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1.
Abstract– The single‐piece iron meteorite Javorje, with a mass of 4920 g, is the heaviest and largest meteorite found in the territory of Slovenia. The meteorite Javorje is a medium octahedrite with kamacite bandwidth of 0.85 ± 0.26 mm. The bulk composition of Ni (7.83 wt%), Co (0.48 wt%) and trace elements Ga (25 μg/g), Ge (47 μg/g), Ir (7.6 μg/g), As (5.8 μg/g), Au (0.47 μg/g), and Pt (13.4 μg/g) indicates that the meteorite Javorje belongs to the chemical group IIIAB. Mineral and bulk chemical compositions are consistent with other reported group IIIAB meteorites. The presence of numerous rhabdites, carlsbergite, sparse troilite, and chromite and abundance of daubréelites are in accordance with low‐Ni and low‐P IIIAB iron meteorites. The severely weathered surface and secondary weathering products in the interior of the meteorite suggest its high terrestrial age.  相似文献   

2.
Abstract— Noble gases repeatedly have served to widen the scope of meteorite research. During the first half century of such measurements, the emphasis was on the determination of U, Th/He-gas retention ages of iron meteorites, which is the most unsuitable class of meteorites for such studies. With the realization that the He in these meteorites results from the interaction of cosmic rays with meteoritic matter, meteorites became to be used as “the poor man's space probe” that yielded information on the constancy in time and space of the cosmic radiation. Another widening of scope came with the discovery of extremely high noble gas contents in the outermost layers of the individual grains that make up stony meteorites. These gases are of solar origin; they have been implanted as low-energy solar wind (SW) or as solar energetic particles (SEP) into the grains before their compaction. Presently they offer the only opportunity to precisely measure the isotopic composition of solar matter and to learn about potential changes of the Sun in time. Stony meteorites of the “carbonaceous” variety contain “stardust” that carries the undiluted nucleosynthesis products of individual stars that yield incredibly detailed information concerning the parameters that prevailed during the synthesis.  相似文献   

3.
Fossil iron meteorites are extremely rare in the geological sedimentary record. The paleometeorite described here is the first such finding at the Cretaceous‐Paleogene (K‐Pg) boundary. In the boundary clay from the outcrop at the Lechówka quarry (Poland), fragments of the paleometeorite were found in the bottom part of the host layer. The fragments of meteorite (2–6 mm in size) and meteoritic dust are metallic‐gray in color and have a total weight of 1.8181 g. Geochemical and petrographic analyses of the meteorite from Lechówka reveal the presence of Ni‐rich minerals with a total Ni amount of 2–3 wt%. The identified minerals are taenite, kamacite, schreibersite, Ni‐rich magnetite, and Ni‐rich goethite. No relicts of silicates or chromites were found. The investigated paleometeorite apparently represents an independent fall and does not seem to be derived from the K‐Pg impactor. The high degree of weathering did not permit the chemical classification of the meteorite fragments. However, the recognized mineral inventory, lack of silicates, and their pseudomorphs and texture may indicate that the meteorite remains were an iron meteorite.  相似文献   

4.
Abstract— The measured Cu and Cr contents in magmatic iron meteorites appear to contradict the behavior predicted by experimental fractional crystallization studies currently available. To investigate the origin of Cu and Cr concentrations observed in these meteorites, a thorough set of solid metal/liquid metal experiments were conducted in the Fe‐Ni‐S system. In addition to Cu and Cr, partitioning values were also determined for As, Au, Bi, Co, Mo, Ni, Pb, Rh, Ru, Sb, Sn, V, and Zn from the experiments. Experimental results for Cu and Cr showed similar chalcophile partitioning behavior, whereas these elements have differently sloped trends within magmatic iron meteorite groups. Thus, fractional crystallization alone cannot control both the Cu and Cr concentrations in these iron meteorite groups. A simple fractional crystallization model based on our experimental Cu partitioning results was able to match the Cu versus Au trend observed in the S‐poor IVB iron meteorite group but not the decreasing Cu versus Au trends in the IIAB and IIIAB groups or the unique S‐shaped Cu versus Au trend in the IVA group. However, the crystallization model calculations were found to be very sensitive to the specific choice for the mathematical expression of D(Cu), suggesting that any future refinement of the parameterization of D(Cu) should include a reassessment of the Cu fractional crystallization trends. The Cr versus Au trends in magmatic iron meteorite groups are steeper than those of Cu and not explained by fractional crystallization. Other influences, such as the removal of chromite from the crystallizing system or sampling biases during iron meteorite compositional analyses, are likely responsible for the Cr trends in magmatic iron meteorite groups.  相似文献   

5.
We report the first combined atom‐probe tomography (APT) and transmission electron microscopy (TEM) study of a kamacite–tetrataenite (K–T) interface region within an iron meteorite, Bristol (IVA). Ten APT nanotips were prepared from the K–T interface with focused ion beam scanning electron microscopy (FIB‐SEM) and then studied using TEM followed by APT. Near the K‐T interface, we found 3.8 ± 0.5 wt% Ni in kamacite and 53.4 ± 0.5 wt% Ni in tetrataenite. High‐Ni precipitate regions of the cloudy zone (CZ) have 50.4 ± 0.8 wt% Ni. A region near the CZ and martensite interface has <10 nm sized Ni‐rich precipitates with 38.4 ± 0.7 wt% Ni present within a low‐Ni matrix having 25.5 ± 0.6 wt% Ni. We found that Cu is predominantly concentrated in tetrataenite, whereas Co, P, and Cr are concentrated in kamacite. Phosphorus is preferentially concentrated along the K‐T interface. This study is the first precise measurement of the phase composition at high spatial resolution and in 3‐D of the K‐T interface region in a IVA iron meteorite and furthers our knowledge of the phase composition changes in a fast‐cooled iron meteorite below 400 °C. We demonstrate that APT in conjunction with TEM is a useful approach to study the major, minor, and trace elemental composition of nanoscale features within fast‐cooled iron meteorites.  相似文献   

6.
Abstract— The Burnwell, Kentucky, meteorite fell as a single stone on 1990 September 4. The Burnwell meteorite has lower Fa in olivine (15.8 mol%), Fs in orthopyroxene (13.4 mol%), Co in kamacite (0.36 wt%), FeO from bulk chemical analysis (9.43 wt%), and Δ17O (0.51 ± 0.02%), and higher Fe, Ni, Co metal (19.75 wt% from bulk wet chemical analysis) than observed in H chondrites. The Burnwell meteorite plots on extensions of H-L-LL chondrite trends for each of these properties towards more reducing compositions than in H chondrites. Extensions of this trend have been previously suggested in the case of other low-FeO chondrites or silicate inclusions in the HE iron Netschaëvo, but interpretation of the evidence in these meteorites is complicated by terrestrial weathering, chemical disequilibrium or reduction. In contrast, the Burn-well meteorite is an equilibrated fall that exhibits no evidence for reduction. As such, it provides the first definitive evidence for extension of the H-L-LL ordinary chondrite trend beyond typical H values towards more reducing compositions.  相似文献   

7.
Abstract— A set of iron meteorites was investigated for Re-Os isotopes and provides a well-defined isochron age of 4.624 ± 0.017 Ba and an initial 187Os/188Os ratio of 0.095636 ± 0.00009. Actual ages may be a few percent lower due to uncertainty on the 187Re decay constant. Within the small sample number presented here, there is no evidence for age differences between classes. A more detailed study of the meteorite Kodaïkanal shows that the metal reservoir of this meteorite formed approximately at the same time as the other iron meteorites, in contrast with the silicate inclusions which display a formation age of 3.67 Ba with all other chronometers. A collisional origin is in agreement with the data on this meteorite. Major secondary events do not affect the Re-Os system at the bulk rock scale in metal as it is the sole significant reservoir of these two elements. A Re-Os and Rb-Sr investigation of meteoritic troilite exhibits disturbed chronometric systems, which we attribute to the terrestrial history of the meteorite.  相似文献   

8.
Abstract— ‐Iron meteorites exhibit a large range in Ni concentrations, from only 4% to nearly 60%. Most previous experiments aimed at understanding the crystallization of iron meteorites have been conducted in systems with about 10% Ni or less. We performed solid metal/liquid metal experiments to determine the effect of Ni on partition coefficients for 20 trace elements pertinent to iron meteorites. Experiments were conducted in both the end‐member Ni‐S system as well as in the Fe‐Ni‐S system with intermediate Ni compositions applicable to high‐Ni iron meteorites. The Ni content of the system affects solid metal/liquid metal partitioning behavior. For a given S concentration, partition coefficients in the Ni‐S system can be over an order of magnitude larger than in the Fe‐S system. However, for compositions relevant to even the most Ni‐rich iron meteorites, the effect of Ni on partitioning behavior is minor, amounting to less than a factor of two for the majority of trace elements studied. Any effect of Ni also appears minor when it is compared to the large influence S has on element partitioning behavior. Thus, we conclude that in the presence of an evolving S‐bearing metallic melt, crystallization models can safely neglect effects from Ni when considering the full range of iron meteorite compositions.  相似文献   

9.
Abstract— The radicals in the insoluble organic matter (IOM) from the Tagish Lake meteorite were studied by electron paramagnetic resonance and compared to those existing in the Orgueil and Murchison meteorites. As in the Orgueil and Murchison meteorites, the radicals in the Tagish Lake meteorite are heterogeneously distributed and comprise a substantial amount (?42%) of species with a thermally accessible triplet state and with the same singlet‐triplet gap, ΔE ?0.1 eV, as in the Orgueil and Murchison meteorites. These species were identified as diradicaloid moieties. The existence of similar diradicaloid moieties in three different carbonaceous chondrites but not in terrestrial IOM strongly suggests that these moieties could be “fingerprints” of the extraterrestrial origin of meteoritic IOM and markers of its synthetic pathway before its inclusion into a parent body.  相似文献   

10.
The Whitecourt meteorite impact crater, Alberta, Canada is a rare example of a well‐preserved small impact structure, with which thousands of meteorite fragments are associated. As such, this crater represents a unique opportunity to investigate the effect of a low‐energy impact event on an impacting iron bolide. Excellent documentation of meteorite fragment locations and characteristics has generated a detailed distribution map of both shrapnel and regmaglypted meteorite types. The meteorites' distribution, and internal and external characteristics support a low‐altitude breakup of the impactor which caused atmospherically ablated (regmaglypted) meteorites to fall close to the crater and avoid impact‐related deformation. In contrast, shrapnel fragments sustained deformation at macro‐ and microscales resulting from the catastrophic disruption of the impactor. The impactor was significantly fragmented along pre‐existing planes of weakness, including kamacite lamellae and inclusions, resulting in a bias toward low‐mass (<100 g) fragments. Meteorite mineralogy was investigated and the accessory minerals were found to be dominated by sulfides and phosphides with rare carlsbergite, consistent with other low‐Ni IIIAB iron meteorites. Considerations of the total mass of meteoritic material recovered at the site relative to the probable fraction of the impactor that was preserved based on modeling suggests that the crater was formed by a higher velocity, lower mass impactor than previously inferred.  相似文献   

11.
The author carried out a study of pulverised cosmic matter extracted from the soil at the fall locality of the Sikhote Alin iron meteorite shower. Three forms of dust were distinguishable: meteoritic, sharp-angled, irregular particles from the break-up of the meteorite; meteoric, spherical, magnetic particles from ablation; and micro meteorites. Meteoritic and meteoric dust was also discovered in the soil of the regions of fall of the Boguslavka and Yardymly iron meteorites. Experiments made by the author for the purpose of obtaining artificial meteoric dust from meteoritic matter of various types have shown that the meteoric dust obtained from stony meteorites is composed of spherules similar to those extracted from the soil in the areas of fall of the Sikhote Alin, Boguslavka and Yardymly iron meteorites. Cosmic dust, the particles of which are usually called micrometeorites, due to their small size, are not subjected to the influence of temperature as they pass through the Earth's atmosphere and they reach the Earth's surface unaltered. It is proposed that meteoric and cosmic dust comprises the largest part of the cosmic matter falling onto the Earth:  相似文献   

12.
Abstract— The complete (or near complete) differentiation of a chondritic parent body is believed to result in an object with an Fe-Ni core, a thick olivine-dominated mantle and a thin plagioclase/pyroxene crust. Compositional groupings of iron meteorites give direct evidence that at least 60 chondritic parent bodies have been differentiated and subsequently destroyed. A long standing problem has been that our meteorite collections, and apparently our asteroid observations as well, show a great absence of olivine-dominated metal-free mantle material. While the basaltic achondrites (HED meteorites) represent metal-free pyroxene-dominated crustal samples, the isotopic and geochemical evidence implies that this class is derived from only one parent body (perhaps Vesta). Thus the meteoritic (and perhaps astronomical) evidence also suggests a great absence of crustal material resulting from the collisional disruption of numerous parent bodies. One explanation for the rarity of olivine-dominated metal-free and basaltic asteroids that fits all the available evidence is that all differentiated parent bodies, with the exception of Vesta, were either disrupted or had their crusts and mantles stripped very early in the age of the solar system. The resulting basaltic and olivine-dominated metal-free fragments were continually broken down until their sizes dropped at least below our current astronomical measurement limit (～5–10 km for inner-belt objects) and perhaps completely comminuted such that meteorite samples are no longer delivered. Because of their greater strengths and longer survival time in interplanetary space, only the iron and the stony-iron meteorites remain as the final tracers of this differentiation and collisional history. However, other scenarios remain plausible such as those which invoke “space weathering” processes that effectively disguise the distinctive basaltic and olivine spectra of possible remnant crustal and mantle material within the main asteroid belt.  相似文献   

13.
We have analyzed Oktibbeha County, the most Ni-rich iron meteorite, for Ni, Co, Cu, Ga, Ge, As, Sb, Ir, and Au. Cu and Sb are higher than in any other iron, but other trace elements are within the ranges typically found in iron meteorites. Extrapolation of trace element trends in group IAB indicates that Oktibbeha County is a member of this group. This sheds light on the origin of groups IAB and IIICD, which are thought to be derived from impact melts on parent bodies of chondritic composition. Lafayette (iron), another sample reported in the literature to have a similarly high Ni content, is probably a pseudometeorite.  相似文献   

14.
Cadmium is a highly volatile element and its abundance in meteorites may help better understand volatility‐controlled processes in the solar nebula and on meteorite parent bodies. The large thermal neutron capture cross section of 113Cd suggests that Cd isotopes might be well suited to quantify neutron fluences in extraterrestrial materials. The aims of this study were (1) to evaluate the range and magnitude of Cd concentrations in magmatic iron meteorites, and (2) to assess the potential of Cd isotopes as a neutron dosimeter for iron meteorites. Our new Cd concentration data determined by isotope dilution demonstrate that Cd concentrations in iron meteorites are significantly lower than in some previous studies. In contrast to large systematic variations in the concentration of moderately volatile elements like Ga and Ge, there is neither systematic variation in Cd concentration amongst troilites, nor amongst metal phases of different iron meteorite groups. Instead, Cd is strongly depleted in all iron meteorite groups, implying that the parent bodies accreted well above the condensation temperature of Cd (i.e., ≈650 K) and thus incorporated only minimal amounts of highly volatile elements. No Cd isotope anomalies were found, whereas Pt and W isotope anomalies for the same iron meteorite samples indicate a significant fluence of epithermal and higher energetic neutrons. This observation demonstrates that owing to the high Fe concentrations in iron meteorites, neutron capture mainly occurs at epithermal and higher energies. The combined Cd‐Pt‐W isotope results from this study thus demonstrate that the relative magnitude of neutron capture‐induced isotope anomalies is strongly affected by the chemical composition of the irradiated material. The resulting low fluence of thermal neutrons in iron meteorites and their very low Cd concentrations make Cd isotopes unsuitable as a neutron dosimeter for iron meteorites.  相似文献   

15.
Abstract– Although iron isotopes are increasingly used for meteorites studies, no attempt has been made to evaluate the effect of terrestrial weathering on this isotopic tracer. We have thus conducted a petrographic, chemical, and iron isotopic study of equilibrated ordinary chondrites (OC) recovered from hot Moroccan and Algerian Saharan deserts environment. As previously noticed, we observe that terrestrial desertic weathering is characterized by the oxidation of Fe‐Ni metal (Fe0), sulfide and Fe2+ occurring in olivine and pyroxene. It produces Fe‐oxides and oxyhydroxides that partially replace metal, sulfide grains and also fill fractures. The bulk chemical compositions of the ordinary chondrites studied show a strong Sr and Ba enrichment and a S depletion during weathering. Bulk meteoritic iron isotope compositions are well correlated with the degree of weathering and S, Sr, and Ba contents. Most weathered chondrites display the heaviest isotopic composition, by up to 0.1‰, which is of similar magnitude to the isotopic variations resulting from meteorite parent bodies’ formation and evolution. This is probably due to the release of isotopically light Fe2+ to waters on the Earth’s surface. Hence, when subtle Fe isotopic effects have to be studied in chondrites, meteorites with weathering grade above W2 should be avoided.  相似文献   

16.
Tube‐shaped beads excavated from grave pits at the prehistoric Gerzeh cemetery, approximately 3300 BCE, represent the earliest known use of iron in Egypt. Using a combination of scanning electron microscopy and micro X‐ray microcomputer tomography, we show that microstructural and chemical analysis of a Gerzeh iron bead is consistent with a cold‐worked iron meteorite. Thin fragments of parallel bands of taenite within a meteoritic Widmanstätten pattern are present, with structural distortion caused by cold‐working. The metal fragments retain their original chemistry of approximately 30 wt% nickel. The bulk of the bead is highly oxidized, with only approximately 2.4% of the total bead volume remaining as metal. Our results show that the first known example of the use of iron in Egypt was produced from a meteorite, its celestial origin having implications for both the perception of meteorite iron by ancient Egyptians and the development of metallurgical knowledge in the Nile Valley.  相似文献   

17.
Abstract— Infrared spectra of mineral grains from primitive meteorites could be useful for comparison with astronomical infrared spectra since some of their grains might be similar to those formed in the planet‐forming disks around young stars or in the envelopes surrounding late‐type stars. To assess the usefulness of meteorite spectra, olivine grains separated from primitive meteorites have been analyzed using FTIR microscope techniques in the 2–16 μm wavelength range. The sub‐micron sizes of the grains made a complex preparation process necessary. Five characteristic bands were measured near 11.9, 11.2, 10.4, 10.1, and 10.0 μm. The results of 59 analyses allow the calculation of band positions for meteoritic olivines as a function of their iron and magnesium contents. Comparison of the meteoritic results with astronomical data for comets and dust around young and old stars, which exhibit bands similar to the strongest infrared bands observed in the grains (at 11.2 μm), show that the spectral resolution of the astronomical observations is too low to ascertain the exact iron and magnesium (Mg: Fe) ratio of the dust in the 8–13 μm wavelength range.  相似文献   

18.
The mineralogy and bulk chemical compositions of three iron meteorites (Zhaoping, Xifu and Hami) recently found in China are reported here and are classified on the basis of their bulk chemical compositions. Zhaoping contains 93.4 mg/g Ni, 85.9 μg/g Ga, 418 μg/g Ge, 5.24 mg/g Co, 1.94 μg/g Ir, 0.774 μg/g W, and 1.62 μg/g Au and belongs to the low-Ni, low-Au subgroup of IAB. It is a coarse octahedrite and consists of kamacite, taenite, troilite, schreibersite and cohenite. The cohenite has entirely decomposed to graphite and low-Ni kamacite in our samples. Zhaoping contains some inclusions of Mn-free sarcopside which were rarely reported in IAB iron meteorites. Xifu has 74.1 mg/g Ni, 58.8gμg/g Ga, 150 μg/g Ge, and 0.913 μg/g W. Xifu is a member of group IIICD iron meteorite. Like most of IIICD irons, Xifu is a coarsest octahedrite with kamacite bandwidth larger than 3mm, and contains kamacite, taenite and schreibersite. Carbides and graphite are not found in the sample because of its being heterogeneous. Hami has 106 mg/g Ni, 5.36 mg/g Co and 0.922 μg/g Ir. We did not obtain the Ga and Ge contents in Hami because of their low concentrations and the limited precision of the INAA technique. Hami is an unclassified iron meteorite on the basis of the contents of other trace elements, structure and mineralogy. On mineralogy and structure, Hami resembles Rafruti, another unclassified iron meteorite.  相似文献   

19.
We combined high‐resolution and space‐resolved elemental distribution with investigations of magnetic minerals across Fe,Ni‐alloy and troilite interfaces for two nonmagmatic (Morasko and Mundrabilla) IAB group iron meteorites and an octahedrite found in 1993 in Coahuila/Mexico (Coahuila II) preliminarily classified on Ir and Au content as IIAB group. The aim of this study was to elucidate the crystallization and thermal history using gradients of the siderophile elements Ni, Co, Ge, and Ga and the chalcophile elements Cr, Cu, and Se with a focus on magnetic minerals. The Morasko and Coahuila II meteorite show a several mm‐thick carbon‐ and phosphorous‐rich transition zone between Fe,Ni‐alloy and troilite, which is characterized by magnetic cohenite and nonmagnetic or magnetic schreibersite. At Morasko, these phases have a characteristic trace element composition with Mo enriched in cohenite. In both Morasko and Coahuila II, Ni is enriched in schreibersite. The minerals have crystallized from immiscible melts, either by fractional crystallization and C‐ and P‐enrichment in the melt, or by partial melting at temperatures slightly above the eutectic point. During crystallization of Mundrabilla, the field of immiscibility was not reached. Independent of meteorite group and cooling history, the magnetic mineralogy (daubreelite, cohenite and/or schreibersite, magnetite) is very similar to the troilite (and transition zone) for all three investigated iron meteorites. If these minerals can be separated from the metal, they might provide important information about the early solar system magnetic field. Magnetite is interpreted as a partial melting or a terrestrial weathering product of the Fe,Ni‐alloy under oxidizing conditions.  相似文献   

20.
Abstract— We give a nonmathematical review of recent work regarding the Yarkovsky effect on asteroidal fragments. This effect may play a critical, but underappreciated, role in delivering meteorites to Earth. Two variants of the effect cause drifts in orbital elements, notably semimajor axes. The “classic” or “diurnal” Yarkovsky effect is associated with diurnal rotation at low obliquity. More recently, a “seasonal” effect has also been described, associated with high obliquity. Studies of these Yarkovsky effects are combined with studies of resonance effects to clarify meteorite delivery. If there were no Yarkovsky drift, asteroid fragments could reach a resonance only if produced very near that resonance. However, objects in resonances typically reach Earth-crossing orbits within a few million years, which is inconsistent with stone meteorites' cosmic-ray exposure (CRE) ages (5–50 Ma) and iron meteorites' CRE ages (100–1000 Ma). In the new view, on the other hand, large objects in the asteroid belt are “fixed” in semimajor axis, but bodies up to 100 m in diameter are in a constant state of mixing and flow, especially if the thermal conductivity of their surface layers is low. Thus, small asteroid fragments may reach the resonances after long periods of drift in the main belt. Yarkovsky drift effects, combined with resonance effects, appear to explain many meteorite properties, including: (1) the long CRE ages of iron meteorites (due to extensive drift lifetimes in the belt); (2) iron meteorites' sampling of numerous parent bodies; (3) the shorter CRE ages of most stone meteorites (due to faster drift, coupled with weaker strength and more rapid collisional erosion); and (4) the abundance of falls from discrete impact events near resonances, such as the 8 Ma CRE age of H chondrites. Other consequences include: the delivery of meteorite parent bodies to resonances is enhanced; proportions of stone and iron meteorites delivered to Earth may be different from the proportions at the same sizes left in the belt, which in turn may differ from the ratio produced in asteroidal collisions; Rabinowitz's 10–100 m objects may be preferentially delivered to near-Earth space; and the delivery of C-class fragments from the outer belt may be inhibited, compared to classes in other parts of the belt. Thus, Yarkovsky effects may have important consequences in meteoritics and asteroid science.  相似文献   

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