penetrating solar wind plasma and escaping/accelerated ionospheric plasma at very low altitudes (250 km) in the dayside subsolar region. This implies a direct exposure of the martian topside atmosphere to solar wind plasma forcing leading to energization of ionospheric plasma. The ion and electron energization and the ion outflow from Mars is surprisingly similar to that over the magnetized Earth. Narrow “monoenergetic” cold ion beams, ion beams with broad energy distributions, sharply peaked electron energy spectra, and bidirectional streaming electrons are particle features also observed near Mars. Energized martian ionospheric ions (O+, O+2, CO+2, etc.) flow in essentially the same direction as the external sheath flow. This suggests that the planetary ion energization couples directly to processes in the magnetosheath/solar wind. On the other hand, the beam-like distribution of the energized plasma implies more indirect energization processes like those near the Earth, i.e., energization in a magnetized environment by waves and/or parallel (to B) electric fields. The general conditions for martian plasma energization are, however, different from those in the Earth's magnetosphere. Mars has a weak intrinsic magnetic field and solar wind plasma may therefore penetrate deep into the dense ionospheric plasma. Local crustal magnetization, discovered by Acuña et al. [Acuña, M.J., Connerey, J., Ness, N., Lin, R., Mitchell, D., Carlsson, C., McFadden, J., Anderson, K., Rème, H., Mazelle, C., Vignes, D., Wasilewski, P., Cloutier, P., 1999. Science 284, 790-793], provide some dayside shielding against the solar wind. On the other hand, multiple magnetic anomalies may also lead to “hot spots” facilitating ionospheric plasma energization. We discuss the ASPERA-3 findings of martian ionospheric ion energization and present evidences for two types of plasma energization processes responsible for the low- and mid-altitude plasma energization near Mars: magnetic field-aligned acceleration by parallel electric fields and plasma energization by low frequency waves.  相似文献   

4.
The following problems related to the origin of methane on Mars have been considered. (1) Laboratory simulations of the impact phenomena confirm effective heterogeneous chemistry between the products of the fireball. This chemistry lowers the fireball freezing temperature from 2000 to 750 K for methane and to 1100 K for CO/CO2. Production of methane on Mars by cometary impacts is 0.8% of the total production. A probability that the observed methane on Mars came from impact of a single comet is 0.0011. (2) The PFS observations of variations of methane on Mars require a very effective heterogeneous loss of methane. Heterogeneous effect of dust is half that of the surface rocks. Thermochemical equilibrium requires production, not loss, of methane. Existing kinetic data show a very low efficiency of heterogeneous reactions of methane. Highly reactive superoxide ions generated by the solar UV photons on the martian rocks cannot remove methane. The required efficiency of heterogeneous loss of methane on Mars is higher than that on Earth by a factor of ?1000, although the expected efficiency on Earth is stronger than that on Mars because of the liquid ocean and the abundant oxygen. All these inconsistencies may be removed if variations of the rock reflectivity contribute to the PFS observations of methane on Mars. The PFS data on H2CO, HCl, HF, and HBr also raise doubts. (3) Although geologic sources of methane are possible, the lack of current volcanism, hydrothermal activity, hot spots, and very low seepage of gases from the interior are not favorable for geologic methane. Any proposed geological source of methane on Mars should address these problems. Some weak points in the suggested geologic sources are discussed. (4) Measurements of 13C/12C and D/H in methane would be difficult because of the low methane abundance. These ratios are mostly sensitive to a temperature of methane formation and cannot distinguish between biogenic and low-temperature geologic sources. Their analysis requires the carbon isotope ratio in CO2 on Mars, which is known with the insufficient accuracy, and D/H in water, which is different in the atmosphere, polar caps, regolith and interior. Therefore, the stable isotope ratios may not give a unique answer on the origin of methane. (5) Ethane and propane react with OH much faster than methane. If their production relative to methane is similar to that on Earth, then their expected abundances on Mars are of a few parts per trillion. (6) Loss of SO2 in the reaction with peroxide on ice is smaller than its gas-phase loss by an order of magnitude. The overall results strengthen the biogenic origin of martian methane and its low variability.  相似文献   

5.
There have been several reports of methane on Mars at the 10-60 ppbv level. Most suggest that methane is both seasonally and latitudinally variable. Here we review why variable methane on Mars is physically and chemically implausible, and then we critically review the published reports. There is no known mechanism for destroying methane chemically on Mars. But if there is one, methane oxidation would deplete the O2 in Mars’s atmosphere in less than 10,000 years unless balanced by an equally large unknown source of oxidizing power. Physical sequestration does not raise these questions, but adsorption in the regolith or condensation in clathrates ignore competition for adsorption sites or are inconsistent with clathrate stability, respectively. Furthermore, any mechanism that relies on methane’s van der Waals’ attraction is inconsistent with the continued presence of Xe in the atmosphere at the 60 ppbv level. We then use the HITRAN database and transmission calculations to identify and characterize the absorption lines that would be present on Earth or Mars at the wavelengths of the published observations. These reveal strong competing telluric absorption that is most problematic at just those wavelengths where methane’s signature seems most clearly seen from Earth. The competing telluric lines must be removed with models. The best case for martian methane was made for the 12CH4ν3 R0 and R1 lines seen in blueshift when Mars was approaching Earth in early 2003 (Mumma, M.J., Villanueva, G.L., Novak, R.E., Hewagama, T., Bonev, B.P., DiSanti, M.A., Mandell, A.M., Smith, M.D. [2009]. Science 323, 1041-1045). For these the Doppler shift moves the two martian lines into near coincidence with telluric 13CH4ν3 R1 and R2 lines that are 10-50× stronger than the inferred martian lines. By contrast, the 12CH4ν3 R0 and R1 lines when observed in redshift do not contend with telluric 13CH4. For these lines, Mumma et al.’s observations and analyses are consistent with an upper limit on the order of 3 ppbv.  相似文献   

6.
Our ground-based measurements of martian atmospheric water vapor, made throughout Ls=34° to 249°, 24 September 1998 to 23 November 1999, during Mars year 24 (MY 24), show changes in Mars' humidity on hourly, daily, and seasonal timescales. We made concomitant measurement of nearby CO2 bands, and when possible, results were corrected for aerosol extinction using aerosol optical depths derived from our own CO2 analysis. Where there is spatial and temporal overlap, similar results are obtained for water vapor abundances and aerosol opacities as those observed from the Thermal Emission Spectrometer on Mars Global Surveyor. In addition some further discussion of our published earlier water vapor measurements (1991-1995) is included. Six results from this data set are: (1) the measured aerosol opacity in Mars atmosphere was variable but not greater than τ=1, with almost no clear atmosphere being observed, (2) measurements made with the slit crossing many hours of local time on Mars' Earth-facing disk show a diurnal pattern with highest abundances at mid-day and low abundance in very early morning and late afternoon for some but not all measurements, (3) water vapor abundance is patchy on hourly and daily time scales but follows the usual seasonal trends seen by instrumentation on the Mars Atmospheric Water Detector on the Viking Orbiters and by the Thermal Emission Spectrometer on Mars Global Surveyor, (4) there is a slight longitudinal correlation with the ground-ice observed by the Gamma Ray Spectrometer on Mars Odyssey, (5) there is evidence of the Low Southern Latitude Summer Minimum in our water vapor measurements but our data set for southern summer is limited, and (6) MY 24 appears to be wetter than MY 22 and MY 23.  相似文献   

7.
Alberto G. Fairén 《Icarus》2010,208(1):165-48
Water on Mars has been explained by invoking controversial and mutually exclusive solutions based on warming the atmosphere with greenhouse gases (the “warm and wet” Mars) or on local thermal energy sources acting in a global freezing climate (the “cold and dry” Mars). Both have critical limitations and none has been definitively accepted as a compelling explanation for the presence of liquid water on Mars. Here is considered the hypothesis that cold, saline and acidic liquid solutions have been stable on the sub-zero surface of Mars for relatively extended periods of time, completing a hydrogeological cycle in a water-enriched but cold planet. Computer simulations have been developed to analyze the evaporation processes of a hypothetical martian fluid with a composition resulting from the acid weathering of basalt. This model is based on orbiter- and lander-observed surface mineralogy of Mars, and is consistent with the sequence and time of deposition of the different mineralogical units. The hydrological cycle would have been active only in periods of dense atmosphere, as having a minimum atmospheric pressure is essential for water to flow, and relatively high temperatures (over ∼245 K) are required to trigger evaporation and snowfall; minor episodes of limited liquid water on the surface could have occurred at lower temperatures (over ∼225 K). During times with a thin atmosphere and even lesser temperatures (under ∼225 K), only transient liquid water can potentially exist on most of the martian surface. Assuming that surface temperatures have always been maintained below 273 K, Mars can be considered a “cold and wet” planet for a substantial part of its geological history.  相似文献   

8.
We report on laboratory experiments in which we allowed an SNC-derived mineral mix to react with pure water under a simulated Mars atmosphere for 7 months. These experiments were performed at one bar and at three different temperatures in order to simulate the subsurface conditions that most likely exist where liquid water and rock interact on Mars today. The dominant cations dissolved in the solutions we produced, which may be characterized as dilute brines, are Ca2+, Mg2+, Al3+, and Na+, while the major anions are dissolved C, F−, SO2−4 and Cl−. Typical solution pH was in the range of 4.2-6.0. Abundance patterns of elements in our synthetic sulfate-chloride brines are distinctly unlike those of terrestrial ocean water or continental waters, however, they are quite similar to those measured in the martian fines at the Mars Pathfinder and Viking 1 and 2 Landing sites. This suggests that salts present in the martian regolith may have formed over time as a result of the interaction of surface or subsurface liquid water with basalts in the presence of a martian atmosphere similar in composition to that of today. If most of the mobile surface layer was formed during the Noachian when erosion rates were much higher than at present, and if this layer is homogeneous in salt composition, the total amount of salt in the martian fines is approximately the same as in the Earth's oceans. The minimum quantity of circulating water necessary to deposit this amount of salt is approximately equivalent to a global layer 625 m deep.  相似文献   

9.
We present the seasonal and geographical variations of the martian water vapor monitored from the Planetary Fourier Spectrometer Long Wavelength Channel aboard the Mars Express spacecraft. Our dataset covers one martian year (end of Mars Year 26, Mars Year 27), but the seasonal coverage is far from complete. The seasonal and latitudinal behavior of the water vapor is globally consistent with previous datasets, Viking Orbiter Mars Atmospheric Water Detectors (MAWD) and Mars Global Surveyor Thermal Emission Spectrometer (MGS/TES), and with simultaneous results obtained from other Mars Express instruments, OMEGA and SPICAM. However, our absolute water columns are lower and higher by a factor of 1.5 than the values obtained by TES and SPICAM, respectively. In particular, we retrieve a Northern midsummer maximum of 60 pr-μm, lower than the 100-pr-μm observed by TES. The geographical distribution of water exhibits two local maxima at low latitudes, located over Tharsis and Arabia. Global Climate Model (GCM) simulations suggest that these local enhancements are controlled by atmospheric dynamics. During Northern spring, we observe a bulge of water vapor over the seasonal polar cap edge, consistent with the northward transport of water from the retreating seasonal cap to the permanent polar cap. In terms of vertical distribution, we find that the water volume mixing ratio over the large volcanos remains constant with the surface altitude within a factor of two. However, on the whole dataset we find that the water column, normalized to a fixed pressure, is anti-correlated with the surface pressure, indicating a vertical distribution intermediate between control by atmospheric saturation and confinement to a surface layer. This anti-correlation is not reproduced by GCM simulations of the water cycle, which do not include exchange between atmospheric and subsurface water. This situation suggests a possible role for regolith-atmosphere exchange in the martian water cycle.  相似文献   

10.
Details are presented of an improved technique to use atmospheric absorption of magnetically reflecting solar wind electrons to constrain neutral mass densities in the nightside martian upper thermosphere. The helical motion of electrons on converging magnetic field lines, through an extended neutral atmosphere, is modeled to enable prediction of loss cone pitch angle distributions measured by the Magnetometer/Electron Reflectometer (MAG/ER) experiment on Mars Global Surveyor at 400 km altitude. Over the small fraction of Mars' southern hemisphere (∼2.5%) where the permanent crustal magnetic fields are both open to the solar wind and sufficiently strong as to dominate the variable induced martian magnetotail field, spherical harmonic expansions of the crustal fields are used to prescribe the magnetic field along the electron's path, allowing least-squares fitting of measured loss cones, in order to solve for parameters describing the vertical neutral atmospheric mass density profile from 160 to 230 km. Results are presented of mass densities in the southern hemisphere at 2 a.m. LST at the mean altitude of greatest sensitivity, 180 km, continuously over four martian years. Seasonal variability in densities is largely explained by orbital and latitudinal changes in dayside insolation that impacts the nightside through the resulting thermospheric circulation. However, the physical processes behind repeatable rapid, late autumnal cooling at mid-latitudes and near-aphelion warming at equatorial latitudes is not fully clear. Southern winter polar warming is generally weak or nonexistent over several Mars years, in basic agreement with MGS and MRO accelerometer observations. The puzzling response of mid-latitude densities from 160° to 200° E to the 2001 global dust storm suggests unanticipated localized nightside upper thermospheric lateral and vertical circulation patterns may accompany such storms. The downturn of the 11-year cycle of solar EUV flux is likely responsible for lower aphelion densities in 2004 and 2006 (Mars years 27 and 28).  相似文献   

11.
The Dry Valleys of Antarctica are an excellent analog of the environment at the surface of Mars. Soil formation histories involving slow processes of sublimation and migration of water-soluble ions in polar desert environments are characteristic of both Mars and the Dry Valleys. At the present time, the environment in the Dry Valleys is probably the most similar to that in the mid-latitudes on Mars although similar conditions may be found in areas of the polar regions during their respective Mars summers. It is thought that Mars is currently in an interglacial period, and that subsurface water ice is sublimating poleward. Because the Mars sublimation zones seem to be the most similar to the Antarctic Dry Valleys, the Dry Valleys-type Mars climate is migrating towards the poles. Mars has likely undergone drastic obliquity changes, which means that the Dry Valleys analog to Mars may be valid for large parts of Mars, including the polar regions, at different times in geologic history. Dry Valleys soils contain traces of silicate alteration products and secondary salts much like those found in Mars meteorites. A martian origin for some of the meteorite secondary phases has been verified previously; it can be based on the presence of shock effects and other features which could not have formed after the rocks were ejected from Mars, or demonstrable modification of a feature by the passage of the meteorite through Earth's atmosphere (proving the feature to be pre-terrestrial). The martian weathering products provide critical information for deciphering the near-surface history of Mars. Definite martian secondary phases include Ca-carbonate, Ca-sulfate, and Mg-sulfate. These salts are also found in soils from the Dry Valleys of Antarctica. Results of earlier Wright Valley work are consistent with what is now known about Mars based on meteorite and orbital data. Results from recent and current Mars missions support this inference. Aqueous processes are active even in permanently frozen Antarctic Dry Valleys soils, and similar processes are probably also occurring on Mars today, especially at the mid-latitudes. Both weathering products and life in Dry Valleys soils are distributed heterogeneously. Such variations should be taken into account in future studies of martian soils and also in the search for possible life on Mars.  相似文献   

12.
High-resolution infrared imaging spectroscopy of Mars has been achieved at the NASA Infrared Telescope Facility (IRTF) on June 19-21, 2003, using the Texas Echelon Cross Echelle Spectrograph (TEXES). The areocentric longitude was 206°. Following the detection and mapping of hydrogen peroxide H2O2 [Encrenaz et al., 2004. Icarus 170, 424-429], we have derived, using the same data set, a map of the water vapor abundance. The results appear in good overall agreement with the TES results and with the predictions of the Global Circulation Model (GCM) developed at the Laboratory of Dynamical Meteorology (LMD), with a maximum abundance of water vapor of 3±1.5×10−4(17±9 pr-μm). We have searched for CH4 over the martian disk, but were unable to detect it. Our upper limits are consistent with earlier reports on the methane abundance on Mars. Finally, we have obtained new measurements of CO2 isotopic ratios in Mars. As compared to the terrestrial values, these values are: (18O/17O)[M/E] = 1.03 ± 0.09; (13C/12C)[M/E] = 1.00 ± 0.11. In conclusion, in contrast with the analysis of Krasnopolsky et al. [1996. Icarus 124, 553-568], we conclude that the derived martian isotopic ratios do not show evidence for a departure from their terrestrial values.  相似文献   

13.
Steven W. Ruff 《Icarus》2004,168(1):131-143
Spectral features observed in Mars Global Surveyor Thermal Emission Spectrometer data (∼1670-220 cm−1) of martian surface dust provide clues to its mineralogy. An emissivity peak at ∼1630 cm−1 is consistent with the presence of an H2O-bearing mineral. This spectral feature can be mapped globally and shows a distribution related to the classical bright regions on Mars that are known to be dust covered. An important spectral feature at ∼830 cm−1 present in a newly derived average spectrum of surface dust likely is a transparency feature arising from the fine particulate nature of the dust. Its shape and location are consistent with plagioclase feldspars and also zeolites, which essentially are the hydrous form of feldspar. The generally favored visible/near-infrared spectral analog for martian dust, JSC Mars-1 altered tephra, does not display the ∼830 cm−1 feature. Zeolites commonly form from the interaction of low temperature aqueous fluids and volcanic glass in a variety of geologic settings. The combination of spectral features that are consistent with zeolites and the likelihood that Mars has (or had) geologic conditions necessary to produce them makes a strong case for recognizing zeolite minerals as likely components of the martian regolith.  相似文献   

14.
We report observations of Icelandic hillside gully systems that are near duplicates of gullies observed on high-latitude martian hillsides. The best Icelandic analogs involve basaltic talus slopes at the angle of repose, with gully formation by debris flows initiated by ground water saturation, and/or by drainage of water from upslope cliffs. We report not only the existence of Mars analog gullies, but also an erosional sequence of morphologic forms, found both on Mars and in Iceland. The observations support hypotheses calling for creation of martian gullies by aqueous processes. Issues remain whether the water in each case comes only from surficial sources, such as melting of ground ice or snow, or from underground sources such as aquifers that gain surface access in hillsides. Iceland has many examples of the former, but the latter mechanism is not ruled out. Our observations are consistent with the martian debris flow mechanism of F. Costard et al. (2001c, Science295, 110-113), except that classic debris flows begin at midslope more frequently than on Mars. From morphologic observations, we suggest that some martian hillside gully systems not only involve significant evolution by extended erosive activity, but gully formation may occur in episodes, and the time interval since the last episode is considerably less than the time interval needed to erase the gully through normal martian obliteration processes.  相似文献   

15.
Mars was observed near the peak of the strongest SO2 band at 1364-1373 cm−1 with resolving power of 77,000 using the Texas Echelon Cross Echelle Spectrograph on the NASA Infrared Telescope Facility. The observation covered the Tharsis volcano region which may be preferable to search for SO2. The spectrum shows absorption lines of three CO2 isotopomers and three H2O isotopomers. The water vapor abundance derived from the HDO lines assuming D/H = 5.5 times the terrestrial value is 12±1.0 pr. μm, in agreement with the simultaneous MGS/TES observations of 14 pr. μm at the latitudes (50° S to 10° N) of our observation. Summing of spectral intervals at the expected positions of sixteen SO2 lines puts a 2σ upper limit on SO2 of 1 ppb. SO2 may be emitted into the martian atmosphere by seepage and is removed by three-body reactions with OH and O. The SO2 lifetime, 2 years, is longer than the global mixing time 0.5 year, so SO2 should be rather uniformly distributed across Mars. Seepage of SO2 is less than 15,000 tons per year on Mars which is smaller than the volcanic production of SO2 on the Earth by a factor of 700. Because CH4/SO2 is typically 10−4-10−3 in volcanic gases on the Earth, our results show seepage is unlikely to be the source of the recently discovered methane on Mars and therefore strengthen its biogenic origin.  相似文献   

16.
The evolution of the martian atmosphere with regard to its H2O inventory is influenced by thermal loss processes of H, H2, nonthermal atmospheric loss processes of H+, H2+, O, O+, CO2, and O2+ into space, as well as by chemical weathering of the surface soil. The evolution of thermal and nonthermal escape processes depend on the history of the intensity of the solar XUV radiation and the solar wind density. Thus, we use actual data from the observation of solar proxies with different ages from the Sun in Time program for reconstructing the Sun's radiation and particle environment from the present to 3.5 Gyr ago. The correlation between mass loss and X-ray surface flux of solar proxies follows a power law relationship, which indicates a solar wind density up to 1000 times higher at the beginning of the Sun's main sequence lifetime. For the study of various atmospheric escape processes we used a gas dynamic test particle model for the estimation of the pick up ion loss rates and considered pick up ion sputtering, as well as dissociative recombination. The loss of H2O from Mars over the last 3.5 Gyr was estimated to be equivalent to a global martian H2O ocean with a depth of about 12 m, which is smaller than the values reported by previous studies. If ion momentum transport, a process studied in detail by Mars Express is significant on Mars, the water loss may be enhanced by a factor of about 2. In our investigation we found that the sum of thermal and nonthermal atmospheric loss rates of H and all nonthermal escape processes of O to space are not compatible with a ratio of 2:1, and is currently close to about 20:1. Escape to space cannot therefore be the only sink for oxygen on Mars. Our results suggest that the missing oxygen (needed for the validation of the 2:1 ratio between H and O) can be explained by the incorporation into the martian surface by chemical weathering processes since the onset of intense oxidation about 2 Gyr ago. Based on the evolution of the atmosphere-surface-interaction on Mars, an overall global surface sink of about 2×1042 oxygen particles in the regolith can be expected. Because of the intense oxidation of inorganic matter, this process may have led to the formation of considerable amounts of sulfates and ferric oxides on Mars. To model this effect we consider several factors: (1) the amount of incorporated oxygen, (2) the inorganic composition of the martian soil and (3) meteoritic gardening. We show that the oxygen incorporation has also implications for the oxidant extinction depth, which is an important parameter to determine required sampling depths on Mars aimed at finding putative organic material. We found that the oxidant extinction depth is expected to lie in a range between 2 and 5 m for global mean values.  相似文献   

17.
Accelerometer measurements made by Spirit and Opportunity during their entries through the martian atmosphere are reported. Vertical profiles of atmospheric density, pressure, and temperature with sub-km vertical resolution were obtained using these data between 10 and 100 km. Spirit's temperature profile is ∼10 K warmer than Opportunity's between 20 and 80 km. Unlike all other martian entry profiles, Spirit's temperature profile does not contain any large amplitude, long wavelength oscillations and is nearly isothermal below 30 km. Opportunity's temperature profile contains a strong inversion between 8 and 12 km. A moderate dust storm, which occurred on Mars shortly before these two atmospheric entries, may account for some of the differences between the two profiles. The poorly known angle of attack and unknown wind velocity may cause the temperature profiles to contain errors of tens of Kelvin at 10 km, but these errors would be an order of magnitude smaller above 30 km. On broad scales, the two profiles are consistent with Mars Global Surveyor Thermal Emission Spectrometer (TES) pressure/temperature profiles. Differences exist on smaller scales, particularly associated with the near-isothermal portion of Spirit's profile and the temperature inversion in Opportunity's profile.  相似文献   

18.
Hydrogen peroxide (H2O2) has been suggested as a possible oxidizer of the martian surface. Photochemical models predict a mean column density in the range of 1015-1016 cm−2. However, a stringent upper limit of the H2O2 abundance on Mars (9×1014 cm−2) was derived in February 2001 from ground-based infrared spectroscopy, at a time corresponding to a maximum water vapor abundance in the northern summer (30 pr. μm, Ls=112°). Here we report the detection of H2O2 on Mars in June 2003, and its mapping over the martian disk using the same technique, during the southern spring (Ls=206°) when the global water vapor abundance was ∼10 pr. μm. The spatial distribution of H2O2 shows a maximum in the morning around the sub-solar latitude. The mean H2O2 column density (6×1015 cm−2) is significantly greater than our previous upper limit, pointing to seasonal variations. Our new result is globally consistent with the predictions of photochemical models, and also with submillimeter ground-based measurements obtained in September 2003 (Ls=254°), averaged over the martian disk (Clancy et al., 2004, Icarus 168, 116-121).  相似文献   

19.
Long-exposure spectroscopy of Mars and Venus with the Extreme Ultraviolet Explorer (EUVE) has revealed emissions of He 584 Å on both planets and He 537 Å/O+ 539 Å and He+ 304 Å on Venus. Our knowledge of the solar emission at 584 Å, eddy diffusion in Mars' upper atmosphere, electron energy distributions above Mars' ionopause, and hot oxygen densities in Mars' exosphere has been significantly improved since our analysis of the first EUVE observation of Mars [Krasnopolsky, Gladstone, 1996, Helium on Mars: EUVE and Phobos data and implications for Mars' evolution, J. Geophys. Res. 101, 15,765-15,772]. These new results and a more recent EUVE observation of Mars are the motivation for us to revisit the problem in this paper. We find that the abundance of helium in the upper atmosphere, where the main loss processes occur, is similar to that in the previous paper, though the mixing ratio in the lower and middle atmosphere is now better estimated at 10±6 ppm. Our estimate of the total loss of helium is almost unchanged at 8×1023 s−1, because a significant decrease in the loss by electron impact ionization above the ionopause is compensated by a higher loss in collisions with hot oxygen. We neglect the outgassing of helium produced by radioactive decay of U and Th because of the absence of current volcanism and a very low upper limit to the seepage of volcanic gases. The capture of solar wind α-particles is currently the only substantial source of helium on Mars, and its efficiency remains at 0.3. A similar analysis of EUV emissions from Venus results in a helium abundance in the upper atmosphere which is equal to the mean of the abundances measured previously with two optical and two mass spectrometers, and a derived helium mixing ratio in the middle and lower atmosphere of 9±6 ppm. Helium escape by ionization and sweeping out of helium ions by the solar wind above the ionopause is smaller than that calculated by Prather and McElroy [1983, Helium on Venus: implications for uranium and thorium, Science 220, 410-411] by a factor of 3. However, charge exchange of He+ ions with CO2 and N2 between the exobase and ionopause and collisions with hot oxygen ignored previously add to the total loss which appears to be at the level of 106 cm−2 s−1 predicted by Prather and McElroy [1983, Science 220, 410-411]. The loss of helium is compensated by outgassing of helium produced by radioactive decay of U and Th and by the capture of the solar wind α-particles with an efficiency of 0.1. We also compare our derived α-particle capture efficiencies for Mars and Venus with observed X-ray emissions resulting from the charge exchange of solar wind heavy ions with the extended atmospheres on both planets [Dennerl et al., 2002, Discovery of X-rays from Venus with Chandra, Astron. Astrophys. 386, 319-330; Dennerl, 2002, Discovery of X-rays from Mars with Chandra, Astron. Astrophys. 394, 1119-1128]. The emissions from both disk and halo on Mars agree with our calculated values; however, we do not see a reasonable explanation for the X-ray halo emission on Venus. The ratio of the charge exchange efficiencies derived from the disk X-ray emissions of Mars and Venus is similar to the ratio of the capture efficiencies for these planets. The surprisingly bright emission of He+ at 304 Å observed by EUVE and Venera 11 and 12 suggests that charge exchange in the flow of the solar wind α-particles around the ionopause is much stronger than in the flow of α-particles into the ionosphere.  相似文献   

20.
David Andrew Fisher 《Icarus》2007,187(2):430-441
A time varying stable isotope model for the D/H history of Mars water cycle is developed with variable atmosphere, space loss rate, ground and ice cap flux rates. It considers coupled ground reservoirs and traces D/H in the air and reservoirs secularly and over obliquity cycles. The various flux rates are prescribed time variables that simulate surface flux, and solar driven space loss rates. Predicted bulk averages for the ice cap, ground ice reservoirs and atmosphere span the observed ranges reported by Mumma et al. [Mumma, M.J., Novak, R.E., DiSanti, M.A., Bonev, B., Dello Russo, N., Magee-Sauer, K., 2003. The Martian Atmosphere. Conference Reports of “Sixth International Conference on Mars Atmosphere,” No. 3186]. When the dominant obliquity cycle variations are scaled so that the model delivers present seasonal variations, the present long term bulk D/H average for the ice cap is ∼+2.7 (equivalent to +1700‰ in δ(D) wrt SMOW). The obliquity driven D/H cycle in the ice cap's layers varies between 3 and 6. The smaller more accessible reservoirs have larger bulk averages with the smallest being able to reach D/H values over 9 within ∼105 years. Small hypothetical solar activity driven variations in the escape rate to space and in the fractionation constant [Krasnopolsky, V.A., Feldman, P.D., 2001. Science 294, 1914-1917] for the escape process can produce a “solar wiggle” whose D/H amplitude can reach 0.1 (δ(D) amplitude of 100‰). Because of the temporal variability, a single modern measured atmospheric D/H ratio at a particular Ls cannot tell very much about the total water inventory of Mars. A bulk average for the Northern Ice Cap and better still a dated vertical profile of D/H from the ice cap would, however, go a long way towards illuminating the “modern” water history of Mars. The age and stability of the Northern Ice Cap and the D/H history locked in the layering is discussed. An ice cap that is very young and exchanges its mass through the atmosphere often will necessarily have a large D/H.  相似文献   

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