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1.
We investigate the possibility of interstellar masers in transitions of the methanol isotopomers CH3OD, 13CH3OH and CH318OH, and of CH3SH. The model used, in which masers are pumped through the first and second torsionally excited states by IR radiation, has accounted successfully for the Class II masers in main species methanol, 12CH316OH. Several potential maser candidates are identified for CH3OD, their detectability depending on the enrichment of this species in star-forming regions. In 13CH3OH and CH318OH the best maser candidates are direct counterparts of the well-known 6.7- and 12.2-GHz methanol masers, but the lower interstellar abundance of these substituted species means that the expected brightness is greatly reduced. The maser candidates in CH3SH are also weak. By comparing these species we find that the large b -component of the dipole moment in methanol plays a significant role in its propensity to form masers, as does the strong torsion–rotation interaction due to the light hydroxyl frame. Thus the exceptional brightness of interstellar methanol masers is due to a favourable combination of molecular properties as well as high interstellar abundance.  相似文献   

2.
The neighbouring lines a 6D5/2– x 6Po3/2 (1272.617 Å) and a 6D5/2– w 2Po3/2 (1272.657 Å) have been observed in the UV spectrum of χ Lupi to be of comparable intensity. The latter, Δ S  = 2, transition would be expected to be very weak. The two upper states should display negligible mixing. We give a detailed, quantitative discussion of how the two upper states are in fact strongly mixed through their mixing with 3d6(3D)4p 4Po3/2, and hence we explain the relative strengths of the two UV lines.  相似文献   

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A model is constructed of the material in front of the star Cygnus OB2 no. 12 in which dense cores are embedded in diffuse clumps of gas. The model reproduces the measured abundances of C2 and CO, and predicts a column density of 91010 cm2 for HCO+.  相似文献   

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We present rate coefficients for rotational transitions induced in collisions between H2 molecules. Rotational levels J  ≤ 8 and kinetic temperatures T  ≤ 1000 K are considered. The interaction potential computed by Schwenke has been used, together with the quantal coupled channels method of calculating the cross-sections. Comparison is made with the more recent of previous results.  相似文献   

6.
The identity of the carriers of the diffuse interstellar bands (DIBs) is one of the most fascinating puzzles of modern spectroscopy. Over the last few years the number of known DIBs has grown substantially. In this paper we discuss the two recently discovered near-infrared weak interstellar features which have already been proposed as fingerprints of the buckminsterfullerene We present and discuss measurements of the two related DIBs within a larger sample of reddened targets, observed with different spectrometers, telescopes and site conditions. We provide additional arguments in favour of the interstellar origin of the two bands. We find evidence around the 9577-Å DIB of far-wing structures, which may affect broad-band measurements. We estimate corrections and errors for telluric and stellar blends, and show that the cores of the two DIBs are well correlated with a ratio near unity within 20 per cent. Finally, we discuss their relation to the laboratory spectra of and the search for two expected weaker transitions.  相似文献   

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The behaviour of the  Δν= 2 CO  bands around 2.3 μm was examined by comparing observed and synthetic spectra in stars in globular clusters of different metallicity. Changes in the 12C/13C isotopic ratio and the carbon abundances were investigated in stars from 3500–4900 K in the galactic globular clusters M71, M5, M3 and M13, covering the metallicity range from −0.7 to −1.6. We found relatively low carbon abundances that are not affected by the value of oxygen abundance. For most giants, the 12C/13C ratios determined are consistent with the equilibrium value for the CN cycle. This suggests complete mixing on the ascent of the red giant branch, in contrast to the substantially higher values predicted across this range of parameters by the current generation of models. We found some evidence for a larger dispersion of 12C/13C in giants of M71 of metallicity  [μ]=[M/H]=−0.7  in comparison with the giants of M3, M5 and M13, which are more metal deficient. Finally, we show evidence for lower 12C/13C in giants of globular clusters with lower metallicities, as predicted by theory.  相似文献   

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The superposition of configurations (SOC) method has been used to calculate f -values for the Mg  ii doublet at 1240 Å, which has been observed in the interstellar medium near stars such as ζ Ophiuchi. Our best value for the multiplet oscillator strength is 0.00083. SOC calculations have also been undertaken for the stronger (3s−3p) doublet at 2800 Å giving a multiplet f -value of 0.92.  相似文献   

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The theory of Anstee &38; O'Mara is extended to the line broadening of transitions of singly ionized atoms by collisions with neutral hydrogen atoms. The theory is used to calculate broadening cross-sections for strong lines of singly ionized calcium, magnesium and barium. The broadening cross-sections calculated are compared with both theoretical and empirical results of other workers.  相似文献   

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Radiative transfer modelling of the Infrared Space Observatory ( ISO ) spectrum of IRAS 22036+5306 has shown that its unusual 11-μm band can be suitably modelled with an alumina-olivine mixture substantially dominated by the former. The results of this work add further credence to recent findings that significant amounts of Al  2O3  dust grains are present in the dust shells of stars near or beyond the tip of the asymptotic giant branch. Indeed, in the case of IRAS 22036+5306, Al  2O3  dominates the dust composition to the extent that it shifts the 9.8-μm band due to amorphous silicates to 11 μm. IRAS 22036+5306 may be an unusual case in that the inner dust torus is maintained at a sufficiently high temperature for Al  2O3  condensation, but not silicate.  相似文献   

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The stability of C60 and C70 fullerenes in the interstellar medium deposited on dust surface or embedded in meteorites and comets has been simulated with γ irradiation and with He+ ion bombardment. It is shown by vibrational spectroscopy that a γ radiation dose of 2.6 MGy (1 Gy = 1 joule absorbed energy per kilogram) causes partial oligomerization of both C60 and C70 fullerenes. Oligomers are made by fullerene cages chemically connected each other which can yield back free fullerenes by a thermal treatment. The amount of irreversibly polymerized fullerenes caused by 2.6 MGy as deduced as the toluene insoluble fraction has been determined as 1.7 and 15 per cent by weight, respectively, for C60 and C70 fullerene. The radiation dose generated by radionuclides decay and expected to be delivered to fullerenes buried at a depth of more than 20 m in comets and meteorites is about 3 MGy per 109 yr. Since fullerenes are by far resistant to such radiation dose they can survive for at least some billion years inside comets and meteorites and in fact have been detected inside certain carbonaceous chondrites. On the other hand, the direct exposure of fullerenes to cosmic rays for instance when they are adsorbed or deposited on the surface of carbon dust corresponds to the delivery of a radiation dose comprised between 30 and 65 MGy per 109 yr. Experimental bombardment of both C60 and C70 fullerenes for instance with He+ ions has shown that the complete amorphization occurs at about 250 MGy. Thus in ∼4 Gyr exposure to cosmic rays it is expected a complete amorphization.  相似文献   

19.
Using three independent theoretical approaches (CA, HFR + CP, AUTOSTRUCTURE), oscillator strengths have been calculated for a set of Tc  ii transitions of astrophysical interest and the reliability of their absolute scale has been assessed. The examination of the spectra emitted by some Ap stars has allowed the identification of Tc  ii transitions in HD 125248. This Tc  ii detection should however await confirmation from spectral synthesis relying on dedicated model atmospheres. New partition functions are also provided for Tc  i , Tc  ii and Tc  iii for temperatures ranging between 4000 and 13 000 K.  相似文献   

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