High-sensitive measurement of uranium L_III-edge X-ray absorption near-edge structure (XANES) for the determination of the oxidation states of uranium in crustal materials     

Yuhei Yamamoto  Yoshio Takahashi  Yutaka Kanai  Yoshio Watanabe  Tomoya Uruga  Hajime Tanida  Yasuko Terada  Hiroshi Shimizu   《Applied Geochemistry》2008,23(8):2452-2461

The uranium L_III-edge XANES spectra for natural rocks at the concentration range of 0.96–124 mg kg⁻¹ were measured using a log spiral bent crystal Laue analyzer (BCLA) combined with a multi-element Ge detector. It was found that the quality of the XANES spectra using the BCLA was greatly improved due to a reduction of interfering fluorescence from major components such as Rb and Sr. The ratio of signal to background intensities in the U L_III-edge XANES spectra increased by a factor of 2.9–17 with the use of the BCLA, which greatly enhanced the detection limit for the speciation of the oxidation states of U or the U(IV)/U(VI) ratio of natural samples. In addition, it was demonstrated that the fluorescence XANES method coupled with the BCLA enable determination of the speciation of U for various natural samples such as acidic igneous rocks, ferromanganese nodules, sediments, and some sedimentary rocks such as shale and limestone.  相似文献   

Transfer of60Co from midwater squid to sperm whales     

Takeshi Umezu  Hiroshi Ebihara  Yōko Minamisako  Hiroshi Watanabe 《Journal of Oceanography》1984,40(5):382-390

Sperm whales are notable squid-eaters. They feed mainly on medium to large-sized cephalopods at midwater levels and defecate near the surface. This suggests the existence of an upward transport of⁶⁰Co by sperm whales from the mesopelagic zone (150–1,200 m). To elucidate this squid-whale route for this artificial radionuclide,⁶⁰Co content was determined in squid and in predator whales captured by commercial whaling. In the Cephalopoda livers⁶⁰Co levels of 30–500 mBq kg^–1 wet were found and in the viscera of Odontoceti (toothed whales) 15–40 mBq kg^–1 wet. About 0.3% of⁸⁰Co ingested was estimated to be retained in a 23-year-old male sperm whale. In the livers of Bryde's whales,⁶⁰Co levels of 40–80 mBq kg^–1 wet were detected, but not in euphausiids and sardines, their possible prey. The level of Co in sperm whales was nearly the same as in Bryde's whales. Specific radioactivity⁶⁰Co/⁵⁹Co in mBq µg^–1 was several times higher in sperm whale (1.1–1.6) than in cephalopods (0.19–0.77). Eating prey with a high content of⁶⁰Co in the 1960's may have contributed to the present body burden in sperm whales with a long-life span. However, the origin of⁶⁰Co in Bryde's whales is unknown.  相似文献   

Vertical distributions of some chemical substances in surface sediments of a meromictic Lake Suigetsu     

Michiro Matsuyama 《Journal of Oceanography》1974,30(5):209-215

Vertical distributions of some chemical substances in the surface sediments of a typical meromictic lake, Lake Suigetsu, were measured. Metallic elements such as iron, manganese, nickel, zinc, copper and chromium showed no significant slopes in vertical direction. While, boron and total sulfur contents in the sediments decreased from the surface to the stratum 35–40 cm, and below which both substances showed no more appreciable changes. From an average sedimentation rate (about 1.1 mm/yr), estimated from the radiocarbon dating of the sediment, the sediments above the stratum 35–40 cm were thought to be deposited after the beginning of the salt water intrusion to the lake by the excavation of a canal in 1665, by which Lake Suigetsu was connected to a polyhaline lake (Lake Kugushi) directly connected to the sea. Vertical distributions of boron and total sulfur in the sediments and also of chlorinity of the interstitial waters seem to correspond to past change in the lake condition from freshwater one to a two-layered system of a deeper salt water covered by a upper freshwater.  相似文献   

Difference in the prevailing periods of internal tides between Sagami and Suruga Bays: Numerical experiments     

Atsushi Ohwaki  Masaji Matsuyama  Hideki Nagashima 《Journal of Oceanography》1994,50(4):449-463

Current measurements in the surface layer in Sagami and Suruga Bays showed existence of significant tidal currents which are considered to be mainly due to internal tides (Inaba, 1982; Ohwaki,ea al., 1991). In addition, the prevailing period of the tidal currents is semidiurnal in Sagami Bay, but diurnal in Suruga Bay. To explain this difference in the prevailing, periods, numerical experiments were carried out using a two layer model. The internal tides are generated on the Izu Ridge outside the two bays. The semidiurnal internal tide propagates into Sagami Bay having characteristics of an internal inertia-gravity wave, while it propagates into Suruga Bay having characteristics of either an internal inertia-gravity wave or an internal Kelvin wave. The diurnal internal tide behaves only as an internal Kelvin wave, because the diurnal period is longer than the inertia period. Thus, the diurnal internal tide generated on the Izu Ridge can be propagated into Suruga Bay, while it cannot propagate into the inner region of Sagami Bay, though it is trapped around Oshima Island, which is located at the mouth of Sagami Bay. The difference in the propagation characteristics between the semidiurnal and diurnal internal tides can give a mechanism to explain the difference in the prevailing periods of the internal tides between Sagami and Suruga Bays.  相似文献   

Near inertial motion excited by wind change in a margin of the Typhoon 9019   总被引：1，自引：0，他引：1  

Akio Maeda  Kazuki Uejima  Toru Yamashiro  Masahito Sakurai  Hiroshi Ichikawa  Masaki Chaen  Keisuke Taira  Shinjirou Mizuno 《Journal of Oceanography》1996,52(3):375-388

An excitation of inertial oscillation in the upper layer east of course of Typhoon 9019 was fortuitously observed at three surface buoys deployed during the Ocean Mixed Layer Experiment (OMLET). The observed inertial oscillation was compared with wind fluctuation measured at Ocean Weather Station T (29°N, 135°E) which was placed at the center of a triangle with three vertexes occupied by the respective surface buoys. Inertial oscillation is effectively excited in the mixed layer at the eastern margin of the typhoon by a rapid decrease of wind rather than by prevailing strong wind. It is shown by means of a least square deviation that the inertial oscillation observed in the mixed layer has a period of 23.9 hours shorter than the local inertial period of 24.7 hours. This shorter period suggests that the inertial oscillation has the finite velocities of phase and group as an inertial internal wave. A theoretically obtained ratio of vertical component of group velocity to that of phase velocity, approximately agrees with observed value. The inertial internal wave is excited by fluctuation of divergence with near inertial period in the mixed layer.  相似文献   

Evidence for predominance of internal tidal currents in Sagami and Suruga bays     

Atsushi Ohwaki  Masaji Matsuyama  Shizuo Iwata 《Journal of Oceanography》1991,47(5):194-206

Tidal currents observed in a surface layer overlying deep water in Sagami and Suruga Bays frequently have large amplitude in summer and fall. Numerical experiments show that the current amplitude due to the surface tides is below 1.0 cm sec^–1 for the semidiurnal and diurnal constituents in the inner region of the two bays. The observed current amplitudes are larger than the calculated ones due to the surface tides. Therefore, the observed tidal currents are indicated to be due mainly to the internal tides. In addition, the semidiurnal currents dominate the diurnal currents in Sagami Bay, while the opposite occurs in Suruga Bay. These results suggest that the prevailing periods of the internal tides differ between the two bays,i.e., the internal tide has a semidiurnal period in Sagami Bay and a diurnal period in Suruga Bay.  相似文献   

The study of the Kuroshio in the East China Sea and the currents east of the Ryukyu Islands   总被引：3，自引：0，他引：3  

Yuan Yaochu  Endoh Masahiro  Ishizaki Hiroshi 《海洋学报(英文版)》1991,10(3):373-391

In this study, the inverse method is used to compute the Kuroshio in the East China Sea and southeast of Kyushu and the currents east of the Ryukyu Islands, on the basis of hydrographic data obtained during September-October, 1987 by R/V Chofu Maru. The results show that: (1)A part of the Taiwan Warm Current has a tendency to converge to the shelf break; (2) the Kuroshio flows across the section C3 (PN) with a reduced current width, and the velocity of the Kuroshio at the section C3 increases and its maximum current speed is about 158 cm/s, and its volume transport here is about 26×106m3/s; (3) the Kuroshio has two current cores at the sections C3 (PN) and B2 (at the Tokara Strait); (4) the currents east of the Ryukyu Islands are found to flow northward over the Ryukyu Trench during September-October, 1987. The velocities of the currents are not strong throughout the depths. At the section C2 east of the Ryukyu Islands, the maximum current speed is at the 699 m levei and its magnitude is 25 cm/s, and i  相似文献   

Scattering of Semidiurnal Internal Kelvin Wave at Step Bottom Topography     

Yuji?KawamuraEmail author  Yujiro?Kitade  Masaji?Matsuyama 《Journal of Oceanography》2005,61(1):59-68

A three-dimensional, multi-level model was used to study the energy dissipation of semidiurnal internal Kelvin waves due to their interaction with bottom topography. A simplified topography consisting of a channel with an additional shallow bay was used to clarify the wave’s scattering process. When the first mode semidiurnal internal wave given at an open boundary arrives at the bay mouth, higher-mode internal waves are generated at a step bottom of the bay mouth. As a result, the energy of the first mode internal Kelvin wave is effectively decayed. The decay rate of the internal Kelvin wave depends on both the width and length of the additional bay. The maximum decay rate was found when a resonance condition occurs the bay, that is, the bay length is equal to a quarter of wave length of the first mode internal wave on the shallow region. The decay rate in the wide bay cases is higher than that in a narrow case, due to a contribution from the scattering due to the Poincare wave that emanates from the corners of the bay head. The decay rate with the additional bay is 1.1–1.8 times that of the case without the additional bay. The decay rate due to the scattering process is found to be of the same order as that of the internal and bottom friction.  相似文献   

Satellite detection of red tide in Ariake Sound, 1998–2001     

Joji Ishizaka  Yasuhisa Kitaura  Yasuharu Touke  Hiroaki Sasaki  Akihiko Tanaka  Hiroshi Murakami  Toshikazu Suzuki  Kazumi Matsuoka  Hideaki Nakata 《Journal of Oceanography》2006,62(1):37-45

High resolution SeaWiFS data was used to detect red tide events that occurred in the Ariake Sound, Japan, a small embayment known as one of the most productive areas in Japan. SeaWiFS chlorophyll data clearly showed that a large red tide event, which damaged seaweed (Nori) cultures, started early in December 2000 in Isahaya Bay, expanded to the whole sound and persisted to the end of February 2001. The monthly average of SeaWiFS data from May 1998 to December 2001 indicated that the chlorophyll peaks appeared twice a year, in early summer and in fall, after the peaks of rain and river discharge. The SeaWiFS data showed that the red tide event during 2000–2001 winter was part of the fall bloom; however, it started later and continued significantly longer than other years. Satellite ocean color data is useful to detect the red tide; however the algorithms require improvement to accurately estimate chlorophyll in highly turbid water and in red tide areas.  相似文献   

Turbulent structure in water under laboratory wind waves     

Ikuo Yoshikawa  Hiroshi Kawamura  Kuniaki Okuda  Yoshiaki Toba 《Journal of Oceanography》1988,44(3):143-156

The structure of the turbulent boundary layer underneath laboratory wind waves was studied by using a combination of a high-sensitivity thermometer array with a two-component sonic flowmeter. The temperature fluctuations are used to detect movements of water parcels, with temperature as a passive quantity. The turbulence energy was dominant in the frequency range (0.01 0.1 Hz), which was much smaller than the wind-wave frequency (2 5 Hz), and in which the turbulence was anisotropic. There was a frequency range (0.2 2 Hz for velocity, 0.2 5 Hz for temperature fluctuation) where the turbulence was isotropic and had a –5/3 slope in the energy spectrum. These points are the same as those in previous works. However, by analyses of the time series by using a variable-interval time-averaging technique (VITA), it has been found that conspicuous events in this main turbulence energy band are the downward bursting from the vicinity of the water surface. Thus the structure of the water layer underneath the wind waves has characters which are similar to the familiar turbulent boundary layer over a rough solid wall, as already conceived. It has been found that, at the same time, the turbulence energy can be related to quantities of the wind waves (the root mean squared water level fluctuation and the wave peak frequency), for different wind and wave conditions. That is, the turbulence underneath the wind waves develops under a close coupling with the wind waves.  相似文献