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1.
Using synthetic spectra derived from an updated model atmosphere together with a continuum model that includes contributions from haze, cloud and ground, we have re-analyzed the recently published (Geballe et al., 2003, Astrophys. J. 583, L39-L42) high-resolution 3 μm spectrum of Titan which contains newly-detected bands of HCN (in emission) and C2H2 and CH3D (in absorption), in addition to previously detected bands of CH4. In the 3.10-3.54 μm interval the analysis yields strong evidence for the existence of a cloud deck or optically thick haze layer at about the 10 mbar (∼ 100 km) level. The haze must extend well above this altitude in order to mask the strong CH4 lines at 3.20-3.50 μm. These cloud and haze components must be transparent at 2.87-2.92 μm, where analysis of the CH3D spectrum demonstrates that Titan's surface is glimpsed through a second cloud deck at about the 100 mbar (∼ 50 km) level. Through a combination of areal distribution and optical depth this cloud deck has an effective transmittance of ∼ 20%. The spectral shape of Titan's continuum indicates that the higher altitude cloud and haze particles responsible for suppressing the CH4 absorptions have a largely organic make-up. The rotational temperature of the HCN ranges from 140 to 180 K, indicating that the HCN emission occurs over a wide range of altitudes. This emission, remodeled using an improved collisional deactivation rate, implies mesospheric mixing ratio curves that are consistent with previously predictions. The stratospheric and mesospheric C2H2 mixing ratios are ∼10−5, considerably less than previous model predictions (Yung et al., 1984), but approximately consistent with recent observational results. Upper limits to mixing ratios of HC3N and C4H2 are derived from non-detections of those species near 3.0 μm.  相似文献   

2.
We report observation and analysis of a high-resolution 2.87-3.54 μm spectrum of the southern temperate region of Saturn obtained with NIRSPEC at Keck II. The spectrum reveals absorption and emission lines of five molecular species as well as spectral features of haze particles. The ν2+ν3 band of CH3D is detected in absorption between 2.87 and 2.92 μm; and we derived from it a mixing ratio approximately consistent with the Infrared Space Observatory result. The ν3 band of C2H2 also is detected in absorption between 2.95 and 3.05 μm; analysis indicates a sudden drop in the C2H2 mixing ratio at 15 mbar (130 km above the 1 bar level), probably due to condensation in the low stratosphere. The presence of the ν3+ν9+ν11 band of C2H6 near 3.07 μm, first reported by Bjoraker et al. [Bjoraker, G.L., Larson, H.P., Fink, U., 1981. Astrophys. J. 248, 856-862], is confirmed, and a C2H6 condensation altitude of 10 mbar (140 km) in the low stratosphere is determined. We assign weak emission lines within the 3.3 μm band of CH4 to the ν7 band of C2H6, and derive a mixing ratio of 9±4×10−6 for this species. Most of the C2H6 3.3 μm line emission arises in the altitude range 460-620 km (at ∼μbar pressure levels), much higher than the 160-370 km range where the 12 μm thermal molecular line emission of this species arises. At 2.87-2.90 μm the major absorber is tropospheric PH3. The cloud level determined here and at 3.22-3.54 is 390-460 mbar (∼30 km), somewhat higher than found by Kim and Geballe [Kim, S.J., Geballe, T.R., 2005. Icarus 179, 449-458] from analysis of a low resolution spectrum. A broad absorption feature at 2.96 μm, which might be due to NH3 ice particles in saturnian clouds, is also present. The effect of a haze layer at about 125 km (∼12 mbar level) on the 3.20-3.54 μm spectrum, which was not apparent in the low resolution spectrum, is clearly evident in the high resolution data, and the spectral properties of the haze particles suggest that they are composed of hydrocarbons.  相似文献   

3.
In July 1994, the Shoemaker-Levy 9 (SL9) impacts introduced hydrogen cyanide (HCN) to Jupiter at a well confined latitude band around −44°, over a range of specific longitudes corresponding to each of the 21 fragments (Bézard et al. 1997, Icarus 125, 94-120). This newcomer to Jupiter's stratosphere traces jovian dynamics. HCN rapidly mixed with longitude, so that observations recorded later than several months after impact witnessed primarily the meridional transport of HCN north and south of the impact latitude band. We report spatially resolved spectroscopy of HCN emission 10 months and 6 years following the impacts. We detect a total mass of HCN in Jupiter's stratosphere of 1.5±0.7×1013 g in 1995 and 1.7±0.4×1013 g in 2000, comparable to that observed several days following the impacts (Bézard et al. 1997, Icarus 125, 94-120). In 1995, 10 months after impact, HCN spread to −30° and −65° latitude (half column masses), consistent with a horizontal eddy diffusion coefficient of Kyy=2-3×1010 cm2 s−1. Six years following impact HCN is observed in the northern hemisphere, while still being concentrated at 44° south latitude. Our meridional distribution of HCN suggests that mixing occurred rapidly north of the equator, with Kyy=2-5×1011 cm2 s−1, consistent with the findings of Moreno et al. (2003, Planet. Space Sci. 51, 591-611) and Lellouch et al. (2002, Icarus 159, 112-131). These inferred eddy diffusion coefficients for Jupiter's stratosphere at 0.1-0.5 mbar generally exceed those that characterize transport on Earth. The low abundance of HCN detected at high latitudes suggests that, like on Earth, polar regions are dynamically isolated from lower latitudes.  相似文献   

4.
We obtained time-resolved, near-infrared spectra of Io during the 60-90 min following its reappearance from eclipse by Jupiter on five occasions in 2004. The purpose was to search for spectral changes, particularly in the well-known SO2 frost absorption bands, that would indicate surface-atmosphere exchange of gaseous SO2 induced by temperature changes during eclipse. These observations were a follow-on to eclipse spectroscopy observations in which Bellucci et al. [Bellucci et al., 2004. Icarus 172, 141-148] reported significant changes in the strengths of two strong SO2 bands in data acquired with the VIMS instrument aboard the Cassini spacecraft. One of the bands (4.07 μm [ν1 + ν3]) observed by Bellucci et al. is visible from ground-based observatories and is included in our data. We detected no changes in Io’s spectrum at any of the five observed events during the approximately 60-90 min during which spectra were obtained following Io’s emergence from Jupiter’s shadow. The areas of the three strongest SO2 bands in the region 3.5-4.15 μm were measured for each spectrum; the variation of the band areas with time does not exceed that which can be explained by the Io’s few degrees of axial rotation during the intervals of observation, and in no case does the change in band strength approach that seen in the Cassini VIMS data. Our data are of sufficient quality and resolution to show the weak 2.198 μm (4549.6 cm−1) 4ν1 band of SO2 frost on Io for what we believe is the first time. At one of the events (June 22, 2004), we began the acquisition of spectra ∼6 min before Io reappeared from Jupiter’s shadow, during which time it was detected through its own thermal emission. No SO2 bands were superimposed on the purely thermal spectrum on this occasion, suggesting that the upper limit to condensed SO2 in the vertical column above Io’s surface was ∼4 × 10−5 g cm−2.  相似文献   

5.
New laboratory spectra of crystalline and amorphous diacetylene ice have been recorded in the range of 7000-500 cm−1 (1.4-20 μm) to aid in the identification of solid diacetylene on Saturn's moon Titan. We have established that amorphous diacetylene ice is stable only at temperatures less than 70±1 K. With respect to observations on Titan, the best approach would be to utilize future space-based telescopes to search for the ν4 (3277/3271 cm−1) in absorption against the reflected light from the sun and the slightly weaker ν8 absorption bands (676/661 cm−1) in absorption against the continuum emission.  相似文献   

6.
R.T Clancy  B.J Sandor 《Icarus》2004,168(1):116-121
The 362.156 GHz absorption spectrum of H2O2 in the Mars atmosphere was observed on September 4 of 2003, employing the James Clerk Maxwell Telescope (JCMT) sub-millimeter facility on Mauna Kea, Hawaii. Radiative transfer analysis of this line absorption yields an average volume mixing ratio of 18±0.4 ppbv within the lower (0-30 km) Mars atmosphere, in general accordance with standard photochemical models (e.g., Nair et al., 1994, Icarus 111, 124-150). Our derived H2O2 abundance is roughly three times greater than the upper limit retrieved by Encrenaz et al. (2002, Astron. Astrophys. 396, 1037-1044) from infrared spectroscopy, although part of this discrepancy may result from the different solar longitudes (Ls) of observation. Aphelion-to-perihelion thermal forcing of the global Mars hygropause generates substantial (>200%) increases in HOx abundances above ∼10 km altitudes between the Ls=112° period of the Encrenaz et al. upper limit measurement and the current Ls=250° period of detection (Clancy and Nair, 1996, J. Geophys. Res. 101, 12785-12590). The observed H2O2 line absorption weakens arguments for non-standard homogeneous (Encrenaz et al., 2002, Astron. Astrophys. 396, 1037-1044) or heterogeneous (Krasnopolsky, 2003a, J. Geophys. Res. 108; 2003b, Icarus 165, 315-325) chemistry, which have been advocated partly on the basis of infrared (8 μm) non-detections for Mars H2O2. Observation of Mars H2O2 also represents the first measurement of a key catalytic specie in a planetary atmosphere other than our own.  相似文献   

7.
The near-infrared spectrum of Titan, Saturn's largest moon and one of the Cassini/Huygens' space mission primary targets, covers the 0.8 to 5 micron region in which it shows several weak CH4 absorption regions, and in particular one centered near 2.75 micron. Due to the interference of telluric absorption, only part of this window region (2.9-3.1 μm) has previously been observed from the ground [Noll, K.S., Geballe, T.R., Knacke, R., Pendleton, F., Yvonne, J., 1996. Icarus 124, 625-631; Griffith, C.A., Owen, T., Miller, G.A., Geballe, T., 1998. Nature 395, 575-578; Griffith, C.A., Owen, T., Geballe, T.R., Rayner, J., Rannou, P., 2003. Science 300, 628-630; Geballe, T.R., Kim, S.J., Noll, K.S., Griffith, C.A., 2003. Astrophys. J. 583, L39-L42]. We report here on the first spectroscopic observations of Titan covering the whole 2.4-4.9 μm region by two instruments on board the Infrared Space Observatory (ISO) in 1997. These observations show the 2.75-μm window in its complete extent for the first time. In this study we have also used a high-resolution Titan spectrum in the 2.9-3.6 μm region taken with the Keck [Geballe, T.R., Kim, S.J., Noll, K.S., Griffith, C.A., 2003. Astrophys. J. 583, L39-L42; Kim, S.J., Geballe, T.R., Noll, K.S., Courtin, R., 2005. Icarus 173, 522-532] to infer information on the atmospheric parameters (haze extinction, single scattering albedo, methane abundance, etc.) by fitting the methane bands with a detailed microphysical model of Titan's atmosphere (updated from Rannou, P., McKay, C.P., Lorenz, R.D., 2003. Planet. Space Sci. 51, 963-976). We have included in this study an updated version of a database for the CH4 absorption coefficients [STDS, Wenger, Ch., Champion, J.-P., 1998. J. Quant. Spectrosc. Radiat. Transfer 59, 471-480. See also http://www.u-bourgogne.fr/LPUB/TSM/sTDS.html for latest updates; Boudon, V., Champion, J.-P., Gabard, T., Loëte, M., Michelot, F., Pierre, G., Rotger, M., Wenger, Ch., Rey, M., 2004. J. Mol. Spectrosc. 228, 620-634]. For the atmosphere we find that (a) the haze extinction profile that best matches the data is one with higher (by 40%) extinction in the atmosphere with respect to Rannou et al. (2003) down to about 30 km where a complete cut-off occurs; (b) the methane mixing ratio at Titan's surface cannot exceed 3% on a disk-average basis, yielding a maximum CH4 column abundance of 2.27 km-am in Titan's atmosphere. From the derived surface albedo spectrum in the 2.7-3.08 micron region, we bring some constraints on Titan's surface composition. The albedo in the center of the methane window varies from 0.01 to 0.08. These values, compared to others reported in the other methane windows, show a strong compatibility with the water ice spectrum in the near-infrared. Without confirming its existence from this work alone, our data then appear to be compatible with water ice. A variety of other ices, such as CO2, NH3, tholin material or hydrocarbon liquid cannot be excluded from our data, but an additional unidentified component with a signature around 2.74 micron is required to satisfy the data.  相似文献   

8.
We have found that 0.8 MeV proton irradiation of crystalline H2O-ice results in temperature dependent amorphization. The H2O-ice's phase was determined using the near infrared spectrum from 1.0 μm (10,000 cm−1) to 2.5 μm (4000 cm−1). In crystalline H2O-ice, the 1.65-μm (6061 cm−1) band is strong while it is nearly absent in the amorphous spectrum [Schmitt, B., Quirico, E., Trotta, F., Grundy, W.M., 1998. In: Schmitt, B., de Bergh, C., Festou, M. (Eds.), Solar System Ices. Kluwer Academic, Norwell, MA, 1998, pp. 199-240]. In this experiment, at low temperatures (9, 25, and 40 K), irradiation of crystalline H2O-ice produced the amorphous H2O-ice's spectrum. However, at 50 K, some crystalline absorptions persisted after irradiation and at 70 and 100 K the crystalline spectrum showed only slight changes after irradiation. Our results agree with previous H2O-ice irradiation studies examining the crystalline peaks near 44 and 62 μm by Moore and Hudson [Moore, M.H., Hudson, R.L., 1992. Astrophys. J. 401, 353-360] and near 3.07 μm by Strazzulla et al. [Strazzulla, G., Baratta, G.A., Leto, G., Foti, G., 1992. Europhys. Lett. 18, 517-522] and by Leto and Baratta [Leto, G., Baratta, G.A., 2003. Astron. Astrophys. 397, 7-13]. We present a method of measuring band areas to quantify the phase and radiation dose of icy Solar System surfaces.  相似文献   

9.
The goal of this study was to explore prebiotic chemistry in a range of plausible early Earth and Mars atmospheres. To achieve this laboratory continuous flow plasma irradiation experiments were performed on N2/H2/CO/CO2 gas mixtures chosen to represent mildly reducing early Earth and Mars atmospheres derived from a secondary volcanic outgassing of volatiles in chemical equilibrium with magmas near present day oxidation state. Under mildly reducing conditions (91.79% N2, 5.89% H2, 2.21% CO, and 0.11% CO2), simple nitriles are produced in the gas phase with yield (G in molecules per 100 eV), for the key prebiotic marker molecule HCN at G∼1×10−3 (0.1 nmol J−1). In this atmosphere localized HCN concentrations possibly could approach the 10−2 M needed for HCN oligomerization. Yields under mildly oxidizing conditions (45.5% N2, 0.1% H2, 27.2% CO, 27.2% CO2) are significantly less as expected, with HCN at G∼3×10−5 (). Yields in a Triton atmosphere which can be plausibly extrapolated to represent what might be produced in trace CH4 conditions (99.9% N2, 0.1% CH4) are significant with HCN at G∼1×10−2 (1 nmol J−1) and tholins produced. Recently higher methane abundance atmospheres have been examined for their greenhouse warming potential, and higher abundance hydrogen atmospheres have been proposed based on a low early Earth exosphere temperature. A reducing (64.04% N2, 28.8% H2, 3.60% CO2, and 3.56% CH4), representing a high CH4 and H2 abundance early Earth atmosphere had HCN yields of G∼5×10−3 (0.5 nmol J−1). Tholins generated in high methane hydrogen gas mixtures is much less than in a similar mixture without hydrogen. The same mixture with the oxidizing component CO2 removed (66.43% N2, 29.88% H2, 0% CO2, and 3.69% CH4) had HCN yields of G∼1×10−3 (0.1 nmol J−1) but more significant tholin yields.  相似文献   

10.
A V-band nova search was carried out in NGC 3627 with archival Hubble Space Telescope WFPC2 data which was obtained in the period between November 1997 and January 1998. A total of four novae candidates were discovered which corresponds to a global nova rate of R = 83.65 ± 7.58 yr−1. Taking into account the K-band luminosity obtained from 2MASS (Jarrett et al., 2003) yielded a luminosity specific nova rate (LSNR) of νK = 9.60 ± 1.64 novae per year per 1010L⊙,K. Excluding one of the candidates which may be a long-period variable leads to a LSNR of νK = 7.20 ± 1.23 novae per year per 1010L⊙,K. These values are higher than other known nova rates for external galaxies except the Magellanic Clouds.  相似文献   

11.
Jeremy Bailey  Linda Ahlsved 《Icarus》2011,213(1):218-232
We have obtained spatially resolved spectra of Titan in the near-infrared J, H and K bands at a resolving power of ∼5000 using the near-infrared integral field spectrometer (NIFS) on the Gemini North 8 m telescope. Using recent data from the Cassini/Huygens mission on the atmospheric composition and surface and aerosol properties, we develop a multiple-scattering radiative transfer model for the Titan atmosphere. The Titan spectrum at these wavelengths is dominated by absorption due to methane with a series of strong absorption band systems separated by window regions where the surface of Titan can be seen. We use a line-by-line approach to derive the methane absorption coefficients. The methane spectrum is only accurately represented in standard line lists down to ∼2.1 μm. However, by making use of recent laboratory data and modeling of the methane spectrum we are able to construct a new line list that can be used down to 1.3 μm. The new line list allows us to generate spectra that are a good match to the observations at all wavelengths longer than 1.3 μm and allow us to model regions, such as the 1.55 μm window that could not be studied usefully with previous line lists such as HITRAN 2008. We point out the importance of the far-wing line shape of strong methane lines in determining the shape of the methane windows. Line shapes with Lorentzian, and sub-Lorentzian regions are needed to match the shape of the windows, but different shape parameters are needed for the 1.55 μm and 2 μm windows. After the methane lines are modeled our observations are sensitive to additional absorptions, and we use the data in the 1.55 μm region to determine a D/H ratio of 1.77 ± 0.20 × 10−4, and a CO mixing ratio of 50 ± 11 ppmv. In the 2 μm window we detect absorption features that can be identified with the ν5 + 3ν6 and 2ν3 + 2ν6 bands of CH3D.  相似文献   

12.
Radio spectroscopic observations of Comet 19P/Borrelly were performed during the 1994 apparition and at, and near, the time of the Deep Space 1 flyby in 2001. HCN, CS, CH3OH, and H2CO were detected using the 30-m telescope of the Institut de Radioastronomie Millimétrique and the James Clerk Maxwell Telescope, and their production rates relative to water are estimated to be 0.06-0.11, 0.07, 1.7, and 0.4%, respectively. Only upper limits are derived for H2S and CO. The upper limit for CO/H2O (<15%) is not very constraining, while the upper limit for the H2S/H2O ratio of 0.45% is near the bottom of the range of values measured for other comets. Observations of the OH radical at the Nançay radio telescope provide water production rates a few weeks before the 1994 and 2001 perihelia. Observations of the 110-101 water line at 557 GHz with the Odin satellite yield a water production rate of (2.5±0.5)×1028 s−1 on September 22, 2001, at the time of the Deep Space 1 encounter, and (3.3±0.6)×1028 s−1 averaged over the September 22-24, 2001 period. The line shapes are asymmetric and blueshifted by V0∼−0.18 km s−1 for the best observed HCN lines recorded one week after perihelion. The HCN line shapes, and the similar OH and HCN velocity shifts over the September-November 1994 and August-September 2001 periods, favor anisotropic outgassing towards the Sun. Strong outgassing directed along the primary dust jet seen on visible images is not excluded by the HCN line shapes, but unrealistically high gas expansion velocities are required to explain the line shapes in that case.  相似文献   

13.
Neptune was observed by the Infrared Space Observatory (ISO) Long-Wavelength Spectrometer (LWS) between 46 and 185 μm. At wavelengths between 50 and 110 μm the accuracy of these measurements is ?0.3 K. Observations of this planet made by the ISO Short-Wavelength Spectrometer between 28 and 44 μm were combined with the LWS data to determine a disk-averaged temperature profile and derive several physical quantities. The combined spectra are matched best by a He/(H2+He) mass ratio of 26.4+2.6−3.5%, reflecting a He molar fraction of 14.9+1.7−2.2%, assuming the molar fraction of CH4 to be 2% in the troposphere. This He abundance is consistent with one derived from analysis of joint Voyager-2 IRIS and radio occultation experiment data, a technique whose accuracy has recently been called into question. For a disk average, the para-H2 fraction is found to be no more than ∼1.5% different from its equilibrium value, and the N2 mixing ratio is probably less than 0.7%. The composite spectrum is best fit by invoking a CH4 ice condensate cloud. Using a Mie approximation to particle scattering and absorption, best-fit particle sizes lie between 15 and 40 μm. The composite spectra are relatively insensitive to the vertical distribution of the cloud, but the particle scale height must be greater than 5% of the gas scale height. The best models are consistent with an effective temperature for Neptune that is 59.5±0.6 K, a value slightly lower than derived by the Voyager IRIS experiment—possibly Neptune's mid- and far-infrared emission has changed during the seven years that lie between its encounter with Voyager 2 and the first spectra taken of this planet with ISO. The model spectra are also ostensibly lower than ground-based observations in the spectral range of 17-24 μm, but this discrepancy can be relieved by perturbing the temperature of the lower stratosphere where the LWS spectrum is not particularly sensitive, combined with the uncertainty in the absolute calibration of the ground-based measurements.  相似文献   

14.
Hydrocarbons such as acetylene (C2H2) and ethane (C2H6) are important tracers in Jupiter's atmosphere, constraining our models of the chemical and dynamical processes. However, our knowledge of the vertical and meridional variations of their abundances has remained sparse. During the flyby of the Cassini spacecraft in December 2000, the Composite Infrared Spectrometer (CIRS) instrument was used to map the spatial variation of emissions from 10 to 1400 cm−1 (1000-7 μm). In this paper we analyze a zonally averaged set of CIRS spectra taken at the highest (0.48 cm−1) resolution, firstly to infer atmospheric temperatures in the stratosphere at 0.5-20 mbar via the ν4 band of CH4, and in the troposphere at 150-400 mbar, via the H2 absorption at 600-800 cm−1. Stratospheric temperatures at 5 mbar are generally warmer in the north than the south by 7-8 K, while tropospheric temperatures show no such asymmetry. Both latitudinal temperature profiles however do show a pattern of maxima and minima which are largely anti-correlated between the two levels. We then use the derived temperature profiles to infer the vertical abundances of C2H2 and C2H6 by modeling tropospheric absorption (∼200 mbar) and stratospheric emission (∼5 mbar) in the C2H2ν5 and C2H6ν9 bands, and also emission of the acetylene (ν4+ν5)−ν4 hotband (∼0.1 mbar). Acetylene shows a distinct north-south asymmetry in the stratosphere, with 5 mbar abundances greatest close to 20° N and decreasing from there towards both poles by a factor of ∼4. At 200 mbar in contrast, acetylene is nearly flat at a level of ∼3×10−9. Additionally, the abundance gradient of C2H2 between 10 and 0.1 mbar is derived, based on interpolated temperatures at 0.1 mbar, and is found to be positive and uniform with latitude to within errors. Ethane at both 5 and 200 mbar shows increasing VMR towards polar regions of ∼1.75 towards 70° N and ∼2.0 towards 70° S. An explanation for the meridional trends is proposed in terms of a combination of photochemistry and dynamics. Poleward, the decreasing UV flux is predicted to decrease the abundances of C2H2 and C2H6 by factors of 2.7 and 3.5, respectively, at latitude 70°. However, the lifetime of C2H6 in the stratosphere (3×1010 s at 5 mbar) is much longer than the dynamical timescale for meridional mixing inferred from Comet SL-9 debris (5-50×108 s), and therefore the rising abundance towards high latitudes likely indicates that meridional mixing dominates over photochemical effects. For C2H2, the opposite occurs, with the relatively short photochemical lifetime (3×107 s), compared to meridional mixing times, ensuring that the expected photochemical trends are visible.  相似文献   

15.
Laboratory spectra of methane-nitrogen mixtures have been recorded in the near-infrared range (1.0-1.65 μm) in conditions similar to Titan's near surface, to facilitate the interpretation of the DISR/DLIS (DISR—Descent Imager/Spectral Radiometer) spectra taken during the last phase of the descent of the Huygens Probe, when the surface was illuminated by a surface-science lamp. We used a 0.03 cm−1 spectral resolution, adequate to resolve the lines at high pressure (pN2∼1.5 bar). By comparing the laboratory spectra with synthetic calculations in the well-studied ν2+2ν3 band (7515-7620 cm−1), we determine a methane absorption column density of 178±20 cm atm and a temperature of 118±10 K in our experiment. From this, we derive the methane absorption coefficients over 1.0-1.65 μm with a 0.03 cm−1 sampling, allowing for the extrapolation of the results to any other methane column density under the relevant pressure and temperature conditions. We then revisit the calibration and analysis of the Titan “lamp-on” DLIS spectra. We infer a 5.1±0.8% methane-mixing ratio in the first 25 m of Titan's atmosphere. The CH4 mixing ratio measured 90 s after landing from a distance of 45 cm is found to be 0.92±0.25 times this value, thus showing no post-landing outgassing of methane in excess of ∼20%. Finally, we determine the surface reflectivity as seen between 25 m and 45 cm and find that the 1500 nm absorption band is deeper in the post-landing spectrum as compared to pre-landing.  相似文献   

16.
A. Bar-Nun  G. Notesco 《Icarus》2007,190(2):655-659
Recent attempts using high resolution spectra to detect N+2 in several comets were unsuccessful [Cochran, A.L., Cochran, W.D., Baker, E.S., 2000. Icarus 146, 583-593; Cochran, A.L., 2002. Astrophys. J. 576, L165-L168]. The upper limits on N+2 in comparison with the positively detected CO+ for Comets C/1995 O1 Hale-Bopp, 122P/1995 S1 de Vico and 153P/2002 C1 Ikeya-Zhang range between . Ar was not detected in three recent comets [Weaver, H.A., Feldman, P.D., Combi, M.R., Krasnopolsky, V., Lisse, C.M., Shemansky, D.E., 2002. Astrophys. J. 576, L95-L98], with upper limits of Ar/CO<(3.4-7.8)×10−2 for Comets C/1999 T1 McNaught-Hartley, C/2001 A2 LINEAR and C/2000 WM1 LINEAR. The Ar detected by Stern et al. [Stern, S.A., Slater, D.C., Festou, M.C., Parker, J.Wm., Gladstone, G.R., A'Hearn, M.F., Wilkinson, E., 2000. Astrophys. J. 544, L169-L172] for Comet C/1995 O1 Hale-Bopp, gives a ratio Ar/CO=7.25×10−2, which was not confirmed by Cosmovici et al. [Cosmovici, C.B., Bratina, V., Schwarz, G., Tozzi, G., Mumma, M.J., Stalio, R., 2006. Astrophys. Space Sci. 301, 135-143]. Trying to solve the two problems, we studied experimentally the trapping of N2+CO+Ar in amorphous water ice, at 24-30 K. CO was found to be trapped in the ice 20-70 times more efficiently than N2 and with the same efficiency as Ar. The resulting Ar/CO ratio of 1.2×10−2 is consistent with Weaver et al.'s [Weaver, H.A., Feldman, P.D., Combi, M.R., Krasnopolsky, V., Lisse, C.M., Shemansky, D.E., 2002. Astrophys. J. 576, L95-L98] non-detection of Ar. However, with an extreme starting value for N2/CO = 0.22 in the region where the ice grains which agglomerated to produce comet nuclei were formed, the expected N2/CO ratio in the cometary ice should be 6.6×10−3, much higher than its non-detection limit.  相似文献   

17.
The outer Solar System object (29981) 1999 TD10 was observed simultaneously in the R, and J and H bands in September 2001, and in B, V, R, and I in October 2002. We derive B−V=0.80±0.05 mag, V−R=0.48±0.05 mag, R−I=0.44±0.05 mag, R−J=1.24±0.05 mag, and J−H=0.61±0.07 mag. Combining our data with the data from Rousselot et al. (2003, Astron. Astrophys. 407, 1139) we derive a synodic period of 15.382±0.001 hr in agreement with the period from Rousselot et al. Our observations at the same time, with better S/N and seeing, show no evidence of a coma, contrary to the claim by Choi et al. (2003, Icarus 165, 101).  相似文献   

18.
Hydrogen peroxide (H2O2) has been suggested as a possible oxidizer of the martian surface. Photochemical models predict a mean column density in the range of 1015-1016 cm−2. However, a stringent upper limit of the H2O2 abundance on Mars (9×1014 cm−2) was derived in February 2001 from ground-based infrared spectroscopy, at a time corresponding to a maximum water vapor abundance in the northern summer (30 pr. μm, Ls=112°). Here we report the detection of H2O2 on Mars in June 2003, and its mapping over the martian disk using the same technique, during the southern spring (Ls=206°) when the global water vapor abundance was ∼10 pr. μm. The spatial distribution of H2O2 shows a maximum in the morning around the sub-solar latitude. The mean H2O2 column density (6×1015 cm−2) is significantly greater than our previous upper limit, pointing to seasonal variations. Our new result is globally consistent with the predictions of photochemical models, and also with submillimeter ground-based measurements obtained in September 2003 (Ls=254°), averaged over the martian disk (Clancy et al., 2004, Icarus 168, 116-121).  相似文献   

19.
We report the discovery of the forbidden electronic a1Δ→X3Σ− transition of the SO radical on Io at 1.7 μm with the W. M. Keck II telescope on 24 September 1999 (UT), while the satellite was eclipsed by Jupiter. The shape of the SO emission band suggests a rotational temperature of ∼1000 K; i.e., the gas is extremely hot. We interpret the observed emission rate of ∼2×1027 photons s−1 to be caused by SO molecules in the excited a1Δ state being directly ejected from the vent at a thermodynamic quenching temperature of ∼1500 K, assuming a SO/SO2 abundance ratio of ∼0.1 and a total venting rate of ∼1031 molecules s−1 (Strobel and Wolven 2001, Astrophys. Space Sci. 277, 1-17). The shape of our complete (1.6-2.5 μm) spectrum suggests that the volcano Loki contains a small (∼2 km2) hot spot at 960±12 K, as well as a larger (∼50 km2) area at 640±5 K.  相似文献   

20.
We report on spectro-imaging infrared observations of Jupiter's auroral zones, acquired in October 1999 and October 2000 with the FTS/BEAR instrument at the Canada-France-Hawaii Telescope. The use of narrow-band filters at 2.09 and 2.12 μm, combined with high spectral resolution (0.2 cm−1), allowed us to map emission from the H2S1(1) quadrupole line and from several H3+ lines. The H2 and H3+ emission appears to be morphologically different, especially in the north, where the latter notably exhibits a “hot spot” near 150°-170° System III longitude. This hot spot coincides in position with the region of increased and variable hydrocarbon, FUV and X-ray emission, but is not seen in the more uniform H2S1(1) emission. We also present the first images of the H2 emission in the southern polar region. The spectra include a total of 14 H3+ lines, including two hot lines from the 3ν2-ν2 band, detected on Jupiter for the first time. They can be used to determine H3+ column densities, rotational (Trot) and vibrational (Tvib) temperatures. We find the mean Tvib of the v2=3 state to be lower (960±50 K) than the mean Trot in v2=2 (1170±75 K), indicating an underpopulation of the v2=3 level with respect to local thermodynamical equilibrium. Rotational temperatures and associated column densities are generally higher and lower, respectively, than inferred previously from ν2 observations. This is a likely consequence of a large positive temperature gradient in the sub-microbar auroral atmosphere. While the signal-to-noise is not sufficient to take full advantage of the 2-D capabilities of the observations, the search for correlations between line intensities, Tvib and column densities, indicates that variations in line intensities are mostly due to correlated variations in the H3+ column densities. The thermostatic role played by H3+ at ionospheric levels may provide an explanation. The exception is the northern “hot spot,” which exhibits a Tvib about 250 K higher than other regions. A partial explanation might invoke a homopause elevation in this region, but a fully consistent scenario is not yet available. The different distributions of the H2 and H3+ emission are equally difficult to explain.  相似文献   

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