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The petrogenesis of calc-alkaline magmatism in the Eocene AbsarokaVolcanic Province (AVP) is investigated at Washburn volcano,a major eruptive center in the low-K western belt of the AVP.New 40Ar/39Ar age determinations indicate that magmatism atthe volcano commenced as early as 55 Ma and continued untilat least 52 Ma. Although mineral and whole-rock compositionaldata reflect near equilibrium crystallization of modal phenocrysts,petrogenetic modeling demonstrates that intermediate compositionmagmas are hybrids formed by mixing variably fractionated andcontaminated mantle-derived melts and heterogeneous siliciccrustal melts. Nd and Sr isotopic compositions along with traceelement data indicate that silicic melts in the Washburn systemare derived from deep-crustal rocks broadly similar in compositionto granulite-facies xenoliths in the Wyoming Province. Our preferredexplanation for these features is that mantle-derived basalticmagma intruded repeatedly in the deep continental crust leadingto fractional crystallization, silicic melt production, andhomogenization of magmas, followed by ascent to shallow reservoirsand crystallization of new plagioclase-rich mineral assemblagesin equilibrium with the intermediate hybrid liquids. The implicationsof this process are that (1) some calc-alkaline magmas may onlybe recognized as hybrids on purely chemical grounds, particularlyin systems where mixing precedes and is widely separated fromcrystallization in space and time, and (2) given the role ascribedto crustal processes at Washburn volcano, the variation betweenrocks that follow calc-alkaline trends in the western AVP andthose that follow shoshonitic trends in the east cannot simplyreflect higher pressures of fractionation to the east in Moho-levelmagma chambers in the absence of crustal interaction. KEY WORDS: petrogenesis; magma mixing; calc-alkaline; Absaroka Volcanic Province; 40Ar/39Ar dates 相似文献
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Magmatic Evolution of the La Pacana Caldera System, Central Andes, Chile: Compositional Variation of Two Cogenetic, Large-Volume Felsic Ignimbrites 总被引:10,自引:3,他引:10
LINDSAY J. M.; SCHMITT A. K.; TRUMBULL R. B.; DE SILVA S. L.; SIEBEL W.; EMMERMANN R. 《Journal of Petrology》2001,42(3):459-486
La Pacana is one of the largest known calderas on Earth, andis the source of at least two major ignimbrite eruptions witha combined volume of some 2700 km3. These ignimbrites have stronglycontrasting compositions, raising the question of whether theyare genetically related. The Toconao ignimbrite is crystal poor,and contains rhyolitic (7677 wt % SiO2) tube pumices.The overlying Atana ignimbrite is a homogeneous tuff whose pumiceis dacitic (6670 wt % SiO2), dense (4060% vesicularity)and crystal rich (3040 % crystals). Phase equilibriaindicate that the Atana magma equilibrated at temperatures of770790°C with melt water contents of 3·14·4wt %. The pre-eruptive Toconao magma was cooler (730750°C)and its melt more water rich (6·36·8 wt% H2O). A pressure of 200 MPa is inferred from mineral barometryfor the Atana magma chamber. Isotope compositions are variablebut overlapping for both units (87Sr/86Sri 0·70940·7131;143Nd/144Nd 0·512220·51230) and are consistentwith a dominantly crustal origin. Glass analyses from Atanapumices are similar in composition to those in Toconao tubepumices, demonstrating that the Toconao magma could representa differentiated melt of the Atana magma. Fractional crystallizationmodelling suggests that the Toconao magma can be produced by30% crystallization of the observed Atana mineral phases. Toconaomelt characteristics and intensive parameters are consistentwith a volatile oversaturation-driven eruption. However, thelow H2O content, high viscosity and high crystal content ofthe Atana magma imply an external eruption trigger. KEY WORDS: Central Andes; crystal-rich dacite; eruption trigger; high-silica rhyolite; zoned magma chamber 相似文献
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GURENKO ANDREY A.; TRUMBULL ROBERT B.; THOMAS RAINER; LINDSAY JAN M. 《Journal of Petrology》2005,46(12):2495-2526
Glass inclusions in plagioclase and orthopyroxene from daciticpumice of the Cabrits Dome, Plat Pays Volcanic Complex in southernDominica reveal a complexity of element behavior and LiBisotope variations in a single volcanic center that would gounnoticed in a whole-rock study. Inclusions and matrix glassesare high-silica rhyolite with compositions consistent with about50% fractional crystallization of the observed phenocrysts.Estimated crystallization conditions are 760880°C,200 MPa and oxygen fugacity of FMQ + 1 to +2 log units (whereFMQ is the fayalitemagnetitequartz buffer). Manyinclusion glasses are volatile-rich (up to 6 wt % H2O and 2900ppm Cl), but contents range down to 1 wt % H2O and 2000 ppmCl as a result of shallow-level degassing. Sulfur contents arelow throughout, with <350 ppm S. The trace element compositionof inclusion glasses shows enrichment in light rare earth elements(LREE; (La/Sm)n = 2·56·6) and elevatedBa, Th and K contents compared with whole rocks and similaror lower Nb and heavy REE (HREE; (Gd/Yb)n = 0·51·0).Lithium and boron concentrations and isotope ratios in meltinclusions are highly variable (2060 ppm Li with 7Li= +4 to +15 ± 2; 60100 ppm B with 11B = +6 to+13 ± 2) and imply trapping of isotopically heterogeneous,hybrid melts. Multiple sources and processes are required toexplain these features. The mid-ocean ridge basalt (MORB)-likeHREE, Nb and Y signature reflects the parental magma(s) derivedfrom the mantle wedge. Positive Ba/Nb, B/Nb and Th/Nb correlationsin inclusion glasses indicate coupled enrichment in stronglyfluid-mobile (Ba, B) and less-mobile (Th, Nb) trace elements,which can be explained by fractional crystallization of plagioclase,orthopyroxene and FeTi oxides. The 7Li and 11B valuesare at the high end of known ranges for other island arc magmas.We attribute the high values to a 11B and 7Li-enriched slabcomponent derived from sea-floor-altered oceanic crust and possiblyfurther enriched in heavy isotopes by dehydration fractionation.The heterogeneity of isotope ratios in the evolved, trappedmelts is attributed to shallow-level assimilation of older volcanicrocks of the Plat Pays Volcanic Complex. KEY WORDS: subduction; volcanic arcs; igneous processes; melt inclusions; SIMS; trace elements; lithium and boron isotopes; diffusion 相似文献
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Off-the-shelf GIS toolboxes are inadequate for pedagogic purposes. Urban World , an Arc View application, attempts to address this shortcoming by including special features designed to foster student progress towards a better understanding of urban environments. This paper provides context for the Urban World system in an active, authentic learning environment for students of urban geography and planning at junior and senior levels in undergraduate curricula at universities in the United States. The paper describes the rationale for, and implementation of, several components of Urban World : a special graphid user interface; productivity tools for facilitating the acquisition of practical skills of mapping and spatial analysis; tools for accessing, undertaking, and submitting homework assignments in a paper-less class; and various devices for assisting students to undertake spatial reasoning. GIS are Seen as an enabling technology for improving understanding by means of engaging students in empirical analysis. Spatial problem solvers and decision makers reach sound conclusions by employing reasoning skills applied to well-formed databases; scientific research makcs progress with sound reasoning of many types. The effective teaching and learning about the geography of our world requires a strong foundation of spatid reasoning. 相似文献
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From global politics to local land users: applying the United Nations Convention to combat desertification in Swaziland 总被引:1,自引:0,他引:1
This paper explores the relevance of the United Nations Convention to Combat Desertification (UNCCD) and its related National Action Programmes (NAPs) to people affected by land degradation and change in Swaziland. Household data collected from three chiefdoms are examined, together with policy analyses and information from interviews with policymakers and NGO representatives, as the barriers that inhibit successful implementation of the UNCCD at the national level are explored. We demonstrate how the issues addressed by Swaziland's NAP do not always match the environmental challenges that most threaten the sustainability of rural livelihoods, despite the 'participatory' and 'consultative' approach taken in developing the policy. This is because the more powerful members of society restricted the public's access to policy space. We argue that local involvement in environmental policy and decision-making as prescribed from the international political arena is insufficient to ensure empowerment and democracy in dealing with land degradation in national and local contexts, particularly within highly centralized political systems. Although the UNCCD represents a useful global framework in which to situate local anti-degradation initiatives, in centralized political systems, its success depends upon changes being made to the ethos of national facilitating organizations. Only when the power balance is challenged and greater moves are made towards decentralization will local land users be able to assume a meaningful role in combating desertification. 相似文献
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LINDSAY P. KELLER 《Meteoritics & planetary science》1998,33(4):913-919
Abstract— The fine-grained matrix of the Semarkona unequilibrated ordinary chondrite contains an assemblage of Fe carbides that are associated with oxides, sulfides, carbonates, and hydrated silicates. The carbides consist of fine-scale epitactic intergrowths of cohenite (Fe3C) and Hägg carbide (Fe5C2) that formed as by-products of gas-solid reactions on the Semarkona parent body. The carbide intergrowths resulted from prograde reactions at moderate temperatures in the presence of a highly reducing carbon-bearing gas. The carburization occurred prior to the aqueous alteration episode that produced the Fe-rich phyllosilicates throughout the interchondrule matrix and the thin magnetite rims surrounding the carbide grains. The occurrence of the carbide intergrowths places an upper limit of <500 °C on the maximum postaccretional thermal processing that occurred on the Semarkona parent body. 相似文献
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A polarizable sphere embedded in a conducting half-space can give rise to negative voltage transients in a coincident-loop time-domain electromagnetic system. Such transients have been observed in field situations. Our results are obtained from a model in which the contributions of the host rock, the currents in the sphere, and the interaction between the sphere and the host rock are separated and superposed. This model uses approximations to the integral equation solutions rather than finite-element or finite-difference approximations, and so allows very rapid computation. The theoretical demonstration suggests that interpretation of the negative voltage transients as a polarization response is valid, but more detailed interpretation of polarization properties may not be possible, because the superposition of the polarization response on the normal response depends strongly on the position of the target. 相似文献