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1.
Compositional data analysis was performed on chemical compositions of martian surface materials in order to unravel scenarios of past and present weathering and to evaluate the role of meteoritic accumulation. The observed chemical variability is analyzed by means of principal component analysis. Potential reservoirs that may have contributed primary material to soil formation are assessed. Chemical alteration in the course of in situ weathering is described in terms of alteration vectors that link the compositions of fresh rocks and their weathering crusts. The interplay of localized chemical alteration and global scale re-distribution and mixing of fines material is documented through the identification of different soil forming branches. These branches emanate from distinct compositional domains, which comprise basaltic and basalt-andesitic primary materials, and they converge to a global dust composition, which represents the product of chemical and physical disintegration and subsequent global mixing. Mass balance considerations applied to localized weathering phenomena are in line with findings from experimental acid-sulfate weathering on olivine-bearing basalts and the persistence of secondary silica in evaporitic rocks. In addition the composition and oxidation state of involved volcanic gases is deduced. Our findings corroborate the past activity of volcanic exhalation products in combination with liquid water. We conclude that average martian crust is dominated by basaltic materials at its topmost level and that the amount of meteoritic accumulation may contribute about 6 wt% to the martian fines. From the meteoritic contribution minimum soil formation rates of 60±20 cm/Gyr are derived. Sequestration of atmospheric oxygen during weathering of primary materials may account for the oxygen deficiency of the martian atmosphere. A 4-14-m-thick layer of oxidized martian fines may account for the estimated deficit of 1.7×1018 mol O2 in the martian atmosphere depending on the primary oxidation state of volatile volcanic emanations.  相似文献   

2.
The Dry Valleys of Antarctica are an excellent analog of the environment at the surface of Mars. Soil formation histories involving slow processes of sublimation and migration of water-soluble ions in polar desert environments are characteristic of both Mars and the Dry Valleys. At the present time, the environment in the Dry Valleys is probably the most similar to that in the mid-latitudes on Mars although similar conditions may be found in areas of the polar regions during their respective Mars summers. It is thought that Mars is currently in an interglacial period, and that subsurface water ice is sublimating poleward. Because the Mars sublimation zones seem to be the most similar to the Antarctic Dry Valleys, the Dry Valleys-type Mars climate is migrating towards the poles. Mars has likely undergone drastic obliquity changes, which means that the Dry Valleys analog to Mars may be valid for large parts of Mars, including the polar regions, at different times in geologic history. Dry Valleys soils contain traces of silicate alteration products and secondary salts much like those found in Mars meteorites. A martian origin for some of the meteorite secondary phases has been verified previously; it can be based on the presence of shock effects and other features which could not have formed after the rocks were ejected from Mars, or demonstrable modification of a feature by the passage of the meteorite through Earth's atmosphere (proving the feature to be pre-terrestrial). The martian weathering products provide critical information for deciphering the near-surface history of Mars. Definite martian secondary phases include Ca-carbonate, Ca-sulfate, and Mg-sulfate. These salts are also found in soils from the Dry Valleys of Antarctica. Results of earlier Wright Valley work are consistent with what is now known about Mars based on meteorite and orbital data. Results from recent and current Mars missions support this inference. Aqueous processes are active even in permanently frozen Antarctic Dry Valleys soils, and similar processes are probably also occurring on Mars today, especially at the mid-latitudes. Both weathering products and life in Dry Valleys soils are distributed heterogeneously. Such variations should be taken into account in future studies of martian soils and also in the search for possible life on Mars.  相似文献   

3.
Using data of the ASPERA-3 instrument on board the European Mars Express spacecraft we investigate the effect of the martian crustal fields on electrons intruding from the magnetosheath. For the crustal field strength we use published data obtained by the Mars Global Surveyor MAG/ER instrument for a fixed altitude of 400 km. We use statistics on 13 months of 80-100 eV electron observations to show that the electron intrusion altitude determined by a probability measure is approximately linearly dependent on the total field strength at 400 km altitude. We show that on the dayside the mean electron intrusion altitude describes the location of the Magnetic Pile-Up Boundary (MPB) such that we can quantify the effect of the crustal fields on the MPB. On the nightside we quantify the shielding of precipitating electrons by the crustal fields.  相似文献   

4.
The goal of this work is to determine the spectroscopic properties of sulfate in martian soil analogs over the wavelength range 0.3 to 25 μm (which is relevant to existing and planned remotely sensed data sets for Mars). Sulfate is an abundant component of martian soil (up to 9% SO3 by weight) and apparently exists as a particulate in the soil but also as a cement. Although previous studies have addressed the spectroscopic identity of sulfates on Mars, none have used laboratory mixtures of materials with sulfates at the abundances measured by landed spacecraft, nor have any works considered the effect of salt-cementation on spectral properties of soil materials. For this work we created mixtures of a palagonitic soil (JSC Mars-1) and sulfates (MgSO4 and CaSO4·2H2O). The effects of cementation were determined and separated from the effects of packing and hydration by measuring the samples as loose powders, packed powders, cemented materials, and disaggregated materials. The results show that the presence of particulate sulfate is best observed in the 4-5 μm region. Soils cemented with sulfate exhibit a pronounced restrahlen band between 8 and 9 μm as well as well-defined absorptions in the 4-5 μm region. Cementation effects are distinct from packing effects and disaggregation of cemented samples rapidly diminishes the strength of the restrahlen bands. The results of this study show that sulfate in loose materials is more detectable in the near infrared (4-5 μm) than in the thermal infrared (8-9 μm). However, cemented materials are easily distinguished from loose mixtures in the thermal infrared because of the high values of their absorption coefficient in this region. Together these results suggest that both wavelength regions are important for determining the spatial extent and physical form of sulfates on the surface of Mars.  相似文献   

5.
The Short Wavelength Channel of the Planetary Fourier Spectrometer (PFS) covers the 8333-1750 cm−1 (1.2-5.7 μm) spectral range, that is well suited to study the reflectance properties of the martian soil. These properties vary with time due to the dust dynamics in the martian environment. Wind can blow off dust exposing soil and fresh rocks and can support grain mobility inducing local dust settling. We have analyzed PFS data from January 2004 to April 2005. A detailed photometric study of the radiance acquired from the planet has been performed in order to compare correctly measurements obtained at different viewing geometries and to produce a mosaic image of the planet. The results show good agreement with data from the Thermal Emission Spectrometer (on-board NASA Mars Global Surveyor orbiter), although some variations are observed. Some albedo changes could be due to small to medium scale dust storms. A very accurate estimation of the limb-darkening parameter has been computed from the analyzed data. The obtained values are compared with a surface roughness and a thermal inertia map in order to assess the relation between the limb-darkening parameter and the physical properties of surface.  相似文献   

6.
《Planetary and Space Science》2007,55(14):2151-2163
This paper describes a method for identifying martian dust devils and convective vortices in meteorological data. We have combined analysis of terrestrial dust devil fieldwork, re-analysis of martian meteorological data and laboratory experiments to explore fully the meteorological signature of dust devils. Both martian and terrestrial dust devils have similar characteristics implying a common formation mechanism. Terrestrial fieldwork therefore provides vital data that can be used to aid in the identification of their martian counterparts. Finally, a martian surface instrument package is suggested that will best detect dust devils and convective vortices without the need for visual confirmation.  相似文献   

7.
The extensive impact cratering record on Mars combined with evidence from SNC meteorites suggests that a significant fraction of the surface is composed of materials subjected to variable shock pressures. Pressure-induced structural changes in minerals during high-pressure shock events alter their thermal infrared spectral emission features, particularly for feldspars, in a predictable fashion. To understand the degree to which the distribution and magnitude of shock effects influence martian surface mineralogy, we used standard spectral mineral libraries supplemented by laboratory spectra of experimentally shocked bytownite feldspar [Johnson, J.R., Hörz, F., Christensen, P., Lucey, P.G., 2002b. J. Geophys. Res. 107 (E10), doi:10.1029/2001JE001517] to deconvolve Thermal Emission Spectrometer (TES) data from six relatively large (>50 km) impact craters on Mars. We used both TES orbital data and TES mosaics (emission phase function sequences) to study local and regional areas near the craters, and compared the differences between models using single TES detector data and 3×2 detector-averaged data. Inclusion of shocked feldspar spectra in the deconvolution models consistently improved the rms errors compared to models in which the spectra were not used, and resulted in modeled shocked feldspar abundances of >15% in some regions. However, the magnitudes of model rms error improvements were within the noise equivalent rms errors for the TES instrument [Hamilton V., personal communication]. This suggests that while shocked feldspars may be a component of the regions studied, their presence cannot be conclusively demonstrated in the TES data analyzed here. If the distributions of shocked feldspars suggested by the models are real, the lack of spatial correlation to crater materials may reflect extensive aeolian mixing of martian regolith materials composed of variably shocked impact ejecta from both local and distant sources.  相似文献   

8.
Bullock MA  Stoker CR  McKay CP  Zent AP 《Icarus》1994,107(1):142-154
The Viking Gas Chromatograph Mass Spectrometer failed to detect organic compounds on Mars, and both the Viking Labeled Release and the Viking Gas Exchange experiments indicated a reactive soil surface. These results have led to the widespread belief that there are oxidants in the martian soil. Since H2O2 is produced by photochemical processes in the atmosphere of Mars, and has been shown in the laboratory to reproduce closely the Viking LR results, it is a likely candidate for a martian soil oxidant. Here, we report on the results of a coupled soil/atmosphere transport model for H2O2 on Mars. Upon diffusing into the soil, its concentration is determined by the extent to which it is adsorbed and by the rate at which it is catalytically destroyed. An analytical model for calculating the distribution of H2O2 in the martian atmosphere and soil is developed. The concentration of H2O2 in the soil is shown to go to zero at a finite depth, a consequence of the nonlinear soil diffusion equation. The model is parameterized in terms of an unknown quantity, the lifetime of H2O2 against heterogeneous catalytic destruction in the soil. Calculated concentrations are compared with a H2O2 concentration of 30 nmoles/cm3, inferred from the Viking Labeled Release experiment. A significant result of this model is that for a wide range of H2O2 lifetimes (up to 10(5) years), the extinction depth was found to be less than 3 m. The maximum possible concentration in the top 4 cm is calculated to be approximately 240 nmoles/cm3, achieved with lifetimes of greater than 1000 years. Concentrations higher than 30 nmoles/cm3 require lifetimes of greater than 4.3 terrestrial years. For a wide range of H2O2 lifetimes, it was found that the atmospheric concentration is only weakly coupled with soil loss processes. Losses to the soil become significant only when lifetimes are less than a few hours. If there are depths below which H2O2 is not transported, it is plausible that organic compounds, protected from an oxidizing environment, may still exist. They would have been deposited by meteors, or be the organic remains of past life.  相似文献   

9.
We have studied the interaction of fast solar wind hydrogen atoms with the martian atmosphere by a three-dimensional Monte Carlo simulation. These energetic neutral hydrogen atoms, H-ENAs, are formed upstream of the martian bow shock. Both H-ENAs scattered and non-scattered from the martian atmosphere/exosphere were studied. The colliding H-ENAs were found to scatter both to the dayside and nightside. On the dayside they contribute to the so-called H-ENA albedo. On the nightside the heated and scattered hydrogen atoms were found also in the martian wake. The density, the energy distribution function and the direction of the velocity of H-ENAs on the nightside are presented. The present study describes a novel “ENA sounding” technique in which energetic neutral atoms are used to derive information of the properties of planetary exosphere and atmosphere in a similar manner as the solar wind photons are used to derive atmospheric densities by measuring the scattered UV light. A detailed study of the direction and energy of the scattered and non-scattered H-ENAs suggest that the ENA sounding is a method to study the interaction between the planetary atmosphere and the solar wind and to monitor the density, and likely also the magnetization, of the planetary upper atmosphere. Already present-day ENA instrument should be capable to detect the analyzed particle fluxes.  相似文献   

10.
The region surrounding the Mawrth Vallis outflow channel on Mars hosts thick layered deposits containing diverse phyllosilicate minerals. Here we report detection of the Ca-sulfate bassanite on the outflow channel floor, requiring a more complex aqueous chemistry than previously inferred for this region. The sulfate-bearing materials underlie phyllosilicate-bearing strata, and provide an opportunity for testing proposed models of martian geochemical evolution with a future landed mission.  相似文献   

11.
A radiative transfer model is used to quantitatively investigate aspects of the martian ultraviolet radiation environment, past and present. Biological action spectra for DNA inactivation and chloroplast (photosystem) inhibition are used to estimate biologically effective irradiances for the martian surface under cloudless skies. Over time Mars has probably experienced an increasingly inhospitable photobiological environment, with present instantaneous DNA weighted irradiances 3.5-fold higher than they may have been on early Mars. This is in contrast to the surface of Earth, which experienced an ozone amelioration of the photobiological environment during the Proterozoic and now has DNA weighted irradiances almost three orders of magnitude lower than early Earth. Although the present-day martian UV flux is similar to that of early Earth and thus may not be a critical limitation to life in the evolutionary context, it is a constraint to an unadapted biota and will rapidly kill spacecraft-borne microbes not covered by a martian dust layer. Microbial strategies for protection against UV radiation are considered in the light of martian photobiological calculations, past and present. Data are also presented for the effects of hypothetical planetary atmospheric manipulations on the martian UV radiation environment with estimates of the biological consequences of such manipulations.  相似文献   

12.
We calculate new estimates of ground-ice stability and the depth distribution of the ice table (the depth boundary between ice-free soil above and ice-cemented soil below) and compare these theoretical estimates of the distribution of ground ice with the observed distribution of leakage neutrons measured by the Neutron Spectrometer instrument of the Mars Odyssey spacecraft's Gamma Ray Spectrometer instrument suite. Our calculated ground-ice distribution contains improvements over previous work in that we include the effects of the high thermal conductivity of ice-cemented soil at and below the ice table, we include the surface elevation dependence of the near-surface atmospheric humidity, and we utilize new high resolution maps of thermal inertia, albedo, and elevation from Mars Global Surveyor observations. Results indicate that ground ice should be about 5 times shallower than in previous predictions. While results are dependent on the atmospheric humidity, depths are generally between a few millimeters and a few meters with typical values of a few centimeters. Results are also geographically similar to previous predictions with differences due to the higher resolution of thermal inertia and the inclusion of elevation effects on humidity. Comparison with the measured epithermal-neutron count rates in the southern hemisphere indicate that the geographic distribution of the count rate is best correlated with ground ice in equilibrium with 10 to 20 pr μm (precipitable micrometers) column abundance of atmospheric water, assuming a uniform distribution with CO2; however, given the uncertainties, 5 to 30 pr μm also may be viable. This water abundance represents a longer-term average over 100 to 1000 yr. There is a high degree of correlation between the depth of the ice table and the epithermal count rate that agrees remarkably well with predicted count rates as a function of ice-table depth. These results indicate that ground ice in the upper meter of the martian soil is in diffusive equilibrium with the atmosphere. Since ground ice in this depth zone is expected to undergo saturation/desiccation cycles with orbital variations, this ice should be younger than about 500 kyr and was emplaced under similar cold and dry climate conditions of today. Remaining differences between the predicted depths of the ice table and those inferred from the neutron data are likely to be due to subpixel heterogeneity in the martian surface including the presence of rocks, slopes, and patches of soil with varying thermophysical properties.  相似文献   

13.
Methane, a potential biosignature, has recently been detected in the martian atmosphere. This Note focuses on field investigations/operational simulations and laboratory studies which resulted in successful detection of methane within arid terrestrial soils, as distinct from the usual methanogen environment, but in at least partial analogy to martian conditions.  相似文献   

14.
Yan Tang  Yujie Huang 《Icarus》2006,180(1):88-92
The detection of gray crystalline hematite deposits on Mars by Thermal Emission Spectrometer (TES) has been used to argue for the presence of liquid water on Mars in the distant past. By methanol-thermal treatment of anhydrous FeCl3 at low temperatures (70-160 °C), crystalline gray hematite with layered structure was synthesized, based on this result an alternative explanation for the origin of martian hematite deposits is suggested. Methane could be abundant in the early martian atmosphere; process such as photochemical oxidation of methane could result in the formation of ocean or pool of organic compounds such as methanol, which provides an environment for the formation of large-scale hematite deposits on Mars.  相似文献   

15.
The near-infrared reflectance spectra of the martian surface present strong absorption features attributed to hydration water present in the regolith. In order to characterize the relationships between this water and atmospheric vapor and decipher the physical state of water molecules in martian regolith analogs, we designed and built an experimental setup to measure near-IR reflectance spectra under martian atmospheric conditions. Six samples were studied that cover part of the diversity of Mars surface mineralogy: a hydrated ferric oxide (ferrihydrite), two igneous samples (volcanic tuff, and dunite sand), and three potential water rich soil materials (Mg-sulfate, smectite powder and a palagonitic soil, the JSC Mars-1 regolith stimulant). Sorption and desorption isotherms were measured at 243 K for water vapor pressure varying from 10−5 to ∼0.3 mbar (relative humidity: 10−4 to 75%). These measurements reveal a large diversity of behavior among the sample suite in terms of absolute amount of water adsorbed, shape of the isotherm and hysteresis between the adsorption and desorption branches. Simultaneous in situ spectroscopic observations permit a detailed analysis of the spectral signature of adsorbed water and also point to clear differences between the samples. Ferric (oxy)hydroxides like ferrihydrite or other phases present in palagonitic soils are very strong water adsorbent and may play an important role in the current martian water cycle by allowing large exchange of water between dust-covered regions and atmosphere at diurnal and seasonal scales.  相似文献   

16.
A circular albedo feature in the Arabia Terra province was first hypothesized as an ancient impact basin using Viking-era information. To test this unpublished hypothesis, we have analyzed the Viking era-information together with layers of new data derived from the Mars Global Surveyor (MGS) and Mars Odyssey (MO) missions. Our analysis indicates that Arabia Terra is an ancient geologic province of Mars with many distinct characteristics, including predominantly Noachian materials, a unique part of the highland-lowland boundary, a prominent paleotectonic history, the largest region of fretted terrain on the planet, outflow channels with no obvious origins, extensive exposures of eroded layered sedimentary deposits, and notable structural, albedo, thermal inertia, gravity, magnetic, and elemental signatures. The province also is marked by special impact crater morphologies, which suggest a persistent volatile-rich substrate. No one characteristic provides definitive answers to the dominant event(s) that shaped this unique province. Collectively the characteristics reported here support the following hypothesized sequence of events in Arabia Terra: (1) an enormous basin, possibly of impact origin, formed early in martian history when the magnetic dynamo was active and the lithosphere was relatively thin, (2) sediments and other materials were deposited in the basin during high erosion rates while maintaining isostatic equilibrium, (3) sediments became water enriched during the Noachian Period, and (4) basin materials were uplifted in response to the growth of the Tharsis Bulge, resulting in differential erosion exposing ancient stratigraphic sequences. Parts of the ancient basin remain water-enriched to the present day.  相似文献   

17.
Prelaunch planetary protection protocols on spacecraft are designed to reduce the numbers and diversity of viable bioloads on surfaces in order to mitigate the forward contamination of planetary surfaces. In addition, there is a growing appreciation that prelaunch spacecraft cleaning protocols will be required to reduce the levels of biogenic signature molecules on spacecraft to levels that will not compromise life-detection experiments on landers. The biogenic molecule, adenosine triphosphate (ATP) was tested for long-term stability under simulated Mars surface conditions of high UV flux, low temperature, low pressure, Mars atmosphere, and clear-sky dust loading conditions. Data on UV-induced ATP degradation rates were then extrapolated to a diversity of global conditions using a radiative transfer model for UV on Mars. The UV-induced degradation of ATP tested at 4.1 W m−2 UVC (200-280 nm), −10 °C, 7.1 mb, 95% CO2 gas composition, and an atmospheric opacity of τ=0.1 yielded a half-life for ATP of 1342 kJ m−2; or extrapolated to approximately 22 sols on equatorial Mars with an atmospheric opacity of τ=0.5. Temperature was found to moderately affect ATP degradation rates under martian conditions; tests at −80 or 20 °C yielded ATP half-lives of 2594 or 1183 kJ m−2, respectively. The ATP degradation rates reported here are over 10 orders of magnitude slower than the UV-induced biocidal rates reported in the literature on the inactivation of strongly UV-resistant bacterial spores from Bacillus pumilus SAFR-032 [Schuerger, A.C., Richards, J.T., Newcombe, D.A., Venkateswaran, K.J., 2006. Icarus 181, 52-62]. Extrapolating results to global Mars conditions, residence times for a 99% reduction of ATP on spacecraft surfaces ranged from 158 sols on Sun-exposed surfaces to approximately 32,000 sols for the undersides of landers similar to Viking. However, spacecraft materials greatly affected the survival times of ATP under martian conditions. Stainless steel was found to enhance the UV degradation of ATP by over 2 orders of magnitude compared to ATP-doped iridited aluminum, graphite, and astroquartz coupons. Extrapolating these results to global conditions, ATP on stainless steel might be expected to persist between 2 and 320 sols for upper and lower surfaces of landers. Liquid chromatography-mass spectrometry data supported the conclusion that UV irradiation acted to remove the γ-phosphate group from ATP, and no evidence was observed for the UV-degradation of d-ribose or adenine moieties. Long residence times for ATP on spacecraft materials under martian conditions suggest that prelaunch cleaning protocols may need to be strengthened to mitigate against possible ATP contamination of life-detection experiments on Mars landers.  相似文献   

18.
S. Vennerstrom 《Icarus》2011,215(1):234-241
Based on data from the Mars Global Surveyor magnetometer we examine periods of significantly enhanced magnetic disturbances in the martian space environment. Using almost seven years of observations during the maximum and early declining phase of the previous solar cycle the occurrence pattern and typical time profile of such periods is investigated and compared to solar wind measurements at Earth. Typical durations of the events are 20-40 h, and there is a tendency for large events to last longer, but a large spread in duration and intensity are found. The large and medium intensity events at Mars are found to occur predominantly in association with interplanetary sector boundaries, with solar wind dynamic pressure enhancements being the most likely interplanetary driver. In addition it is found that, on time scales of months to several years, the dominant cause of global variability of the magnetic field disturbance at Mars is solar wind dynamic pressure variations associated with the eccentricity of the martian orbit around the Sun.  相似文献   

19.
We have performed field experiments to further develop and validate the Mars Oxidation Instrument (MOI) as well as measurement strategies for the in situ characterization of oxidation mechanisms, kinetics, and carbon cycling on Mars. Using the Atacama Desert as a test site for the current dry conditions on Mars, we characterized the chemical reactivity of surface and near-surface atmosphere in the dry core of the Atacama. MOI is a chemiresistor-based sensor array that measures the reaction rates of chemical films that are sensitive to particular types of oxidants or that mimic chemical characteristics of pre-biotic and biotic materials. With these sensors, the chemical reactivity of a planetary environment is characterized by monitoring the resistance of the film as a function of time. Our instrumental approach correlates reaction rates with dust abundance, UV flux, humidity, and temperature, allowing discrimination between competing hypotheses of oxidant formation and organic decomposition. The sensor responses in the Atacama are consistent with an oxidative attack by strong acids triggered by dust accumulation, followed by transient wetting due to an increase in relative humidity during the night. We conclude that in the Atacama Desert, and perhaps on Mars, low pH resulting from acid accumulation, combined with limited water availability and high oxidation potential, can result in oxidizing acid reactions on dust and soil surfaces during low-moisture transient wetting events (i.e. thin films of water). These soil acids are expected to play a significant role in the oxidizing nature of the soils, the formation of mineral surface coatings, and the chemical modification of organics in the surface material.  相似文献   

20.
Through a combination of aerobraking (drag deceleration) and ablation, meteoroids which enter planetary atmospheres may be slowed sufficiently to soft-land as meteorites. Results of an earlier study suggest that the current 6 mbar atmosphere of Mars is sufficient to aerobrake significant numbers of small (<10 kg) asteroidal-type meteoroids into survivable, low-velocity (<500 m s−1) impacts with the planet's surface. Since rates of meteorite production depend upon the density of Mars's atmosphere, they must also change as the martian climate changes. However, to date, martian meteorite production has received relatively little attention in the literature Here we expand upon our previous work to study martian meteorite production rates and how they depend upon variations of the martian atmosphere, and to estimate the ranges of mass, velocity and entry-angle that produce meteorites. We find that even the current atmosphere of Mars is sufficient to soft-land significant fractions of incident stony and iron objects, and that these fractions increase dramatically for denser martian atmospheres. Therefore, like impact cratering, meteorite populations may preserve evidence of past martian climates.  相似文献   

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